File name: Pandora187s1_PittsburghPA_20230807_L2Fit_fout2c5d20230706p1-8.txt
File generation date: 20241126T173927.1Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c5p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 187
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora187_OF_v4d20210517.txt
Instrument calibration file used: Pandora187s1_CF_v5d20230706.txt
Level 1 file used: Pandora187s1_PittsburghPA_20230807_L1_smca1c5d20230706p1-8.txt
Full location name: Pittsburgh, PA - Lawrenceville ACHD (USEPA AQS ID 42-003-0008)
Short location name: PittsburghPA
Country of location: United States
Location latitude [deg]: 40.4655
Location longitude [deg]: -79.9608
Location altitude [m]: 265
Local noon date: 20230807
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 194 335
Nominal wavelengths inside fitting window [nm]: 305.0595 305.2010 305.3424 305.4838 305.6252 305.7666 305.9080 306.0494 306.1908 306.3321 306.4735 306.6148 306.7561 306.8974 307.0387 307.1800 307.3213 307.4626 307.6038 307.7451 307.8863 308.0275 308.1687 308.3099 308.4511 308.5923 308.7335 308.8746 309.0158 309.1569 309.2980 309.4391 309.5802 309.7213 309.8624 310.0035 310.1445 310.2856 310.4266 310.5676 310.7086 310.8496 310.9906 311.1316 311.2726 311.4135 311.5545 311.6954 311.8363 311.9772 312.1181 312.2590 312.3999 312.5408 312.6816 312.8225 312.9633 313.1041 313.2449 313.3857 313.5265 313.6673 313.8080 313.9488 314.0895 314.2303 314.3710 314.5117 314.6524 314.7931 314.9338 315.0744 315.2151 315.3557 315.4963 315.6370 315.7776 315.9182 316.0587 316.1993 316.3399 316.4804 316.6210 316.7615 316.9020 317.0425 317.1830 317.3235 317.4640 317.6044 317.7449 317.8853 318.0257 318.1662 318.3066 318.4470 318.5873 318.7277 318.8681 319.0084 319.1488 319.2891 319.4294 319.5697 319.7100 319.8503 319.9905 320.1308 320.2710 320.4113 320.5515 320.6917 320.8319 320.9721 321.1123 321.2524 321.3926 321.5327 321.6728 321.8130 321.9531 322.0932 322.2333 322.3733 322.5134 322.6534 322.7935 322.9335 323.0735 323.2135 323.3535 323.4935 323.6335 323.7734 323.9134 324.0533 324.1932 324.3332 324.4731 324.6129 324.7528 324.8927
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20230807T132905.9Z 8619.561874 285 1 18.82 2 56.12 97.24 49.53 249.90 0.00 1 0.00 1 0 17 2.767e-02 1.025e-02 3.019e-02 8.872e-03 2.394706e-01 4.584767e-03 2.880453e-03 -6.000000e+00 1.633751e-02 231.89 -2.00 3.49 -2.00 317.52 0.00e+00 -1.812060e-04 7.021631e-04 5.494636e-05 -6.000000e+00 7.268576e-04 289.05 -2.00 20.00 -2.00 316.68 0.00e+00 1.788 0.000 302.00 328.00 3 6.1019e+00 1.2215e-02 2.1553e-02 -6.0000e+00 4.0909e-02 2.3945e-02 1.3747e-02 1.2626e-02 -6.0000e+00 4.4115e-02 1.3942e-02 8.2915e-03 6.1167e-03 -6.0000e+00 2.6287e-02 -1.1651e-02 4.1172e-03 1.6760e-03 -6.0000e+00 1.1221e-02 1.5522e-04 7.0351e-04 2.6275e-04 1.9567e-05 -6.0000e+00 7.7192e-04 2.3063e-03 9.3833e-05 12 9 9 12 1 1 99.99 17.63 0.86 0.00231 0.00759 7 6 1 5 0 2329.270 21.06 15.00 17.63 30.04 27.4 997.56 13957 1156 -63 -11677 -11634 -6614 2464 -7466 1885 -2636 -951 3927 -2875 2498 -1729 3664 -2181 8577 -2874 3465 1065 -4038 -4451 1936 -934 -1567 -914 1797 -541 210 997 3516 9347 105 -1635 -2763 -638 -5857 -720 -1922 -1194 237 716 -1292 853 -506 47 -357 -1519 106 1284 269 -547 817 1959 1732 1531 1418 786 -848 175 1728 2342 1273 2308 -1257 515 -1766 -357 -138 417 960 1115 -439 103 1140 -2176 -1674 -1780 -230 -1074 -1312 -2892 -1532 -605 127 332 1563 -72 1066 168 589 645 -96 -1836 -153 445 12 333 -751 -827 -1052 -60 -13 -865 -1096 63 -732 1448 421 391 625 729 -239 -488 -1098 -323 349 -15 132 -1182 1293 -684 546 -713 21 311 1304 1579 361 623 22 535 -110 724 -899 1280 -218 276 -900 -252 -1496 1217 125 -7 -1360 -1208 -629 228 -855 218 -335 -118 476 -415 389 -317 695 -456 1667 -650 761 243 -1045 -1191 514 -268 -468 -268 479 -138 53 262 966 2601 32 -480 -819 -205 -2322 -325 -935 -623 127 391 -723 465 -278 25 -186 -849 59 690 156 -337 521 1267 1146 1028 944 517 -569 121 1269 1845 1059 1840 -951 388 -1355 -272 -118 382 901 1031 -394 84 896 -1616 -1204 -1378 -198 -957 -1279 -3022 -1665 -701 156 425 2019 -93 1293 188 598 607 -91 -1910 -173 556 17 465 -1017 -1040 -1229 -69 -16 -1139 -1516 90 -1024 2095 651 625 981 1080 -354 -668 -1459 -436 496 -24 196 -1793 1873 -1053 787 -991 28 394 1703 2202 540 962 32 802 -174 1209 -1581 2255 -396 493 -1572 -422 -2459
SS 20230807T133333.9Z 8619.564976 288 1 38.39 2 55.28 98.04 50.30 250.86 0.00 1 0.00 1 0 17 1.078e-02 6.310e-03 7.705e-03 2.431e-03 2.388474e-01 1.255155e-03 2.906584e-03 -6.000000e+00 6.364460e-03 231.89 -2.00 3.49 -2.00 317.40 0.00e+00 3.238442e-04 1.865947e-04 9.057674e-05 -6.000000e+00 2.832321e-04 289.05 -2.00 20.00 -2.00 316.56 0.00e+00 1.751 0.000 302.00 328.00 3 4.4644e+00 3.3331e-03 2.1288e-02 -6.0000e+00 1.5936e-02 2.7423e-02 3.7377e-03 1.2690e-02 -6.0000e+00 1.7188e-02 1.4371e-03 2.2414e-03 6.1427e-03 -6.0000e+00 1.0241e-02 -5.9060e-03 1.1087e-03 1.7233e-03 -6.0000e+00 4.3698e-03 8.2817e-04 1.8246e-04 7.1982e-05 2.0669e-05 -6.0000e+00 3.0072e-04 2.3510e-03 -1.3623e-05 12 1 1 12 1 1 99.98 17.63 0.26 0.00235 0.00372 87 33 1 5 0 434.090 21.06 15.00 17.63 30.19 27.4 998.91 -362 624 -686 -3187 -3625 -1423 -1589 -957 -19 -2131 -3119 -3535 -447 -1452 -499 -643 422 1512 344 1880 1228 335 31 1637 626 -55 -149 -468 -653 749 -386 1177 2013 -745 -3929 -2500 -2088 -1610 -1111 -891 -1058 -748 -228 -565 84 -71 161 -713 -621 -227 695 347 908 809 1275 1065 1269 707 689 817 978 1525 1686 1746 -229 -423 -772 -216 383 375 269 346 356 886 217 376 -422 -974 -539 -1115 -1023 -1515 -2167 -1477 -844 -525 157 396 504 543 227 -173 -151 201 -174 -29 471 642 -72 -182 -549 -1069 101 0 -956 -644 -450 -298 487 424 153 193 519 -21 75 -111 -231 -150 -108 -307 -471 -186 214 299 293 -274 827 1219 990 936 505 431 250 454 -45 -285 -113 -287 -453 -29 -503 -703 -38 70 -79 -352 -358 -145 -172 -115 -3 -300 -439 -514 -70 -263 -101 -142 96 352 84 467 311 85 8 444 180 -16 -44 -129 -169 190 -105 337 614 -235 -1199 -750 -689 -620 -509 -469 -548 -402 -125 -312 51 -42 94 -407 -347 -128 411 220 602 512 822 702 845 469 493 587 731 1111 1324 1431 -186 -314 -593 -164 315 315 244 323 328 774 176 299 -309 -698 -413 -969 -900 -1461 -2220 -1585 -968 -639 200 511 642 654 252 -174 -141 188 -175 -32 580 861 -100 -242 -680 -1235 114 0 -1244 -876 -640 -442 758 640 240 297 821 -31 102 -145 -307 -211 -164 -490 -755 -292 323 428 399 -356 1032 1575 1373 1376 772 671 400 700 -74 -486 -197 -509 -795 -48 -824 -1120
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