File name: Pandora187s1_PittsburghPA_20230813_L2Fit_fwvt1c3d20220705p1-8.txt File generation date: 20230814T112200.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 187 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora187_OF_v4d20210517.txt Instrument calibration file used: Pandora187s1_CF_v3d20220705.txt Level 1 file used: Pandora187s1_PittsburghPA_20230813_L1_smca1c3d20220705p1-8.txt Full location name: Pittsburgh, PA - Lawrenceville ACHD (USEPA AQS ID 42-003-0008) Short location name: PittsburghPA Country of location: United States Location latitude [deg]: 40.4655 Location longitude [deg]: -79.9608 Location altitude [m]: 265 Local noon date: 20230813 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1607 1755 Nominal wavelengths inside fitting window [nm]: 492.0854 492.2072 492.3291 492.4509 492.5727 492.6944 492.8162 492.9379 493.0597 493.1814 493.3031 493.4247 493.5464 493.6680 493.7896 493.9112 494.0328 494.1544 494.2760 494.3975 494.5190 494.6405 494.7620 494.8835 495.0049 495.1264 495.2478 495.3692 495.4906 495.6119 495.7333 495.8546 495.9760 496.0973 496.2185 496.3398 496.4611 496.5823 496.7035 496.8247 496.9459 497.0671 497.1882 497.3093 497.4305 497.5516 497.6726 497.7937 497.9147 498.0358 498.1568 498.2778 498.3988 498.5197 498.6407 498.7616 498.8825 499.0034 499.1243 499.2452 499.3660 499.4868 499.6076 499.7284 499.8492 499.9700 500.0907 500.2114 500.3321 500.4528 500.5735 500.6942 500.8148 500.9354 501.0560 501.1766 501.2972 501.4177 501.5383 501.6588 501.7793 501.8998 502.0202 502.1407 502.2611 502.3816 502.5020 502.6223 502.7427 502.8630 502.9834 503.1037 503.2240 503.3443 503.4645 503.5848 503.7050 503.8252 503.9454 504.0656 504.1858 504.3059 504.4260 504.5461 504.6662 504.7863 504.9064 505.0264 505.1464 505.2664 505.3864 505.5064 505.6263 505.7463 505.8662 505.9861 506.1060 506.2258 506.3457 506.4655 506.5853 506.7051 506.8249 506.9447 507.0644 507.1842 507.3039 507.4236 507.5433 507.6629 507.7826 507.9022 508.0218 508.1414 508.2610 508.3805 508.5001 508.6196 508.7391 508.8586 508.9780 509.0975 509.2169 509.3363 509.4557 509.5751 509.6945 509.8138 509.9332 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-249: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 250-398: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230813T114619.1Z 8625.490499 165 1 37.59 2 76.52 82.10 45.69 90.36 0.00 1 0.00 1 0 22 2.124e-03 2.119e-03 7.730e-04 7.719e-04 6.380217e+03 5.985875e+01 4.252358e+02 -6.000000e+00 1.423811e+02 289.18 -2.00 20.00 -2.00 505.27 0.00e+00 7.161308e-04 2.345482e-05 4.791269e-05 -6.000000e+00 6.546769e-05 289.18 -2.00 20.00 -2.00 500.45 0.00e+00 2.967768e-01 1.664423e-02 4.330748e-02 -6.000000e+00 4.608163e-02 231.68 -2.00 3.49 -2.00 502.04 0.00e+00 4.184 0.001 489.00 513.00 1 5.3765e+00 1.2947e-03 6.9694e-03 -6.0000e+00 3.5840e-03 6.8074e-03 3.1215e-04 1.0687e-03 -6.0000e+00 8.7845e-04 4.8673e-03 3.4137e-03 1.2121e-04 2.4610e-05 -6.0000e+00 3.5749e-04 -5.5497e-03 -1.3438e-04 12 1 1 12 1 1 99.98 17.72 0.89 -0.00555 0.01813 80 30 1 4 0 461.820 21.17 15.00 17.72 27.72 27.2 980.26 -94 -69 123 30 56 57 353 415 193 21 50 69 -48 -154 -193 -131 67 50 133 -38 23 78 184 271 383 281 198 183 -73 -273 -216 52 244 180 -53 -211 -258 -226 -98 40 30 50 109 191 136 5 33 -78 -155 -236 -485 -525 -444 -257 -13 -36 -93 -188 -55 16 271 253 228 91 91 -35 83 2 -165 -204 -136 -4 35 -37 -130 -227 -378 -224 -121 -3 -195 -220 -85 -139 -187 -204 -141 -148 -37 153 288 456 304 107 -95 -17 -79 -221 -327 -377 -333 -245 -236 -259 -390 -529 -496 -167 35 212 80 165 173 209 265 372 431 318 271 112 67 271 303 433 353 130 8 265 196 278 78 -225 -99 -15 55 29 63 -116 -23 -73 -46 80 68 76 46 -12 -202 -185 -157 -93 -69 124 30 57 59 370 436 203 22 51 71 -49 -156 -194 -133 69 52 140 -40 24 81 191 281 395 289 202 185 -75 -280 -221 53 253 181 -54 -218 -266 -231 -100 41 30 51 112 197 141 5 34 -79 -154 -240 -486 -522 -441 -257 -13 -35 -94 -190 -56 17 276 257 231 91 91 -35 85 2 -165 -203 -135 -4 35 -37 -130 -226 -373 -219 -118 -3 -190 -216 -83 -139 -179 -197 -136 -144 -36 149 282 447 298 104 -91 -17 -76 -209 -308 -355 -317 -238 -224 -250 -382 -521 -489 -164 34 209 80 166 176 213 271 381 441 325 275 113 67 267 298 425 347 128 8 260 191 268 75 -215 -94 -14 53 28 62 -116 -23 -72 -45 80 67 75 45 -11 -202 -184 -155 SQ 20230813T121408.0Z 8625.509815 175 1 45.56 2 71.26 86.47 40.54 95.02 0.00 1 0.00 1 0 15 2.098e-03 2.086e-03 1.059e-03 1.056e-03 4.790137e+03 8.052725e+01 3.183963e+02 -6.000000e+00 1.406265e+02 289.18 -2.00 20.00 -2.00 505.24 0.00e+00 5.814194e-04 3.196911e-05 3.885579e-05 -6.000000e+00 6.465359e-05 289.18 -2.00 20.00 -2.00 500.38 0.00e+00 1.775558e-01 2.292404e-02 3.367888e-02 -6.000000e+00 4.549190e-02 231.68 -2.00 3.49 -2.00 501.97 0.00e+00 3.073 0.000 489.00 513.00 1 6.2968e+00 1.7827e-03 5.2105e-03 -6.0000e+00 3.5386e-03 7.0566e-03 4.3034e-04 8.1583e-04 -6.0000e+00 8.6664e-04 2.2929e-03 2.5705e-03 1.6809e-04 2.0811e-05 -6.0000e+00 3.5319e-04 -8.7037e-03 -6.7721e-05 10 0 0 10 0 0 99.93 17.72 0.84 -0.00870 0.00913 61 19 1 4 0 746.520 21.17 15.00 17.72 27.93 27.4 981.85 -132 -51 46 -73 11 113 196 305 265 -47 131 81 -92 -54 -184 -201 93 144 58 -4 -128 147 251 325 418 102 261 156 -111 -300 -74 -73 380 282 -84 -168 -249 -189 -188 -13 48 160 -29 182 121 91 32 -41 -135 -245 -591 -432 -269 -204 -41 -194 37 -157 -16 13 224 185 431 19 42 -40 -20 8 -133 -372 -179 -128 19 42 -38 -141 -444 -28 -1 -23 -186 -281 -140 -5 -65 -280 -217 -234 -27 62 223 340 244 -23 43 -16 -82 -260 -374 -212 -390 -238 -308 -225 -329 -389 -384 -158 -24 139 145 205 212 168 345 385 373 224 197 69 284 287 350 339 327 76 168 337 214 314 -49 -90 -82 11 116 -85 -18 -24 -129 105 89 21 -14 23 21 -63 -243 -309 -228 -130 -51 47 -76 11 116 204 317 275 -48 134 82 -92 -54 -183 -202 95 148 60 -4 -136 157 267 347 445 109 274 162 -114 -304 -74 -74 388 292 -88 -178 -263 -199 -197 -14 50 168 -30 193 128 96 34 -43 -137 -245 -583 -422 -262 -200 -40 -197 38 -163 -17 13 233 193 446 19 43 -41 -20 8 -131 -364 -175 -125 18 41 -38 -138 -431 -27 -1 -22 -179 -272 -136 -5 -64 -278 -216 -234 -27 62 225 343 246 -24 42 -15 -78 -245 -350 -198 -368 -228 -301 -224 -316 -376 -371 -152 -23 135 142 201 210 168 346 387 375 223 196 68 276 277 337 326 315 74 161 322 203 296 -46 -84 -76 10 109 -81 -17 -23 -127 105 89 21 -14 23 21 -62 -237 -299 -219 SQ 20230813T121955.0Z 8625.513831 178 1 5.81 2 70.16 87.39 39.48 96.06 0.00 1 0.00 1 0 15 1.959e-03 1.952e-03 1.503e-04 1.501e-04 4.354909e+03 1.123647e+01 2.859219e+02 -6.000000e+00 1.313488e+02 289.18 -2.00 20.00 -2.00 505.28 0.00e+00 5.551442e-04 4.545759e-06 3.801190e-05 -6.000000e+00 6.037575e-05 289.18 -2.00 20.00 -2.00 500.51 0.00e+00 1.268818e-01 3.226601e-03 3.293352e-02 -6.000000e+00 4.245687e-02 231.68 -2.00 3.49 -2.00 502.10 0.00e+00 2.914 0.000 489.00 513.00 1 5.6062e-01 2.5081e-04 4.9824e-03 -6.0000e+00 3.3032e-03 -3.4701e-03 6.0623e-05 7.7984e-04 -6.0000e+00 8.0789e-04 7.3006e-01 7.4555e-04 2.3989e-05 2.1359e-05 -6.0000e+00 3.2992e-04 -1.6319e-02 6.3366e-05 10 0 0 10 0 0 -24.44 17.72 0.93 -0.01632 -0.01115 773 237 1 4 0 7.130 21.17 15.00 17.72 28.22 27.5 985.20 -163 5 103 50 8 79 273 320 236 157 122 71 -2 -133 -124 -133 -26 65 45 -25 -29 96 238 331 338 268 184 96 -116 -188 -155 -10 179 214 11 -266 -354 -237 -131 11 68 79 103 148 127 84 7 -56 -128 -275 -418 -434 -353 -192 -88 -96 -137 -163 -89 72 217 260 277 166 39 -48 -2 4 -95 -183 -166 -48 -26 -12 -103 -258 -345 -215 -125 -82 -109 -184 -219 -166 -115 -160 -174 -155 -62 99 206 281 265 65 -50 -95 -105 -163 -289 -379 -325 -212 -127 -145 -338 -477 -408 -207 17 172 166 173 135 150 255 368 394 322 250 193 197 257 369 398 263 161 165 188 214 154 -4 -125 -104 -57 21 78 5 -60 -61 -32 18 67 116 89 29 -102 -242 -233 -115 -160 5 104 50 8 82 279 329 243 161 123 73 -2 -134 -126 -136 -27 66 46 -26 -31 101 251 349 356 281 192 98 -117 -189 -154 -10 181 220 11 -271 -361 -247 -136 12 70 83 105 151 130 86 7 -58 -130 -273 -409 -421 -342 -188 -87 -96 -140 -163 -89 73 219 262 279 171 40 -48 -2 4 -93 -179 -162 -47 -25 -12 -101 -252 -335 -207 -123 -78 -104 -178 -213 -163 -114 -159 -174 -155 -62 99 203 277 261 63 -49 -93 -101 -154 -280 -356 -309 -205 -126 -141 -333 -472 -403 -205 17 171 166 175 138 150 256 369 394 321 254 194 197 255 366 394 261 159 163 186 209 150 -4 -120 -100 -54 20 76 5 -59 -60 -32 18 68 116 89 29 -100 -242 -231 -114 SQ 20230813T122001.1Z 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