File name: Pandora187s1_PittsburghPA_20230826_L2Fit_fout2c5d20230706p1-8.txt File generation date: 20241126T180817.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 187 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora187_OF_v4d20210517.txt Instrument calibration file used: Pandora187s1_CF_v5d20230706.txt Level 1 file used: Pandora187s1_PittsburghPA_20230826_L1_smca1c5d20230706p1-8.txt Full location name: Pittsburgh, PA - Lawrenceville ACHD (USEPA AQS ID 42-003-0008) Short location name: PittsburghPA Country of location: United States Location latitude [deg]: 40.4655 Location longitude [deg]: -79.9608 Location altitude [m]: 265 Local noon date: 20230826 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 194 335 Nominal wavelengths inside fitting window [nm]: 305.0595 305.2010 305.3424 305.4838 305.6252 305.7666 305.9080 306.0494 306.1908 306.3321 306.4735 306.6148 306.7561 306.8974 307.0387 307.1800 307.3213 307.4626 307.6038 307.7451 307.8863 308.0275 308.1687 308.3099 308.4511 308.5923 308.7335 308.8746 309.0158 309.1569 309.2980 309.4391 309.5802 309.7213 309.8624 310.0035 310.1445 310.2856 310.4266 310.5676 310.7086 310.8496 310.9906 311.1316 311.2726 311.4135 311.5545 311.6954 311.8363 311.9772 312.1181 312.2590 312.3999 312.5408 312.6816 312.8225 312.9633 313.1041 313.2449 313.3857 313.5265 313.6673 313.8080 313.9488 314.0895 314.2303 314.3710 314.5117 314.6524 314.7931 314.9338 315.0744 315.2151 315.3557 315.4963 315.6370 315.7776 315.9182 316.0587 316.1993 316.3399 316.4804 316.6210 316.7615 316.9020 317.0425 317.1830 317.3235 317.4640 317.6044 317.7449 317.8853 318.0257 318.1662 318.3066 318.4470 318.5873 318.7277 318.8681 319.0084 319.1488 319.2891 319.4294 319.5697 319.7100 319.8503 319.9905 320.1308 320.2710 320.4113 320.5515 320.6917 320.8319 320.9721 321.1123 321.2524 321.3926 321.5327 321.6728 321.8130 321.9531 322.0932 322.2333 322.3733 322.5134 322.6534 322.7935 322.9335 323.0735 323.2135 323.3535 323.4935 323.6335 323.7734 323.9134 324.0533 324.1932 324.3332 324.4731 324.6129 324.7528 324.8927 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230826T112436.2Z 8638.475419 60 1 45.68 2 82.74 82.50 157.56 295.89 0.00 1 0.00 1 0 25 6.104e-01 1.656e-02 4.395e-01 1.363e-02 7.999831e-01 8.050695e-03 8.862770e-03 -6.000000e+00 3.661416e-01 230.74 -2.00 3.49 -2.00 321.93 0.00e+00 -1.930119e-03 4.971224e-03 1.765102e-03 -6.000000e+00 1.719276e-02 288.42 -2.00 20.00 -2.00 321.44 0.00e+00 7.290 0.007 302.00 328.00 3 1.4535e+00 3.3408e-02 8.3883e-02 -6.0000e+00 9.2064e-01 3.7129e-01 4.9982e-02 4.7744e-02 -6.0000e+00 1.0012e+00 -5.1805e-01 4.9263e-02 2.4306e-02 -6.0000e+00 5.9258e-01 2.0496e-01 2.1903e-02 7.3111e-03 -6.0000e+00 2.5219e-01 5.1581e-05 -4.4133e-04 3.9995e-04 9.3927e-05 -6.0000e+00 1.7328e-02 2.8104e-03 6.5787e-05 12 8 8 10 0 0 73.00 17.50 0.61 0.00281 -0.00051 48 15 1 5 0 951.510 20.96 15.00 17.50 28.68 27.9 985.25 900000 900000 5894 -193100 -264522 -118935 -207784 -55571 900000 -143628 -228799 56219 -128167 900000 -182459 900000 -83141 900000 -90096 900000 900000 -40629 -127861 -51883 900000 -83376 -18659 -56917 26077 -4528 -21799 -41271 900000 134781 -13956 50377 281511 11177 -21657 40426 -21975 21858 29223 49821 11033 65724 58660 29132 -16029 24819 18421 4002 3101 15420 31775 28701 12980 15551 41176 -9044 17543 12924 17742 10643 19583 2972 10951 -3078 5229 4278 10464 564 5226 -186 -4623 2380 -12433 -3322 -10331 956 -8397 4037 -423 -1632 2277 3034 355 4516 3037 2589 1973 146 3388 -456 -2374 -4261 -2488 -3580 1203 55 2 -1362 288 709 -3682 -3025 -2247 -258 786 41 -799 898 -94 611 -390 -245 -560 -450 -182 998 546 694 -8 462 326 -988 1070 1014 2217 -945 458 549 380 331 173 -779 234 26 -345 -342 -201 -453 900000 900000 78 -2561 -3800 -1577 -2756 -737 900000 -1905 -4138 746 -1700 900000 -4839 900000 -1103 900000 -1521 900000 900000 -539 -3545 -751 900000 -1910 -247 -961 346 -60 -342 -945 900000 1787 -286 668 3733 243 -809 1072 -1113 841 1085 1520 497 1743 1711 1198 -1105 1251 1124 318 276 1329 2486 2436 1325 1526 3003 -1068 1652 1423 2141 1553 2727 485 1685 -584 1040 987 2470 151 1296 -45 -1054 458 -2688 -700 -2740 273 -3096 1504 -180 -751 1081 1517 190 2360 1587 1291 926 67 1509 -231 -1426 -3074 -2062 -3418 1162 53 2 -1086 213 543 -3159 -2724 -2152 -265 904 54 -1179 1367 -144 901 -557 -345 -817 -693 -294 1607 854 1036 -12 647 443 -1317 1415 1496 3733 -1689 884 1133 838 787 439 -2066 624 69 -907 -845 -461 -989 SS 20230826T113559.5Z 8638.483328 63 1 45.86 2 80.59 84.31 159.37 300.08 0.00 1 0.00 1 0 17 4.779e-01 7.868e-03 2.263e-01 4.963e-03 6.630614e-01 2.779641e-03 7.500248e-03 -6.000000e+00 2.807815e-01 230.74 -2.00 3.49 -2.00 321.38 0.00e+00 1.451932e-03 1.438058e-03 5.977600e-04 -6.000000e+00 1.251640e-02 288.42 -2.00 20.00 -2.00 320.77 0.00e+00 5.815 0.003 302.00 328.00 3 1.3067e+00 1.0055e-02 6.6901e-02 -6.0000e+00 7.0122e-01 1.0098e-01 1.4089e-02 3.7248e-02 -6.0000e+00 7.5708e-01 -1.4964e-01 1.3857e-02 1.9108e-02 -6.0000e+00 4.5138e-01 5.1383e-02 6.4872e-03 6.7853e-03 -6.0000e+00 1.9289e-01 2.6991e-04 -4.4731e-04 1.4576e-04 7.3939e-05 -6.0000e+00 1.3320e-02 3.6595e-03 -2.3936e-05 11 8 0 10 0 0 99.22 17.51 0.44 0.00366 0.00030 132 41 1 5 0 347.380 20.96 15.00 17.51 29.56 27.8 990.79 -176804 -128156 -134762 -160920 -151377 -178480 -164134 -145276 -94246 -123213 -148225 -144928 -78750 -88813 -85979 -67861 -52233 -24599 -42213 -14194 -18445 -35485 -49092 -10501 -8084 -43667 -40142 -37213 -45459 -21398 -34456 -10303 35731 -63 -20542 -10718 1315 -5905 -10469 43 -2937 240 3182 496 -244 1655 4782 -756 -32 1398 7129 2728 3439 438 6684 4806 3408 4847 5668 542 2051 3921 3899 3615 2819 381 1232 -494 1258 1977 2115 2353 1625 465 -1196 -1367 -2788 -3163 -3003 -1403 -1891 -735 -1266 -1584 61 281 1422 1836 1842 1851 872 -168 -260 -417 -1008 -1145 -547 91 -293 65 -960 -933 -216 132 -1769 -1275 -1149 -623 770 143 -6 458 691 60 -423 -403 -18 -97 -89 -351 -2 752 478 296 259 -545 512 755 466 231 179 397 100 324 -296 -505 281 -94 -99 56 -56 -535 -1400 -733 -889 -1345 -1065 -1649 -1444 -1214 -539 -1030 -1695 -1849 -658 -1055 -1248 -985 -735 -292 -650 -175 -243 -562 -950 -168 -137 -1018 -1010 -882 -1166 -476 -1050 -294 743 -2 -765 -368 45 -263 -603 3 -210 18 242 40 -20 136 391 -68 -3 141 766 343 473 68 1029 788 582 809 913 92 359 753 855 884 715 97 312 -134 380 680 790 903 613 166 -393 -407 -810 -969 -1061 -580 -914 -397 -746 -998 40 199 1039 1360 1347 1285 570 -105 -161 -277 -770 -1018 -559 95 -322 69 -1045 -916 -200 128 -1877 -1419 -1361 -723 981 205 -10 735 1090 92 -613 -574 -26 -150 -145 -585 -4 1162 718 429 362 -739 689 1114 783 433 363 850 228 785 -706 -1247 703 -237 -245 144 -136 -1234 SS 20230826T114505.1Z 8638.489643 68 1 45.69 2 78.86 85.76 160.76 303.86 0.00 1 0.00 1 0 25 2.669e-01 6.093e-03 1.536e-01 3.168e-03 5.832375e-01 1.726959e-03 6.666152e-03 -6.000000e+00 1.568474e-01 230.74 -2.00 3.49 -2.00 320.93 0.00e+00 1.167832e-03 7.749951e-04 9.523556e-04 -6.000000e+00 6.991417e-03 288.42 -2.00 20.00 -2.00 320.29 0.00e+00 4.994 0.002 302.00 328.00 3 1.5722e+00 5.8008e-03 5.7823e-02 -6.0000e+00 3.9171e-01 3.6188e-02 7.7146e-03 3.2583e-02 -6.0000e+00 4.2290e-01 -5.8002e-02 7.2973e-03 1.5713e-02 -6.0000e+00 2.5214e-01 1.4368e-02 3.5314e-03 5.4801e-03 -6.0000e+00 1.0776e-01 4.7749e-04 -4.6136e-04 9.4098e-05 5.7876e-05 -6.0000e+00 7.4405e-03 3.0419e-03 -2.2972e-05 10 0 0 10 0 0 98.40 17.51 0.45 0.00304 -0.00043 138 42 1 5 0 331.030 20.96 14.98 17.51 30.15 27.9 994.29 -20418 -64776 -79767 -110160 -94090 -77525 -120159 -58802 -84744 -73027 -96357 -63861 -64287 -40984 -39618 -24530 -33949 -10160 -20412 -10433 -13182 -18557 -26755 -18453 -13603 -24389 -15364 -23455 -22981 -13055 -10267 -10494 12717 -7741 -9026 -9930 -4557 -2948 -6036 -54 -2494 1426 -288 1370 745 2599 1029 1474 -1670 391 1263 411 1245 1538 3209 2084 2359 1132 2094 -412 2254 2423 3587 2525 2305 635 -60 -129 445 1257 1089 1421 1122 939 51 -531 -1661 -2292 -2315 -1421 -1320 -1457 -2100 -1229 -713 394 954 1102 1313 1314 723 27 -333 -565 -812 -721 210 234 -108 -41 -408 -783 6 -216 -1468 -872 -632 -259 486 259 58 450 469 60 8 29 -297 -317 -377 -405 -195 185 355 192 18 -641 550 932 521 539 284 217 -114 284 -123 -318 164 -118 -129 224 -173 -479 -63 -364 -560 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