File name: Pandora187s1_PittsburghPA_20231229_L2Fit_fwvt1c5d20230706p1-8.txt File generation date: 20241126T191323.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 187 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora187_OF_v4d20210517.txt Instrument calibration file used: Pandora187s1_CF_v5d20230706.txt Level 1 file used: Pandora187s1_PittsburghPA_20231229_L1_smca1c5d20230706p1-8.txt Full location name: Pittsburgh, PA - Lawrenceville ACHD (USEPA AQS ID 42-003-0008) Short location name: PittsburghPA Country of location: United States Location latitude [deg]: 40.4655 Location longitude [deg]: -79.9608 Location altitude [m]: 265 Local noon date: 20231229 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1607 1755 Nominal wavelengths inside fitting window [nm]: 492.0774 492.1992 492.3211 492.4429 492.5647 492.6865 492.8082 492.9300 493.0517 493.1735 493.2952 493.4168 493.5385 493.6602 493.7818 493.9034 494.0250 494.1466 494.2682 494.3897 494.5113 494.6328 494.7543 494.8758 494.9972 495.1187 495.2401 495.3615 495.4829 495.6043 495.7257 495.8470 495.9684 496.0897 496.2110 496.3323 496.4535 496.5748 496.6960 496.8172 496.9384 497.0596 497.1807 497.3019 497.4230 497.5441 497.6652 497.7863 497.9074 498.0284 498.1494 498.2704 498.3914 498.5124 498.6334 498.7543 498.8752 498.9961 499.1170 499.2379 499.3588 499.4796 499.6004 499.7212 499.8420 499.9628 500.0835 500.2043 500.3250 500.4457 500.5664 500.6870 500.8077 500.9283 501.0489 501.1695 501.2901 501.4107 501.5312 501.6518 501.7723 501.8928 502.0133 502.1337 502.2542 502.3746 502.4950 502.6154 502.7358 502.8561 502.9765 503.0968 503.2171 503.3374 503.4577 503.5779 503.6982 503.8184 503.9386 504.0588 504.1790 504.2991 504.4193 504.5394 504.6595 504.7796 504.8996 505.0197 505.1397 505.2597 505.3797 505.4997 505.6197 505.7396 505.8595 505.9795 506.0994 506.2192 506.3391 506.4589 506.5788 506.6986 506.8184 506.9381 507.0579 507.1776 507.2974 507.4171 507.5367 507.6564 507.7761 507.8957 508.0153 508.1349 508.2545 508.3741 508.4936 508.6132 508.7327 508.8522 508.9716 509.0911 509.2105 509.3300 509.4494 509.5688 509.6882 509.8075 509.9269 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-249: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 250-398: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20231229T131717.5Z 8763.553675 295 1 46.07 2 85.31 126.15 73.66 286.24 0.00 1 0.00 1 0 15 2.224e-03 2.220e-03 1.422e-04 1.421e-04 4.861672e+03 1.017615e+01 3.288487e+02 -6.000000e+00 1.412393e+02 275.17 -2.00 20.00 -2.00 505.32 0.00e+00 2.132734e-03 4.188944e-06 1.186588e-04 -6.000000e+00 6.633661e-05 275.17 -2.00 20.00 -2.00 500.69 0.00e+00 1.087652e+00 3.031777e-03 4.618188e-02 -6.000000e+00 4.815901e-02 223.17 -2.00 3.49 -2.00 502.26 0.00e+00 10.315 0.020 489.00 513.00 1 1.9787e+00 2.3433e-04 1.5332e-02 -6.0000e+00 3.7297e-03 -4.9180e-03 5.6431e-05 1.2749e-03 -6.0000e+00 9.1473e-04 5.8054e-02 6.2472e-04 2.2759e-05 7.6227e-05 -6.0000e+00 3.7387e-04 1.8239e-03 -2.9222e-05 10 0 0 10 0 0 45.81 18.81 1.54 0.00182 0.00616 835 257 1 4 0 54.970 22.19 15.00 18.81 8.01 28.0 919.26 -240 -55 23 -18 -43 72 289 335 256 170 128 85 -38 -132 -124 -121 -36 58 58 1 6 159 326 386 395 282 200 83 -111 -197 -148 -11 138 197 -25 -267 -318 -205 -80 38 107 128 170 187 157 90 10 -67 -154 -331 -431 -431 -359 -229 -125 -149 -139 -141 -57 133 308 354 324 214 93 17 2 0 -94 -181 -158 -79 -55 -73 -189 -317 -379 -261 -203 -129 -150 -258 -256 -210 -173 -212 -212 -140 -49 102 244 307 245 74 -88 -111 -125 -180 -288 -391 -363 -230 -185 -230 -405 -525 -433 -201 5 181 196 230 229 266 377 456 496 406 299 251 252 319 393 403 288 176 150 178 191 140 -20 -139 -113 -55 13 26 -55 -109 -65 -8 32 67 100 37 -24 -129 -252 -267 -174 -228 -53 23 -18 -43 73 288 335 256 169 126 86 -38 -131 -123 -121 -36 57 58 1 6 164 338 388 398 283 200 85 -111 -196 -147 -11 138 196 -25 -271 -323 -207 -81 38 108 130 174 192 162 92 11 -67 -154 -325 -430 -425 -355 -228 -123 -149 -141 -144 -59 133 308 354 333 219 95 18 2 0 -92 -176 -153 -77 -54 -71 -185 -308 -366 -257 -200 -127 -148 -249 -248 -205 -170 -209 -210 -139 -49 102 245 309 248 74 -87 -109 -119 -174 -278 -377 -353 -221 -181 -229 -397 -517 -427 -198 5 180 197 234 235 268 381 463 503 411 300 250 257 323 398 408 293 179 153 180 194 140 -20 -139 -113 -54 13 26 -55 -111 -67 -8 33 68 102 37 -25 -132 -258 -271 -176 SQ 20231229T133027.0Z 8763.562813 298 1 14.41 2 83.32 128.44 76.01 288.07 0.00 1 0.00 1 0 15 1.969e-03 1.970e-03 1.572e-04 1.571e-04 3.642111e+03 1.102028e+01 2.494247e+02 -6.000000e+00 1.250790e+02 275.17 -2.00 20.00 -2.00 505.31 0.00e+00 1.747647e-03 4.623564e-06 9.716519e-05 -6.000000e+00 5.874709e-05 275.17 -2.00 20.00 -2.00 500.63 0.00e+00 8.392595e-01 3.359859e-03 3.552226e-02 -6.000000e+00 4.265047e-02 223.17 -2.00 3.49 -2.00 502.20 0.00e+00 7.841 0.009 489.00 513.00 1 1.3649e+00 2.5984e-04 1.1567e-02 -6.0000e+00 3.3031e-03 -1.5639e-03 6.2855e-05 9.6399e-04 -6.0000e+00 8.1014e-04 1.5483e-01 6.4342e-04 2.5400e-05 6.2395e-05 -6.0000e+00 3.3109e-04 -1.2650e-03 -1.4693e-05 10 0 0 10 0 0 -41.60 18.81 1.26 -0.00126 0.00320 608 187 1 4 0 22.890 22.19 15.00 18.81 8.10 28.1 920.56 -167 -45 60 -14 -40 38 223 311 221 148 136 77 13 -95 -109 -83 -22 76 25 -25 -33 101 300 358 341 257 186 110 -103 -149 -113 13 139 184 -38 -279 -338 -199 -82 58 112 112 145 138 119 69 -15 -78 -159 -288 -395 -411 -345 -196 -105 -148 -177 -164 -78 102 256 315 303 214 85 4 16 9 -63 -148 -146 -89 -50 -44 -154 -278 -331 -231 -133 -80 -93 -211 -240 -173 -139 -178 -176 -116 -20 104 202 280 206 19 -71 -119 -132 -151 -246 -328 -276 -199 -167 -211 -387 -493 -392 -185 29 180 156 189 164 198 313 374 397 354 268 202 242 285 381 391 246 153 149 147 175 134 5 -96 -71 -32 39 39 -39 -90 -95 -43 4 57 77 53 -22 -112 -224 -213 -119 -162 -44 58 -14 -40 38 227 318 226 151 137 77 13 -93 -107 -82 -22 77 26 -25 -34 103 308 367 350 263 189 111 -102 -150 -113 13 138 185 -38 -288 -348 -204 -84 59 114 115 150 144 121 69 -16 -79 -160 -285 -395 -407 -341 -191 -104 -149 -180 -164 -78 102 258 317 305 220 87 4 16 9 -61 -144 -143 -86 -49 -43 -151 -271 -321 -228 -131 -79 -91 -204 -233 -169 -137 -176 -175 -116 -20 105 204 276 203 18 -71 -117 -127 -143 -238 -318 -262 -192 -164 -211 -381 -487 -387 -182 29 179 157 192 164 199 317 379 403 358 269 201 246 287 383 394 248 155 150 148 175 134 5 -95 -69 -31 39 39 -39 -90 -97 -45 4 57 78 54 -22 -114 -225 -213 -118 SQ 20231229T133041.6Z 8763.562982 298 2 14.29 2 83.29 128.48 76.05 288.11 0.00 1 0.00 1 0 15 1.991e-03 1.993e-03 1.550e-04 1.549e-04 3.609849e+03 1.084117e+01 2.449833e+02 -6.000000e+00 1.264312e+02 275.17 -2.00 20.00 -2.00 505.30 0.00e+00 1.693003e-03 4.544455e-06 9.414086e-05 -6.000000e+00 5.938093e-05 275.17 -2.00 20.00 -2.00 500.62 0.00e+00 8.425748e-01 3.306791e-03 3.562255e-02 -6.000000e+00 4.310768e-02 223.17 -2.00 3.49 -2.00 502.19 0.00e+00 7.806 0.009 489.00 513.00 1 1.3433e+00 2.5571e-04 1.1505e-02 -6.0000e+00 3.3386e-03 -1.6059e-03 6.1892e-05 9.6318e-04 -6.0000e+00 8.1872e-04 1.5908e-01 4.3815e-04 2.4990e-05 6.0313e-05 -6.0000e+00 3.3468e-04 -2.0087e-03 -1.1987e-07 10 0 0 10 0 0 -46.70 18.81 1.26 -0.00201 0.00103 608 187 1 4 0 22.890 22.19 15.00 18.81 8.10 28.1 920.56 -191 -45 59 -19 -62 30 223 312 191 149 129 96 -19 -89 -105 -102 -23 48 60 -12 -44 136 299 369 375 272 185 100 -102 -178 -120 -4 127 180 -18 -294 -342 -192 -81 52 116 106 132 143 122 67 -20 -79 -144 -290 -381 -411 -325 -188 -118 -163 -175 -160 -78 103 267 317 293 195 74 9 17 8 -70 -158 -150 -67 -33 -50 -156 -271 -326 -219 -151 -66 -92 -217 -234 -175 -136 -152 -188 -116 -42 98 198 272 210 33 -96 -121 -125 -150 -257 -338 -283 -192 -147 -220 -376 -505 -393 -209 43 182 161 184 175 189 301 402 403 359 282 227 229 293 372 408 246 157 138 169 182 129 18 -108 -67 -23 34 62 -20 -99 -88 -45 10 78 74 24 -6 -136 -232 -246 -128 -182 -43 58 -19 -62 31 229 313 192 153 131 97 -19 -89 -104 -101 -24 48 61 -12 -45 141 310 383 389 282 190 102 -102 -176 -118 -4 127 183 -18 -298 -346 -194 -83 53 120 107 135 146 126 68 -20 -80 -146 -290 -375 -400 -317 -185 -118 -165 -176 -162 -79 104 272 322 297 197 74 9 17 8 -69 -156 -148 -66 -33 -49 -154 -267 -319 -213 -146 -64 -89 -211 -230 -173 -135 -152 -184 -113 -41 96 196 271 209 33 -94 -120 -122 -144 -245 -322 -272 -187 -142 -216 -374 -504 -392 -208 43 183 159 184 177 192 308 412 413 367 286 228 229 291 368 405 244 156 137 168 180 127 18 -107 -67 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11.51 28.4 943.90 -58 55 107 14 -81 17 180 254 181 125 135 109 49 -54 -52 -78 -7 60 40 -49 -61 73 246 310 304 204 163 98 -61 -104 -56 63 168 180 -67 -333 -386 -227 -84 48 85 100 93 106 95 34 -44 -70 -116 -240 -322 -348 -265 -150 -98 -162 -199 -208 -114 46 183 232 228 154 22 -8 13 40 -46 -123 -128 -45 -19 -27 -126 -249 -284 -162 -66 -16 -36 -159 -184 -155 -115 -172 -163 -135 -36 69 154 218 143 -12 -124 -134 -124 -122 -200 -249 -210 -145 -133 -187 -370 -469 -350 -131 70 205 155 137 104 106 207 281 332 275 245 227 235 276 366 363 213 128 128 153 190 156 30 -70 -26 11 63 88 -39 -104 -113 -54 -20 46 69 46 5 -104 -199 -189 -62 -57 54 105 14 -83 18 186 263 188 129 137 110 49 -55 -53 -78 -7 61 42 -52 -62 75 254 320 313 210 166 102 -62 -105 -56 63 172 181 -69 -342 -397 -232 -86 48 86 101 96 110 98 35 -45 -71 -119 -240 -318 -340 -258 -148 -98 -159 -199 -210 -115 46 186 235 231 155 22 -8 13 39 -45 -121 -125 -44 -19 -26 -124 -244 -276 -156 -64 -15 -34 -154 -180 -153 -114 -172 -159 -132 -35 68 153 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22.19 15.00 18.81 11.51 28.4 943.90 -57 58 113 4 -80 -4 195 255 173 124 124 115 42 -69 -55 -68 0 66 41 -59 -70 71 235 308 308 203 177 100 -59 -108 -56 64 153 176 -57 -342 -389 -229 -79 47 96 97 91 113 90 47 -36 -60 -122 -234 -326 -332 -262 -153 -92 -159 -206 -205 -118 63 181 234 230 150 34 -23 17 33 -52 -130 -124 -36 -23 -43 -136 -255 -284 -159 -65 -7 -36 -161 -195 -149 -115 -160 -178 -125 -45 68 152 216 160 -15 -114 -131 -118 -139 -201 -237 -209 -146 -133 -204 -370 -454 -349 -140 77 212 149 165 121 113 211 273 326 287 246 222 223 304 358 357 226 128 129 157 193 153 26 -74 -35 -5 60 81 -29 -99 -102 -58 -27 47 66 48 -9 -97 -197 -173 -62 -57 57 111 4 -80 -4 202 265 180 128 127 116 42 -69 -54 -68 0 67 43 -60 -72 73 244 320 319 209 181 101 -60 -110 -56 64 156 178 -59 -353 -401 -235 -80 48 98 99 93 116 94 49 -37 -61 -121 -235 -323 -325 -256 -150 -92 -158 -206 -208 -119 64 184 238 233 152 34 -23 17 33 -51 -128 -122 -35 -23 -43 -135 -250 -277 -153 -63 -7 -34 -156 -192 -148 -114 -156 -174 -122 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2.880 22.19 15.01 18.82 11.53 28.4 943.90 -74 63 115 -1 -74 -6 188 246 173 114 131 105 41 -56 -56 -67 -2 66 34 -56 -78 68 229 308 304 205 160 99 -52 -105 -54 54 169 174 -62 -341 -380 -229 -90 52 95 98 97 107 91 36 -16 -72 -121 -241 -318 -354 -260 -156 -87 -148 -201 -209 -116 55 187 233 216 148 32 -11 2 32 -44 -125 -116 -41 -11 -36 -130 -271 -278 -150 -56 -2 -31 -159 -187 -153 -117 -149 -181 -127 -50 62 151 220 158 -13 -126 -126 -122 -131 -199 -248 -215 -141 -130 -197 -366 -469 -345 -132 76 187 166 154 116 120 219 284 313 280 242 213 214 285 359 347 208 117 124 163 189 149 33 -53 -26 10 72 86 -30 -101 -116 -74 -28 37 74 42 -11 -105 -200 -186 -44 -72 63 115 -1 -75 -7 193 254 178 117 132 108 42 -57 -57 -68 -2 67 35 -58 -82 72 241 325 321 215 167 102 -53 -105 -54 54 171 179 -63 -349 -388 -233 -94 54 99 99 99 110 93 37 -16 -74 -122 -240 -312 -344 -252 -153 -86 -150 -205 -210 -117 55 189 235 217 148 32 -11 2 31 -43 -122 -113 -40 -11 -35 -128 -264 -269 -144 -53 -2 -30 -154 -182 -150 -115 -148 -181 -128 -49 61 149 219 157 -13 -124 -125 -120 -127 -190 -237 -207 -137 -129 -193 -362 -465 -342 -130 75 186 166 156 116 121 220 286 315 280 240 215 214 285 357 346 207 117 123 161 186 146 32 -51 -25 10 69 84 -30 -99 -115 -74 -28 37 74 42 -11 -103 -195 -184 -44 SQ 20231229T144624.1Z 8763.615557 331 2 8.97 2 73.23 142.98 88.95 299.08 0.00 1 0.00 1 0 15 1.718e-03 1.717e-03 9.132e-05 9.123e-05 1.709396e+03 6.079865e+00 1.156203e+02 -6.000000e+00 1.091366e+02 275.16 -2.00 20.00 -2.00 505.28 0.00e+00 5.962193e-04 2.666973e-06 3.493339e-05 -6.000000e+00 5.125853e-05 275.16 -2.00 20.00 -2.00 500.52 0.00e+00 2.691258e-01 1.957647e-03 1.739346e-02 -6.000000e+00 3.721206e-02 223.18 -2.00 3.49 -2.00 502.11 0.00e+00 3.412 0.001 489.00 513.00 1 7.8003e-02 1.5148e-04 5.0154e-03 -6.0000e+00 2.8819e-03 2.0154e-03 3.6924e-05 4.5269e-04 -6.0000e+00 7.0676e-04 1.0993e+00 3.0879e-04 1.4834e-05 2.2735e-05 -6.0000e+00 2.8890e-04 -3.4507e-04 -1.1701e-05 10 0 0 10 0 0 -109.90 18.82 0.92 -0.00035 0.00180 2013 618 1 4 0 2.880 22.19 15.01 18.82 11.53 28.4 943.90 -69 61 106 -1 -84 2 189 248 180 125 132 104 34 -62 -61 -75 -5 57 50 -60 -72 68 236 302 301 212 167 116 -56 -99 -61 58 165 183 -57 -335 -379 -223 -82 50 94 99 107 100 94 33 -25 -60 -127 -238 -328 -344 -264 -146 -86 -153 -206 -207 -121 41 178 236 223 152 37 -16 9 29 -49 -119 -124 -41 -22 -36 -135 -260 -290 -162 -72 -3 -43 -143 -180 -148 -114 -159 -172 -127 -43 65 148 220 159 -25 -129 -133 -122 -141 -198 -251 -213 -140 -125 -192 -375 -460 -347 -138 66 206 151 154 99 114 202 289 319 284 243 213 240 289 365 357 217 133 138 164 187 156 41 -55 -36 0 72 85 -19 -105 -108 -63 -26 48 55 44 -16 -127 -201 -189 -58 -68 61 107 -1 -86 2 194 255 186 128 134 107 35 -63 -62 -76 -5 58 51 -63 -76 71 250 310 309 223 174 119 -57 -99 -60 58 167 189 -58 -343 -389 -227 -85 52 98 100 109 102 97 33 -25 -60 -129 -237 -322 -333 -256 -143 -86 -155 -204 -208 -122 41 180 238 225 152 37 -16 9 28 -48 -116 -121 -40 -21 -35 -132 -254 -281 -155 -69 -3 -41 -138 -176 -145 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-0.00060 0.00184 2013 618 1 4 0 2.880 22.19 15.01 18.82 11.53 28.4 943.90 -58 52 118 3 -89 6 182 250 170 115 134 111 50 -57 -59 -66 -9 62 41 -54 -67 70 243 318 305 202 176 115 -53 -101 -67 58 168 177 -70 -329 -389 -230 -87 45 92 88 97 103 84 46 -37 -65 -121 -240 -335 -340 -254 -147 -91 -155 -204 -214 -110 55 193 239 226 139 35 -17 8 25 -56 -132 -112 -48 -19 -30 -122 -258 -289 -159 -63 -8 -27 -152 -176 -154 -106 -164 -188 -134 -32 65 150 215 146 -9 -124 -140 -111 -139 -202 -255 -203 -133 -130 -194 -369 -459 -356 -139 75 207 158 153 100 114 206 282 316 275 244 197 234 293 372 368 219 125 130 166 183 144 31 -69 -30 12 62 83 -29 -102 -111 -80 -24 35 78 46 -5 -99 -201 -194 -47 -57 51 119 3 -92 6 187 258 175 118 136 114 51 -57 -60 -67 -9 64 42 -57 -71 74 250 327 314 207 184 118 -54 -101 -67 58 171 182 -71 -337 -399 -234 -89 46 95 89 99 105 87 47 -38 -66 -123 -239 -329 -330 -247 -144 -90 -156 -203 -215 -110 56 195 242 228 140 36 -17 8 25 -55 -129 -109 -47 -18 -29 -120 -252 -280 -153 -60 -7 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0.92 -0.00050 0.00176 2013 618 1 4 0 2.880 22.19 15.01 18.82 11.54 28.4 943.90 -58 47 111 4 -85 3 182 245 174 126 137 111 40 -45 -55 -63 0 69 39 -59 -73 76 249 309 304 199 177 94 -63 -92 -56 50 163 173 -72 -338 -372 -225 -87 52 96 103 92 104 93 30 -29 -83 -125 -234 -318 -339 -260 -150 -82 -161 -203 -210 -112 44 189 237 227 145 25 -24 18 36 -50 -128 -109 -40 -17 -31 -134 -259 -293 -160 -63 -9 -24 -149 -193 -156 -109 -153 -169 -128 -42 62 150 214 158 -17 -124 -133 -109 -135 -207 -243 -201 -143 -129 -204 -381 -462 -348 -132 63 200 156 153 110 103 207 289 320 282 243 217 240 288 367 353 217 129 121 149 187 149 11 -55 -48 19 72 89 -31 -110 -99 -63 -24 47 69 57 -11 -116 -208 -175 -58 -57 46 109 4 -87 3 187 253 180 130 139 111 41 -46 -56 -64 0 70 41 -61 -77 78 256 319 314 204 185 98 -64 -92 -56 50 166 178 -73 -347 -382 -230 -88 54 97 104 94 107 96 31 -29 -83 -127 -234 -312 -330 -252 -147 -82 -162 -203 -211 -113 45 191 240 229 145 25 -24 18 36 -49 -125 -107 -39 -16 -31 -132 -253 -285 -154 -61 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18.81 0.92 -0.00043 0.00190 2013 618 1 4 0 2.880 22.19 15.00 18.81 11.54 28.4 943.90 -64 61 106 3 -75 11 185 252 180 134 139 114 49 -57 -54 -76 -12 70 33 -46 -68 71 235 311 297 199 169 100 -47 -100 -67 52 172 170 -59 -330 -377 -235 -82 42 104 100 100 108 89 30 -30 -75 -122 -236 -332 -347 -260 -133 -87 -163 -201 -211 -132 56 174 222 226 150 24 -14 6 30 -42 -137 -118 -46 -15 -35 -122 -258 -296 -155 -59 4 -30 -142 -194 -152 -105 -160 -176 -132 -50 71 157 214 156 -15 -115 -131 -121 -146 -209 -245 -201 -136 -130 -200 -377 -478 -347 -145 73 207 147 152 109 103 197 287 329 287 245 220 235 294 340 369 223 123 131 163 185 145 27 -58 -33 4 74 86 -23 -108 -107 -81 -19 35 69 45 3 -110 -198 -171 -66 -63 61 104 3 -77 11 190 260 186 137 141 115 50 -58 -55 -78 -12 72 34 -48 -72 73 242 321 306 204 177 104 -48 -100 -67 52 174 176 -60 -339 -387 -240 -83 42 105 102 102 111 92 31 -31 -75 -124 -236 -326 -337 -252 -130 -86 -165 -200 -212 -133 57 176 225 228 150 25 -14 6 29 -41 -133 -115 -45 -15 -34 -119 -252 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0 -131.83 18.81 0.92 -0.00060 0.00173 2013 618 1 4 0 2.880 22.19 15.00 18.81 11.54 28.4 943.90 -74 53 111 0 -78 -3 186 257 165 128 140 101 42 -49 -64 -68 -9 71 38 -49 -64 73 249 305 304 201 171 110 -53 -104 -64 49 178 174 -74 -348 -376 -226 -87 57 96 91 97 105 90 35 -28 -66 -123 -243 -317 -340 -258 -139 -79 -162 -201 -201 -124 51 195 234 219 142 28 -8 16 24 -47 -126 -116 -46 -15 -38 -130 -255 -288 -152 -62 -13 -32 -133 -188 -153 -117 -164 -174 -134 -42 79 149 210 155 -24 -117 -140 -112 -133 -201 -258 -191 -132 -133 -205 -376 -460 -334 -146 74 208 156 148 111 115 203 288 322 278 241 209 230 290 355 343 213 123 117 163 181 148 25 -66 -33 7 80 87 -32 -100 -109 -70 -30 41 67 42 3 -103 -205 -175 -67 -73 53 109 0 -81 -3 191 266 170 132 142 101 43 -50 -65 -70 -9 73 40 -51 -67 75 257 315 313 207 179 114 -54 -105 -64 49 181 179 -75 -358 -386 -231 -88 57 97 92 99 107 93 36 -28 -66 -125 -243 -312 -331 -251 -136 -79 -164 -200 -202 -125 52 197 237 221 143 29 -8 16 24 -46 -123 -113 -45 -15 -37 -128 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0 10 0 0 -105.89 18.81 0.92 -0.00068 0.00144 2013 618 1 4 0 2.880 22.19 15.00 18.81 11.54 28.4 943.76 -64 63 113 10 -78 4 190 252 183 122 139 97 38 -52 -58 -65 1 53 47 -66 -73 82 232 307 300 209 177 112 -60 -97 -53 44 175 174 -53 -325 -394 -226 -83 54 95 95 95 105 92 22 -33 -68 -117 -235 -331 -341 -264 -143 -86 -168 -198 -199 -119 45 185 221 224 151 31 -20 7 43 -44 -123 -116 -32 -22 -37 -128 -257 -299 -160 -68 -13 -22 -157 -191 -154 -114 -166 -176 -137 -39 77 154 215 157 -17 -122 -141 -111 -138 -205 -255 -207 -131 -133 -200 -384 -460 -354 -124 71 212 167 147 116 104 200 277 317 278 241 221 237 280 360 366 209 139 130 163 183 166 21 -65 -35 13 70 81 -32 -102 -103 -77 -32 36 71 38 -4 -104 -193 -174 -61 -63 62 111 10 -80 4 196 261 189 126 142 97 39 -53 -59 -67 1 54 49 -69 -75 85 239 318 309 214 180 115 -61 -97 -53 44 178 175 -54 -334 -405 -231 -85 55 96 97 97 108 95 22 -34 -68 -119 -235 -326 -332 -257 -140 -86 -170 -198 -200 -120 45 188 224 226 151 31 -20 7 43 -43 -121 -113 -31 -21 -36 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-9.7014e-06 10 0 0 10 0 0 -123.72 18.81 0.92 -0.00084 0.00143 2013 618 1 4 0 2.880 22.19 15.00 18.81 11.54 28.4 943.76 -58 66 108 8 -85 0 183 256 176 123 129 114 44 -57 -62 -51 -8 74 47 -61 -72 77 240 309 299 203 167 99 -38 -96 -58 51 161 179 -63 -331 -380 -230 -75 41 91 93 98 112 83 34 -25 -75 -126 -241 -324 -353 -263 -144 -98 -149 -195 -208 -118 48 182 228 224 143 29 -22 19 26 -44 -125 -120 -42 -10 -38 -122 -249 -291 -157 -75 -7 -26 -151 -190 -155 -105 -163 -175 -124 -40 69 159 218 158 -15 -124 -130 -121 -142 -199 -248 -214 -141 -135 -196 -371 -466 -350 -141 66 205 158 146 102 114 200 293 320 278 239 219 225 292 354 351 213 134 134 158 191 151 35 -62 -27 8 78 75 -34 -103 -110 -73 -20 49 75 54 -14 -113 -204 -185 -55 -58 66 106 8 -87 0 189 265 182 126 132 115 46 -58 -63 -52 -8 75 49 -64 -74 79 247 319 309 209 170 103 -39 -97 -58 51 164 179 -64 -340 -391 -235 -76 42 93 94 100 115 86 35 -25 -76 -128 -241 -319 -344 -256 -141 -98 -151 -195 -209 -119 49 184 231 226 144 29 -23 19 25 -43 -123 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-1.3091e-04 -1.1985e-05 10 0 0 10 0 0 -69.07 18.81 0.92 -0.00013 0.00189 2013 618 1 4 0 2.880 22.19 15.00 18.81 11.54 28.4 943.76 -66 68 113 1 -77 -5 194 245 179 118 150 109 47 -53 -64 -63 -13 58 33 -54 -57 75 245 314 307 205 163 103 -56 -107 -57 54 160 174 -65 -332 -375 -227 -80 58 95 93 99 108 90 30 -32 -77 -122 -243 -329 -350 -263 -156 -83 -151 -201 -215 -112 54 189 229 211 149 27 -10 14 37 -49 -134 -110 -38 -24 -17 -134 -259 -287 -152 -62 0 -25 -170 -192 -151 -117 -156 -166 -130 -39 65 165 214 154 -9 -122 -137 -117 -138 -198 -244 -213 -149 -125 -192 -377 -471 -341 -148 69 199 148 154 104 113 214 281 316 267 249 214 231 278 362 358 224 129 139 165 177 139 15 -63 -37 7 65 82 -23 -109 -101 -61 -23 42 75 48 -3 -114 -194 -181 -62 -65 67 111 1 -79 -5 199 254 185 121 153 110 48 -55 -65 -63 -13 59 35 -57 -59 77 253 324 316 211 166 106 -57 -108 -57 55 163 175 -66 -342 -386 -232 -81 58 96 94 101 111 93 31 -32 -78 -124 -243 -324 -341 -256 -153 -83 -152 -201 -217 -113 55 192 232 213 150 27 -10 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