File name: Pandora187s1_PittsburghPA_20241020_L2Fit_fout2c3d20220705p1-8.txt File generation date: 20241021T051151.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 187 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora187_OF_v4d20210517.txt Instrument calibration file used: Pandora187s1_CF_v3d20220705.txt Level 1 file used: Pandora187s1_PittsburghPA_20241020_L1_smca1c3d20220705p1-8.txt Full location name: Pittsburgh, PA - Lawrenceville ACHD (USEPA AQS ID 42-003-0008) Short location name: PittsburghPA Country of location: United States Location latitude [deg]: 40.4655 Location longitude [deg]: -79.9608 Location altitude [m]: 265 Local noon date: 20241020 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 194 335 Nominal wavelengths inside fitting window [nm]: 305.0947 305.2360 305.3774 305.5187 305.6601 305.8014 305.9427 306.0840 306.2253 306.3666 306.5079 306.6491 306.7904 306.9316 307.0728 307.2141 307.3553 307.4965 307.6376 307.7788 307.9200 308.0611 308.2023 308.3434 308.4845 308.6256 308.7667 308.9078 309.0489 309.1899 309.3310 309.4720 309.6131 309.7541 309.8951 310.0361 310.1771 310.3181 310.4591 310.6000 310.7410 310.8819 311.0228 311.1637 311.3046 311.4455 311.5864 311.7273 311.8681 312.0090 312.1498 312.2907 312.4315 312.5723 312.7131 312.8539 312.9946 313.1354 313.2761 313.4169 313.5576 313.6983 313.8390 313.9797 314.1204 314.2611 314.4018 314.5424 314.6831 314.8237 314.9643 315.1049 315.2455 315.3861 315.5267 315.6673 315.8078 315.9484 316.0889 316.2294 316.3699 316.5104 316.6509 316.7914 316.9319 317.0723 317.2128 317.3532 317.4936 317.6340 317.7744 317.9148 318.0552 318.1956 318.3359 318.4763 318.6166 318.7569 318.8972 319.0375 319.1778 319.3181 319.4584 319.5986 319.7389 319.8791 320.0193 320.1596 320.2998 320.4400 320.5801 320.7203 320.8605 321.0006 321.1407 321.2809 321.4210 321.5611 321.7012 321.8412 321.9813 322.1214 322.2614 322.4014 322.5415 322.6815 322.8215 322.9615 323.1014 323.2414 323.3814 323.5213 323.6612 323.8012 323.9411 324.0810 324.2209 324.3607 324.5006 324.6405 324.7803 324.9201 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241020T122154.3Z 9059.515212 266 1 45.64 2 82.65 110.75 57.49 278.15 0.00 1 0.00 1 0 17 6.116e-01 1.702e-02 4.212e-01 1.131e-02 7.887383e-01 6.563040e-03 8.782208e-03 -6.000000e+00 3.600197e-01 225.36 -2.00 3.49 -2.00 321.92 0.00e+00 2.612935e-03 3.899195e-03 3.487032e-03 -6.000000e+00 1.662481e-02 282.45 -2.00 20.00 -2.00 321.46 0.00e+00 7.228 0.007 302.00 328.00 3 6.9470e-01 2.6104e-02 8.5139e-02 -6.0000e+00 8.9477e-01 3.1619e-01 4.0151e-02 5.5406e-02 -6.0000e+00 9.7601e-01 -4.2621e-01 4.2605e-02 2.5686e-02 -6.0000e+00 5.7609e-01 1.5927e-01 1.9095e-02 9.0895e-03 -6.0000e+00 2.4978e-01 1.2037e-04 -1.2857e-03 3.3286e-04 1.0601e-04 -6.0000e+00 1.7566e-02 -2.8753e-02 0.0000e+00 12 8 8 10 0 0 -66.54 19.09 0.63 -0.02875 -0.03841 68 21 1 5 0 670.970 22.50 15.00 19.09 11.12 30.4 885.90 900000 900000 900000 -276643 -118261 -249874 900000 -230626 900000 -227603 35431 -188700 77427 900000 -134294 79895 162788 900000 -89085 7041 -7156 -7422 -165714 900000 -54421 -56151 -97682 -26943 -70222 5202 -58392 -47786 900000 38976 6396 145424 156204 -5096 -6620 18197 4916 -18641 31967 21927 26205 15118 41438 1065 5922 9584 26083 8033 3314 16231 22483 2856 13793 19272 8693 15307 261 14807 16913 12044 11055 3593 8939 2526 8097 9219 8670 2742 7519 -48 3926 -6682 -5103 -4790 -31609 1010 -296 4705 151 80 2438 3812 -8487 4097 1541 3587 -655 45 1743 -93 -1722 -1348 -1203 -1541 999 234 -275 -1371 753 35 -2582 -1744 -745 -726 1186 -536 82 460 590 -633 227 118 43 -195 -582 109 -235 687 -349 1062 -635 -31 1511 1700 658 134 -7 -14 -104 277 -319 -534 672 -98 97 -273 73 -672 900000 900000 900000 -4059 -1302 -2750 900000 -2538 900000 -2960 390 -2077 852 900000 -1881 879 1792 900000 -1337 77 -79 -82 -5969 900000 -762 -843 -2248 -297 -1194 57 -1227 -1100 900000 515 102 1600 1719 -135 -219 561 195 -1005 1091 845 981 649 1414 57 326 559 1464 610 292 1375 1905 308 1366 1782 861 1398 29 1597 2066 1750 1703 593 1426 459 1577 2039 2099 724 1837 -12 830 -1419 -1033 -1033 -10471 291 -102 1766 65 37 1167 1909 -5016 2173 827 1796 -320 21 796 -47 -1033 -951 -993 -1459 982 227 -247 -1110 558 27 -2197 -1554 -704 -751 1360 -714 120 708 907 -953 324 166 62 -299 -944 178 -371 1029 -511 1484 -874 -41 1989 2480 1123 237 -13 -29 -231 657 -814 -1416 1791 -266 255 -679 169 -1482 SS 20241020T123309.8Z 9059.523031 269 1 45.88 2 80.66 112.70 59.53 279.72 0.00 1 0.00 1 0 25 4.442e-01 7.355e-03 2.458e-01 4.100e-03 6.725319e-01 2.258652e-03 7.645852e-03 -6.000000e+00 2.559598e-01 225.36 -2.00 3.49 -2.00 321.37 0.00e+00 1.979874e-04 1.149373e-03 1.460818e-03 -6.000000e+00 1.134584e-02 282.45 -2.00 20.00 -2.00 320.83 0.00e+00 5.863 0.004 302.00 328.00 3 4.6822e-01 7.9785e-03 6.7509e-02 -6.0000e+00 6.3248e-01 7.8732e-02 1.1347e-02 3.8684e-02 -6.0000e+00 6.8608e-01 -1.2181e-01 1.1843e-02 1.9933e-02 -6.0000e+00 4.0931e-01 3.7256e-02 5.5592e-03 6.2610e-03 -6.0000e+00 1.7612e-01 6.0744e-04 -1.1533e-03 1.2006e-04 7.7490e-05 -6.0000e+00 1.2364e-02 -2.9697e-02 0.0000e+00 11 8 0 10 0 0 -15.48 19.09 0.49 -0.02970 -0.03836 174 53 1 5 0 263.590 22.50 15.00 19.09 12.63 30.2 894.50 -92033 -75553 -116026 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783 510 638 47 386 392 1005 845 546 178 99 213 645 1005 741 901 618 398 -226 -436 -960 -799 -2654 -362 -685 -535 -689 -902 230 158 -370 1115 1180 620 1010 -169 271 -727 -457 -760 357 56 137 -526 -662 -894 4 -36 -2008 -895 -1106 -322 400 692 88 722 489 172 159 -196 59 -328 -367 -534 149 563 805 155 440 -1062 956 917 686 425 377 264 -75 224 -327 -743 56 327 -519 475 -334 -642 SS 20241020T124332.4Z 9059.530236 274 1 45.94 2 78.86 114.53 61.39 281.15 0.00 1 0.00 1 0 25 3.088e-01 6.072e-03 8.035e-02 2.109e-03 5.908596e-01 1.133144e-03 6.807077e-03 -6.000000e+00 1.779691e-01 225.36 -2.00 3.49 -2.00 320.94 0.00e+00 1.810033e-03 5.008798e-04 1.142370e-03 -6.000000e+00 7.888439e-03 282.45 -2.00 20.00 -2.00 320.37 0.00e+00 4.994 0.002 302.00 328.00 3 2.9713e-01 3.7162e-03 5.7682e-02 -6.0000e+00 4.3976e-01 4.7378e-02 4.9445e-03 3.2928e-02 -6.0000e+00 4.7702e-01 -6.7601e-02 4.8973e-03 1.6180e-02 -6.0000e+00 2.8459e-01 1.5609e-02 2.3836e-03 5.7029e-03 -6.0000e+00 1.2246e-01 1.7111e-03 -1.1069e-03 6.2192e-05 6.3492e-05 -6.0000e+00 8.5965e-03 -3.0194e-02 0.0000e+00 10 0 0 10 0 0 -68.21 19.08 0.42 -0.03019 -0.03851 320 98 1 5 0 143.510 22.50 15.01 19.08 13.83 30.4 902.02 -101871 -86073 -98071 -108975 -116972 -97495 -126025 -82869 -98186 -78358 -92460 -68069 -62420 -45891 -42104 -31563 -26203 -25249 -19163 -19102 -8067 -23963 -21551 -18546 -9144 -18653 -12268 -20635 -19405 -14650 -12905 -8875 4444 -4685 -11263 -7114 -8142 -4708 -3780 1007 -1190 1830 1565 3547 1439 1362 1417 363 46 789 2303 1032 2904 1678 2680 1538 2093 1094 1660 153 1578 2361 3600 2569 1257 323 -77 226 919 1731 1323 1278 915 1255 -195 -346 -1745 -1783 -3123 -1178 -1179 -1191 -2131 -1329 -281 0 58 660 1271 1004 862 -151 -331 -692 -535 -617 530 589 39 -73 -590 -891 -15 18 -1569 -1035 -707 -432 313 406 30 313 495 207 54 58 -17 -176 -435 -494 -179 200 507 229 204 -519 575 776 416 395 333 134 29 103 -217 -268 129 -162 -251 214 -33 -296 -705 -595 -825 -998 -1072 -729 -1367 -666 -1046 -747 -1072 -700 -759 -601 -661 -531 -470 -496 -422 -444 -173 -606 -563 -515 -250 -595 -373 -662 -607 -473 -483 -376 189 -231 -572 -350 -452 -302 -295 89 -121 194 174 397 167 162 171 46 6 111 355 179 542 344 575 348 483 253 372 35 369 608 1037 827 421 106 -25 76 346 739 617 617 434 557 -80 -128 -622 -656 -1324 -578 -669 -763 -1491 -979 -200 0 46 529 1001 829 663 -110 -235 -520 -454 -550 536 671 47 -86 -643 -880 -14 18 -1662 -1149 -830 -545 431 621 49 534 826 329 81 86 -26 -279 -734 -855 -304 325 797 347 298 -733 796 1160 703 677 615 261 60 226 -505 -647 316 -403 -613 496 -72 -622 SS 20241020T124933.9Z 9059.534420 277 1 45.94 2 77.82 115.61 62.47 281.98 0.00 1 0.00 1 0 25 2.130e-01 5.598e-03 5.477e-02 1.637e-03 5.481568e-01 8.587645e-04 6.311947e-03 -6.000000e+00 1.227694e-01 225.36 -2.00 3.49 -2.00 320.64 0.00e+00 1.978454e-03 3.470321e-04 9.178637e-04 -6.000000e+00 5.441559e-03 282.45 -2.00 20.00 -2.00 320.04 0.00e+00 4.601 0.002 302.00 328.00 3 2.8553e-01 2.6855e-03 5.3018e-02 -6.0000e+00 3.0336e-01 2.6824e-02 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