File name: Pandora187s1_PittsburghPA_20241025_L2Fit_fout2c5d20230706p1-8.txt File generation date: 20241126T212817.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 187 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora187_OF_v4d20210517.txt Instrument calibration file used: Pandora187s1_CF_v5d20230706.txt Level 1 file used: Pandora187s1_PittsburghPA_20241025_L1_smca1c5d20230706p1-8.txt Full location name: Pittsburgh, PA - Lawrenceville ACHD (USEPA AQS ID 42-003-0008) Short location name: PittsburghPA Country of location: United States Location latitude [deg]: 40.4655 Location longitude [deg]: -79.9608 Location altitude [m]: 265 Local noon date: 20241025 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 194 335 Nominal wavelengths inside fitting window [nm]: 305.0595 305.2010 305.3424 305.4838 305.6252 305.7666 305.9080 306.0494 306.1908 306.3321 306.4735 306.6148 306.7561 306.8974 307.0387 307.1800 307.3213 307.4626 307.6038 307.7451 307.8863 308.0275 308.1687 308.3099 308.4511 308.5923 308.7335 308.8746 309.0158 309.1569 309.2980 309.4391 309.5802 309.7213 309.8624 310.0035 310.1445 310.2856 310.4266 310.5676 310.7086 310.8496 310.9906 311.1316 311.2726 311.4135 311.5545 311.6954 311.8363 311.9772 312.1181 312.2590 312.3999 312.5408 312.6816 312.8225 312.9633 313.1041 313.2449 313.3857 313.5265 313.6673 313.8080 313.9488 314.0895 314.2303 314.3710 314.5117 314.6524 314.7931 314.9338 315.0744 315.2151 315.3557 315.4963 315.6370 315.7776 315.9182 316.0587 316.1993 316.3399 316.4804 316.6210 316.7615 316.9020 317.0425 317.1830 317.3235 317.4640 317.6044 317.7449 317.8853 318.0257 318.1662 318.3066 318.4470 318.5873 318.7277 318.8681 319.0084 319.1488 319.2891 319.4294 319.5697 319.7100 319.8503 319.9905 320.1308 320.2710 320.4113 320.5515 320.6917 320.8319 320.9721 321.1123 321.2524 321.3926 321.5327 321.6728 321.8130 321.9531 322.0932 322.2333 322.3733 322.5134 322.6534 322.7935 322.9335 323.0735 323.2135 323.3535 323.4935 323.6335 323.7734 323.9134 324.0533 324.1932 324.3332 324.4731 324.6129 324.7528 324.8927 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241025T122654.3Z 9064.518684 273 1 45.99 2 82.86 113.00 21.01 183.22 0.00 1 0.00 1 0 17 6.176e-01 1.378e-02 4.386e-01 1.063e-02 8.207817e-01 6.081696e-03 9.003329e-03 -6.000000e+00 3.587038e-01 224.93 -2.00 3.49 -2.00 321.96 0.00e+00 7.131521e-04 3.625617e-03 1.203369e-03 -6.000000e+00 1.631491e-02 281.82 -2.00 20.00 -2.00 321.52 0.00e+00 7.407 0.007 302.00 328.00 3 8.6440e-01 2.4202e-02 8.4730e-02 -6.0000e+00 8.8614e-01 4.0529e-01 3.7109e-02 4.8033e-02 -6.0000e+00 9.6350e-01 -5.4557e-01 3.9349e-02 2.6203e-02 -6.0000e+00 5.7200e-01 2.1127e-01 1.7650e-02 8.7138e-03 -6.0000e+00 2.4651e-01 8.2594e-05 -4.4831e-04 3.0444e-04 1.1551e-04 -6.0000e+00 1.7206e-02 -8.5866e-03 6.6943e-05 12 8 8 10 0 0 -42.95 19.45 0.65 -0.00859 -0.01196 80 25 1 5 0 574.710 22.80 14.99 19.45 9.50 29.9 877.27 -107071 900000 -245184 22157 -258577 900000 -247477 -81646 -216503 -146103 -175596 -208349 -136318 -119339 -138699 -43956 67422 -68691 16049 -20526 900000 -130404 -79033 -49849 27577 -90380 -35475 -88948 -53953 -37016 -59252 66083 900000 76590 -37154 61609 37960 55563 -26048 36732 7025 31381 8584 66055 23355 -6755 28333 1415 14331 1455 38542 4144 25605 4278 32890 -4299 21525 18902 17008 2728 5357 8580 16821 10532 6993 -3960 8144 7131 5388 13729 3773 10063 5793 5101 -1461 -854 -9974 -5425 -556 -2841 -3575 -621 -811 -751 4854 800 -6355 2367 4602 2163 1712 -2776 1978 -1709 -1137 -2835 -1530 -1723 -548 963 -579 -399 -1103 35 -3465 -1871 -1875 -71 -60 521 -364 833 191 -520 302 81 129 -453 163 -752 525 600 1227 608 -183 -608 1637 1100 372 499 -66 321 -259 580 -275 -275 81 114 -339 411 -511 -593 -1109 900000 -3174 229 -3348 900000 -2991 -846 -2650 -1513 -1819 -3139 -1412 -1236 -2220 -455 698 -841 166 -213 900000 -3315 -1265 -657 286 -2042 -468 -1926 -813 -523 -1283 684 900000 793 -945 638 550 806 -1052 951 277 1040 373 1642 895 -357 1086 75 713 90 1876 322 1777 403 2487 -494 1962 1742 1533 277 549 951 1986 1505 1094 -689 1282 1211 1055 2844 942 2429 1416 1162 -319 -167 -2066 -1146 -131 -830 -1244 -241 -346 -342 2232 406 -3614 1255 2355 1080 803 -1303 889 -871 -671 -2014 -1260 -1629 -548 931 -524 -321 -832 27 -2954 -1659 -1781 -73 -70 687 -540 1290 299 -796 440 116 190 -711 267 -1255 835 911 1789 863 -253 -820 2178 1638 648 898 -131 683 -592 1417 -722 -750 223 317 -921 1042 -1214 -1331 SS 20241025T123809.2Z 9064.526495 276 1 46.02 2 80.91 114.95 21.29 190.39 0.00 1 0.00 1 0 25 5.448e-01 7.832e-03 1.830e-01 3.917e-03 6.996156e-01 2.164868e-03 7.854172e-03 -6.000000e+00 3.137714e-01 224.93 -2.00 3.49 -2.00 321.44 0.00e+00 9.294713e-04 1.119266e-03 8.601793e-04 -6.000000e+00 1.388441e-02 281.82 -2.00 20.00 -2.00 320.92 0.00e+00 6.004 0.004 302.00 328.00 3 7.2428e-01 7.7046e-03 6.9155e-02 -6.0000e+00 7.7475e-01 1.2677e-01 1.1057e-02 3.9405e-02 -6.0000e+00 8.4038e-01 -1.6945e-01 1.1622e-02 2.1007e-02 -6.0000e+00 5.0139e-01 5.6650e-02 5.4318e-03 7.1036e-03 -6.0000e+00 2.1604e-01 3.9569e-04 -1.4241e-04 1.1310e-04 8.5036e-05 -6.0000e+00 1.5166e-02 -8.9187e-03 6.3709e-05 11 8 0 10 0 0 -8.92 19.45 0.42 -0.00892 -0.00999 196 60 1 5 0 234.730 22.80 15.00 19.45 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110 422 81 -79 285 146 103 145 526 420 730 649 795 563 804 754 565 338 313 772 1011 981 724 -105 19 457 362 1018 821 996 591 390 197 -388 -846 -1102 -2666 -490 -796 -514 -633 -366 141 282 -430 854 1170 996 565 -209 -20 -472 -887 -962 -95 230 90 -128 -754 -744 -226 -219 -1710 -1115 -997 -530 512 342 52 662 779 421 141 -127 -120 -343 -669 -619 -332 724 975 518 130 -680 930 1164 746 880 397 467 64 291 -372 -864 206 -138 -567 138 -327 -427 SS 20241025T125001.0Z 9064.534734 281 1 45.87 2 78.88 117.05 21.87 197.70 0.00 1 0.00 1 0 25 3.333e-01 6.147e-03 7.138e-02 1.907e-03 6.007711e-01 1.016663e-03 6.884917e-03 -6.000000e+00 1.919281e-01 224.93 -2.00 3.49 -2.00 320.91 0.00e+00 1.946765e-03 4.486956e-04 8.897866e-04 -6.000000e+00 8.493244e-03 281.82 -2.00 20.00 -2.00 320.35 0.00e+00 5.004 0.002 302.00 328.00 3 6.0038e-01 3.3056e-03 5.7880e-02 -6.0000e+00 4.7390e-01 5.5487e-02 4.4170e-03 3.3024e-02 -6.0000e+00 5.1406e-01 -6.4674e-02 4.4217e-03 1.6593e-02 -6.0000e+00 3.0670e-01 1.3569e-02 2.1527e-03 6.1051e-03 -6.0000e+00 1.3214e-01 1.2291e-03 -2.6653e-04 5.5123e-05 6.4193e-05 -6.0000e+00 9.2774e-03 -8.9484e-03 4.6844e-05 10 0 0 10 0 0 18.41 19.45 0.39 -0.00895 -0.01095 370 114 1 5 0 123.950 22.80 15.00 19.45 12.13 30.1 893.20 -119496 -107197 -108973 -106596 -120365 -107626 -126025 -102378 -92936 -82011 -88433 -88545 -70341 -48665 -47630 -28459 -27436 -27397 -25156 -20283 -13120 -25869 -23481 -15772 -13268 -20545 -17824 -21860 -21603 -16764 -15244 -9304 1809 -3691 -11309 -7559 -8371 -4346 -2137 -1233 -139 1750 1386 3728 1937 1786 1369 323 89 976 2320 1478 2564 1965 3086 2135 2244 1183 1734 138 1246 2318 3009 2708 1598 419 -36 230 756 1239 1391 1427 1210 1123 337 -202 -1679 -2201 -2841 -1259 -1038 -1396 -1974 -1439 -579 -257 221 795 1312 966 1019 -121 -233 -652 -753 -714 390 592 -5 -84 -528 -729 -106 -150 -1285 -925 -816 -426 293 305 113 361 545 150 25 76 -134 -298 -335 -436 -252 161 395 147 234 -359 585 699 508 568 308 210 28 105 -223 -265 56 -127 -239 133 -90 -278 -909 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