File name: Pandora187s1_PittsburghPA_20241030_L2Fit_fwvt1c3d20220705p1-8.txt
File generation date: 20241031T054001.4Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c3p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 187
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora187_OF_v4d20210517.txt
Instrument calibration file used: Pandora187s1_CF_v3d20220705.txt
Level 1 file used: Pandora187s1_PittsburghPA_20241030_L1_smca1c3d20220705p1-8.txt
Full location name: Pittsburgh, PA - Lawrenceville ACHD (USEPA AQS ID 42-003-0008)
Short location name: PittsburghPA
Country of location: United States
Location latitude [deg]: 40.4655
Location longitude [deg]: -79.9608
Location altitude [m]: 265
Local noon date: 20241030
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1607 1755
Nominal wavelengths inside fitting window [nm]: 492.0854 492.2072 492.3291 492.4509 492.5727 492.6944 492.8162 492.9379 493.0597 493.1814 493.3031 493.4247 493.5464 493.6680 493.7896 493.9112 494.0328 494.1544 494.2760 494.3975 494.5190 494.6405 494.7620 494.8835 495.0049 495.1264 495.2478 495.3692 495.4906 495.6119 495.7333 495.8546 495.9760 496.0973 496.2185 496.3398 496.4611 496.5823 496.7035 496.8247 496.9459 497.0671 497.1882 497.3093 497.4305 497.5516 497.6726 497.7937 497.9147 498.0358 498.1568 498.2778 498.3988 498.5197 498.6407 498.7616 498.8825 499.0034 499.1243 499.2452 499.3660 499.4868 499.6076 499.7284 499.8492 499.9700 500.0907 500.2114 500.3321 500.4528 500.5735 500.6942 500.8148 500.9354 501.0560 501.1766 501.2972 501.4177 501.5383 501.6588 501.7793 501.8998 502.0202 502.1407 502.2611 502.3816 502.5020 502.6223 502.7427 502.8630 502.9834 503.1037 503.2240 503.3443 503.4645 503.5848 503.7050 503.8252 503.9454 504.0656 504.1858 504.3059 504.4260 504.5461 504.6662 504.7863 504.9064 505.0264 505.1464 505.2664 505.3864 505.5064 505.6263 505.7463 505.8662 505.9861 506.1060 506.2258 506.3457 506.4655 506.5853 506.7051 506.8249 506.9447 507.0644 507.1842 507.3039 507.4236 507.5433 507.6629 507.7826 507.9022 508.0218 508.1414 508.2610 508.3805 508.5001 508.6196 508.7391 508.8586 508.9780 509.0975 509.2169 509.3363 509.4557 509.5751 509.6945 509.8138 509.9332
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-249: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 250-398: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20241030T123136.6Z 9069.521951 106 1 45.92 2 83.15 115.07 64.89 126.29 0.00 1 0.00 1 0 22 2.238e-03 2.231e-03 1.655e-04 1.654e-04 7.086296e+03 1.254940e+01 4.804980e+02 -6.000000e+00 1.454397e+02 281.20 -2.00 20.00 -2.00 505.32 0.00e+00 1.411455e-03 4.938929e-06 8.331989e-05 -6.000000e+00 6.771954e-05 281.20 -2.00 20.00 -2.00 500.65 0.00e+00 4.954635e-01 3.515266e-03 5.380831e-02 -6.000000e+00 4.835250e-02 224.50 -2.00 3.49 -2.00 502.22 0.00e+00 7.666 0.008 489.00 513.00 1 2.1915e+00 2.7227e-04 1.1800e-02 -6.0000e+00 3.7523e-03 -1.0601e-02 6.5411e-05 1.3896e-03 -6.0000e+00 9.1962e-04 7.0922e-02 2.0090e-03 2.5935e-05 4.9532e-05 -6.0000e+00 3.7638e-04 -1.0555e-02 -5.3175e-05 10 0 0 10 0 0 90.41 19.55 1.38 -0.01055 0.00338 697 214 1 4 0 65.870 22.90 15.00 19.55 21.78 30.7 957.24 -282 -108 48 25 17 145 344 365 239 128 98 46 -27 -91 -69 -50 53 120 103 27 19 163 312 371 351 213 107 -3 -226 -289 -240 -90 83 173 1 -254 -302 -173 -60 77 133 125 162 187 144 75 16 -71 -192 -340 -482 -487 -382 -251 -132 -146 -157 -123 -16 184 341 371 353 217 71 -3 -10 -13 -132 -235 -190 -106 -75 -74 -192 -319 -372 -250 -181 -122 -163 -249 -253 -187 -108 -132 -144 -68 54 207 347 392 331 131 -8 -73 -98 -173 -285 -401 -412 -313 -265 -274 -413 -536 -438 -216 -8 166 170 175 189 194 324 436 433 374 266 176 197 280 386 407 273 150 104 129 150 97 -43 -133 -86 -48 42 66 -20 -51 -50 19 64 97 93 79 24 -93 -225 -243 -158 -267 -103 46 25 17 146 349 372 244 130 99 46 -27 -90 -68 -50 53 121 103 27 20 167 320 380 360 218 109 -3 -224 -284 -241 -88 83 175 1 -262 -311 -178 -61 79 136 128 168 189 146 76 17 -73 -194 -337 -472 -472 -370 -245 -131 -148 -161 -123 -16 185 344 374 356 218 73 -3 -10 -13 -131 -231 -187 -105 -74 -73 -190 -315 -363 -243 -174 -118 -158 -243 -249 -185 -108 -132 -144 -69 53 204 343 388 326 129 -7 -72 -94 -164 -267 -376 -391 -303 -262 -268 -410 -535 -438 -216 -8 168 172 180 190 196 330 444 442 381 269 177 196 285 392 413 270 148 103 128 151 97 -43 -133 -86 -47 42 65 -20 -52 -52 20 65 99 95 81 24 -96 -230 -247 -160
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SQ 20241030T124237.1Z 9069.529596 109 2 6.22 2 81.27 116.98 63.29 128.68 0.00 1 0.00 1 0 22 2.005e-03 2.002e-03 1.444e-04 1.443e-04 5.991826e+03 1.077302e+01 4.082403e+02 -6.000000e+00 1.303160e+02 281.20 -2.00 20.00 -2.00 505.30 0.00e+00 1.151121e-03 4.295531e-06 6.953855e-05 -6.000000e+00 6.067116e-05 281.20 -2.00 20.00 -2.00 500.61 0.00e+00 3.649539e-01 3.074265e-03 4.641950e-02 -6.000000e+00 4.330714e-02 224.50 -2.00 3.49 -2.00 502.18 0.00e+00 6.223 0.004 489.00 513.00 1 9.4971e-02 2.3812e-04 9.6488e-03 -6.0000e+00 3.3612e-03 -7.4059e-03 5.7415e-05 1.1800e-03 -6.0000e+00 8.2314e-04 7.1545e-01 1.0864e-03 2.2769e-05 4.1205e-05 -6.0000e+00 3.3726e-04 -2.1842e-02 6.0388e-05 10 0 0 10 0 0 -72.37 19.55 1.21 -0.02184 -0.01431 738 227 1 4 0 7.880 22.90 15.00 19.55 22.58 30.7 961.94 -135 21 134 64 -3 74 262 311 204 156 127 65 -13 -84 -63 -78 4 81 71 -27 -31 118 287 349 324 205 154 38 -120 -160 -125 8 146 171 -38 -322 -375 -247 -102 43 98 101 140 144 98 52 -23 -85 -185 -313 -424 -418 -300 -183 -107 -123 -181 -184 -71 93 236 305 265 176 36 -27 -14 -4 -85 -194 -153 -88 -66 -52 -177 -293 -346 -223 -113 -64 -74 -178 -210 -146 -119 -155 -146 -86 18 157 277 339 278 93 -46 -74 -87 -146 -264 -368 -360 -298 -222 -256 -422 -512 -429 -208 35 205 163 155 140 173 270 356 412 307 235 178 221 285 396 409 257 152 129 151 160 119 -9 -95 -69 -4 64 81 -49 -83 -63 -14 25 65 94 53 17 -70 -201 -183 -80 -129 20 131 64 -3 75 269 313 205 160 130 65 -13 -83 -63 -78 4 83 72 -28 -32 122 298 363 337 213 159 38 -120 -158 -123 8 146 174 -39 -327 -380 -249 -106 44 101 102 142 147 100 53 -23 -85 -187 -312 -416 -407 -292 -179 -106 -124 -180 -185 -72 94 240 310 269 177 36 -28 -14 -4 -84 -191 -150 -87 -65 -51 -175 -289 -339 -217 -110 -62 -72 -173 -206 -145 -118 -156 -143 -84 18 155 275 338 276 92 -44 -73 -84 -139 -249 -347 -343 -289 -220 -252 -421 -513 -430 -208 35 207 162 155 142 176 276 365 422 314 238 179 220 283 391 404 255 150 127 149 158 119 -9 -94 -68 -3 62 80 -49 -84 -63 -14 26 66 96 54 17 -70 -204 -184 -81
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