File name: Pandora187s1_PittsburghPA_20241108_L2Fit_fout2c3d20220705p1-8.txt File generation date: 20241109T051147.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 187 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora187_OF_v4d20210517.txt Instrument calibration file used: Pandora187s1_CF_v3d20220705.txt Level 1 file used: Pandora187s1_PittsburghPA_20241108_L1_smca1c3d20220705p1-8.txt Full location name: Pittsburgh, PA - Lawrenceville ACHD (USEPA AQS ID 42-003-0008) Short location name: PittsburghPA Country of location: United States Location latitude [deg]: 40.4655 Location longitude [deg]: -79.9608 Location altitude [m]: 265 Local noon date: 20241108 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 194 335 Nominal wavelengths inside fitting window [nm]: 305.0947 305.2360 305.3774 305.5187 305.6601 305.8014 305.9427 306.0840 306.2253 306.3666 306.5079 306.6491 306.7904 306.9316 307.0728 307.2141 307.3553 307.4965 307.6376 307.7788 307.9200 308.0611 308.2023 308.3434 308.4845 308.6256 308.7667 308.9078 309.0489 309.1899 309.3310 309.4720 309.6131 309.7541 309.8951 310.0361 310.1771 310.3181 310.4591 310.6000 310.7410 310.8819 311.0228 311.1637 311.3046 311.4455 311.5864 311.7273 311.8681 312.0090 312.1498 312.2907 312.4315 312.5723 312.7131 312.8539 312.9946 313.1354 313.2761 313.4169 313.5576 313.6983 313.8390 313.9797 314.1204 314.2611 314.4018 314.5424 314.6831 314.8237 314.9643 315.1049 315.2455 315.3861 315.5267 315.6673 315.8078 315.9484 316.0889 316.2294 316.3699 316.5104 316.6509 316.7914 316.9319 317.0723 317.2128 317.3532 317.4936 317.6340 317.7744 317.9148 318.0552 318.1956 318.3359 318.4763 318.6166 318.7569 318.8972 319.0375 319.1778 319.3181 319.4584 319.5986 319.7389 319.8791 320.0193 320.1596 320.2998 320.4400 320.5801 320.7203 320.8605 321.0006 321.1407 321.2809 321.4210 321.5611 321.7012 321.8412 321.9813 322.1214 322.2614 322.4014 322.5415 322.6815 322.8215 322.9615 323.1014 323.2414 323.3814 323.5213 323.6612 323.8012 323.9411 324.0810 324.2209 324.3607 324.5006 324.6405 324.7803 324.9201 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241108T124533.6Z 9078.531639 62 1 46.46 2 82.78 119.41 150.64 61.79 0.00 1 0.00 1 0 25 5.930e-01 5.842e-02 4.722e-01 3.251e-02 7.914399e-01 1.939137e-02 9.655989e-03 -6.000000e+00 3.511976e-01 223.73 -2.00 3.49 -2.00 321.78 0.00e+00 -1.225932e-02 1.023957e-02 3.033586e-03 -6.000000e+00 1.801125e-02 280.08 -2.00 20.00 -2.00 321.29 0.00e+00 7.340 0.007 302.00 328.00 3 2.2373e+00 7.0232e-02 8.2670e-02 -6.0000e+00 8.7331e-01 8.3542e-01 9.1094e-02 4.3764e-02 -6.0000e+00 9.5823e-01 -9.4083e-01 7.8331e-02 2.6515e-02 -6.0000e+00 5.6730e-01 3.5126e-01 3.7080e-02 1.6060e-02 -6.0000e+00 2.4710e-01 1.9871e-05 -3.1108e-03 9.8955e-04 2.7100e-04 -6.0000e+00 1.7893e-02 -3.0823e-02 0.0000e+00 12 8 8 10 0 0 94.41 19.64 0.89 -0.03082 -0.05420 16 5 1 5 0 2903.060 23.01 15.00 19.64 11.97 30.3 899.52 900000 900000 900000 900000 -80206 -55999 900000 -32287 -47116 -134570 104565 900000 -93447 16511 -114023 900000 -11090 900000 -60198 900000 900000 -27533 -127531 900000 48657 7130 42913 900000 900000 126196 -80955 -41716 900000 900000 191923 91262 900000 30646 138380 125074 54468 51844 900000 218434 75729 55068 261840 26580 5764 28725 54975 39725 -5349 36656 153246 12332 74849 142168 72151 25904 13545 53897 97683 26074 62127 -6244 23339 -4208 3524 31564 36050 -924 28229 -5553 8292 8278 -15251 6417 32795 10738 -7338 15738 4745 10406 10529 6560 -41064 14303 12531 25167 4235 14553 21857 6408 -676 -12363 -7807 -15089 2488 7841 4382 -2748 2287 5689 -3510 -3132 -3523 -4731 3632 124 -1411 3215 -480 -1862 -1180 2031 2807 4596 514 1476 -4898 4479 -2845 1172 -3909 2526 4222 8571 905 633 -545 19 1096 766 914 -3703 2302 -767 -797 -602 923 -1320 900000 900000 900000 900000 -2533 -1769 900000 -1020 -1488 -5579 3303 900000 -3321 522 -6753 900000 -350 900000 -2733 900000 900000 -928 -11581 900000 1537 240 1355 900000 900000 3986 -6137 -2460 900000 900000 6062 2883 900000 1226 4371 3951 2867 2948 900000 6900 3189 2783 8271 1791 498 2117 3721 3262 -755 3705 5532 1792 6417 6095 5860 3156 1864 5351 7053 4295 7429 -1451 4055 -1016 882 6837 8134 -311 6878 -1754 2039 1812 -3992 1404 6289 3053 -2930 5717 2109 4649 5012 3434 -35948 7293 6390 10732 2073 6107 8482 3123 -405 -9735 -6816 -16137 2386 7006 3747 -2257 1656 4082 -2962 -2777 -3338 -4932 3909 158 -2029 4664 -727 -2773 -1666 2709 3794 6409 785 2265 -7769 6174 -4076 1560 -5292 3101 5077 10810 1422 1130 -1083 41 2277 1714 2181 -9600 5710 -1973 -2002 -1521 2134 -2937 SS 20241108T125645.4Z 9078.539414 65 1 45.93 2 80.95 121.38 148.81 65.04 0.00 1 0.00 1 0 25 4.699e-01 7.263e-03 2.082e-01 3.747e-03 6.805036e-01 2.054711e-03 7.744974e-03 -6.000000e+00 2.691721e-01 223.73 -2.00 3.49 -2.00 321.38 0.00e+00 4.429166e-04 1.034583e-03 1.839186e-03 -6.000000e+00 1.188585e-02 280.08 -2.00 20.00 -2.00 320.87 0.00e+00 6.027 0.004 302.00 328.00 3 1.4404e-01 7.1671e-03 6.9175e-02 -6.0000e+00 6.6323e-01 1.0633e-01 1.0231e-02 3.9839e-02 -6.0000e+00 7.2046e-01 -1.3707e-01 1.0885e-02 2.0516e-02 -6.0000e+00 4.2975e-01 4.3081e-02 5.1259e-03 6.5032e-03 -6.0000e+00 1.8522e-01 7.1322e-04 -1.0922e-03 1.0918e-04 8.2141e-05 -6.0000e+00 1.3076e-02 -3.2223e-02 0.0000e+00 11 8 0 10 0 0 -117.41 19.64 0.46 -0.03222 -0.04043 208 64 1 5 0 220.630 23.01 15.00 19.64 13.14 30.2 907.42 -70660 -142769 -81543 -171043 -144156 -149981 -173145 -158881 -140920 -131018 -170050 -135512 -120677 -68408 -99837 -40477 -61055 -9637 -48620 -20670 -33338 -47602 -48840 -17316 -41517 -36685 -29551 -51292 -26235 -24001 -21388 -21959 29431 -8603 -4829 -16258 641 -9902 416 1069 -197 2469 1855 8156 213 283 -1546 3612 -2764 2951 2301 4133 2428 4833 4532 1951 3990 3658 3968 2403 1570 2978 5726 3464 1853 500 1463 -822 1908 2296 3321 1748 1936 655 233 -1150 -2691 -3055 -7260 -946 -980 -719 -1803 -906 -309 358 -789 1292 1540 1380 390 300 -643 -579 -317 -1048 191 187 40 -164 -499 -1089 86 -119 -1335 -902 -799 -661 394 445 109 219 511 300 81 -49 -272 -132 -428 -111 -261 462 454 418 -79 -541 477 747 518 294 303 81 70 -55 -95 -468 218 -79 -99 170 -76 -302 -258 -806 -298 -1363 -814 -897 -1438 -1319 -1123 -1044 -2146 -1395 -1363 -591 -1492 -403 -852 -90 -727 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4.1269e-03 3.3435e-02 -6.0000e+00 4.6436e-01 -5.3549e-02 4.1649e-03 1.6278e-02 -6.0000e+00 2.7698e-01 9.9508e-03 2.0392e-03 5.3029e-03 -6.0000e+00 1.1938e-01 2.2147e-03 -1.2018e-03 5.3075e-05 6.3514e-05 -6.0000e+00 8.4281e-03 -3.2234e-02 0.0000e+00 10 0 0 10 0 0 -125.78 19.63 0.39 -0.03223 -0.04127 397 122 1 5 0 115.500 23.01 15.00 19.63 14.58 30.4 915.91 -97674 -107418 -85515 -107343 -101930 -114336 -105563 -95625 -90819 -80144 -77797 -73223 -62194 -43486 -42778 -21115 -28334 -17534 -24196 -13984 -19510 -23551 -24566 -13859 -18593 -16547 -14633 -18849 -19366 -14448 -11265 -9775 2508 -6107 -8999 -10386 -6610 -6739 -1948 -789 -588 975 1233 2173 2065 1674 849 1108 -265 1648 1165 1941 1888 2310 2230 2074 1600 1516 1759 629 1390 2560 2786 2447 1510 330 424 -441 809 1122 1413 1240 1266 1102 128 -283 -1583 -2023 -2491 -1240 -846 -1115 -2054 -1292 -764 -263 145 924 936 1111 680 -107 -426 -522 -629 -574 309 480 189 -136 -470 -733 165 -157 -1194 -908 -849 -303 384 296 45 261 552 173 132 213 -209 -193 -564 -468 -300 219 407 167 137 -412 631 945 416 470 262 210 90 74 -221 -340 138 -131 -200 148 -79 -297 -647 -919 -635 -971 -806 -1015 -937 -880 -909 -789 -791 -804 -763 -562 -684 -324 -526 -355 -567 -313 -475 -602 -672 -374 -571 -529 -468 -609 -619 -475 -422 -425 111 -312 -457 -539 -369 -450 -153 -73 -61 107 141 253 244 203 106 142 -36 235 186 342 364 482 493 479 381 359 404 145 333 673 827 807 517 111 141 -154 312 493 675 613 614 503 54 -108 -577 -763 -1071 -621 -489 -729 -1468 -884 -558 -203 117 754 755 852 535 -80 -309 -399 -544 -520 319 557 232 -164 -523 -738 156 -155 -1280 -1023 -1015 -387 537 461 70 415 937 280 202 317 -319 -311 -967 -821 -516 361 649 256 203 -588 884 1425 710 815 491 412 186 163 -520 -767 315 -304 -494 347 -176 -629 SS 20241108T131504.4Z 9078.552134 73 1 45.91 2 78.03 124.71 145.72 69.80 0.00 1 0.00 1 0 25 2.302e-01 5.729e-03 4.506e-02 1.408e-03 5.542902e-01 7.353898e-04 6.397470e-03 -6.000000e+00 1.318740e-01 223.72 -2.00 3.49 -2.00 320.60 0.00e+00 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