File name: Pandora187s1_PittsburghPA_20241125_L2Fit_fwvt1c3d20220705p1-8.txt File generation date: 20241126T051835.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 187 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora187_OF_v4d20210517.txt Instrument calibration file used: Pandora187s1_CF_v3d20220705.txt Level 1 file used: Pandora187s1_PittsburghPA_20241125_L1_smca1c3d20220705p1-8.txt Full location name: Pittsburgh, PA - Lawrenceville ACHD (USEPA AQS ID 42-003-0008) Short location name: PittsburghPA Country of location: United States Location latitude [deg]: 40.4655 Location longitude [deg]: -79.9608 Location altitude [m]: 265 Local noon date: 20241125 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1607 1755 Nominal wavelengths inside fitting window [nm]: 492.0854 492.2072 492.3291 492.4509 492.5727 492.6944 492.8162 492.9379 493.0597 493.1814 493.3031 493.4247 493.5464 493.6680 493.7896 493.9112 494.0328 494.1544 494.2760 494.3975 494.5190 494.6405 494.7620 494.8835 495.0049 495.1264 495.2478 495.3692 495.4906 495.6119 495.7333 495.8546 495.9760 496.0973 496.2185 496.3398 496.4611 496.5823 496.7035 496.8247 496.9459 497.0671 497.1882 497.3093 497.4305 497.5516 497.6726 497.7937 497.9147 498.0358 498.1568 498.2778 498.3988 498.5197 498.6407 498.7616 498.8825 499.0034 499.1243 499.2452 499.3660 499.4868 499.6076 499.7284 499.8492 499.9700 500.0907 500.2114 500.3321 500.4528 500.5735 500.6942 500.8148 500.9354 501.0560 501.1766 501.2972 501.4177 501.5383 501.6588 501.7793 501.8998 502.0202 502.1407 502.2611 502.3816 502.5020 502.6223 502.7427 502.8630 502.9834 503.1037 503.2240 503.3443 503.4645 503.5848 503.7050 503.8252 503.9454 504.0656 504.1858 504.3059 504.4260 504.5461 504.6662 504.7863 504.9064 505.0264 505.1464 505.2664 505.3864 505.5064 505.6263 505.7463 505.8662 505.9861 506.1060 506.2258 506.3457 506.4655 506.5853 506.7051 506.8249 506.9447 507.0644 507.1842 507.3039 507.4236 507.5433 507.6629 507.7826 507.9022 508.0218 508.1414 508.2610 508.3805 508.5001 508.6196 508.7391 508.8586 508.9780 509.0975 509.2169 509.3363 509.4557 509.5751 509.6945 509.8138 509.9332 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-249: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 250-398: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241125T132855.0Z 9095.561748 240 1 46.07 2 79.58 129.33 41.57 189.37 0.00 1 0.00 1 0 22 1.945e-03 1.934e-03 8.229e-04 8.216e-04 3.701310e+03 5.884028e+01 2.545388e+02 -6.000000e+00 1.248967e+02 278.12 -2.00 20.00 -2.00 505.26 0.00e+00 1.222241e-03 2.430754e-05 6.963758e-05 -6.000000e+00 5.844372e-05 278.12 -2.00 20.00 -2.00 500.46 0.00e+00 3.981580e-01 1.769263e-02 3.165550e-02 -6.000000e+00 4.208103e-02 223.05 -2.00 3.49 -2.00 502.05 0.00e+00 5.311 0.003 489.00 513.00 1 5.6703e+00 1.3713e-03 8.0174e-03 -6.0000e+00 3.2614e-03 1.2818e-02 3.3160e-04 8.1210e-04 -6.0000e+00 8.0139e-04 3.0786e-03 2.8380e-03 1.3189e-04 4.3578e-05 -6.0000e+00 3.2672e-04 -1.6711e-02 -1.4412e-04 10 0 0 10 0 0 99.72 18.62 0.89 -0.01671 0.00297 47 14 1 4 0 979.960 21.98 15.00 18.62 8.10 30.2 888.63 -213 5 229 14 10 76 243 270 111 49 209 119 56 -111 -66 -214 69 122 86 -35 -59 56 215 238 177 282 227 152 -69 -263 -135 53 235 182 -35 -287 -246 -169 -55 30 67 25 76 92 -19 62 75 -7 -118 -279 -388 -294 -298 -185 -36 -166 -124 -37 -133 7 196 195 330 131 -57 -64 102 95 -68 -159 -192 -68 12 -67 -153 -262 -372 -205 -36 -150 -232 -215 -130 -42 -156 -280 -205 -146 -95 96 254 228 176 78 -14 -126 -114 -230 -154 -290 -358 -274 -218 -144 -359 -446 -332 -203 -63 249 78 287 166 119 256 374 466 265 466 80 197 305 433 337 171 96 79 217 123 254 65 -102 57 66 4 70 -77 65 -344 2 -46 80 12 -23 82 -3 -116 -292 -150 -205 5 225 14 11 77 248 278 114 50 211 119 57 -114 -67 -221 69 123 88 -37 -62 59 226 251 187 296 237 156 -70 -264 -135 53 237 187 -36 -301 -258 -176 -57 32 69 26 79 97 -19 63 78 -7 -120 -279 -382 -286 -290 -181 -36 -168 -127 -38 -133 7 196 196 342 135 -59 -65 102 94 -67 -155 -187 -66 12 -66 -150 -256 -361 -197 -34 -143 -223 -207 -126 -41 -153 -278 -204 -145 -95 96 256 231 178 79 -14 -123 -110 -219 -145 -272 -339 -263 -213 -143 -348 -434 -322 -197 -62 243 77 285 167 121 260 381 473 269 467 80 194 299 423 330 167 94 77 212 120 245 62 -97 54 63 4 68 -76 64 -346 2 -47 81 12 -23 83 -3 -115 -287 -147 SQ 20241125T133321.2Z 9095.564829 243 1 10.09 2 78.93 130.15 41.73 190.99 0.00 1 0.00 1 0 22 2.031e-03 2.021e-03 1.304e-03 1.303e-03 3.638445e+03 9.246348e+01 2.567060e+02 -6.000000e+00 1.304051e+02 278.12 -2.00 20.00 -2.00 505.27 0.00e+00 1.129428e-03 3.847397e-05 6.483160e-05 -6.000000e+00 6.101524e-05 278.12 -2.00 20.00 -2.00 500.51 0.00e+00 3.636418e-01 2.794826e-02 3.004921e-02 -6.000000e+00 4.392144e-02 223.05 -2.00 3.49 -2.00 502.09 0.00e+00 5.026 0.002 489.00 513.00 1 5.0939e+00 2.1640e-03 7.5865e-03 -6.0000e+00 3.4044e-03 1.1074e-02 5.2551e-04 7.8269e-04 -6.0000e+00 8.3591e-04 5.7223e-03 2.0659e-03 2.0930e-04 4.0895e-05 -6.0000e+00 3.4120e-04 -2.7204e-02 -3.3636e-05 12 1 1 12 1 1 93.90 18.62 0.90 -0.02720 -0.01287 9 14 1 4 0 1008.250 21.98 14.99 18.62 8.28 30.2 889.69 -81 -35 127 47 -31 62 375 331 268 198 181 96 -91 -146 -96 -199 -12 161 69 -89 7 159 156 310 35 271 220 173 36 -191 -148 -164 -12 161 123 -345 -180 -226 11 -38 145 63 126 -23 38 50 68 -23 5 -283 -358 -363 -311 -219 85 -23 -154 -141 -103 16 201 148 78 58 84 -117 -94 12 10 -248 -102 -147 76 38 -87 -273 -449 -259 -160 -37 -249 -277 -104 -57 -66 -143 -77 -242 9 94 223 399 252 108 90 -107 -155 -201 -291 -310 -456 -179 -131 -308 -321 -412 -395 -316 -94 200 225 67 72 142 204 300 476 300 410 213 301 393 246 248 254 120 161 243 285 181 58 -105 -218 -40 6 78 -14 76 -44 -100 223 198 72 -9 -96 -73 -16 -406 -245 -80 -34 125 48 -31 63 386 344 278 204 185 97 -91 -145 -95 -199 -12 165 72 -93 7 164 161 320 37 279 225 180 37 -194 -149 -166 -12 162 126 -355 -185 -231 12 -39 147 64 129 -24 39 52 70 -24 5 -285 -356 -357 -305 -216 85 -23 -154 -142 -104 16 205 151 80 58 84 -117 -96 12 10 -245 -100 -145 76 38 -87 -269 -440 -252 -155 -36 -241 -270 -102 -56 -66 -143 -75 -236 9 93 221 396 250 107 88 -106 -151 -193 -276 -294 -437 -174 -129 -301 -317 -408 -391 -313 -94 199 226 68 72 142 205 302 478 300 407 209 303 393 246 248 253 119 160 241 282 177 57 -102 -211 -38 6 77 -14 75 -44 -100 225 199 73 -9 -96 -72 -16 -395 -238 SQ 20241125T133835.6Z 9095.568468 246 1 45.87 2 78.18 131.13 41.96 192.90 0.00 1 0.00 1 0 22 1.855e-03 1.850e-03 2.718e-04 2.715e-04 3.411001e+03 1.921666e+01 2.391546e+02 -6.000000e+00 1.191440e+02 278.12 -2.00 20.00 -2.00 505.27 0.00e+00 1.055740e-03 8.015280e-06 6.044903e-05 -6.000000e+00 5.575401e-05 278.12 -2.00 20.00 -2.00 500.48 0.00e+00 3.239059e-01 5.825869e-03 2.834111e-02 -6.000000e+00 4.014827e-02 223.05 -2.00 3.49 -2.00 502.07 0.00e+00 4.730 0.002 489.00 513.00 1 3.6313e+00 4.5113e-04 7.1365e-03 -6.0000e+00 3.1115e-03 6.4185e-03 1.0950e-04 7.3499e-04 -6.0000e+00 7.6476e-04 2.5851e-02 3.3606e-03 4.3657e-05 3.7943e-05 -6.0000e+00 3.1164e-04 -1.4543e-02 -1.7516e-04 10 0 0 10 0 0 99.55 18.62 0.92 -0.01454 0.00877 217 67 1 4 0 211.310 21.98 15.00 18.62 8.53 30.1 891.79 -165 7 125 45 9 73 228 286 245 151 98 71 -4 -80 -108 -112 -25 94 75 -20 -40 95 236 320 331 224 193 91 -83 -218 -136 -34 162 187 28 -266 -369 -252 -117 12 59 104 99 149 120 88 4 -64 -140 -254 -375 -381 -343 -193 -91 -144 -148 -175 -108 20 191 224 260 145 81 -35 25 34 -72 -138 -170 -79 -26 -10 -125 -229 -291 -184 -98 -76 -61 -194 -232 -143 -99 -159 -168 -123 -64 56 204 312 245 52 -73 -84 -80 -142 -248 -315 -320 -227 -184 -176 -306 -443 -387 -209 -37 188 131 161 130 123 181 322 383 331 271 229 198 258 353 378 225 139 147 144 219 210 64 -117 -54 -49 23 63 -22 -78 -126 -45 -11 46 87 54 13 -38 -180 -202 -98 -162 7 125 45 9 76 233 293 251 154 99 73 -4 -81 -109 -114 -25 95 77 -21 -42 99 248 337 348 234 201 94 -84 -219 -136 -34 164 191 28 -271 -377 -263 -121 12 61 108 100 152 123 90 4 -66 -142 -254 -369 -370 -333 -189 -91 -145 -152 -176 -109 20 193 226 262 146 83 -35 25 34 -71 -135 -166 -77 -25 -10 -123 -224 -283 -177 -94 -73 -59 -187 -225 -140 -98 -158 -168 -123 -64 57 201 308 242 51 -73 -83 -78 -135 -235 -298 -305 -219 -181 -171 -300 -437 -381 -206 -37 186 131 162 132 123 182 323 384 331 276 231 199 257 351 375 223 138 146 142 215 205 63 -113 -52 -47 23 62 -22 -76 -125 -45 -11 46 88 54 13 -38 -176 -202 -97 SQ 20241125T134311.8Z 9095.571665 249 1 45.89 2 77.52 132.01 42.18 194.56 0.00 1 0.00 1 0 15 1.913e-03 1.911e-03 4.024e-04 4.020e-04 3.251998e+03 2.825389e+01 2.304098e+02 -6.000000e+00 1.228594e+02 278.12 -2.00 20.00 -2.00 505.27 0.00e+00 1.028207e-03 1.185133e-05 5.880776e-05 -6.000000e+00 5.749845e-05 278.12 -2.00 20.00 -2.00 500.48 0.00e+00 2.986674e-01 8.625592e-03 2.666456e-02 -6.000000e+00 4.140810e-02 223.05 -2.00 3.49 -2.00 502.07 0.00e+00 4.500 0.002 489.00 513.00 1 4.3975e+00 6.6823e-04 6.7869e-03 -6.0000e+00 3.2090e-03 6.6687e-03 1.6247e-04 6.9641e-04 -6.0000e+00 7.8900e-04 1.2434e-02 3.7480e-03 6.4669e-05 3.7011e-05 -6.0000e+00 3.2130e-04 -1.3760e-02 -2.0349e-04 10 0 0 10 0 0 99.95 18.62 0.95 -0.01376 0.01224 165 51 1 4 0 277.920 21.98 15.00 18.62 8.80 30.1 892.97 -139 16 164 13 33 49 271 321 199 106 125 51 35 -111 -140 -83 -23 63 88 11 -17 142 224 337 315 255 144 177 -78 -153 -157 -39 181 213 -59 -290 -372 -225 -128 -20 61 27 125 146 105 33 -22 -71 -97 -301 -427 -412 -412 -238 -71 -125 -149 -191 -104 33 194 253 293 151 92 -6 2 0 -62 -170 -102 -138 -2 -39 -98 -191 -278 -220 -74 -110 -4 -207 -189 -144 -125 -171 -170 -163 -66 105 214 270 211 70 -80 -53 -97 -141 -224 -334 -345 -228 -199 -216 -372 -436 -368 -180 -48 160 161 154 111 117 204 285 393 345 271 180 180 297 349 383 255 183 91 222 223 248 38 -85 -26 -31 38 56 -3 -68 -138 -38 65 30 54 48 74 -77 -170 -201 -165 -135 15 162 13 33 50 279 333 206 109 128 52 35 -110 -139 -83 -23 64 92 11 -18 151 237 358 334 270 151 183 -80 -155 -158 -40 185 220 -60 -296 -381 -229 -130 -21 61 28 127 150 107 34 -22 -71 -100 -304 -423 -404 -404 -235 -71 -127 -148 -193 -105 34 196 256 296 152 92 -6 2 0 -62 -168 -101 -136 -2 -39 -97 -189 -272 -214 -71 -106 -3 -201 -185 -142 -124 -171 -165 -158 -65 103 211 267 209 69 -78 -53 -95 -135 -214 -318 -331 -222 -191 -210 -366 -430 -363 -177 -47 158 161 156 113 120 204 285 392 343 277 182 181 296 347 380 253 182 91 220 219 242 37 -83 -25 -30 37 55 -3 -66 -136 -38 65 30 54 48 74 -76 -166 -201 -163 SQ 20241125T134924.6Z 9095.575979 252 1 45.90 2 76.65 133.20 42.52 196.78 0.00 1 0.00 1 0 22 1.978e-03 1.977e-03 1.769e-04 1.768e-04 3.040067e+03 1.235674e+01 2.126624e+02 -6.000000e+00 1.270371e+02 278.12 -2.00 20.00 -2.00 505.27 0.00e+00 9.571672e-04 5.205032e-06 5.452233e-05 -6.000000e+00 5.945072e-05 278.12 -2.00 20.00 -2.00 500.50 0.00e+00 2.614657e-01 3.780866e-03 2.574407e-02 -6.000000e+00 4.281274e-02 223.05 -2.00 3.49 -2.00 502.08 0.00e+00 4.226 0.001 489.00 513.00 1 2.8380e+00 2.9271e-04 6.3885e-03 -6.0000e+00 3.3179e-03 4.1262e-03 7.1200e-05 6.6278e-04 -6.0000e+00 8.1565e-04 6.1677e-02 3.6381e-03 2.8574e-05 3.3675e-05 -6.0000e+00 3.3225e-04 -1.3854e-02 -1.9291e-04 10 0 0 10 0 0 99.87 18.62 0.91 -0.01385 0.01138 675 207 1 4 0 67.980 21.98 15.00 18.62 9.00 30.0 894.02 -232 -31 100 39 -15 59 258 319 238 149 125 84 1 -131 -106 -111 -34 86 84 11 -20 114 277 352 358 242 188 103 -89 -188 -187 -38 139 194 26 -279 -345 -254 -114 13 65 96 123 150 136 100 10 -80 -127 -282 -405 -441 -351 -217 -115 -101 -156 -161 -80 60 207 283 285 191 95 17 9 4 -68 -177 -182 -87 -31 -36 -99 -251 -337 -218 -127 -61 -75 -199 -204 -160 -137 -165 -186 -131 -63 72 195 303 260 71 -65 -88 -84 -161 -264 -357 -330 -214 -162 -172 -334 -463 -395 -195 -22 133 148 157 126 165 261 363 399 371 288 240 206 308 357 400 258 161 136 194 201 176 41 -84 -69 -79 -5 35 -31 -90 -92 -33 -3 71 93 71 31 -75 -195 -243 -138 -224 -30 99 40 -15 60 267 332 248 154 129 85 1 -131 -106 -111 -35 88 87 11 -20 117 286 363 370 249 192 104 -92 -191 -188 -39 142 195 26 -288 -356 -261 -116 13 66 98 126 155 141 103 10 -81 -127 -286 -404 -435 -345 -215 -115 -100 -157 -163 -81 61 212 289 290 194 96 17 9 4 -68 -175 -180 -86 -31 -36 -98 -249 -332 -213 -123 -59 -73 -195 -201 -154 -133 -161 -182 -129 -63 72 195 303 260 71 -64 -86 -80 -156 -254 -343 -320 -204 -157 -170 -333 -462 -394 -194 -22 133 150 156 126 166 264 368 404 374 288 238 202 301 348 390 251 157 133 189 201 174 40 -83 -67 -77 -5 33 -30 -89 -92 -33 -4 72 95 71 31 -75 -192 -237 -134 SQ 20241125T140758.6Z 9095.588872 259 1 9.30 2 74.16 136.86 43.78 203.21 0.00 1 0.00 1 0 15 2.030e-03 2.027e-03 1.412e-03 1.411e-03 3.009530e+03 9.849357e+01 2.054592e+02 -6.000000e+00 1.303470e+02 278.12 -2.00 20.00 -2.00 505.27 0.00e+00 8.370659e-04 4.157425e-05 4.994527e-05 -6.000000e+00 6.097974e-05 278.12 -2.00 20.00 -2.00 500.49 0.00e+00 2.201406e-01 3.025011e-02 2.694548e-02 -6.000000e+00 4.387028e-02 223.05 -2.00 3.49 -2.00 502.08 0.00e+00 3.600 0.001 489.00 513.00 1 5.3731e+00 2.3423e-03 5.6078e-03 -6.0000e+00 3.4011e-03 6.9498e-03 5.7025e-04 6.5580e-04 -6.0000e+00 8.3402e-04 5.3559e-03 9.3361e-05 2.2771e-04 3.1340e-05 -6.0000e+00 3.4122e-04 -2.4626e-02 3.4384e-05 12 1 1 12 1 1 75.31 18.62 0.90 -0.02463 -0.02398 8 14 1 4 0 1031.950 21.98 15.00 18.62 9.43 29.9 895.58 -6 152 197 -118 34 -84 254 319 131 137 56 116 42 -81 -118 39 -55 219 66 -43 -117 -118 104 279 234 207 166 -19 31 -229 -18 -46 349 198 -65 -124 -190 -217 -251 -24 144 164 166 267 140 -89 61 -76 -106 -190 -380 -204 -390 -203 -156 -180 -277 -195 -51 -12 141 277 266 -98 117 -97 -60 233 12 49 -148 -3 -89 -219 -131 -239 -379 -273 -53 -25 -151 -232 -74 -84 -303 -155 -176 -174 -208 20 298 325 260 -21 -84 -68 14 -197 -301 -320 -269 -387 -12 -296 -402 -514 -346 -72 52 149 156 200 190 265 234 426 411 430 214 288 151 407 115 316 171 -12 198 222 236 297 141 -135 -28 -44 24 28 61 13 -74 -293 86 104 27 -109 -17 -19 -327 -174 42 -6 148 195 -121 34 -86 265 334 138 143 58 118 43 -82 -119 39 -56 226 67 -44 -121 -123 109 290 244 214 171 -19 31 -233 -18 -46 347 200 -67 -128 -196 -223 -258 -24 147 168 171 276 146 -92 63 -77 -106 -193 -379 -201 -384 -201 -157 -179 -279 -197 -51 -12 144 282 271 -100 118 -97 -59 233 12 48 -146 -3 -89 -218 -130 -236 -373 -266 -52 -24 -147 -227 -73 -83 -294 -150 -172 -171 -205 20 296 324 260 -21 -83 -66 14 -190 -289 -306 -259 -379 -11 -291 -399 -512 -344 -72 52 148 157 197 190 266 236 430 414 431 213 284 148 408 112 316 166 -11 197 220 233 291 138 -131 -27 -42 23 27 59 13 -74 -293 86 105 27 -109 -17 -19 -320 -168 41 SQ 20241125T141243.3Z 9095.592167 262 1 45.91 2 73.55 137.82 44.16 204.80 0.00 1 0.00 1 0 15 1.861e-03 1.864e-03 2.419e-04 2.417e-04 3.085828e+03 1.690098e+01 2.168628e+02 -6.000000e+00 1.194942e+02 278.12 -2.00 20.00 -2.00 505.26 0.00e+00 8.836211e-04 7.114850e-06 5.104190e-05 -6.000000e+00 5.591858e-05 278.12 -2.00 20.00 -2.00 500.49 0.00e+00 1.843971e-01 5.174749e-03 2.564516e-02 -6.000000e+00 4.026741e-02 223.05 -2.00 3.49 -2.00 502.07 0.00e+00 3.475 0.001 489.00 513.00 1 3.5861e+00 4.0047e-04 5.4220e-03 -6.0000e+00 3.1207e-03 1.0833e-03 9.7526e-05 6.4013e-04 -6.0000e+00 7.6705e-04 3.2597e-02 3.3845e-03 3.9082e-05 3.1514e-05 -6.0000e+00 3.1255e-04 -1.6447e-02 -1.6611e-04 10 0 0 10 0 0 99.73 18.62 0.90 -0.01645 0.00703 307 94 1 4 0 149.500 21.98 14.99 18.62 9.39 30.0 895.91 -144 -7 113 21 -12 61 261 316 219 133 115 84 20 -103 -78 -97 -28 60 87 -16 -64 90 235 342 327 265 192 124 -60 -183 -153 -40 178 213 1 -288 -372 -225 -105 -25 85 71 100 125 127 45 -33 -69 -135 -250 -391 -412 -311 -196 -99 -107 -153 -148 -103 30 169 236 225 168 41 -13 2 24 -50 -183 -145 -58 -7 -18 -74 -246 -299 -189 -104 -34 -82 -189 -180 -152 -125 -156 -181 -127 -66 72 200 277 230 61 -62 -82 -116 -171 -236 -309 -317 -191 -131 -195 -323 -467 -381 -198 -23 155 160 145 127 137 205 310 373 342 259 214 206 299 317 409 251 172 150 191 206 197 70 -80 -71 -39 9 69 -48 -92 -114 -47 -11 44 85 91 35 -37 -184 -205 -118 -140 -7 112 20 -12 63 271 330 229 138 118 85 20 -104 -78 -98 -29 62 89 -16 -66 93 244 355 339 274 197 126 -60 -187 -155 -41 177 215 1 -297 -385 -232 -107 -25 87 73 103 129 133 46 -35 -70 -135 -246 -391 -407 -307 -195 -97 -107 -154 -150 -105 31 173 242 230 170 41 -13 2 24 -50 -182 -144 -58 -7 -18 -71 -245 -295 -184 -101 -33 -80 -186 -173 -147 -122 -153 -178 -125 -65 71 200 279 231 61 -61 -80 -112 -167 -227 -297 -308 -183 -128 -193 -322 -468 -382 -198 -23 152 158 144 128 139 208 316 379 346 260 213 203 293 310 399 246 168 146 186 199 190 69 -79 -70 -38 8 66 -47 -92 -114 -48 -11 43 84 89 36 -37 -181 -201 -115 SQ 20241125T141756.5Z 9095.595793 265 1 9.37 2 72.89 138.90 44.60 206.53 0.00 1 0.00 1 0 22 2.750e-03 2.755e-03 2.869e-03 2.866e-03 3.114736e+03 2.008051e+02 2.253279e+02 -6.000000e+00 1.766303e+02 278.12 -2.00 20.00 -2.00 505.24 0.00e+00 9.460667e-04 8.461106e-05 5.384393e-05 -6.000000e+00 8.289945e-05 278.12 -2.00 20.00 -2.00 500.42 0.00e+00 2.581281e-01 6.163415e-02 1.931509e-02 -6.000000e+00 5.994319e-02 223.05 -2.00 3.49 -2.00 502.01 0.00e+00 3.349 0.001 489.00 513.00 1 6.6013e+00 4.7717e-03 5.1059e-03 -6.0000e+00 4.6355e-03 4.6571e-03 1.1673e-03 5.4177e-04 -6.0000e+00 1.1570e-03 1.6162e-03 1.7444e-02 4.6302e-04 3.6769e-05 -6.0000e+00 4.6240e-04 -7.8831e-03 -8.5966e-04 12 1 1 12 1 1 99.16 18.62 0.85 -0.00788 0.11311 3 6 1 4 0 2341.890 21.98 15.00 18.62 9.42 30.0 896.62 900000 -375 160 258 223 393 238 432 56 100 -75 193 -77 -169 -292 -45 235 -224 412 294 68 45 129 500 255 -100 345 3 -151 -777 -267 68 615 -35 -479 -187 176 -446 -88 376 260 71 259 10 -305 193 8 -180 3 -338 -489 -100 -293 -297 -47 -252 -277 -277 38 -151 270 107 177 35 -125 -66 465 -190 325 -250 -218 -66 138 150 -258 -176 -336 126 -93 -145 -288 -477 -444 67 -230 -191 -145 -242 -247 60 386 57 219 226 5 148 -266 -549 -73 -352 -421 -113 -110 -561 -39 -293 -453 -34 -216 257 -13 -36 202 311 218 220 600 227 604 225 86 372 211 132 452 73 186 135 401 507 245 83 -190 100 -122 -174 315 -42 -524 -259 84 -35 -253 -41 384 180 -214 -19 -220 900000 -372 161 255 225 404 248 453 59 104 -77 196 -78 -170 -293 -46 239 -232 430 311 70 46 133 516 264 -103 352 3 -156 -797 -271 69 630 -36 -491 -192 180 -458 -90 380 263 73 265 10 -316 199 9 -183 3 -343 -489 -98 -288 -295 -47 -249 -277 -280 38 -154 274 108 180 35 -125 -66 470 -191 323 -248 -215 -66 137 149 -257 -174 -331 123 -90 -140 -281 -468 -438 66 -222 -185 -141 -236 -243 59 380 57 217 223 5 142 -261 -533 -70 -337 -406 -110 -105 -548 -38 -290 -448 -33 -214 254 -13 -36 206 308 217 220 596 226 614 227 86 370 209 131 449 72 185 134 394 493 237 80 -183 96 -118 -171 311 -40 -516 -257 84 -35 -253 -41 377 175 -207 -19 -218 SQ 20241125T182518.3Z 9095.767573 407 1 46.01 2 64.05 200.35 82.85 261.36 0.00 1 0.00 1 0 15 3.348e-03 3.318e-03 2.546e-03 2.539e-03 2.720399e+03 1.777679e+02 1.869065e+02 -6.000000e+00 2.149767e+02 278.10 -2.00 20.00 -2.00 505.20 0.00e+00 6.459946e-04 7.447478e-05 3.818726e-05 -6.000000e+00 1.005844e-04 278.10 -2.00 20.00 -2.00 500.32 0.00e+00 2.112439e-01 5.494330e-02 2.324975e-02 -6.000000e+00 7.239058e-02 223.05 -2.00 3.49 -2.00 501.91 0.00e+00 2.272 0.000 489.00 513.00 1 8.0367e+00 4.2545e-03 3.8128e-03 -6.0000e+00 5.6115e-03 1.0348e-02 1.0391e-03 5.4924e-04 -6.0000e+00 1.3770e-03 4.5022e-04 1.2361e-03 4.0943e-04 2.2709e-05 -6.0000e+00 5.6262e-04 -2.9958e-02 2.1932e-05 10 0 0 10 0 0 98.62 18.62 0.86 -0.02996 -0.02138 19 6 1 4 0 2420.900 21.98 15.00 18.62 19.84 31.1 963.39 -213 85 256 -287 301 109 229 273 -120 -625 247 170 -66 58 -101 -424 70 228 440 149 -62 28 -66 180 -109 -166 384 815 309 -292 -481 -19 495 260 -212 53 -29 79 -241 185 -274 -100 -95 418 110 -126 -108 63 -113 -165 -421 57 -416 -338 473 -363 -230 386 180 -321 226 -25 407 -197 -257 -153 296 551 -173 -297 -325 -330 245 -23 -345 -272 -604 10 394 -104 -435 -837 148 146 -42 -494 -410 -227 -202 46 798 160 218 373 -297 195 -269 -349 -299 -81 -567 -424 -369 -331 -158 -217 -601 189 -177 19 461 45 463 381 -110 408 708 297 724 -5 -262 472 467 190 46 227 -281 308 466 640 186 -23 255 234 169 -113 116 241 -1174 205 400 67 -59 -243 -27 -88 -307 -359 -364 -214 86 263 -286 304 112 240 287 -126 -658 255 173 -67 58 -102 -429 72 236 460 157 -66 30 -71 193 -117 -178 406 846 317 -297 -488 -19 506 270 -224 56 -31 84 -254 194 -288 -105 -101 443 117 -134 -114 66 -115 -165 -417 55 -406 -332 468 -368 -236 398 187 -336 236 -26 422 -204 -265 -156 296 543 -170 -291 -317 -323 239 -23 -339 -265 -587 9 375 -100 -417 -811 143 143 -41 -490 -408 -227 -203 46 801 162 221 376 -298 192 -260 -333 -283 -76 -539 -409 -362 -329 -159 -219 -575 189 -169 18 443 44 453 376 -110 405 700 293 706 -5 -254 450 444 182 44 216 -268 291 438 596 173 -21 247 215 156 -106 109 231 -1152 200 392 66 -58 -240 -26 -85 -294 -340 -344