File name: Pandora187s1_PittsburghPA_20250521_L2Fit_fout2c5d20230706p1-8.txt
File generation date: 20250522T052451.5Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c5p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 187
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora187_OF_v4d20210517.txt
Instrument calibration file used: Pandora187s1_CF_v5d20230706.txt
Level 1 file used: Pandora187s1_PittsburghPA_20250521_L1_smca1c5d20230706p1-8.txt
Full location name: Pittsburgh, PA - Lawrenceville ACHD (USEPA AQS ID 42-003-0008)
Short location name: PittsburghPA
Country of location: United States
Location latitude [deg]: 40.4655
Location longitude [deg]: -79.9608
Location altitude [m]: 265
Local noon date: 20250521
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 194 335
Nominal wavelengths inside fitting window [nm]: 305.0595 305.2010 305.3424 305.4838 305.6252 305.7666 305.9080 306.0494 306.1908 306.3321 306.4735 306.6148 306.7561 306.8974 307.0387 307.1800 307.3213 307.4626 307.6038 307.7451 307.8863 308.0275 308.1687 308.3099 308.4511 308.5923 308.7335 308.8746 309.0158 309.1569 309.2980 309.4391 309.5802 309.7213 309.8624 310.0035 310.1445 310.2856 310.4266 310.5676 310.7086 310.8496 310.9906 311.1316 311.2726 311.4135 311.5545 311.6954 311.8363 311.9772 312.1181 312.2590 312.3999 312.5408 312.6816 312.8225 312.9633 313.1041 313.2449 313.3857 313.5265 313.6673 313.8080 313.9488 314.0895 314.2303 314.3710 314.5117 314.6524 314.7931 314.9338 315.0744 315.2151 315.3557 315.4963 315.6370 315.7776 315.9182 316.0587 316.1993 316.3399 316.4804 316.6210 316.7615 316.9020 317.0425 317.1830 317.3235 317.4640 317.6044 317.7449 317.8853 318.0257 318.1662 318.3066 318.4470 318.5873 318.7277 318.8681 319.0084 319.1488 319.2891 319.4294 319.5697 319.7100 319.8503 319.9905 320.1308 320.2710 320.4113 320.5515 320.6917 320.8319 320.9721 321.1123 321.2524 321.3926 321.5327 321.6728 321.8130 321.9531 322.0932 322.2333 322.3733 322.5134 322.6534 322.7935 322.9335 323.0735 323.2135 323.3535 323.4935 323.6335 323.7734 323.9134 324.0533 324.1932 324.3332 324.4731 324.6129 324.7528 324.8927
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250521T133035.8Z 9272.562914 238 1 45.80 2 51.74 95.27 50.61 201.37 0.00 1 0.00 1 0 17 1.240e-02 7.048e-03 6.910e-03 2.059e-03 2.528199e-01 1.066365e-03 3.078935e-03 -6.000000e+00 7.320737e-03 231.31 -2.00 3.49 -2.00 317.39 0.00e+00 6.917227e-04 1.565056e-04 1.407899e-04 -6.000000e+00 3.178552e-04 283.16 -2.00 20.00 -2.00 316.67 0.00e+00 1.611 0.000 302.00 328.00 3 4.5268e+00 2.8318e-03 2.0726e-02 -6.0000e+00 1.8343e-02 3.0121e-02 3.1678e-03 1.3411e-02 -6.0000e+00 1.9793e-02 1.6611e-03 1.9218e-03 6.5091e-03 -6.0000e+00 1.1758e-02 -7.5375e-03 9.5631e-04 1.9353e-03 -6.0000e+00 5.0118e-03 8.5706e-04 2.2417e-04 6.0737e-05 2.2378e-05 -6.0000e+00 3.4548e-04 -1.8083e-02 3.5973e-06 11 8 0 10 0 0 99.99 19.03 0.34 -0.01808 -0.01640 90 28 1 5 0 508.510 22.40 15.00 19.03 21.06 32.0 993.99 521 -1506 -753 -5122 -3973 -2735 -1197 -1527 -413 -2373 -4253 -2359 -1341 -863 -757 -412 -796 1267 -731 1845 711 20 -5 1590 651 -419 -751 -1266 -858 474 690 1222 3475 -608 -3229 -2637 -1662 -1636 -719 -1212 -1246 -880 -436 -67 203 -36 298 -76 -848 484 719 619 757 1102 1002 1593 1393 820 499 1119 1313 1804 2185 1541 90 -621 -364 -632 -3254 482 193 457 520 726 227 -193 -183 -713 -1568 -891 -899 -1177 -2171 -1515 -686 -669 -508 407 475 583 416 118 -79 377 55 46 599 550 79 -496 -342 -935 -8 171 -989 -783 -513 -333 362 390 172 278 371 123 -31 124 -85 -106 -25 -339 -565 -44 3 85 220 -163 666 1465 1080 946 662 549 329 437 184 -390 9 -333 -424 -315 -431 -842 52 -168 -86 -578 -394 -254 -115 -163 -49 -300 -545 -302 -189 -139 -139 -83 -168 272 -167 424 168 5 -1 397 172 -116 -208 -332 -230 123 189 359 1078 -201 -1031 -822 -559 -583 -303 -598 -670 -493 -250 -38 116 -21 166 -42 -457 259 405 373 482 734 687 1106 983 578 346 770 935 1375 1798 1345 78 -501 -273 -467 -2660 428 187 456 514 686 199 -153 -131 -496 -1169 -743 -839 -1207 -2185 -1593 -768 -799 -636 518 599 699 459 129 -81 377 60 50 722 727 109 -664 -426 -1080 -9 199 -1261 -1047 -716 -485 554 583 269 431 591 181 -43 160 -111 -147 -37 -535 -900 -68 4 122 299 -211 826 1857 1472 1373 1003 850 522 672 300 -666 15 -591 -748 -538 -709 -1346
SS 20250521T133509.6Z 9272.566083 241 1 15.31 2 50.87 96.08 50.91 202.74 0.00 1 0.00 1 0 17 1.126e-02 6.958e-03 7.073e-03 2.754e-03 2.500992e-01 1.430543e-03 3.047602e-03 -6.000000e+00 6.645823e-03 231.31 -2.00 3.49 -2.00 316.75 0.00e+00 6.347987e-04 1.770431e-04 6.937910e-05 -6.000000e+00 2.885403e-04 283.16 -2.00 20.00 -2.00 316.04 0.00e+00 1.581 0.000 302.00 328.00 3 4.3586e+00 3.7591e-03 2.0367e-02 -6.0000e+00 1.6652e-02 3.7699e-02 4.1900e-03 1.3148e-02 -6.0000e+00 1.7968e-02 -6.8801e-03 2.4570e-03 6.4113e-03 -6.0000e+00 1.0674e-02 -3.6340e-03 1.1794e-03 1.8633e-03 -6.0000e+00 4.5500e-03 1.0475e-03 1.4347e-04 8.0370e-05 2.1806e-05 -6.0000e+00 3.1358e-04 -1.8384e-02 6.3736e-06 12 9 1 12 1 1 99.02 19.03 0.27 -0.01838 -0.01731 12 12 1 5 0 1176.950 22.40 14.99 19.03 21.50 32.0 997.14 1537 -452 1932 -4334 -4370 -910 -1892 646 -1923 -340 -2765 329 -1496 91 -737 -241 -452 1504 332 2555 463 -546 802 738 965 101 -214 -486 501 516 1125 4 2501 -1566 -3306 -3435 -2246 -1802 -1291 -928 -1494 -786 -564 270 -28 433 -124 -468 -798 188 552 564 779 1156 1227 1226 1297 207 892 610 1475 1432 1831 1175 313 -841 -431 -129 545 -10 261 245 -95 717 204 568 -516 -564 -479 -859 -1090 -1128 -2392 -1249 -893 -875 -354 299 662 291 406 -331 275 67 152 -563 883 480 173 -332 -384 -1025 296 203 -1143 -1144 -646 -285 432 650 346 362 402 198 46 43 -400 -34 -97 -330 -455 -25 88 113 406 -181 628 1156 893 1032 670 557 394 271 148 -420 -47 -327 -593 -195 -446 -629 207 -68 294 -664 -596 -113 -249 92 -312 -57 -474 56 -286 19 -182 -65 -128 433 100 781 147 -174 257 249 340 37 -79 -169 160 162 370 1 942 -629 -1269 -1295 -912 -770 -656 -546 -884 -482 -355 170 -18 270 -76 -305 -512 120 370 371 539 836 912 928 995 159 669 458 1138 1187 1638 1029 272 -735 -350 -102 463 -9 251 244 -95 675 193 480 -400 -422 -380 -770 -1012 -1147 -2612 -1418 -1006 -1052 -445 383 838 353 486 -362 276 67 161 -666 1062 635 238 -445 -479 -1187 354 237 -1463 -1538 -905 -388 617 982 546 566 597 271 62 56 -528 -47 -135 -485 -676 -37 123 162 550 -235 777 1468 1217 1493 944 802 582 420 228 -677 -77 -548 -990 -314 -740 -1011
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