File name: Pandora187s1_PittsburghPA_20250824_L2Fit_fwvt1c5d20230706p1-8.txt
File generation date: 20250825T053022.1Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c5p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 187
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora187_OF_v4d20210517.txt
Instrument calibration file used: Pandora187s1_CF_v5d20230706.txt
Level 1 file used: Pandora187s1_PittsburghPA_20250824_L1_smca1c5d20230706p1-8.txt
Full location name: Pittsburgh, PA - Lawrenceville ACHD (USEPA AQS ID 42-003-0008)
Short location name: PittsburghPA
Country of location: United States
Location latitude [deg]: 40.4655
Location longitude [deg]: -79.9608
Location altitude [m]: 265
Local noon date: 20250824
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1607 1755
Nominal wavelengths inside fitting window [nm]: 492.0774 492.1992 492.3211 492.4429 492.5647 492.6865 492.8082 492.9300 493.0517 493.1735 493.2952 493.4168 493.5385 493.6602 493.7818 493.9034 494.0250 494.1466 494.2682 494.3897 494.5113 494.6328 494.7543 494.8758 494.9972 495.1187 495.2401 495.3615 495.4829 495.6043 495.7257 495.8470 495.9684 496.0897 496.2110 496.3323 496.4535 496.5748 496.6960 496.8172 496.9384 497.0596 497.1807 497.3019 497.4230 497.5441 497.6652 497.7863 497.9074 498.0284 498.1494 498.2704 498.3914 498.5124 498.6334 498.7543 498.8752 498.9961 499.1170 499.2379 499.3588 499.4796 499.6004 499.7212 499.8420 499.9628 500.0835 500.2043 500.3250 500.4457 500.5664 500.6870 500.8077 500.9283 501.0489 501.1695 501.2901 501.4107 501.5312 501.6518 501.7723 501.8928 502.0133 502.1337 502.2542 502.3746 502.4950 502.6154 502.7358 502.8561 502.9765 503.0968 503.2171 503.3374 503.4577 503.5779 503.6982 503.8184 503.9386 504.0588 504.1790 504.2991 504.4193 504.5394 504.6595 504.7796 504.8996 505.0197 505.1397 505.2597 505.3797 505.4997 505.6197 505.7396 505.8595 505.9795 506.0994 506.2192 506.3391 506.4589 506.5788 506.6986 506.8184 506.9381 507.0579 507.1776 507.2974 507.4171 507.5367 507.6564 507.7761 507.8957 508.0153 508.1349 508.2545 508.3741 508.4936 508.6132 508.7327 508.8522 508.9716 509.0911 509.2105 509.3300 509.4494 509.5688 509.6882 509.8075 509.9269
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-249: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 250-398: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250824T112549.2Z 9367.476264 61 1 9.83 2 82.26 82.23 96.85 77.33 0.00 1 0.00 1 0 22 2.640e-03 2.631e-03 1.794e-04 1.792e-04 1.136210e+04 1.459843e+01 7.232871e+02 -6.000000e+00 1.765596e+02 288.57 -2.00 20.00 -2.00 505.32 0.00e+00 1.143069e-03 5.458167e-06 7.987592e-05 -6.000000e+00 8.126023e-05 288.57 -2.00 20.00 -2.00 500.62 0.00e+00 6.136990e-01 3.822127e-03 7.828823e-02 -6.000000e+00 5.723349e-02 230.90 -2.00 3.49 -2.00 502.19 0.00e+00 6.903 0.006 489.00 513.00 1 1.3194e+00 2.9664e-04 1.1820e-02 -6.0000e+00 4.4508e-03 -2.6278e-02 7.1019e-05 1.9070e-03 -6.0000e+00 1.0905e-03 1.8587e-01 8.4704e-04 2.6869e-05 3.9241e-05 -6.0000e+00 4.4430e-04 -7.9857e-03 -6.4893e-05 10 0 0 10 0 0 -103.62 17.82 1.53 -0.00799 -0.00211 534 164 1 4 0 17.790 21.27 14.99 17.82 28.15 32.9 963.08 -409 -148 37 92 101 192 388 458 347 181 147 30 -56 -208 -191 -165 -63 84 126 55 -11 139 304 395 399 325 203 50 -196 -363 -330 -154 92 238 103 -161 -312 -243 -161 -16 69 121 194 230 241 142 74 -21 -165 -390 -542 -584 -486 -282 -97 -79 -77 -93 -27 174 347 413 400 288 127 -17 -32 -43 -183 -267 -269 -144 -82 -30 -134 -347 -460 -380 -280 -213 -189 -233 -239 -193 -143 -167 -208 -134 -3 183 377 486 457 201 7 -76 -110 -158 -344 -522 -528 -371 -206 -189 -330 -534 -539 -360 -104 123 193 225 235 298 428 518 579 469 292 163 135 242 400 487 355 195 157 127 158 113 -52 -224 -176 -93 -27 15 -11 -72 -19 81 74 103 126 102 35 -66 -238 -278 -198 -386 -141 36 91 99 192 394 468 355 184 148 30 -56 -206 -189 -164 -64 86 127 56 -11 143 314 408 412 334 208 51 -197 -360 -325 -153 92 241 106 -163 -315 -245 -166 -17 71 122 197 234 247 145 75 -21 -168 -391 -536 -572 -475 -278 -97 -80 -77 -94 -27 177 354 422 407 292 128 -17 -33 -44 -183 -265 -267 -142 -82 -29 -134 -344 -454 -372 -272 -206 -184 -228 -236 -192 -143 -163 -204 -132 -3 180 372 479 448 200 7 -73 -103 -150 -325 -496 -493 -354 -201 -184 -327 -536 -543 -363 -105 125 192 225 236 302 436 530 593 480 298 165 135 241 396 482 351 194 156 126 156 111 -51 -224 -176 -91 -27 15 -11 -72 -19 83 77 106 131 105 36 -68 -241 -280 -199
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SQ 20250824T112609.3Z 9367.476496 61 3 9.78 2 82.19 82.28 96.79 77.38 0.00 1 0.00 1 0 22 2.635e-03 2.626e-03 1.789e-04 1.787e-04 1.127847e+04 1.454588e+01 7.201979e+02 -6.000000e+00 1.761682e+02 288.57 -2.00 20.00 -2.00 505.32 0.00e+00 1.130278e-03 5.441645e-06 7.883714e-05 -6.000000e+00 8.108153e-05 288.57 -2.00 20.00 -2.00 500.62 0.00e+00 5.968252e-01 3.811408e-03 7.755096e-02 -6.000000e+00 5.710937e-02 230.90 -2.00 3.49 -2.00 502.19 0.00e+00 6.855 0.006 489.00 513.00 1 1.3236e+00 2.9580e-04 1.1728e-02 -6.0000e+00 4.4411e-03 -2.5982e-02 7.0848e-05 1.8931e-03 -6.0000e+00 1.0882e-03 1.8661e-01 8.8465e-04 2.6813e-05 3.8668e-05 -6.0000e+00 4.4332e-04 -4.1569e-03 -9.2593e-05 10 0 0 10 0 0 -167.95 17.82 1.53 -0.00416 0.00198 534 164 1 4 0 17.790 21.27 14.99 17.82 28.15 32.9 963.96 -422 -150 41 104 80 192 395 458 340 201 117 24 -71 -191 -164 -143 -49 81 146 39 15 153 296 386 421 290 192 73 -179 -352 -333 -126 82 220 98 -190 -326 -268 -154 -2 63 137 191 235 234 153 81 -55 -181 -374 -540 -588 -482 -296 -113 -69 -57 -82 -28 123 331 414 388 268 114 -5 -38 -46 -147 -265 -246 -141 -74 -38 -165 -350 -456 -374 -286 -208 -167 -236 -251 -173 -126 -161 -188 -113 12 214 353 481 450 228 -3 -70 -108 -169 -344 -552 -528 -355 -207 -179 -333 -544 -551 -390 -110 115 177 231 246 256 404 548 591 458 315 151 141 216 376 482 362 223 159 153 168 116 -47 -202 -157 -89 -41 12 -30 -73 -2 58 71 112 117 134 55 -62 -232 -304 -226 -399 -142 40 103 78 193 401 468 348 205 118 25 -70 -189 -162 -142 -49 83 146 39 15 158 305 399 435 299 196 74 -179 -348 -328 -125 82 223 99 -192 -331 -271 -160 -2 65 138 193 240 240 157 82 -56 -185 -375 -534 -576 -471 -291 -112 -70 -57 -83 -29 125 338 422 395 272 115 -5 -39 -46 -147 -264 -244 -140 -74 -38 -165 -348 -450 -366 -278 -202 -162 -231 -247 -172 -126 -157 -184 -111 12 210 348 473 441 221 -2 -67 -102 -161 -326 -525 -494 -339 -203 -174 -331 -546 -555 -393 -111 117 175 231 248 260 411 560 605 470 321 153 142 215 373 477 359 221 158 151 166 114 -46 -197 -157 -87 -40 12 -30 -73 -2 59 74 116 122 139 57 -63 -235 -306 -228
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