File name: Pandora53s1_Potchefstroom-METSI_20230827_L2Fit_fwvt1c0d20220413p1-8.txt File generation date: 20230827T222101.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c0p1-8 Local principal investigator: Stuart Piketh Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 53 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora53_OF_v5d20210210.txt Instrument calibration file used: Pandora53s1_CF_v103d20220413.txt Level 1 file used: Pandora53s1_Potchefstroom-METSI_20230827_L1_smca1c0d20220413p1-8.txt Full location name: Gerhard Minnebron Mooi River Ecosystem Trails for Scientific Investigations Short location name: Potchefstroom-METSI Country of location: South Africa Location latitude [deg]: -26.4907 Location longitude [deg]: 27.1322 Location altitude [m]: 1440 Local noon date: 20230827 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1683 1833 Nominal wavelengths inside fitting window [nm]: 492.0454 492.1661 492.2868 492.4075 492.5281 492.6487 492.7693 492.8899 493.0105 493.1311 493.2516 493.3722 493.4927 493.6132 493.7337 493.8541 493.9746 494.0950 494.2154 494.3358 494.4562 494.5766 494.6969 494.8172 494.9376 495.0579 495.1781 495.2984 495.4187 495.5389 495.6591 495.7793 495.8995 496.0197 496.1398 496.2599 496.3801 496.5002 496.6202 496.7403 496.8604 496.9804 497.1004 497.2204 497.3404 497.4604 497.5803 497.7002 497.8202 497.9401 498.0599 498.1798 498.2997 498.4195 498.5393 498.6591 498.7789 498.8986 499.0184 499.1381 499.2578 499.3775 499.4972 499.6169 499.7365 499.8562 499.9758 500.0954 500.2150 500.3345 500.4541 500.5736 500.6931 500.8126 500.9321 501.0515 501.1710 501.2904 501.4098 501.5292 501.6486 501.7680 501.8873 502.0066 502.1259 502.2452 502.3645 502.4838 502.6030 502.7222 502.8414 502.9606 503.0798 503.1989 503.3181 503.4372 503.5563 503.6754 503.7945 503.9135 504.0325 504.1516 504.2706 504.3896 504.5085 504.6275 504.7464 504.8653 504.9842 505.1031 505.2220 505.3408 505.4596 505.5784 505.6972 505.8160 505.9348 506.0535 506.1722 506.2910 506.4096 506.5283 506.6470 506.7656 506.8842 507.0028 507.1214 507.2400 507.3585 507.4771 507.5956 507.7141 507.8326 507.9510 508.0695 508.1879 508.3063 508.4247 508.5431 508.6615 508.7798 508.8981 509.0164 509.1347 509.2530 509.3713 509.4895 509.6077 509.7259 509.8441 509.9623 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Azimuth motor temperature [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230827T043834.1Z 8639.193450 173 1 5.58 2 88.93 78.09 119.86 208.84 0.00 1 0.00 1 0 15 5.565e-03 5.514e-03 1.230e-03 1.226e-03 4.093661e+03 7.198569e+01 2.653510e+02 -6.000000e+00 2.984851e+02 279.16 -2.00 20.00 -2.00 505.38 0.00e+00 3.143113e-03 3.338892e-05 1.761198e-04 -6.000000e+00 1.534635e-04 279.16 -2.00 20.00 -2.00 501.05 0.00e+00 1.035851e+00 2.346479e-02 4.692859e-02 -6.000000e+00 1.098438e-01 227.01 -2.00 3.06 -2.00 502.55 0.00e+00 18.681 0.038 489.00 513.00 1 4.2891e+00 1.7877e-03 2.3805e-02 -6.0000e+00 8.3890e-03 -4.6641e-02 4.6314e-04 1.5429e-03 -6.0000e+00 2.2116e-03 2.4990e-03 -4.8695e-04 1.1350e-04 6.9508e-05 -6.0000e+00 5.2681e-04 -6.4726e-02 -4.9988e-05 12 9 9 12 5 5 -14.33 14.86 2.95 -0.06473 -0.06810 6 12 1 4 0 770.900 18.52 15.00 14.86 2.96 27.60 13.9 763.44 900000 -1116 -947 -399 487 695 681 973 751 768 559 45 37 -217 -218 -532 -142 -135 114 414 602 334 471 553 197 449 568 195 156 -170 -566 -1055 -818 -500 -497 150 305 238 124 87 -80 98 -58 421 572 386 349 280 223 -42 -264 -882 -1148 -1122 -1285 -1073 -42 334 229 556 825 367 618 600 696 464 162 170 -122 -362 -257 -306 -279 -282 -225 3 -110 -467 -524 -681 -494 -1221 -945 -821 -1032 -857 -560 -352 -684 -518 -291 -179 306 516 283 772 324 -131 -266 -852 -967 -1009 -574 -428 -332 172 -139 -106 -286 -413 -252 -152 441 527 743 960 1099 1149 1168 886 278 268 491 406 157 436 521 324 482 278 -36 188 18 -291 -166 -368 -426 -129 67 107 441 284 300 461 250 -18 88 -337 -699 -782 -677 900000 -987 -842 -367 453 651 643 933 716 730 534 42 35 -204 -203 -496 -133 -127 108 401 580 324 458 538 194 438 555 190 153 -163 -537 -995 -776 -478 -487 148 302 235 123 85 -78 97 -57 419 569 389 348 278 223 -42 -259 -859 -1097 -1066 -1240 -1049 -41 336 230 558 825 371 627 604 700 465 163 168 -122 -359 -251 -297 -273 -279 -223 3 -109 -458 -514 -664 -480 -1201 -923 -807 -1027 -850 -558 -352 -685 -517 -291 -180 308 529 288 786 326 -131 -260 -832 -943 -981 -557 -422 -337 176 -141 -108 -289 -415 -255 -154 455 546 777 1011 1150 1213 1240 940 293 278 510 419 164 452 542 340 504 292 -38 198 19 -302 -170 -379 -439 -134 71 114 474 304 324 500 270 -20 95 -365 -741 -825 -711 SQ 20230827T044118.9Z 8639.195357 177 1 50.55 2 88.33 77.78 120.14 208.26 0.00 1 0.00 1 0 15 4.396e-03 4.368e-03 1.250e-04 1.247e-04 3.495174e+03 7.249820e+00 2.297838e+02 -6.000000e+00 2.357375e+02 279.16 -2.00 20.00 -2.00 505.37 0.00e+00 3.018732e-03 3.393070e-06 1.702398e-04 -6.000000e+00 1.212058e-04 279.16 -2.00 20.00 -2.00 500.98 0.00e+00 1.034115e+00 2.394182e-03 4.165232e-02 -6.000000e+00 8.677036e-02 227.01 -2.00 3.06 -2.00 502.49 0.00e+00 17.097 0.029 489.00 513.00 1 2.3143e+00 1.8246e-04 2.1686e-02 -6.0000e+00 6.6264e-03 -3.9909e-02 4.7395e-05 1.3797e-03 -6.0000e+00 1.7478e-03 2.1839e-02 -1.1172e-03 1.1577e-05 6.5199e-05 -6.0000e+00 4.1600e-04 1.5031e-02 -5.5496e-04 12 9 1 12 4 4 68.42 14.87 2.22 0.01503 0.00728 561 104 1 4 0 90.080 18.52 15.00 14.87 3.11 28.10 13.9 764.38 900000 -714 -471 -207 402 665 732 862 717 684 548 182 34 -177 -329 -322 -184 -32 -63 237 410 258 327 393 270 391 496 208 -94 -84 -466 -675 -377 -318 -310 136 306 106 -16 -68 -124 -99 92 206 355 343 215 117 -25 -280 -471 -808 -895 -834 -904 -701 -228 161 324 395 417 337 388 406 382 350 283 191 -40 -168 -162 -391 -284 -133 -187 -137 -91 -164 -353 -538 -620 -828 -808 -681 -729 -715 -594 -595 -586 -625 -373 -41 93 280 484 454 219 19 -374 -617 -734 -762 -512 -474 -402 -99 -80 -82 -122 -212 -228 -25 212 394 635 911 938 895 767 754 530 394 447 302 172 363 352 292 437 312 103 149 40 -162 -200 -170 -321 -163 2 90 133 260 328 322 329 148 -47 -218 -401 -538 -639 900000 -638 -430 -190 375 627 706 833 699 665 527 173 33 -167 -308 -300 -173 -31 -61 231 399 252 320 385 267 385 489 205 -93 -82 -443 -644 -362 -308 -305 135 305 105 -16 -68 -122 -98 90 206 355 348 216 117 -25 -278 -463 -785 -864 -798 -867 -682 -225 163 326 398 419 341 395 410 387 351 285 189 -40 -165 -160 -385 -277 -131 -185 -137 -90 -162 -345 -521 -600 -807 -794 -666 -720 -705 -591 -594 -584 -623 -373 -41 94 287 491 464 221 19 -371 -599 -710 -734 -493 -466 -406 -101 -81 -84 -122 -212 -230 -25 219 408 664 946 983 946 807 789 556 407 461 311 177 376 366 305 456 326 107 155 42 -166 -204 -174 -327 -168 2 95 141 277 352 344 354 160 -51 -232 -422 -562 -665 SQ 20230827T044411.7Z 8639.197357 181 1 27.33 2 87.70 77.46 120.43 207.64 0.00 1 0.00 1 0 15 3.668e-03 3.650e-03 1.231e-04 1.229e-04 2.895638e+03 7.054525e+00 1.907725e+02 -6.000000e+00 1.967290e+02 279.16 -2.00 20.00 -2.00 505.35 0.00e+00 2.336331e-03 3.337423e-06 1.332015e-04 -6.000000e+00 1.011568e-04 279.16 -2.00 20.00 -2.00 500.89 0.00e+00 1.019892e+00 2.363807e-03 3.399736e-02 -6.000000e+00 7.242855e-02 227.01 -2.00 3.06 -2.00 502.41 0.00e+00 15.388 0.021 489.00 513.00 1 1.8896e+00 1.8022e-04 1.9300e-02 -6.0000e+00 5.5309e-03 -3.0272e-02 4.6948e-05 1.2076e-03 -6.0000e+00 1.4592e-03 4.1478e-02 -6.7980e-04 1.1414e-05 5.1824e-05 -6.0000e+00 3.4718e-04 4.2944e-03 -5.0455e-04 12 1 1 12 4 4 51.75 14.88 1.77 0.00429 -0.00042 538 99 1 4 0 50.770 18.52 15.01 14.88 3.27 28.30 13.9 765.63 900000 -491 -337 -150 401 633 622 696 568 573 465 166 46 -132 -234 -264 -109 -3 -70 162 326 194 295 299 185 309 401 164 -136 -17 -360 -503 -251 -257 -313 88 239 68 -8 -58 -72 -93 94 188 274 254 95 38 -91 -310 -395 -667 -730 -685 -807 -641 -247 122 234 292 331 266 295 345 329 286 241 167 -36 -129 -125 -275 -184 -78 -135 -111 -35 -63 -256 -416 -483 -707 -728 -573 -642 -664 -563 -574 -588 -594 -332 -32 98 227 402 350 130 -19 -365 -528 -563 -581 -344 -368 -363 -125 -81 -76 -59 -167 -173 -8 201 320 535 751 785 725 627 630 456 336 440 282 119 339 274 283 360 286 26 126 20 -123 -96 -55 -221 -130 29 93 131 255 308 284 257 85 -86 -212 -337 -414 -508 900000 -444 -312 -140 380 607 602 686 557 560 455 161 44 -126 -222 -250 -104 -3 -68 159 322 193 294 299 183 309 402 164 -134 -16 -345 -484 -243 -252 -311 89 242 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