File name: Pandora53s1_Potchefstroom-METSI_20240710_L2Fit_fwvt1c0d20220413p1-8.txt File generation date: 20240710T222655.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c0p1-8 Local principal investigator: Stuart Piketh Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 53 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora53_OF_v5d20210210.txt Instrument calibration file used: Pandora53s1_CF_v103d20220413.txt Level 1 file used: Pandora53s1_Potchefstroom-METSI_20240710_L1_smca1c0d20220413p1-8.txt Full location name: Gerhard Minnebron Mooi River Ecosystem Trails for Scientific Investigations Short location name: Potchefstroom-METSI Country of location: South Africa Location latitude [deg]: -26.4907 Location longitude [deg]: 27.1322 Location altitude [m]: 1440 Local noon date: 20240710 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1683 1833 Nominal wavelengths inside fitting window [nm]: 492.0454 492.1661 492.2868 492.4075 492.5281 492.6487 492.7693 492.8899 493.0105 493.1311 493.2516 493.3722 493.4927 493.6132 493.7337 493.8541 493.9746 494.0950 494.2154 494.3358 494.4562 494.5766 494.6969 494.8172 494.9376 495.0579 495.1781 495.2984 495.4187 495.5389 495.6591 495.7793 495.8995 496.0197 496.1398 496.2599 496.3801 496.5002 496.6202 496.7403 496.8604 496.9804 497.1004 497.2204 497.3404 497.4604 497.5803 497.7002 497.8202 497.9401 498.0599 498.1798 498.2997 498.4195 498.5393 498.6591 498.7789 498.8986 499.0184 499.1381 499.2578 499.3775 499.4972 499.6169 499.7365 499.8562 499.9758 500.0954 500.2150 500.3345 500.4541 500.5736 500.6931 500.8126 500.9321 501.0515 501.1710 501.2904 501.4098 501.5292 501.6486 501.7680 501.8873 502.0066 502.1259 502.2452 502.3645 502.4838 502.6030 502.7222 502.8414 502.9606 503.0798 503.1989 503.3181 503.4372 503.5563 503.6754 503.7945 503.9135 504.0325 504.1516 504.2706 504.3896 504.5085 504.6275 504.7464 504.8653 504.9842 505.1031 505.2220 505.3408 505.4596 505.5784 505.6972 505.8160 505.9348 506.0535 506.1722 506.2910 506.4096 506.5283 506.6470 506.7656 506.8842 507.0028 507.1214 507.2400 507.3585 507.4771 507.5956 507.7141 507.8326 507.9510 508.0695 508.1879 508.3063 508.4247 508.5431 508.6615 508.7798 508.8981 509.0164 509.1347 509.2530 509.3713 509.4895 509.6077 509.7259 509.8441 509.9623 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Azimuth motor temperature [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240710T050848.0Z 8957.214444 71 1 7.90 2 88.99 64.51 129.06 96.83 0.00 1 0.00 1 0 15 4.025e-03 3.991e-03 3.810e-04 3.802e-04 7.670044e+03 2.380049e+01 5.105251e+02 -6.000000e+00 2.156958e+02 279.12 -2.00 20.00 -2.00 505.36 0.00e+00 1.842771e-03 1.035725e-05 1.145165e-04 -6.000000e+00 1.110315e-04 279.12 -2.00 20.00 -2.00 500.90 0.00e+00 8.929624e-01 7.328579e-03 6.291824e-02 -6.000000e+00 7.946720e-02 225.65 -2.00 3.06 -2.00 502.43 0.00e+00 18.835 0.038 489.00 513.00 1 2.4680e+00 5.5818e-04 2.4047e-02 -6.0000e+00 6.0666e-03 -2.4860e-02 1.4476e-04 1.9098e-03 -6.0000e+00 1.6045e-03 1.5468e-02 -2.1747e-03 3.4354e-05 8.0433e-05 -6.0000e+00 3.8121e-04 2.0519e-02 -7.6187e-04 12 9 1 12 5 5 39.66 14.87 1.81 0.02052 0.00543 57 69 1 4 0 136.070 18.52 14.99 14.87 1.47 27.30 15.7 732.28 900000 -550 -282 -203 296 685 747 812 735 601 560 372 83 -75 -248 -236 -155 33 16 136 294 214 330 351 280 336 391 323 -103 -101 -393 -567 -392 -290 -324 -52 204 104 -9 -55 -137 -113 65 157 202 218 99 61 48 -235 -412 -699 -856 -827 -848 -733 -282 15 189 241 365 304 317 358 356 276 217 220 32 -190 -217 -320 -249 -76 -143 -101 -55 -125 -203 -412 -583 -766 -807 -651 -589 -680 -548 -568 -542 -555 -373 -88 125 198 407 344 263 181 -193 -602 -692 -720 -466 -481 -522 -256 -220 -90 -119 -114 -165 -129 79 242 453 830 869 923 760 623 524 356 405 376 155 296 339 275 373 414 108 134 89 -50 -74 -92 -199 -159 0 69 82 243 274 273 306 188 33 -158 -385 -381 -571 900000 -498 -256 -188 279 653 719 787 711 583 544 357 79 -71 -234 -222 -146 32 16 134 290 212 328 349 277 334 390 322 -102 -100 -380 -547 -374 -282 -319 -52 206 105 -9 -54 -137 -112 65 157 204 220 101 62 48 -236 -410 -678 -822 -795 -810 -709 -278 15 191 244 368 307 319 362 361 279 219 220 32 -188 -213 -315 -243 -74 -141 -100 -55 -123 -199 -400 -563 -743 -790 -635 -580 -670 -546 -569 -542 -554 -372 -88 125 202 416 348 264 179 -189 -577 -660 -682 -447 -465 -515 -259 -224 -91 -121 -114 -167 -131 81 249 470 863 899 965 795 654 546 369 418 384 159 302 348 284 386 427 112 139 91 -51 -75 -93 -203 -164 0 73 86 259 291 292 329 201 35 -169 -409 -396 -597 SQ 20240710T051121.7Z 8957.216223 75 1 19.18 2 88.47 64.22 128.50 96.51 0.00 1 0.00 1 0 15 3.548e-03 3.525e-03 1.191e-04 1.188e-04 6.717070e+03 7.353844e+00 4.504290e+02 -6.000000e+00 1.901935e+02 279.12 -2.00 20.00 -2.00 505.36 0.00e+00 1.605216e-03 3.235431e-06 1.001146e-04 -6.000000e+00 9.790825e-05 279.12 -2.00 20.00 -2.00 500.86 0.00e+00 8.818769e-01 2.295355e-03 5.560400e-02 -6.000000e+00 7.008698e-02 225.65 -2.00 3.06 -2.00 502.39 0.00e+00 17.495 0.031 489.00 513.00 1 1.1958e+00 1.7490e-04 2.2160e-02 -6.0000e+00 5.3503e-03 -2.1028e-02 4.5407e-05 1.7211e-03 -6.0000e+00 1.4155e-03 6.5238e-02 -1.4294e-03 1.0798e-05 7.0799e-05 -6.0000e+00 3.3615e-04 1.3898e-02 -7.4423e-04 12 1 1 12 4 4 58.21 14.87 1.62 0.01390 0.00398 611 113 1 4 0 30.720 18.52 15.00 14.87 1.54 27.10 15.7 732.68 900000 -390 -268 -145 322 616 648 710 625 569 539 259 90 -62 -208 -192 -104 65 -38 76 273 206 247 319 175 249 359 208 -126 -70 -264 -480 -256 -185 -343 -47 168 82 -4 -36 -101 -92 40 135 224 190 76 37 -7 -274 -396 -627 -718 -659 -755 -685 -319 -8 164 233 307 269 273 269 273 258 226 182 49 -132 -120 -284 -179 -44 -131 -145 -88 -91 -165 -347 -456 -642 -712 -558 -616 -651 -556 -615 -586 -567 -357 -59 82 208 333 338 214 93 -252 -549 -580 -616 -403 -363 -427 -255 -165 -118 -32 -75 -153 -57 56 243 436 682 829 760 661 556 437 366 432 374 193 259 277 220 334 347 104 127 79 -34 -43 8 -141 -119 6 61 93 188 244 231 254 121 -9 -177 -316 -350 -447 900000 -354 -244 -135 305 591 628 692 617 561 526 250 87 -59 -197 -184 -98 63 -37 75 270 205 246 318 176 248 359 208 -125 -69 -255 -462 -247 -180 -338 -47 170 83 -4 -36 -100 -92 39 135 225 193 77 37 -8 -274 -392 -612 -693 -628 -725 -668 -317 -8 166 235 308 270 277 274 278 262 227 183 49 -131 -118 -276 -175 -43 -129 -145 -89 -90 -162 -337 -442 -624 -691 -545 -608 -644 -555 -610 -581 -561 -357 -58 82 210 338 344 213 91 -245 -530 -556 -586 -383 -352 -423 -256 -168 -120 -32 -75 -154 -58 57 250 452 703 858 795 691 582 454 378 445 381 198 264 284 226 344 357 107 131 81 -34 -43 8 -143 -122 6 63 98 199 257 245 271 130 -10 -188 -332 -365 -462 SQ 20240710T051141.2Z 8957.216449 75 2 19.18 2 88.41 64.18 128.43 96.47 0.00 1 0.00 1 0 15 3.523e-03 3.501e-03 1.157e-04 1.155e-04 6.576750e+03 7.138158e+00 4.417686e+02 -6.000000e+00 1.888560e+02 279.12 -2.00 20.00 -2.00 505.35 0.00e+00 1.566555e-03 3.143578e-06 9.779741e-05 -6.000000e+00 9.721982e-05 279.12 -2.00 20.00 -2.00 500.85 0.00e+00 8.741940e-01 2.230895e-03 5.440056e-02 -6.000000e+00 6.959413e-02 225.65 -2.00 3.06 -2.00 502.38 0.00e+00 17.317 0.030 489.00 513.00 1 1.1613e+00 1.6997e-04 2.1908e-02 -6.0000e+00 5.3127e-03 -1.9922e-02 4.4162e-05 1.6926e-03 -6.0000e+00 1.4056e-03 6.9077e-02 -1.4126e-03 1.0498e-05 6.9365e-05 -6.0000e+00 3.3378e-04 1.2057e-02 -7.3317e-04 12 1 1 12 4 4 70.40 14.87 1.59 0.01206 0.00226 611 113 1 4 0 30.720 18.52 15.00 14.87 1.54 27.10 15.7 732.96 900000 -391 -281 -137 321 618 642 713 624 580 521 234 102 -49 -226 -223 -81 40 -50 86 282 176 250 310 193 261 354 216 -109 -68 -256 -432 -210 -180 -340 -66 141 78 -4 -30 -108 -97 43 155 217 198 73 2 -23 -260 -394 -616 -725 -642 -745 -692 -323 -22 143 221 289 275 286 270 282 245 206 197 56 -146 -137 -263 -180 -24 -127 -150 -94 -59 -173 -328 -451 -630 -701 -546 -607 -625 -538 -610 -592 -561 -357 -33 95 186 343 328 199 123 -269 -551 -573 -603 -395 -353 -429 -269 -181 -101 -25 -84 -176 -76 72 237 425 674 819 764 641 564 442 358 436 382 163 271 302 216 328 325 122 124 95 -52 -53 -39 -143 -119 -17 71 123 205 248 232 261 145 2 -162 -343 -371 -452 900000 -354 -259 -127 304 593 621 695 615 572 508 226 99 -47 -216 -213 -78 38 -49 85 279 175 249 309 194 261 354 216 -108 -67 -250 -416 -202 -175 -339 -66 142 79 -4 -29 -108 -97 43 156 218 201 74 2 -23 -259 -390 -601 -699 -619 -714 -673 -321 -22 146 222 294 277 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