File name: Pandora53s1_Potchefstroom-METSI_20240914_L2Fit_fout2c2d20230223p1-8.txt File generation date: 20240916T163314.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Stuart Piketh Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 53 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora53_OF_v5d20210210.txt Instrument calibration file used: Pandora53s1_CF_v2d20230223.txt Level 1 file used: Pandora53s1_Potchefstroom-METSI_20240914_L1_smca1c2d20230223p1-8.txt Full location name: Gerhard Minnebron Mooi River Ecosystem Trails for Scientific Investigations Short location name: Potchefstroom-METSI Country of location: South Africa Location latitude [deg]: -26.4907 Location longitude [deg]: 27.1322 Location altitude [m]: 1440 Local noon date: 20240914 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 103 "redoing cal analysis" First and last pixel inside fitting window: 259 401 Nominal wavelengths inside fitting window [nm]: 305.0454 305.1861 305.3267 305.4673 305.6079 305.7485 305.8891 306.0297 306.1702 306.3108 306.4513 306.5919 306.7324 306.8729 307.0134 307.1539 307.2943 307.4348 307.5752 307.7157 307.8561 307.9965 308.1369 308.2773 308.4177 308.5581 308.6984 308.8388 308.9791 309.1194 309.2597 309.4000 309.5403 309.6806 309.8209 309.9611 310.1014 310.2416 310.3818 310.5220 310.6622 310.8024 310.9426 311.0827 311.2229 311.3630 311.5031 311.6433 311.7834 311.9234 312.0635 312.2036 312.3437 312.4837 312.6237 312.7638 312.9038 313.0438 313.1837 313.3237 313.4637 313.6036 313.7436 313.8835 314.0234 314.1633 314.3032 314.4431 314.5830 314.7228 314.8627 315.0025 315.1424 315.2822 315.4220 315.5618 315.7015 315.8413 315.9811 316.1208 316.2605 316.4002 316.5400 316.6797 316.8193 316.9590 317.0987 317.2383 317.3780 317.5176 317.6572 317.7968 317.9364 318.0760 318.2155 318.3551 318.4946 318.6342 318.7737 318.9132 319.0527 319.1922 319.3317 319.4711 319.6106 319.7500 319.8894 320.0288 320.1683 320.3076 320.4470 320.5864 320.7257 320.8651 321.0044 321.1437 321.2831 321.4224 321.5616 321.7009 321.8402 321.9794 322.1187 322.2579 322.3971 322.5363 322.6755 322.8147 322.9538 323.0930 323.2321 323.3713 323.5104 323.6495 323.7886 323.9277 324.0668 324.2058 324.3449 324.4839 324.6229 324.7620 324.9010 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Azimuth motor temperature [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240914T045333.7Z 9023.203862 199 1 50.97 2 81.07 81.84 122.72 209.18 0.00 1 0.00 1 0 33 5.318e-01 1.017e-01 1.836e-01 6.319e-03 7.850808e-01 3.922424e-03 1.193419e-02 -6.000000e+00 3.394156e-01 227.73 -2.00 3.06 -2.00 321.06 0.00e+00 -9.436889e-02 1.858465e-03 1.711159e-03 -6.000000e+00 2.258860e-02 279.61 -2.00 20.00 -2.00 320.51 0.00e+00 6.108 0.001 302.00 328.00 3 4.0345e+00 1.3356e-02 1.0480e-01 -6.0000e+00 8.6750e-01 -4.4410e-02 1.9094e-02 1.2386e-01 -6.0000e+00 9.5434e-01 -3.2996e-02 2.0379e-02 1.2735e-01 -6.0000e+00 5.4157e-01 -5.4815e-02 9.6092e-03 1.3367e-01 -6.0000e+00 2.3219e-01 3.2282e-05 -2.2090e-03 2.0964e-04 1.2810e-03 -6.0000e+00 1.7864e-02 4.9189e-03 0.0000e+00 12 8 8 10 0 0 11.52 17.64 0.99 0.00492 -0.01168 18 3 1 5 0 2831.350 20.77 15.00 17.64 22.66 46.60 17.4 875.00 900000 -143596 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 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6485 5818 3802 3931 2100 2607 225 2376 746 2342 2979 5431 6251 8135 11704 12716 12313 9815 6299 7177 1941 4485 3270 3631 4543 3856 4521 6255 5216 5514 9124 -90246 12195 8540 8508 -4264 3891 5237 432 3283 3071 5922 5236 9658 7169 9286 8533 6267 7887 7782 9924 7068 10998 4543 1367 1368 -4376 -1601 -5081 -2606 -521 -811 263 706 -257 -1465 -1970 -2188 -1196 -272 4452 6708 8294 5669 4261 -133 136 -2877 -2523 -3185 -2301 -83 916 262 -395 -722 -4506 -5321 -7491 -5164 -6631 -6272 -5675 2702 1756 3216 3735 2360 3376 2802 3007 SS 20240914T050507.7Z 9023.211895 204 1 50.47 2 78.51 80.48 123.90 206.56 0.00 1 0.00 1 0 25 2.407e-01 5.976e-03 1.817e-01 2.352e-03 5.826705e-01 1.260028e-03 5.823825e-03 -6.000000e+00 1.437459e-01 227.73 -2.00 3.06 -2.00 320.22 0.00e+00 -3.023263e-04 4.556986e-04 1.014092e-03 -6.000000e+00 6.378399e-03 279.61 -2.00 20.00 -2.00 319.65 0.00e+00 4.859 0.001 302.00 328.00 3 3.1781e+00 3.7549e-03 4.9027e-02 -6.0000e+00 3.5716e-01 -5.5291e-02 4.6891e-03 2.7586e-02 -6.0000e+00 3.8682e-01 1.6828e-02 4.4441e-03 1.3590e-02 -6.0000e+00 2.3014e-01 -1.8943e-02 2.2551e-03 4.0363e-03 -6.0000e+00 9.7173e-02 1.9789e-04 5.4342e-05 7.0304e-05 4.9823e-05 -6.0000e+00 7.3835e-03 5.0811e-03 0.0000e+00 10 0 0 10 0 0 -2.86 17.68 0.40 0.00508 0.00549 59 11 1 5 0 855.290 20.77 15.00 17.68 23.18 48.60 17.4 878.03 56645 -82461 -56160 900000 -16743 5795 175540 6432 -10579 57762 140545 36014 18842 59528 33543 -47750 12711 -13661 6588 -2782 13522 7711 5573 3773 -15721 8157 -12663 12562 -3155 2813 12407 4393 4853 421 -1673 -12788 -3754 -10285 1344 -10043 -2211 -1552 -5126 3001 -3435 317 -1516 -470 -1319 -383 1448 493 1920 1438 190 1135 1670 2638 1512 1494 -553 2127 434 1856 1299 325 1065 -82 1030 742 -687 -897 437 -188 837 367 -384 -4330 -1137 642 -795 -507 -1242 -1298 -986 -741 -129 44 542 728 836 1313 1304 1012 1224 623 301 554 37 534 -135 -730 -530 -564 -705 -618 -886 -893 -630 190 -12 -119 58 124 71 166 222 -60 191 -501 -220 -672 -139 134 611 491 271 924 442 681 357 302 -247 -72 -214 77 -106 -217 85 -27 -75 -34 -276 130 -808 -457 900000 -96 27 403 37 -82 252 322 239 181 478 431 -1493 246 -382 163 -81 347 215 168 127 -708 309 -607 461 -134 119 546 245 309 30 -122 -1053 -310 -985 140 -1409 -327 -248 -895 498 -618 56 -278 -87 -258 -79 322 123 522 395 56 351 531 837 478 467 -181 736 171 799 593 148 476 -38 475 389 -405 -560 270 -112 458 183 -179 -2085 -575 368 -538 -364 -990 -1109 -842 -673 -123 43 532 694 749 1094 1107 868 1066 621 325 676 46 682 -166 -875 -586 -617 -815 -758 -1088 -1170 -891 278 -19 -192 94 196 112 250 331 -93 296 -817 -362 -1085 -215 211 920 712 382 1315 689 1119 615 556 -459 -140 -427 162 -230 -482 190 -58 -156 -69 -548 SS 20240914T051120.1Z 9023.216204 207 1 50.52 2 77.14 79.74 124.49 205.11 0.00 1 0.00 1 0 25 7.805e-02 5.066e-03 4.987e-02 1.577e-03 5.289966e-01 8.370345e-04 5.363776e-03 -6.000000e+00 4.661381e-02 227.73 -2.00 3.06 -2.00 319.74 0.00e+00 4.969742e-04 2.572545e-04 6.313068e-04 -6.000000e+00 2.035981e-03 279.61 -2.00 20.00 -2.00 319.14 0.00e+00 4.378 0.000 302.00 328.00 3 2.8937e+00 2.4046e-03 4.4174e-02 -6.0000e+00 1.1583e-01 -5.1624e-02 2.8833e-03 2.4669e-02 -6.0000e+00 1.2545e-01 1.6355e-02 2.4947e-03 1.2094e-02 -6.0000e+00 7.4611e-02 -1.7450e-02 1.2948e-03 3.7353e-03 -6.0000e+00 3.1436e-02 4.0743e-04 1.2103e-05 4.7493e-05 4.3711e-05 -6.0000e+00 2.3690e-03 4.8643e-03 0.0000e+00 10 0 0 10 0 0 -0.38 17.71 0.28 0.00486 0.00496 96 18 1 5 0 525.880 20.77 15.01 17.71 23.50 49.40 17.4 880.35 -2294 -45471 -16203 54626 -25037 12381 660 12308 -19711 5457 19033 -14284 11952 -92 12056 -20007 -84 -1007 9026 -5276 5178 2628 4538 -296 -3307 1100 -1784 746 -1814 -2723 2324 1713 1594 -327 -3964 -6191 -4553 -2529 -1047 -3828 -2439 242 -2184 344 -2253 -614 -1451 -857 -259 -251 609 393 1483 688 817 603 651 1840 667 983 -80 1668 762 1182 1156 703 501 -269 674 523 -8 -312 -19 385 499 203 146 -2063 -729 -424 -808 -508 -1296 -1376 -1205 -597 -301 27 272 694 771 938 685 832 1030 837 295 620 329 510 -193 -853 -302 -380 -648 -646 -947 -884 -510 3 122 207 17 245 61 122 112 101 -14 -296 -302 -426 -344 -3 503 340 322 863 640 811 334 241 -225 35 -287 -101 -71 -197 -72 -185 26 1 -97 -18 -636 -181 298 -287 97 6 119 -298 70 229 -268 207 -2 315 -777 -3 -40 381 -250 229 122 217 -16 -202 68 -116 47 -114 -181 166 142 150 -34 -420 -674 -533 -342 -156 -701 -499 52 -508 80 -548 -149 -361 -216 -67 -68 166 119 486 246 310 240 267 749 271 394 -33 739 354 602 617 371 258 -142 380 312 -5 -220 -13 260 312 123 82 -1167 -437 -273 -603 -403 -1138 -1221 -1140 -599 -301 28 282 695 766 866 601 730 970 845 342 768 422 663 -241 -1037 -357 -445 -763 -809 -1195 -1186 -701 5 190 340 27 389 92 182 166 155 -21 -482 -499 -691 -541 -5 758 494 451 1218 982 1312 566 436 -410 67 -562 -201 -146 -414 -152 -381 52 2 -183 SS 20240914T051650.5Z 9023.220029 210 1 50.49 2 75.93 79.07 124.98 203.80 0.00 1 0.00 1 0 25 4.427e-02 4.676e-03 1.908e-02 1.163e-03 4.880425e-01 6.104902e-04 4.957882e-03 -6.000000e+00 2.644007e-02 227.73 -2.00 3.06 -2.00 319.37 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