File name: Pandora53s1_Potchefstroom-METSI_20250515_L2Fit_fwvt1c2d20230223p1-8.txt File generation date: 20250524T083750.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Stuart Piketh Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 53 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora53_OF_v5d20210210.txt Instrument calibration file used: Pandora53s1_CF_v2d20230223.txt Level 1 file used: Pandora53s1_Potchefstroom-METSI_20250515_L1_smca1c2d20230223p1-8.txt Full location name: Gerhard Minnebron Mooi River Ecosystem Trails for Scientific Investigations Short location name: Potchefstroom-METSI Country of location: South Africa Location latitude [deg]: -26.4907 Location longitude [deg]: 27.1322 Location altitude [m]: 1440 Local noon date: 20250515 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 103 "redoing cal analysis" First and last pixel inside fitting window: 1684 1833 Nominal wavelengths inside fitting window [nm]: 492.0989 492.2196 492.3403 492.4609 492.5815 492.7021 492.8227 492.9432 493.0638 493.1843 493.3048 493.4253 493.5458 493.6663 493.7867 493.9072 494.0276 494.1480 494.2684 494.3888 494.5091 494.6294 494.7498 494.8701 494.9903 495.1106 495.2309 495.3511 495.4713 495.5915 495.7117 495.8319 495.9520 496.0722 496.1923 496.3124 496.4325 496.5525 496.6726 496.7926 496.9127 497.0327 497.1526 497.2726 497.3926 497.5125 497.6324 497.7523 497.8722 497.9921 498.1119 498.2318 498.3516 498.4714 498.5912 498.7109 498.8307 498.9504 499.0702 499.1899 499.3095 499.4292 499.5489 499.6685 499.7881 499.9077 500.0273 500.1469 500.2664 500.3859 500.5055 500.6250 500.7444 500.8639 500.9834 501.1028 501.2222 501.3416 501.4610 501.5803 501.6997 501.8190 501.9383 502.0576 502.1769 502.2962 502.4154 502.5346 502.6538 502.7730 502.8922 503.0114 503.1305 503.2496 503.3687 503.4878 503.6069 503.7260 503.8450 503.9640 504.0830 504.2020 504.3210 504.4399 504.5589 504.6778 504.7967 504.9156 505.0344 505.1533 505.2721 505.3909 505.5097 505.6285 505.7473 505.8660 505.9848 506.1035 506.2222 506.3408 506.4595 506.5781 506.6968 506.8154 506.9339 507.0525 507.1711 507.2896 507.4081 507.5266 507.6451 507.7636 507.8820 508.0005 508.1189 508.2373 508.3557 508.4740 508.5924 508.7107 508.8290 508.9473 509.0656 509.1838 509.3020 509.4203 509.5385 509.6567 509.7748 509.8930 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Azimuth motor temperature [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250515T051406.3Z 9266.218128 292 1 50.71 2 84.46 65.64 68.25 248.53 0.00 1 0.00 1 0 15 2.748e-03 2.735e-03 1.941e-04 1.939e-04 6.990736e+03 1.224406e+01 4.716859e+02 -6.000000e+00 1.483053e+02 281.02 -2.00 20.00 -2.00 505.31 0.00e+00 4.399279e-03 5.287785e-06 2.482186e-04 -6.000000e+00 7.617137e-05 281.02 -2.00 20.00 -2.00 500.67 0.00e+00 6.176500e-01 3.779521e-03 6.317571e-02 -6.000000e+00 5.413496e-02 225.22 -2.00 3.06 -2.00 502.22 0.00e+00 9.118 0.004 489.00 513.00 1 3.6157e+00 2.8844e-04 1.3571e-02 -6.0000e+00 4.1365e-03 -1.9595e-02 7.4922e-05 1.4073e-03 -6.0000e+00 1.0925e-03 1.5601e-02 1.6984e-05 1.7644e-05 1.0210e-04 -6.0000e+00 2.5988e-04 1.4259e-02 -2.6617e-04 10 0 0 10 0 0 96.74 16.33 1.40 0.01426 0.01438 215 40 1 4 0 235.840 19.64 14.99 16.33 11.58 39.60 18.9 786.95 -141 -127 -99 336 518 493 522 429 421 403 158 108 2 -124 -150 -22 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-66 84 113 186 367 558 666 595 452 397 260 214 389 281 118 230 237 173 248 241 35 104 62 -34 26 128 -17 1 29 124 103 165 219 235 221 23 -116 -215 -319 -258 -260 SQ 20250515T052650.2Z 9266.226970 295 1 50.62 2 81.88 64.07 70.81 247.55 0.00 1 0.00 1 0 15 2.490e-03 2.478e-03 1.695e-04 1.694e-04 4.968927e+03 1.036148e+01 3.367161e+02 -6.000000e+00 1.343545e+02 281.01 -2.00 20.00 -2.00 505.29 0.00e+00 3.089693e-03 4.609806e-06 1.762119e-04 -6.000000e+00 6.900686e-05 281.01 -2.00 20.00 -2.00 500.58 0.00e+00 4.523131e-01 3.307213e-03 4.601751e-02 -6.000000e+00 4.904773e-02 225.22 -2.00 3.06 -2.00 502.15 0.00e+00 6.643 0.002 489.00 513.00 1 3.6761e+00 2.5245e-04 9.8274e-03 -6.0000e+00 3.7477e-03 -1.2932e-02 6.5882e-05 1.0212e-03 -6.0000e+00 9.9002e-04 2.0477e-02 2.7834e-04 1.5510e-05 7.3057e-05 -6.0000e+00 2.3544e-04 1.9719e-02 -3.0994e-04 10 0 0 10 0 0 90.72 16.36 1.44 0.01972 0.02165 254 47 1 4 0 199.250 19.64 15.00 16.36 12.33 38.60 19.0 793.06 -107 -120 -98 285 466 434 461 345 360 348 145 133 -27 -106 -94 4 34 -164 -16 160 67 160 202 40 148 283 79 -138 49 -50 -239 -42 -135 -356 -81 117 54 6 44 8 10 56 93 153 84 -14 -79 -77 -245 -294 -438 -432 -406 -598 -602 -327 -102 77 178 213 153 191 86 116 145 150 158 7 -69 -4 -152 9 87 -76 -17 -15 38 -17 -154 -239 -442 -509 -366 -452 -494 -498 -563 -559 -569 -302 27 94 127 202 225 44 -19 -340 -407 -331 -310 -70 -174 -299 -212 -139 -75 24 4 -52 53 110 183 292 489 568 458 392 332 257 192 339 311 71 187 174 158 263 237 -12 47 57 4 116 136 7 41 75 57 88 160 215 241 186 22 -168 -299 -263 -212 -210 -102 -115 -96 281 466 438 473 353 366 354 145 133 -27 -105 -92 4 34 -164 -16 164 69 164 207 41 152 291 81 -142 50 -50 -233 -41 -133 -362 -83 120 55 6 45 8 10 57 95 157 87 -14 -81 -79 -248 -295 -432 -421 -396 -582 -596 -329 -104 79 183 218 155 195 88 119 148 152 159 7 -69 -4 -150 9 87 -76 -18 -15 37 -17 -149 -230 -428 -497 -355 -442 -489 -492 -557 -553 -560 -298 27 94 127 204 225 44 -19 -331 -391 -311 -293 -66 -167 -292 -211 -139 -75 24 4 -51 53 110 185 295 496 580 466 402 339 259 193 339 308 70 188 174 158 262 236 -12 47 56 4 113 132 7 41 75 57 89 162 219 245 190 23 -172 -302 -262 -210 -205 SQ 20250515T053810.9Z 9266.234848 297 1 11.94 2 79.61 62.62 73.08 246.65 0.00 1 0.00 1 0 15 2.384e-03 2.373e-03 1.116e-04 1.115e-04 4.030186e+03 6.696537e+00 2.715421e+02 -6.000000e+00 1.286756e+02 281.01 -2.00 20.00 -2.00 505.28 0.00e+00 2.261510e-03 3.033435e-06 1.311120e-04 -6.000000e+00 6.609044e-05 281.01 -2.00 20.00 -2.00 500.55 0.00e+00 3.330771e-01 2.177204e-03 3.733942e-02 -6.000000e+00 4.697652e-02 225.22 -2.00 3.06 -2.00 502.12 0.00e+00 5.330 0.001 489.00 513.00 1 1.5431e+00 1.6628e-04 7.7921e-03 -6.0000e+00 3.5894e-03 -9.3975e-03 4.3452e-05 8.3644e-04 -6.0000e+00 9.4827e-04 2.0704e-01 3.5470e-04 1.0242e-05 5.6044e-05 -6.0000e+00 2.2549e-04 2.0814e-02 -3.2084e-04 10 0 0 10 0 0 12.96 16.41 1.53 0.02081 0.02327 549 101 1 4 0 21.010 19.75 15.00 16.41 13.01 39.60 19.0 796.80 -45 -60 -82 293 453 396 445 309 336 358 121 83 -19 -92 -94 4 49 -175 -11 152 82 155 206 30 126 218 88 -169 49 -53 -185 28 -104 -367 -103 94 45 13 45 -57 8 70 105 135 47 -52 -79 -54 -257 -240 -386 -444 -392 -579 -584 -336 -40 69 137 200 166 157 123 122 134 156 192 45 -86 -2 -124 -4 60 -87 -100 -46 38 -2 -156 -208 -438 -498 -378 -461 -481 -435 -555 -544 -555 -304 9 80 130 195 166 6 -94 -318 -386 -295 -221 -9 -142 -307 -206 -133 -82 31 44 11 59 96 161 281 425 539 441 321 346 236 242 361 277 68 161 130 149 284 209 24 70 44 9 112 209 55 42 23 68 54 164 208 239 186 9 -172 -271 -301 -195 -162 -43 -58 -80 291 456 402 454 319 345 367 122 84 -19 -91 -93 4 49 -177 -11 157 84 158 211 31 131 226 91 -173 49 -53 -181 27 -104 -376 -106 97 46 13 46 -58 8 71 108 139 49 -54 -81 -55 -260 -240 -380 -431 -381 -562 -576 -338 -41 71 140 205 170 159 126 125 136 158 193 45 -85 -2 -121 -4 59 -86 -100 -46 38 -2 -152 -202 -427 -484 -370 -450 -475 -428 -548 -537 -546 -300 9 80 131 197 166 6 -93 -309 -371 -281 -208 -8 -137 -301 -206 -132 -82 30 43 11 58 96 162 283 431 549 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