File name: Pandora55s1_QueensNY_20211230_L2Fit_fout2c19d20211111p1-8.txt File generation date: 20250606T110933.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c19p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 55 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora55_OF_v4d20190723.txt Instrument calibration file used: Pandora55s1_CF_v19d20211111.txt Level 1 file used: Pandora55s1_QueensNY_20211230_L1_smca1c19d20211111p1-8.txt Full location name: Queens College NYSDEC (USEPA AQS ID 36-081-0124) Short location name: QueensNY Country of location: USA Location latitude [deg]: 40.7361 Location longitude [deg]: -73.8215 Location altitude [m]: 25 Local noon date: 20211230 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 261 404 Nominal wavelengths inside fitting window [nm]: 305.0379 305.1778 305.3178 305.4578 305.5977 305.7376 305.8776 306.0175 306.1574 306.2973 306.4372 306.5770 306.7169 306.8567 306.9966 307.1364 307.2762 307.4160 307.5558 307.6956 307.8354 307.9752 308.1149 308.2547 308.3944 308.5341 308.6738 308.8135 308.9532 309.0929 309.2326 309.3723 309.5119 309.6515 309.7912 309.9308 310.0704 310.2100 310.3496 310.4892 310.6287 310.7683 310.9079 311.0474 311.1869 311.3264 311.4659 311.6054 311.7449 311.8844 312.0239 312.1633 312.3028 312.4422 312.5816 312.7210 312.8604 312.9998 313.1392 313.2786 313.4179 313.5573 313.6966 313.8360 313.9753 314.1146 314.2539 314.3932 314.5324 314.6717 314.8110 314.9502 315.0895 315.2287 315.3679 315.5071 315.6463 315.7855 315.9246 316.0638 316.2030 316.3421 316.4812 316.6204 316.7595 316.8986 317.0377 317.1767 317.3158 317.4549 317.5939 317.7329 317.8720 318.0110 318.1500 318.2890 318.4280 318.5669 318.7059 318.8449 318.9838 319.1227 319.2617 319.4006 319.5395 319.6784 319.8172 319.9561 320.0950 320.2338 320.3726 320.5115 320.6503 320.7891 320.9279 321.0667 321.2054 321.3442 321.4830 321.6217 321.7604 321.8991 322.0379 322.1766 322.3152 322.4539 322.5926 322.7312 322.8699 323.0085 323.1471 323.2857 323.4243 323.5629 323.7015 323.8401 323.9786 324.1172 324.2557 324.3943 324.5328 324.6713 324.8098 324.9483 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211230T151036.5Z 8034.632367 237 1 51.18 2 68.56 153.50 63.09 201.70 0.00 1 0.00 1 0 25 4.744e-01 3.848e-02 1.551e-01 7.227e-03 3.679950e-01 3.837070e-03 4.659847e-03 -6.000000e+00 2.821552e-01 223.27 -2.00 3.51 -2.00 318.95 0.00e+00 4.496832e-03 8.665761e-04 3.486121e-04 -6.000000e+00 1.248570e-02 276.32 -2.00 20.00 -2.00 318.38 0.00e+00 2.711 0.000 302.00 328.00 3 5.7765e+00 1.0348e-02 3.3052e-02 -6.0000e+00 6.9620e-01 1.1939e-01 1.1864e-02 2.0079e-02 -6.0000e+00 7.5739e-01 -7.7963e-02 8.5096e-03 9.9377e-03 -6.0000e+00 4.4779e-01 3.8177e-02 4.4777e-03 4.8206e-03 -6.0000e+00 1.9151e-01 6.5427e-05 -1.2408e-02 2.2816e-04 5.0912e-05 -6.0000e+00 1.4445e-02 1.7099e-02 -1.9421e-03 12 9 8 11 40 0 99.98 22.69 1.10 0.01710 -0.07614 18 3 1 5 0 2842.910 25.58 19.99 22.69 14.59 30.3 997.11 77537 900000 -5299 -67546 216766 900000 4465 900000 233519 42173 -58573 66340 -55141 -93366 900000 22924 -23807 11027 294100 143498 85948 36670 53598 -97 25878 -2924 180219 26102 747 -10082 17160 56313 9208 -8505 19721 -10451 -4390 4894 39650 19529 2688 12339 -3839 -4090 -6999 20907 -8854 21722 -4555 18709 3398 2942 -1748 218 18634 8797 12878 -899 10219 2867 3311 15852 1734 -6485 -2021 -5479 7801 -3616 4110 2510 -5896 -1386 -7743 -2799 10186 29 5416 12276 -1747 -271 -5344 7123 2061 -789 -8249 -2108 -5139 -3668 -3034 -390 -1705 -3888 -93 -2825 -2230 1389 -4439 352 1606 -2637 55 499 2259 5234 3949 819 -450 -566 753 4626 1427 -3594 1778 489 -1745 106 -1394 4232 916 -760 -1940 239 2123 1015 70 1715 -1057 50 2525 -1533 -965 1558 2584 1002 1127 -625 1573 -566 922 -2415 -1184 -2001 -272 900000 1711 900000 -291 -6386 1527 900000 195 900000 1645 1590 -5715 2145 -6227 -17733 900000 1957 -3395 1205 2402 5007 5204 3516 4401 -14 2956 -450 5121 3004 105 -1579 2216 5613 1564 -1784 3152 -2151 -883 1017 6990 4783 855 3835 -1438 -1575 -2799 6539 -3632 6719 -1789 6045 1311 1216 -808 104 7868 4164 6000 -474 4835 1431 1666 7483 1007 -4373 -1368 -3788 4567 -2260 2446 1647 -4563 -1097 -6592 -2254 6983 20 3295 6618 -1072 -176 -4087 5395 1773 -736 -8616 -2204 -5808 -4255 -3568 -446 -1899 -4167 -90 -2653 -2091 1350 -4970 418 2039 -3619 74 626 2610 5694 4429 993 -578 -758 1040 6532 2187 -6004 2896 790 -2739 155 -1983 5738 1318 -1160 -3106 381 3303 1556 106 2447 -1489 68 3372 -2227 -1490 2474 4202 1689 1959 -1147 2952 -1105 1800 -4844 -2317 -3834 -495 900000 SS 20211230T195734.4Z 8034.831648 398 1 50.61 2 76.25 221.92 102.95 254.47 0.00 1 0.00 1 0 25 3.243e-01 1.549e-02 9.031e-02 2.773e-03 5.480887e-01 1.456751e-03 6.390515e-03 -6.000000e+00 1.899303e-01 223.28 -2.00 3.51 -2.00 320.02 0.00e+00 1.835627e-03 4.838681e-04 4.724828e-04 -6.000000e+00 8.489182e-03 276.31 -2.00 20.00 -2.00 319.47 0.00e+00 4.109 0.001 302.00 328.00 3 2.9103e+00 4.2020e-03 4.9506e-02 -6.0000e+00 4.6822e-01 7.0501e-02 5.1338e-03 2.8506e-02 -6.0000e+00 5.1041e-01 -7.1261e-02 4.5664e-03 1.4396e-02 -6.0000e+00 3.0313e-01 2.6288e-02 2.3424e-03 4.4667e-03 -6.0000e+00 1.2817e-01 2.5853e-04 -2.2317e-03 8.3194e-05 5.4995e-05 -6.0000e+00 9.8428e-03 -2.6335e-03 -1.3932e-04 12 8 8 10 0 0 99.90 22.71 0.22 -0.00263 -0.01940 36 7 1 5 0 1405.480 25.58 20.00 22.71 16.05 30.4 1004.79 -44944 900000 900000 -135150 7864 101379 -88485 900000 14027 -57816 -102360 -43732 -79891 -122977 133325 -11615 -47419 102774 102195 61760 21830 6847 15447 -15304 893 -13607 113240 7704 -16900 -21186 4711 17802 624 -16323 7608 56296 -2309 -6086 14425 8473 -3471 4229 -6770 -3452 2056 13683 -6765 10583 10448 11585 724 999 -1319 9651 9658 3412 5527 1778 4415 1938 2684 7708 1267 -1753 3856 -3491 2455 -185 1601 1456 -2678 -774 777 -1547 1956 -355 1829 4028 938 102 -1648 940 -994 -1395 -3548 -1322 -2160 -1250 -1344 -365 -1003 -876 -192 1038 419 1058 -1082 315 -14 -1094 -566 -773 595 1347 603 -483 -645 -780 110 826 341 -1142 142 39 -386 602 689 1851 351 0 -1078 -528 397 1195 197 222 218 1271 392 -164 346 349 686 390 380 -456 85 263 -486 -552 -467 -370 -271 -18 -557 900000 900000 -4820 71 362 -1963 900000 150 -1311 -3706 -1001 -2997 -8392 1037 -407 -2600 1536 1653 1536 809 297 632 -885 48 -887 2350 419 -1130 -1506 290 1118 53 -1736 659 3066 -225 -694 1624 1190 -617 763 -1424 -726 418 2551 -1532 2086 2118 2424 178 267 -393 2804 2981 1158 1907 641 1543 681 941 2716 516 -803 1796 -1760 1149 -88 777 775 -1621 -492 498 -993 1162 -201 938 1944 478 57 -1061 662 -777 -1163 -3148 -1211 -2089 -1244 -1358 -364 -973 -810 -167 874 364 989 -1133 359 -17 -1426 -732 -952 681 1476 673 -566 -790 -994 146 1154 510 -1822 230 64 -609 909 1011 2703 533 -1 -1758 -859 631 1847 299 329 314 1783 566 -253 570 607 1232 721 728 -912 174 549 -1030 -1170 -973 -747 -529 -35 SS 20211230T202350.5Z 8034.849890 410 1 49.82 2 79.73 226.96 107.63 258.24 0.00 1 0.00 1 0 25 5.872e-01 3.662e-02 1.765e-01 5.413e-03 6.825055e-01 3.001582e-03 8.005333e-03 -6.000000e+00 3.499067e-01 223.28 -2.00 3.51 -2.00 321.03 0.00e+00 1.086680e-02 1.309774e-03 1.054916e-03 -6.000000e+00 1.738851e-02 276.30 -2.00 20.00 -2.00 320.53 0.00e+00 5.381 0.003 302.00 328.00 3 2.5617e+00 9.4535e-03 6.4129e-02 -6.0000e+00 8.6536e-01 5.0312e-01 1.2021e-02 3.7324e-02 -6.0000e+00 9.4820e-01 -6.9881e-01 1.0604e-02 2.1188e-02 -6.0000e+00 5.6106e-01 3.0371e-01 5.1761e-03 1.3508e-02 -6.0000e+00 2.3413e-01 8.7712e-05 -4.5150e-03 1.6059e-04 1.6598e-04 -6.0000e+00 1.8055e-02 1.1742e-03 -3.4218e-04 12 9 8 11 32 0 99.83 22.71 0.37 0.00117 -0.03275 23 4 1 5 0 2165.770 25.58 20.00 22.71 16.13 30.5 1005.23 -62949 900000 900000 -132820 173222 900000 -85262 900000 299337 -78513 900000 -53634 -105700 -181515 900000 -2785 -41373 900000 900000 900000 304763 66919 87034 923 30886 33127 900000 113280 -1831 -30179 50695 156705 35407 -12128 99836 31320 30369 -2366 143426 75235 24255 68962 6729 23388 34334 103798 -865 73316 62669 76630 20975 27486 18080 32081 60610 31596 44058 17135 25121 15880 18730 36282 14050 -3477 15191 -3352 22429 1507 10289 9236 -3602 4416 9720 -768 14319 2246 5339 13806 -4277 -11 -6977 -816 2235 -740 -7424 -3287 -5561 -3503 -3597 -1178 -3550 -3429 -1742 -2391 -5028 -970 -5955 -551 -1276 -3308 -1760 -2568 85 3435 1093 -1902 -754 -2115 72 1575 725 -3467 67 -826 -1594 -161 802 3250 -366 1409 -744 980 1755 5065 1368 1948 537 2006 598 301 446 1634 2060 1301 646 -358 875 411 -366 -1470 -1510 -1118 -770 -1622 -1481 900000 900000 -7133 913 900000 -2357 900000 1577 -2189 900000 -1297 -4994 -21972 900000 -95 -2285 900000 900000 900000 1606 1550 1629 39 998 1061 900000 1651 -78 -1753 1570 2118 1730 -995 2884 1652 1634 -190 3414 3898 2244 4522 825 2536 3411 5507 -124 5404 5288 5954 2931 3941 3083 5155 7860 5520 6997 3465 4620 3105 3578 6208 3276 -1063 4268 -1148 5995 487 3212 3204 -1549 1884 4019 -340 5192 833 1762 4073 -1557 -4 -3411 -431 1277 -466 -5225 -2347 -4252 -2743 -2866 -911 -2707 -2484 -1180 -1599 -3598 -745 -5414 -543 -1400 -3914 -2064 -2876 85 3192 1040 -1940 -799 -2381 84 1976 1005 -5348 104 -1311 -2488 -240 1158 4634 -555 2198 -1208 1566 2718 7423 2012 2781 755 2735 854 468 759 2959 3916 2581 1343 -782 1961 941 -848 -3426 -3433 -2440 -1598 -3307