File name: Pandora55s1_QueensNY_20220208_L2Fit_fout2c19d20211111p1-8.txt File generation date: 20250606T112955.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c19p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 55 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora55_OF_v4d20190723.txt Instrument calibration file used: Pandora55s1_CF_v19d20211111.txt Level 1 file used: Pandora55s1_QueensNY_20220208_L1_smca1c19d20211111p1-8.txt Full location name: Queens College NYSDEC (USEPA AQS ID 36-081-0124) Short location name: QueensNY Country of location: USA Location latitude [deg]: 40.7361 Location longitude [deg]: -73.8215 Location altitude [m]: 25 Local noon date: 20220208 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 261 404 Nominal wavelengths inside fitting window [nm]: 305.0379 305.1778 305.3178 305.4578 305.5977 305.7376 305.8776 306.0175 306.1574 306.2973 306.4372 306.5770 306.7169 306.8567 306.9966 307.1364 307.2762 307.4160 307.5558 307.6956 307.8354 307.9752 308.1149 308.2547 308.3944 308.5341 308.6738 308.8135 308.9532 309.0929 309.2326 309.3723 309.5119 309.6515 309.7912 309.9308 310.0704 310.2100 310.3496 310.4892 310.6287 310.7683 310.9079 311.0474 311.1869 311.3264 311.4659 311.6054 311.7449 311.8844 312.0239 312.1633 312.3028 312.4422 312.5816 312.7210 312.8604 312.9998 313.1392 313.2786 313.4179 313.5573 313.6966 313.8360 313.9753 314.1146 314.2539 314.3932 314.5324 314.6717 314.8110 314.9502 315.0895 315.2287 315.3679 315.5071 315.6463 315.7855 315.9246 316.0638 316.2030 316.3421 316.4812 316.6204 316.7595 316.8986 317.0377 317.1767 317.3158 317.4549 317.5939 317.7329 317.8720 318.0110 318.1500 318.2890 318.4280 318.5669 318.7059 318.8449 318.9838 319.1227 319.2617 319.4006 319.5395 319.6784 319.8172 319.9561 320.0950 320.2338 320.3726 320.5115 320.6503 320.7891 320.9279 321.0667 321.2054 321.3442 321.4830 321.6217 321.7604 321.8991 322.0379 322.1766 322.3152 322.4539 322.5926 322.7312 322.8699 323.0085 323.1471 323.2857 323.4243 323.5629 323.7015 323.8401 323.9786 324.1172 324.2557 324.3943 324.5328 324.6713 324.8098 324.9483 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220208T133615.6Z 8074.566847 99 1 15.32 2 74.34 126.41 111.48 42.59 0.00 1 0.00 1 0 25 3.025e-01 1.523e-02 1.512e-01 4.899e-03 5.574980e-01 2.574050e-03 6.488384e-03 -6.000000e+00 1.789842e-01 224.64 -2.00 3.51 -2.00 319.77 0.00e+00 1.604198e-03 7.885752e-04 5.996702e-04 -6.000000e+00 7.923961e-03 275.27 -2.00 20.00 -2.00 319.23 0.00e+00 3.639 0.001 302.00 328.00 3 3.1828e+00 7.2833e-03 4.6217e-02 -6.0000e+00 4.4231e-01 9.6272e-02 8.7497e-03 2.9058e-02 -6.0000e+00 4.8172e-01 -6.1306e-02 7.5964e-03 1.4531e-02 -6.0000e+00 2.8492e-01 2.2917e-02 3.9434e-03 4.5188e-03 -6.0000e+00 1.1914e-01 2.9245e-04 -1.3844e-03 1.4478e-04 5.3504e-05 -6.0000e+00 9.1768e-03 -5.9502e-03 -6.8569e-05 12 9 9 12 1 1 99.94 22.67 0.18 -0.00595 -0.01635 8 6 1 5 0 1682.580 25.58 19.98 22.67 8.82 30.0 1012.36 40444 102631 900000 -136401 30147 900000 -132839 900000 6682 52532 -99069 26436 -74910 -93201 131740 -8081 -39458 39873 68447 28055 98825 -16724 33744 -20894 -10082 -14206 64223 -7254 -13513 -17921 -4677 23008 -8032 -3942 -5490 37853 -10046 1883 9831 8562 -3268 1836 -6252 -2084 6925 7484 -3274 6063 8986 8129 1693 1268 -3491 6718 6286 1697 6466 2761 4010 1856 58 4450 361 -1412 3700 723 1081 -531 2875 176 64 -2101 432 -3294 3163 -80 -282 5610 665 2703 -1671 -484 -2849 -561 -2635 -1572 -2141 -1040 -1341 -1256 466 -96 1247 -359 1409 -213 -69 -659 -259 -1552 -291 296 196 1013 804 139 -949 -757 -75 1400 -429 -1034 650 -736 -986 656 1405 1406 689 -254 -557 -19 852 -503 -190 554 134 1331 474 270 610 326 615 917 443 -457 267 -173 -357 -886 -493 -334 104 -413 252 490 900000 -5471 248 900000 -4947 900000 86 482 -3884 357 -3009 -5424 1177 -308 -2253 1201 1702 1066 2033 -1011 1314 -1428 -674 -1047 2357 -508 -988 -1389 -353 1553 -823 -421 -603 2749 -1179 225 1299 1348 -651 379 -1463 -485 1508 1647 -800 1387 2050 1953 458 376 -1170 2210 2206 645 2438 1083 1544 715 23 1764 161 -700 1874 381 555 -274 1496 102 41 -1444 297 -2288 1993 -48 -158 2879 363 1589 -1144 -365 -2380 -487 -2434 -1508 -2156 -1072 -1405 -1303 463 -91 1117 -318 1263 -208 -74 -777 -328 -2066 -382 370 231 1137 912 165 -1182 -975 -100 1962 -648 -1649 1052 -1197 -1561 992 2053 2062 1040 -400 -899 -31 1337 -779 -287 812 191 1853 679 409 989 557 1086 1658 829 -893 534 -353 -734 -1827 -996 -654 196 -769 SS 20220208T134125.4Z 8074.570433 103 1 47.21 2 73.55 127.42 110.83 43.66 0.00 1 0.00 1 0 25 7.781e-02 5.237e-03 1.198e-02 6.606e-04 5.378759e-01 3.417330e-04 6.287978e-03 -6.000000e+00 4.554088e-02 224.64 -2.00 3.51 -2.00 319.44 0.00e+00 1.085344e-03 9.402734e-05 4.472567e-04 -6.000000e+00 1.980576e-03 275.27 -2.00 20.00 -2.00 318.89 0.00e+00 3.476 0.001 302.00 328.00 3 7.7015e-01 9.5113e-04 4.4228e-02 -6.0000e+00 1.1251e-01 4.0840e-02 1.1201e-03 2.7735e-02 -6.0000e+00 1.2240e-01 -2.1938e-02 9.3152e-04 1.3880e-02 -6.0000e+00 7.2826e-02 8.9020e-05 4.9052e-04 4.1507e-03 -6.0000e+00 3.0543e-02 4.0120e-03 -1.1957e-03 1.9274e-05 5.0215e-05 -6.0000e+00 2.3210e-03 -1.4216e-02 -1.6865e-04 10 0 0 10 0 0 97.28 22.67 0.23 -0.01422 -0.02320 381 72 1 5 0 123.880 25.58 19.99 22.67 9.15 30.3 1013.15 -33517 -15817 -1444 -39602 -29582 -20400 -29665 -9727 -17317 -26666 -26451 -20354 -15035 -21707 1914 -5176 -7062 -4473 1335 268 -1119 -3034 -1449 -2674 -3850 -2437 -1140 -3233 -3301 -5186 -1383 346 514 -2611 -1756 412 -752 -1189 917 -502 -1804 -1199 -1701 -964 -595 744 -757 271 401 1473 1031 1255 1127 1713 1408 494 1265 152 743 237 1367 1406 1705 723 144 169 380 372 1109 931 358 -109 -540 -532 -616 -149 149 539 601 -74 -124 -600 -1338 -1238 -1324 -1102 -664 -543 -279 -309 298 639 736 1319 1062 1156 827 692 -246 -228 -393 -523 -105 310 -395 -752 -396 -836 -80 -163 -89 -268 -5 61 28 531 608 780 321 -188 -566 -119 -191 -291 108 -15 548 1104 453 126 433 -25 266 -14 23 -345 -43 141 -389 -282 -32 38 -35 -70 -491 -229 -20 -789 -504 -306 -511 -155 -339 -628 -662 -523 -432 -826 71 -244 -353 -239 73 16 -69 -195 -94 -188 -298 -199 -94 -270 -270 -439 -124 35 60 -345 -233 53 -101 -170 155 -104 -434 -315 -441 -257 -161 201 -210 76 114 433 327 436 432 660 580 216 567 70 336 106 605 655 874 390 84 100 219 210 649 607 248 -82 -395 -404 -441 -97 94 318 362 -50 -91 -481 -1142 -1142 -1299 -1092 -695 -594 -296 -340 312 624 705 1207 1003 1142 887 807 -323 -304 -521 -677 -129 358 -466 -903 -502 -1073 -108 -230 -132 -429 -9 96 44 815 895 1145 493 -293 -922 -194 -303 -445 165 -21 801 1557 661 194 704 -42 457 -25 42 -671 -85 284 -774 -558 -63 74 -64 -131 SS 20220208T135944.6Z 8074.583155 112 1 45.82 2 70.86 131.11 108.39 47.33 0.00 1 0.00 1 0 25 3.747e-02 5.344e-03 4.556e-03 4.558e-04 4.719073e-01 2.345714e-04 5.604286e-03 -6.000000e+00 2.193043e-02 224.64 -2.00 3.51 -2.00 318.78 0.00e+00 5.507639e-04 5.224845e-05 2.312437e-04 -6.000000e+00 9.537479e-04 275.27 -2.00 20.00 -2.00 318.21 0.00e+00 3.015 0.000 302.00 328.00 3 5.7400e-01 6.3646e-04 3.8495e-02 -6.0000e+00 5.4179e-02 3.0317e-02 7.2985e-04 2.4121e-02 -6.0000e+00 5.8940e-02 -2.1463e-02 5.3575e-04 1.2050e-02 -6.0000e+00 3.5069e-02 2.3915e-03 2.8339e-04 3.4817e-03 -6.0000e+00 1.4708e-02 8.2322e-03 -1.1722e-03 1.3530e-05 4.2729e-05 -6.0000e+00 1.1177e-03 -1.4880e-02 -1.8972e-04 10 0 0 10 0 0 53.16 22.67 0.23 -0.01488 -0.02369 548 104 1 5 0 83.600 25.58 19.99 22.67 10.58 30.3 1013.82 -16121 -10028 -8340 -17548 -14360 -11692 -14005 -8091 -8190 -11870 -10567 -8526 -7180 -7356 -513 -2188 -1796 -2038 971 295 -582 318 -26 -806 -1122 -1638 -1262 -2302 -1630 -873 184 1390 814 -1839 -1446 -457 -542 -176 681 -194 -1012 -747 -1288 -960 -541 18 -657 -295 -226 837 752 965 1310 1069 1159 696 891 250 463 621 1315 1247 1688 662 -21 367 226 432 1027 923 301 -45 -435 -387 -517 -3 193 355 615 22 71 -638 -1407 -1319 -1413 -1188 -745 -544 -375 -370 92 500 542 1193 1148 1119 854 737 -299 -368 -369 -574 -127 353 -391 -713 -424 -823 -156 -180 -95 -246 -27 34 10 622 659 707 381 -203 -425 -216 -202 -188 216 105 636 1245 548 257 427 54 237 -11 60 -301 -64 105 -418 -256 -76 -101 -129 -55 -425 -289 -253 -578 -430 -327 -417 -255 -293 -480 -444 -377 -361 -449 -35 -164 -149 -184 91 29 -61 33 -3 -93 -140 -219 -172 -311 -212 -113 25 215 144 -332 -262 -87 -99 -37 169 -54 -325 -261 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