File name: Pandora55s1_QueensNY_20230717_L2Fit_fwvt1c18d20230426p1-8.txt File generation date: 20240824T115843.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c18p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 55 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora55_OF_v5d20190723.txt Instrument calibration file used: Pandora55s1_CF_v18d20230426.txt Level 1 file used: Pandora55s1_QueensNY_20230717_L1_smca1c18d20230426p1-8.txt Full location name: Queens College NYSDEC (USEPA AQS ID 36-081-0124) Short location name: QueensNY Country of location: USA Location latitude [deg]: 40.7361 Location longitude [deg]: -73.8215 Location altitude [m]: 25 Local noon date: 20230717 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 17 for new VP from 20230426 First and last pixel inside fitting window: 1689 1839 Nominal wavelengths inside fitting window [nm]: 492.0793 492.1997 492.3201 492.4405 492.5609 492.6813 492.8016 492.9220 493.0423 493.1626 493.2829 493.4032 493.5234 493.6436 493.7639 493.8841 494.0043 494.1244 494.2446 494.3647 494.4848 494.6049 494.7250 494.8451 494.9652 495.0852 495.2052 495.3252 495.4452 495.5652 495.6852 495.8051 495.9250 496.0449 496.1648 496.2847 496.4046 496.5244 496.6442 496.7640 496.8838 497.0036 497.1234 497.2431 497.3628 497.4826 497.6022 497.7219 497.8416 497.9612 498.0809 498.2005 498.3201 498.4397 498.5592 498.6788 498.7983 498.9178 499.0373 499.1568 499.2762 499.3957 499.5151 499.6345 499.7539 499.8733 499.9927 500.1120 500.2314 500.3507 500.4700 500.5893 500.7085 500.8278 500.9470 501.0662 501.1854 501.3046 501.4238 501.5429 501.6621 501.7812 501.9003 502.0194 502.1384 502.2575 502.3765 502.4955 502.6145 502.7335 502.8525 502.9714 503.0904 503.2093 503.3282 503.4471 503.5659 503.6848 503.8036 503.9225 504.0413 504.1600 504.2788 504.3976 504.5163 504.6350 504.7537 504.8724 504.9911 505.1097 505.2284 505.3470 505.4656 505.5842 505.7028 505.8213 505.9399 506.0584 506.1769 506.2954 506.4138 506.5323 506.6507 506.7692 506.8876 507.0060 507.1243 507.2427 507.3610 507.4793 507.5976 507.7159 507.8342 507.9525 508.0707 508.1889 508.3071 508.4253 508.5435 508.6617 508.7798 508.8979 509.0160 509.1341 509.2522 509.3702 509.4883 509.6063 509.7243 509.8423 509.9603 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20230717T112650.0Z 8598.476968 100 1 33.29 2 71.71 77.43 67.41 74.28 0.00 1 0.00 1 0 22 2.974e-03 2.958e-03 4.408e-04 4.404e-04 6.190478e+03 2.806779e+01 4.246959e+02 -6.000000e+00 1.643801e+02 289.63 -2.00 20.00 -2.00 505.30 0.00e+00 1.340148e-03 1.216237e-05 7.884007e-05 -6.000000e+00 8.367011e-05 289.63 -2.00 20.00 -2.00 500.59 0.00e+00 2.582019e-01 8.523527e-03 4.071504e-02 -6.000000e+00 5.804405e-02 232.83 -2.00 3.51 -2.00 502.16 0.00e+00 3.144 0.001 489.00 513.00 1 5.1949e+00 6.5333e-04 5.9721e-03 -6.0000e+00 4.4527e-03 -3.0702e-02 1.6845e-04 9.9577e-04 -6.0000e+00 1.1630e-03 6.6179e-03 1.4011e-03 3.8539e-05 5.2320e-05 -6.0000e+00 2.7137e-04 -1.1409e-03 -1.7853e-05 10 0 0 10 0 0 41.19 22.66 0.95 -0.00114 0.00858 40 8 1 4 0 831.960 25.90 20.03 22.66 31.59 36.0 1100.00 -844 -392 -237 294 414 312 586 383 365 258 -204 -222 -196 -273 -297 -180 16 -30 169 501 226 161 215 48 193 293 95 -122 125 -291 -564 -213 -166 -153 269 561 113 -101 -138 -237 -249 -58 109 225 299 425 383 154 -232 -78 -449 -838 -504 -492 -257 7 227 274 313 277 113 212 282 145 211 209 82 -206 -326 -110 -370 -368 -143 -138 -120 49 69 -326 -369 -333 -440 -442 -92 -39 -272 -130 -98 -15 -50 -134 112 32 35 363 477 137 136 -8 -313 -435 -559 -401 -326 -406 62 105 -91 -141 -187 -498 -279 190 206 202 559 624 350 333 530 366 80 162 87 -179 212 263 121 144 258 -17 72 221 -255 -314 63 -198 -349 122 270 208 370 232 140 152 195 -6 -112 -239 -302 -530 -368 -804 -380 -233 293 415 320 599 396 376 263 -209 -224 -195 -273 -296 -180 16 -30 174 512 232 165 221 50 200 304 98 -125 127 -291 -557 -211 -164 -155 280 576 116 -104 -140 -240 -252 -59 112 230 310 441 395 158 -238 -78 -444 -826 -489 -482 -254 7 229 279 319 281 115 217 289 149 215 210 83 -205 -322 -109 -364 -363 -140 -137 -121 49 67 -321 -358 -322 -428 -433 -89 -38 -270 -128 -97 -15 -50 -132 110 32 35 364 472 135 134 -7 -298 -413 -527 -376 -310 -397 61 105 -91 -139 -185 -488 -277 191 206 204 566 635 354 339 539 369 81 160 87 -179 209 261 120 143 255 -17 71 219 -248 -303 61 -191 -341 121 268 209 375 233 141 154 199 -6 -113 -239 -300 -521 -363 SO 20230717T113054.3Z 8598.479796 103 1 33.87 2 70.96 78.03 66.69 74.84 0.00 1 0.00 1 0 22 2.795e-03 2.775e-03 4.001e-04 3.997e-04 5.893321e+03 2.536548e+01 4.083414e+02 -6.000000e+00 1.544680e+02 289.63 -2.00 20.00 -2.00 505.30 0.00e+00 1.210903e-03 1.103948e-05 7.110438e-05 -6.000000e+00 7.862472e-05 289.63 -2.00 20.00 -2.00 500.59 0.00e+00 2.510263e-01 7.738256e-03 3.807294e-02 -6.000000e+00 5.454332e-02 232.83 -2.00 3.51 -2.00 502.16 0.00e+00 3.028 0.000 489.00 513.00 1 5.0409e+00 5.9305e-04 5.6679e-03 -6.0000e+00 4.1842e-03 -2.9208e-02 1.5302e-04 9.4232e-04 -6.0000e+00 1.0928e-03 7.8716e-03 1.3793e-03 3.5000e-05 5.0287e-05 -6.0000e+00 2.5500e-04 -3.9072e-03 -1.7199e-07 10 0 0 10 0 0 64.71 22.65 0.87 -0.00391 0.00566 50 9 1 4 0 677.220 26.00 19.98 22.65 31.79 36.1 1100.00 -876 -385 -225 242 483 277 418 417 294 280 -200 -133 -174 -254 -321 -151 -30 -85 160 448 171 113 210 56 250 339 203 -163 135 -296 -639 -190 -135 -41 192 442 137 -87 -219 -82 -140 -8 101 216 318 286 282 102 -146 -160 -413 -727 -511 -529 -264 33 234 289 319 105 137 221 306 213 161 201 105 -226 -281 -115 -364 -336 -192 -52 -53 72 63 -338 -417 -260 -456 -377 -23 -51 -188 -124 -109 38 -22 -79 124 51 152 272 418 102 252 -3 -268 -319 -556 -459 -320 -415 13 139 -135 -110 -218 -439 -229 121 198 236 389 556 428 266 458 317 99 166 111 -227 205 236 70 104 299 -100 20 181 -207 -203 -60 -191 -272 198 190 167 256 250 138 234 224 57 -156 -200 -346 -530 -331 -834 -373 -222 241 484 284 428 430 303 285 -205 -134 -173 -254 -320 -151 -30 -85 165 458 176 116 216 58 259 352 211 -168 136 -296 -630 -187 -134 -41 200 455 143 -90 -223 -83 -142 -8 104 221 329 297 291 105 -149 -160 -408 -714 -495 -516 -260 33 240 294 324 106 139 226 314 219 164 202 105 -225 -277 -114 -357 -330 -187 -51 -53 72 61 -331 -405 -250 -442 -368 -22 -49 -186 -122 -107 38 -22 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4 0 638.950 26.00 19.98 22.66 32.11 36.1 1100.00 -801 -322 -223 239 523 285 499 385 373 221 -155 -196 -130 -309 -349 -202 45 -74 150 519 151 200 228 104 116 332 161 -84 123 -344 -567 -169 -158 -133 202 384 146 -90 -161 -169 -165 -9 75 231 276 336 180 91 -192 -134 -372 -723 -453 -557 -248 10 244 275 320 190 203 239 238 216 137 198 83 -194 -294 -162 -301 -327 -233 -117 -58 37 39 -245 -420 -342 -409 -444 -67 -15 -222 -146 -171 -34 -68 -96 94 73 96 354 442 15 188 -54 -203 -366 -559 -425 -257 -482 13 135 -99 -109 -147 -460 -271 161 255 217 442 564 381 319 450 427 20 117 34 -136 99 297 109 128 306 -124 54 191 -181 -198 14 -212 -246 178 223 150 283 222 170 216 214 80 -129 -145 -398 -494 -393 -767 -314 -221 239 526 289 513 399 386 226 -157 -199 -129 -305 -350 -200 46 -75 153 532 156 207 236 108 121 346 167 -86 125 -346 -562 -167 -157 -136 208 396 150 -92 -165 -171 -168 -9 76 237 286 350 187 94 -194 -134 -369 -714 -441 -547 -246 11 246 280 325 193 207 245 245 222 140 199 83 -193 -291 -158 -296 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