File name: Pandora55s1_QueensNY_20231211_L2Fit_fout2c17d20220526p1-8.txt File generation date: 20240113T140527.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c17p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 55 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora55_OF_v5d20190723.txt Instrument calibration file used: Pandora55s1_CF_v17d20220526.txt Level 1 file used: Pandora55s1_QueensNY_20231211_L1_smca1c17d20220526p1-8.txt Full location name: Queens College NYSDEC (USEPA AQS ID 36-081-0124) Short location name: QueensNY Country of location: USA Location latitude [deg]: 40.7361 Location longitude [deg]: -73.8215 Location altitude [m]: 25 Local noon date: 20231211 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 262 404 Nominal wavelengths inside fitting window [nm]: 305.1320 305.2720 305.4120 305.5520 305.6920 305.8320 305.9719 306.1119 306.2518 306.3917 306.5317 306.6716 306.8115 306.9514 307.0912 307.2311 307.3709 307.5108 307.6506 307.7905 307.9303 308.0701 308.2099 308.3496 308.4894 308.6292 308.7689 308.9087 309.0484 309.1881 309.3278 309.4675 309.6072 309.7469 309.8866 310.0262 310.1659 310.3055 310.4451 310.5847 310.7243 310.8639 311.0035 311.1431 311.2827 311.4222 311.5618 311.7013 311.8408 311.9803 312.1198 312.2593 312.3988 312.5383 312.6777 312.8172 312.9566 313.0960 313.2355 313.3749 313.5143 313.6536 313.7930 313.9324 314.0717 314.2111 314.3504 314.4897 314.6291 314.7684 314.9077 315.0469 315.1862 315.3255 315.4647 315.6040 315.7432 315.8824 316.0216 316.1608 316.3000 316.4392 316.5783 316.7175 316.8566 316.9958 317.1349 317.2740 317.4131 317.5522 317.6913 317.8303 317.9694 318.1085 318.2475 318.3865 318.5255 318.6645 318.8035 318.9425 319.0815 319.2205 319.3594 319.4984 319.6373 319.7762 319.9151 320.0540 320.1929 320.3318 320.4707 320.6095 320.7484 320.8872 321.0260 321.1649 321.3037 321.4425 321.5812 321.7200 321.8588 321.9975 322.1363 322.2750 322.4137 322.5524 322.6911 322.8298 322.9685 323.1072 323.2458 323.3845 323.5231 323.6617 323.8003 323.9389 324.0775 324.2161 324.3547 324.4932 324.6318 324.7703 324.9089 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231211T153812.2Z 8745.651530 171 1 2.92 2 65.81 162.26 65.43 181.10 0.00 1 0.00 1 0 25 1.204e-02 6.448e-03 5.440e-03 1.645e-03 3.458135e-01 8.466303e-04 4.190515e-03 -6.000000e+00 7.022702e-03 222.88 -2.00 3.51 -2.00 317.30 0.00e+00 -9.651324e-05 1.235546e-04 9.738111e-05 -6.000000e+00 3.104069e-04 277.68 -2.00 20.00 -2.00 316.68 0.00e+00 2.423 0.000 302.00 328.00 3 1.1969e+00 2.2099e-03 2.9704e-02 -6.0000e+00 1.7270e-02 3.5959e-02 2.4858e-03 1.7385e-02 -6.0000e+00 1.8790e-02 -1.2907e-02 1.5123e-03 8.6822e-03 -6.0000e+00 1.1204e-02 1.2231e-03 7.5251e-04 2.4948e-03 -6.0000e+00 4.7706e-03 9.2685e-03 1.6485e-04 5.0038e-05 3.2686e-05 -6.0000e+00 3.6102e-04 7.5665e-03 0.0000e+00 12 9 1 12 5 1 93.07 22.92 0.20 0.00757 0.00881 20 69 1 5 0 138.520 26.21 20.00 22.92 11.70 34.9 977.74 -3699 -4889 -6504 -2726 -2996 -1701 1235 996 -3089 -1296 1862 -1559 -109 1186 -1134 -119 -2081 726 266 221 678 1089 912 1184 294 -346 -445 -196 672 1841 1945 811 -1115 -521 623 -291 412 487 -80 -1300 -1166 -1412 -1337 -972 -634 -986 -372 -520 351 1018 394 644 703 475 747 787 438 436 844 1197 1304 1343 699 -459 -91 447 523 1462 1185 84 -52 -315 -525 -532 -335 76 630 1406 563 -218 -694 -1509 -1558 -1141 -1048 -808 -566 -524 -647 -238 326 678 1430 1392 1124 958 713 -227 -637 -559 -537 -70 716 -189 -903 -227 -781 -90 -220 -16 -312 -326 -38 -42 532 998 675 797 -147 -572 -493 -315 -285 198 106 554 1264 1215 470 555 53 203 303 343 -279 -300 92 -367 -449 -234 -254 -390 142 -381 -540 -719 -270 -278 -158 123 112 -363 -155 223 -212 -17 212 -219 -25 -469 167 64 55 170 275 241 334 83 -100 -125 -56 186 516 555 258 -387 -180 206 -99 146 206 -38 -673 -621 -790 -766 -559 -364 -567 -210 -291 196 584 243 406 472 320 520 563 318 314 596 842 953 1013 552 -387 -76 368 408 1138 961 73 -48 -298 -492 -496 -289 62 488 1111 457 -192 -666 -1485 -1646 -1224 -1153 -944 -670 -636 -781 -275 363 716 1454 1403 1210 1064 855 -292 -845 -736 -688 -84 848 -230 -1141 -292 -1026 -124 -311 -24 -471 -504 -57 -61 742 1353 909 1111 -212 -849 -746 -471 -413 283 150 744 1672 1613 647 799 79 304 468 536 -449 -509 156 -637 -783 -400 -429 -632 229 SS 20231211T154239.6Z 8745.654625 175 1 8.94 2 65.56 163.35 65.46 182.19 0.00 1 0.00 1 0 25 4.192e-02 9.398e-03 1.664e-02 3.966e-03 3.406923e-01 2.033463e-03 4.120705e-03 -6.000000e+00 2.446842e-02 222.88 -2.00 3.51 -2.00 317.66 0.00e+00 2.573451e-04 3.294364e-04 9.041421e-05 -6.000000e+00 1.081292e-03 277.68 -2.00 20.00 -2.00 317.03 0.00e+00 2.400 0.000 302.00 328.00 3 3.8356e+00 5.3459e-03 2.9395e-02 -6.0000e+00 6.0171e-02 5.2910e-02 6.0367e-03 1.7197e-02 -6.0000e+00 6.5459e-02 -3.9216e-03 3.7924e-03 8.6065e-03 -6.0000e+00 3.9031e-02 -1.9831e-03 1.9286e-03 2.5128e-03 -6.0000e+00 1.6627e-02 6.7222e-04 5.4083e-04 1.2145e-04 3.1368e-05 -6.0000e+00 1.2574e-03 4.8313e-03 0.0000e+00 12 9 9 12 5 1 99.96 22.93 0.25 0.00483 0.00890 6 8 1 5 0 1276.120 26.21 20.00 22.93 11.94 35.2 979.50 -4603 25241 -16112 3604 -3935 -917 19982 3448 -3230 -9326 -3674 -4478 -10608 8906 7494 -7908 -15004 5585 5205 3482 2333 1539 -5524 -246 -1195 9642 -1197 -540 1747 396 1822 236 -2699 195 4902 -2581 -1868 779 1994 -3957 -1003 -2746 -1436 -1307 -93 -1399 130 247 1144 310 1264 68 2099 2120 847 1849 334 1803 -170 2720 2036 1557 27 -269 -235 975 -453 1635 985 -1115 112 883 -1080 -433 -697 467 1572 717 273 -393 -274 -1743 -1039 -1432 -1431 -1201 -664 -667 -681 -239 30 -44 1233 1334 961 448 687 -186 -797 -618 -968 -455 641 -187 -441 -106 -1197 426 874 305 -155 378 -47 192 914 774 946 526 -6 -1149 -765 -486 334 -206 -180 422 1189 1108 -427 1016 250 493 175 384 -382 -124 8 -71 -875 -314 -103 -98 -82 -369 1624 -1498 263 -289 -67 1309 293 -314 -993 -382 -513 -1469 1190 1143 -1490 -3159 1028 1003 699 479 321 -1273 -57 -295 2206 -295 -127 393 92 453 65 -804 57 1340 -763 -603 284 826 -1902 -502 -1445 -764 -698 -49 -748 68 129 594 166 706 41 1293 1360 562 1246 229 1219 -116 1810 1400 1137 21 -219 -191 755 -343 1223 784 -970 102 817 -1006 -390 -598 372 1174 533 212 -334 -252 -1727 -1073 -1537 -1599 -1394 -794 -811 -826 -281 33 -47 1255 1348 1015 506 831 -240 -1069 -825 -1250 -556 756 -225 -551 -138 -1607 583 1237 451 -238 587 -72 284 1292 1060 1288 732 -9 -1730 -1165 -733 494 -299 -254 577 1577 1478 -595 1471 377 759 275 615 -634 -211 15 -125 -1551 -549 -176 -164 -135 SS 20231211T154656.3Z 8745.657596 178 1 51.32 2 65.33 164.41 65.51 183.23 0.00 1 0.00 1 0 33 1.158e-02 6.308e-03 6.635e-04 1.993e-04 3.390889e-01 1.023662e-04 4.108291e-03 -6.000000e+00 6.759376e-03 222.88 -2.00 3.51 -2.00 317.32 0.00e+00 -3.022098e-05 1.501919e-05 1.124579e-04 -6.000000e+00 2.987573e-04 277.68 -2.00 20.00 -2.00 316.70 0.00e+00 2.380 0.000 302.00 328.00 3 -7.4516e-02 2.6725e-04 2.9157e-02 -6.0000e+00 1.6622e-02 2.1637e-02 3.0082e-04 1.7054e-02 -6.0000e+00 1.8085e-02 -1.0117e-02 1.8338e-04 8.5301e-03 -6.0000e+00 1.0783e-02 3.5301e-04 9.1338e-05 2.4598e-03 -6.0000e+00 4.5920e-03 3.5031e-02 2.4909e-04 6.0786e-06 3.1468e-05 -6.0000e+00 3.4746e-04 7.0467e-03 0.0000e+00 11 1 0 11 4 0 82.64 22.92 0.21 0.00705 0.00892 1652 312 1 5 0 30.540 26.21 20.00 22.92 12.30 35.2 982.43 -3848 -4041 -5625 -4561 -3521 -2496 -1630 -1177 -2387 -2122 -646 -501 -243 -1 -474 -318 -205 276 299 -184 698 1287 700 453 106 -475 -747 189 1306 1107 1458 1453 -1028 -789 0 -47 334 346 -537 -1172 -884 -1037 -891 -603 -341 -707 -547 -440 500 828 658 957 844 689 600 854 343 668 828 1417 1337 1294 636 -540 -11 172 482 1302 806 89 -351 -726 -553 -768 -149 295 545 1371 326 102 -740 -1518 -1326 -1176 -1183 -841 -637 -519 -634 -187 282 442 1366 1475 1319 910 830 -308 -564 -420 -571 -42 699 12 -817 -338 -760 -139 -96 -116 -307 -246 -93 -69 574 878 871 676 -100 -593 -534 -273 -334 119 208 475 1415 1069 446 521 56 284 171 260 -245 -215 135 -412 -471 -281 -264 -243 60 -384 -429 -597 -445 -318 -226 -161 -131 -291 -267 -83 -70 -39 0 -94 -69 -47 66 69 -44 168 310 177 123 30 -140 -216 52 342 297 426 468 -338 -259 0 -15 120 139 -258 -608 -470 -578 -508 -345 -195 -405 -310 -246 278 474 403 597 562 459 414 603 247 475 578 985 968 965 519 -449 -9 140 371 999 675 80 -327 -675 -530 -705 -132 246 417 1069 261 88 -695 -1519 -1363 -1277 -1316 -958 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