File name: Pandora55s1_QueensNY_20231218_L2Fit_fwvt1c18d20230426p1-8.txt File generation date: 20240824T130036.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c18p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 55 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora55_OF_v5d20190723.txt Instrument calibration file used: Pandora55s1_CF_v18d20230426.txt Level 1 file used: Pandora55s1_QueensNY_20231218_L1_smca1c18d20230426p1-8.txt Full location name: Queens College NYSDEC (USEPA AQS ID 36-081-0124) Short location name: QueensNY Country of location: USA Location latitude [deg]: 40.7361 Location longitude [deg]: -73.8215 Location altitude [m]: 25 Local noon date: 20231218 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 17 for new VP from 20230426 First and last pixel inside fitting window: 1689 1839 Nominal wavelengths inside fitting window [nm]: 492.0793 492.1997 492.3201 492.4405 492.5609 492.6813 492.8016 492.9220 493.0423 493.1626 493.2829 493.4032 493.5234 493.6436 493.7639 493.8841 494.0043 494.1244 494.2446 494.3647 494.4848 494.6049 494.7250 494.8451 494.9652 495.0852 495.2052 495.3252 495.4452 495.5652 495.6852 495.8051 495.9250 496.0449 496.1648 496.2847 496.4046 496.5244 496.6442 496.7640 496.8838 497.0036 497.1234 497.2431 497.3628 497.4826 497.6022 497.7219 497.8416 497.9612 498.0809 498.2005 498.3201 498.4397 498.5592 498.6788 498.7983 498.9178 499.0373 499.1568 499.2762 499.3957 499.5151 499.6345 499.7539 499.8733 499.9927 500.1120 500.2314 500.3507 500.4700 500.5893 500.7085 500.8278 500.9470 501.0662 501.1854 501.3046 501.4238 501.5429 501.6621 501.7812 501.9003 502.0194 502.1384 502.2575 502.3765 502.4955 502.6145 502.7335 502.8525 502.9714 503.0904 503.2093 503.3282 503.4471 503.5659 503.6848 503.8036 503.9225 504.0413 504.1600 504.2788 504.3976 504.5163 504.6350 504.7537 504.8724 504.9911 505.1097 505.2284 505.3470 505.4656 505.5842 505.7028 505.8213 505.9399 506.0584 506.1769 506.2954 506.4138 506.5323 506.6507 506.7692 506.8876 507.0060 507.1243 507.2427 507.3610 507.4793 507.5976 507.7159 507.8342 507.9525 508.0707 508.1889 508.3071 508.4253 508.5435 508.6617 508.7798 508.8979 509.0160 509.1341 509.2522 509.3702 509.4883 509.6063 509.7243 509.8423 509.9603 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20231218T135737.8Z 8752.581688 91 1 5.08 2 75.82 139.29 121.14 77.30 0.00 1 0.00 1 0 15 2.452e-03 2.443e-03 4.119e-04 4.112e-04 5.181670e+03 2.485717e+01 3.874992e+02 -6.000000e+00 1.288985e+02 277.05 -2.00 20.00 -2.00 505.27 0.00e+00 8.321219e-04 1.101037e-05 5.253998e-05 -6.000000e+00 6.689928e-05 277.05 -2.00 20.00 -2.00 500.45 0.00e+00 3.375030e-01 7.978840e-03 3.405178e-02 -6.000000e+00 4.762940e-02 222.90 -2.00 3.51 -2.00 502.04 0.00e+00 3.993 0.001 489.00 513.00 1 3.1211e+00 6.0957e-04 6.5396e-03 -6.0000e+00 3.6401e-03 9.8816e-03 1.5784e-04 9.1891e-04 -6.0000e+00 9.5300e-04 4.6836e-02 1.8274e-03 3.5896e-05 5.5061e-05 -6.0000e+00 2.2356e-04 -1.6906e-04 -6.4964e-05 12 1 1 12 1 1 99.93 22.77 0.86 -0.00017 0.01251 54 103 1 4 0 92.240 26.11 20.01 22.77 20.86 35.9 1025.37 -610 -124 -123 315 531 460 520 412 316 277 -91 -118 -83 -234 -258 -79 100 -7 127 380 159 101 214 32 140 285 78 -194 40 -254 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243 144 384 216 38 189 186 -184 28 270 13 207 254 -32 129 263 -70 -225 56 -107 -151 203 285 156 225 236 150 201 152 93 12 -45 -234 -414 -301 SQ 20231218T140139.4Z 8752.584484 94 1 0.90 2 75.32 140.10 120.41 78.01 0.00 1 0.00 1 0 15 2.543e-03 2.531e-03 7.038e-04 7.026e-04 5.122625e+03 4.248513e+01 3.819387e+02 -6.000000e+00 1.336909e+02 277.05 -2.00 20.00 -2.00 505.27 0.00e+00 8.761332e-04 1.880896e-05 5.538450e-05 -6.000000e+00 6.937992e-05 277.05 -2.00 20.00 -2.00 500.45 0.00e+00 3.175389e-01 1.363680e-02 3.408581e-02 -6.000000e+00 4.938096e-02 222.90 -2.00 3.51 -2.00 502.04 0.00e+00 3.867 0.001 489.00 513.00 1 2.4234e+00 1.0420e-03 6.3945e-03 -6.0000e+00 3.7742e-03 7.9864e-03 2.6986e-04 9.1050e-04 -6.0000e+00 9.8767e-04 9.5898e-02 1.3436e-03 6.1351e-05 5.4593e-05 -6.0000e+00 2.3181e-04 -3.5425e-03 -1.8056e-05 12 1 1 12 1 1 85.38 22.77 0.89 -0.00354 0.00578 16 100 1 4 0 52.030 26.11 20.01 22.77 20.95 36.1 1026.79 -541 -121 -118 470 523 345 516 383 450 280 -33 -180 -232 -243 -344 -125 -37 -62 243 336 244 115 110 5 136 123 53 -63 86 -171 -634 -148 -191 -233 284 388 94 -167 -73 -166 -133 4 105 41 168 222 80 91 -214 -254 -364 -502 -345 -550 -247 -107 244 232 228 76 55 149 98 175 50 121 -34 -240 -385 -66 -356 -334 -123 -164 -11 181 117 -414 -286 -312 -262 -338 39 -17 -228 55 -102 -1 -93 -114 69 60 111 238 330 170 226 -15 -353 -304 -456 -317 -377 -581 -56 101 -83 -101 -166 -418 -264 17 174 272 245 515 222 144 450 230 190 204 129 -142 219 252 38 158 260 -150 2 278 -122 -135 56 -81 -151 207 350 139 362 317 138 175 54 27 68 -25 -221 -564 -364 -527 -120 -119 480 539 358 544 401 469 292 -34 -183 -237 -245 -345 -126 -38 -64 253 353 257 121 116 5 143 129 55 -66 89 -174 -636 -149 -193 -241 296 407 99 -172 -75 -171 -136 4 108 43 176 230 84 94 -218 -256 -361 -493 -334 -538 -243 -107 250 236 233 77 56 152 101 180 51 122 -34 -238 -385 -64 -347 -326 -121 -161 -11 179 116 -402 -279 -302 -254 -326 38 -17 -222 54 -101 -1 -92 -112 68 59 112 240 328 169 218 -14 -335 -282 -427 -295 -357 -568 -56 100 -82 -99 -161 -406 -260 17 173 273 244 512 223 146 454 229 189 199 127 -140 213 246 37 155 253 -146 2 270 -116 -130 53 -78 -146 201 345 137 359 316 137 174 54 27 68 -24 -213 -539 -349 SQ 20231218T140934.3Z 8752.589980 100 1 50.01 2 74.38 141.70 118.98 79.39 0.00 1 0.00 1 0 15 3.468e-03 3.443e-03 1.017e-03 1.015e-03 4.905173e+03 6.134010e+01 3.630967e+02 -6.000000e+00 1.822826e+02 277.05 -2.00 20.00 -2.00 505.27 0.00e+00 1.044357e-03 2.716247e-05 6.010467e-05 -6.000000e+00 9.461836e-05 277.05 -2.00 20.00 -2.00 500.41 0.00e+00 2.457473e-01 1.974151e-02 3.351692e-02 -6.000000e+00 6.739089e-02 222.90 -2.00 3.51 -2.00 502.00 0.00e+00 3.647 0.001 489.00 513.00 1 7.1470e+00 1.5081e-03 6.1213e-03 -6.0000e+00 5.1499e-03 1.2456e-02 3.9102e-04 8.7703e-04 -6.0000e+00 1.3491e-03 8.8179e-04 2.6749e-03 8.8895e-05 5.2459e-05 -6.0000e+00 3.1619e-04 2.4981e-03 -1.1522e-04 12 1 1 12 33 1 99.99 22.78 0.93 0.00250 0.02105 15 3 1 4 0 3125.190 26.11 20.00 22.78 21.14 36.1 1027.47 -663 -379 61 494 374 -32 264 447 101 358 76 70 -197 -37 -121 -107 -116 -116 295 706 465 160 206 -29 -136 498 137 -323 234 -259 -256 112 -200 -164 143 352 63 -351 -144 -310 -333 -229 -32 16 124 274 486 -31 -410 -177 -322 -969 -598 -881 -102 60 63 431 293 187 -158 374 274 336 52 524 398 -338 -459 -360 -318 19 -522 102 -229 -107 179 56 -286 -63 -497 -753 24 340 -396 -63 -518 448 21 -158 -56 -22 181 215 282 88 192 -51 -321 -522 -341 -565 -182 -499 289 -87 -322 -62 -132 -669 -342 34 375 55 432 810 137 158 394 706 -117 154 -133 -161 392 145 850 148 105 308 -91 406 -515 -93 67 -444 -284 173 -122 432 561 -28 95 218 721 173 -332 -266 -273 -624 -219 -649 -374 61 504 386 -33 279 474 107 375 79 72 -202 -38 -122 -109 -118 -121 310 741 489 168 217 -30 -144 525 144 -339 241 -262 -256 112 -203 -170 151 371 66 -366 -149 -319 -343 -237 -33 17 130 287 507 -32 -423 -179 -321 -954 -583 -864 -101 61 64 442 300 191 -162 383 281 345 53 529 399 -337 -455 -353 -311 18 -513 101 -228 -106 176 54 -276 -61 -479 -729 24 329 -388 -62 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