File name: Pandora55s1_QueensNY_20250103_L2Fit_fout2c18d20230426p1-8.txt File generation date: 20250104T050806.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c18p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 55 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora55_OF_v5d20190723.txt Instrument calibration file used: Pandora55s1_CF_v18d20230426.txt Level 1 file used: Pandora55s1_QueensNY_20250103_L1_smca1c18d20230426p1-8.txt Full location name: Queens College NYSDEC (USEPA AQS ID 36-081-0124) Short location name: QueensNY Country of location: USA Location latitude [deg]: 40.7361 Location longitude [deg]: -73.8215 Location altitude [m]: 25 Local noon date: 20250103 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 17 for new VP from 20230426 First and last pixel inside fitting window: 261 404 Nominal wavelengths inside fitting window [nm]: 305.0111 305.1511 305.2911 305.4311 305.5710 305.7110 305.8510 305.9909 306.1308 306.2708 306.4107 306.5506 306.6905 306.8303 306.9702 307.1101 307.2499 307.3897 307.5296 307.6694 307.8092 307.9490 308.0888 308.2286 308.3683 308.5081 308.6478 308.7876 308.9273 309.0670 309.2067 309.3464 309.4861 309.6257 309.7654 309.9050 310.0447 310.1843 310.3239 310.4635 310.6031 310.7427 310.8823 311.0219 311.1614 311.3010 311.4405 311.5800 311.7195 311.8590 311.9985 312.1380 312.2775 312.4169 312.5564 312.6958 312.8352 312.9747 313.1141 313.2535 313.3929 313.5322 313.6716 313.8110 313.9503 314.0896 314.2290 314.3683 314.5076 314.6469 314.7861 314.9254 315.0647 315.2039 315.3432 315.4824 315.6216 315.7608 315.9000 316.0392 316.1784 316.3175 316.4567 316.5958 316.7350 316.8741 317.0132 317.1523 317.2914 317.4305 317.5695 317.7086 317.8476 317.9867 318.1257 318.2647 318.4037 318.5427 318.6817 318.8207 318.9596 319.0986 319.2375 319.3765 319.5154 319.6543 319.7932 319.9321 320.0710 320.2098 320.3487 320.4875 320.6264 320.7652 320.9040 321.0428 321.1816 321.3204 321.4592 321.5979 321.7367 321.8754 322.0141 322.1529 322.2916 322.4303 322.5689 322.7076 322.8463 322.9849 323.1236 323.2622 323.4008 323.5394 323.6780 323.8166 323.9552 324.0938 324.2323 324.3709 324.5094 324.6479 324.7864 324.9249 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250103T134415.1Z 9134.572396 83 1 2.91 2 78.08 134.72 105.04 96.81 0.00 1 0.00 1 0 25 6.177e-01 2.974e-02 3.428e-01 1.749e-02 7.641402e-01 9.654572e-03 9.084143e-03 -6.000000e+00 3.676492e-01 223.39 -2.00 3.51 -2.00 320.85 0.00e+00 1.013199e-02 4.038741e-03 2.787465e-03 -6.000000e+00 1.721694e-02 276.08 -2.00 20.00 -2.00 320.37 0.00e+00 4.693 0.002 302.00 328.00 3 2.3660e+00 2.9729e-02 6.1375e-02 -6.0000e+00 9.0878e-01 3.9241e-01 3.8295e-02 4.0083e-02 -6.0000e+00 9.9311e-01 -5.1461e-01 3.6055e-02 2.4824e-02 -6.0000e+00 5.8943e-01 2.2379e-01 1.7682e-02 1.2143e-02 -6.0000e+00 2.4884e-01 1.8308e-04 -1.5837e-03 4.8349e-04 1.7318e-04 -6.0000e+00 1.9054e-02 3.8324e-03 0.0000e+00 12 9 9 12 1 1 999.00 15.07 0.35 0.00383 -0.00807 1 7 1 5 0 1447.800 25.90 20.03 15.07 7.36 35.9 1027.54 900000 -219115 900000 -214920 900000 -121540 -104740 -48898 900000 -103123 -117126 -160700 -171981 -50469 900000 266697 -117785 900000 900000 143788 -62867 10983 121928 -58862 -33345 291709 900000 -97840 125792 -40774 900000 29646 80559 -1676 48109 43447 2486 12022 4299 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-3809 1099 -1880 344 -3888 3819 -3822 -989 -2407 -1645 -1090 -979 -5476 -1151 -4499 -4099 2126 -2854 -276 1001 -79 -1326 -2906 -1195 -2663 818 1360 -137 -1867 1308 -49 2007 1853 2534 120 -1287 -1273 2544 1238 1671 2154 3006 1767 1380 2403 1010 3689 457 2889 3728 1125 -2062 358 -17 -3605 -3976 -494 -146 -2140 -1199 SS 20250103T140614.2Z 9134.587664 96 1 50.41 2 75.23 139.03 101.01 100.08 0.00 1 0.00 1 0 25 4.605e-01 1.318e-02 1.538e-01 3.071e-03 6.363360e-01 1.648020e-03 7.358408e-03 -6.000000e+00 2.722458e-01 223.39 -2.00 3.51 -2.00 320.51 0.00e+00 3.544347e-03 6.376382e-04 1.581158e-03 -6.000000e+00 1.193120e-02 276.08 -2.00 20.00 -2.00 320.00 0.00e+00 3.844 0.001 302.00 328.00 3 3.1535e+00 4.9482e-03 5.1240e-02 -6.0000e+00 6.7230e-01 9.5888e-02 6.3361e-03 3.5648e-02 -6.0000e+00 7.3307e-01 -6.3513e-02 6.1827e-03 1.7144e-02 -6.0000e+00 4.3534e-01 2.0317e-02 3.0963e-03 6.5622e-03 -6.0000e+00 1.8224e-01 2.2447e-04 -1.5564e-03 9.0109e-05 6.9623e-05 -6.0000e+00 1.3995e-02 7.2847e-03 0.0000e+00 12 8 8 10 0 0 99.99 15.12 0.19 0.00728 -0.00441 94 18 1 5 0 536.120 25.90 20.05 15.12 8.02 35.9 1030.84 -127996 -152836 900000 -183629 -26231 35878 -100934 900000 -81999 -62367 -132863 -101101 -113411 -37779 900000 -34274 -65476 900000 244985 81446 -35562 22886 4479 -47352 -8976 -24072 243534 -10979 -15099 -44066 -6695 30783 -1699 -69 5590 47117 -9402 -14952 13412 13762 -3697 7170 -6110 -4256 712 17089 -3778 8513 8565 10568 3950 3941 -2673 12910 10574 2225 8654 3005 5907 -406 -3239 6700 1023 -2031 3634 -2475 4540 -1956 1484 1933 634 -71 1716 -2722 2842 -572 1053 4662 872 -1410 -1208 2042 -1862 -580 -2542 -939 -3199 -1331 -1731 -812 196 -607 1229 1613 709 1244 40 177 -703 -464 -501 -378 564 1667 395 -687 -988 -1054 -64 907 426 -1521 -302 -161 -292 353 966 1492 697 -328 -1214 -908 407 1087 76 436 125 1231 760 -334 716 405 779 416 230 -566 -83 336 -316 -842 -203 -366 84 -20 -1573 -2811 900000 -4998 -165 121 -1256 900000 -1061 -739 -3171 -1996 -2972 -631 900000 -833 -2411 900000 733 1030 -1339 521 123 -2182 -316 -1031 945 -433 -614 -2400 -291 1123 -96 -4 336 1934 -661 -1240 1020 1236 -446 862 -879 -627 103 2169 -591 1226 1278 1633 698 765 -609 2760 2474 589 2245 831 1576 -113 -923 1827 323 -734 1362 -1009 1720 -783 600 859 316 -38 933 -1513 1422 -273 456 1869 373 -682 -671 1251 -1309 -433 -2034 -778 -2843 -1211 -1603 -741 172 -509 962 1226 560 1074 39 193 -848 -591 -638 -457 628 1739 416 -763 -1150 -1281 -81 1227 626 -2421 -496 -265 -469 542 1433 2205 1064 -525 -2005 -1493 646 1669 115 638 178 1700 1082 -514 1192 721 1450 803 463 -1193 -179 742 -706 -1887 -444 -771 170 -39 SS 20250103T141628.6Z 9134.594776 102 1 50.46 2 73.98 141.11 99.15 101.60 0.00 1 0.00 1 0 25 2.809e-01 1.039e-02 7.363e-02 2.335e-03 5.902894e-01 1.230442e-03 6.834374e-03 -6.000000e+00 1.650238e-01 223.39 -2.00 3.51 -2.00 320.15 0.00e+00 2.910741e-03 4.281598e-04 8.855687e-04 -6.000000e+00 7.262070e-03 276.08 -2.00 20.00 -2.00 319.63 0.00e+00 3.563 0.001 302.00 328.00 3 3.0318e+00 3.5828e-03 4.6915e-02 -6.0000e+00 4.0693e-01 7.9194e-02 4.4384e-03 3.1473e-02 -6.0000e+00 4.4305e-01 -3.1190e-02 4.1296e-03 1.5653e-02 -6.0000e+00 2.6309e-01 3.5615e-03 2.1120e-03 5.7876e-03 -6.0000e+00 1.1075e-01 3.4911e-04 -1.0380e-03 6.8907e-05 6.2358e-05 -6.0000e+00 8.5035e-03 6.0372e-03 0.0000e+00 12 8 8 10 0 0 99.97 15.13 0.24 0.00604 -0.00176 111 21 1 5 0 454.540 25.90 19.98 15.13 7.90 36.0 1030.69 -85480 -133302 900000 -125225 -9729 57858 -86966 900000 -62203 -29152 -109603 -43826 -84079 -19868 69457 182 -44236 88054 68451 23125 -19025 5189 11727 -35395 -3144 -17523 67280 -13351 -14306 -25081 1127 9660 -2448 290 -1776 26074 -5848 -6076 -144 5504 -4764 2417 -4460 -887 72 7492 -1413 1456 5785 2818 3675 107 -628 7255 4743 1587 3804 2626 1063 118 -1099 6175 1541 -286 2022 -1810 2637 -550 1719 1681 353 -144 869 -2135 1778 -889 1834 3058 148 -665 -1396 1066 -2101 -759 -2614 -1265 -2036 -871 -1481 -924 -144 130 1062 1518 1595 968 738 252 -141 -655 -363 -546 199 1607 284 -683 -782 -602 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