File name: Pandora55s1_QueensNY_20250125_L2Fit_fout2c18d20230426p1-8.txt File generation date: 20250128T141326.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c18p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 55 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora55_OF_v5d20190723.txt Instrument calibration file used: Pandora55s1_CF_v18d20230426.txt Level 1 file used: Pandora55s1_QueensNY_20250125_L1_smca1c18d20230426p1-8.txt Full location name: Queens College NYSDEC (USEPA AQS ID 36-081-0124) Short location name: QueensNY Country of location: USA Location latitude [deg]: 40.7361 Location longitude [deg]: -73.8215 Location altitude [m]: 25 Local noon date: 20250125 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 17 for new VP from 20230426 First and last pixel inside fitting window: 261 404 Nominal wavelengths inside fitting window [nm]: 305.0111 305.1511 305.2911 305.4311 305.5710 305.7110 305.8510 305.9909 306.1308 306.2708 306.4107 306.5506 306.6905 306.8303 306.9702 307.1101 307.2499 307.3897 307.5296 307.6694 307.8092 307.9490 308.0888 308.2286 308.3683 308.5081 308.6478 308.7876 308.9273 309.0670 309.2067 309.3464 309.4861 309.6257 309.7654 309.9050 310.0447 310.1843 310.3239 310.4635 310.6031 310.7427 310.8823 311.0219 311.1614 311.3010 311.4405 311.5800 311.7195 311.8590 311.9985 312.1380 312.2775 312.4169 312.5564 312.6958 312.8352 312.9747 313.1141 313.2535 313.3929 313.5322 313.6716 313.8110 313.9503 314.0896 314.2290 314.3683 314.5076 314.6469 314.7861 314.9254 315.0647 315.2039 315.3432 315.4824 315.6216 315.7608 315.9000 316.0392 316.1784 316.3175 316.4567 316.5958 316.7350 316.8741 317.0132 317.1523 317.2914 317.4305 317.5695 317.7086 317.8476 317.9867 318.1257 318.2647 318.4037 318.5427 318.6817 318.8207 318.9596 319.0986 319.2375 319.3765 319.5154 319.6543 319.7932 319.9321 320.0710 320.2098 320.3487 320.4875 320.6264 320.7652 320.9040 321.0428 321.1816 321.3204 321.4592 321.5979 321.7367 321.8754 322.0141 322.1529 322.2916 322.4303 322.5689 322.7076 322.8463 322.9849 323.1236 323.2622 323.4008 323.5394 323.6780 323.8166 323.9552 324.0938 324.2323 324.3709 324.5094 324.6479 324.7864 324.9249 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250125T130530.4Z 9156.545491 150 1 38.68 2 81.82 123.63 69.71 172.86 0.00 1 0.00 1 0 33 6.851e-01 2.904e-02 2.668e-01 5.737e-03 9.452339e-01 3.305425e-03 1.042782e-02 -6.000000e+00 4.106253e-01 224.13 -2.00 3.51 -2.00 321.88 0.00e+00 9.286407e-03 1.755648e-03 5.881233e-03 -6.000000e+00 1.881847e-02 275.30 -2.00 20.00 -2.00 321.45 0.00e+00 6.596 0.005 302.00 328.00 3 1.0444e+00 1.1652e-02 9.1386e-02 -6.0000e+00 1.0167e+00 8.9443e-01 1.5999e-02 7.4319e-02 -6.0000e+00 1.1124e+00 -1.2141e+00 1.5510e-02 2.8769e-02 -6.0000e+00 6.5582e-01 4.9657e-01 7.2212e-03 1.2361e-02 -6.0000e+00 2.7113e-01 9.3308e-05 -2.5906e-03 1.5497e-04 1.3539e-04 -6.0000e+00 2.0977e-02 1.0065e-02 0.0000e+00 12 9 9 12 1 1 90.10 22.61 0.47 0.01007 -0.00940 41 10 1 5 0 920.820 25.90 19.99 22.61 0.58 34.9 1026.32 -148301 -154765 900000 -191799 -942 900000 -114089 900000 -66640 -67057 -210577 -130991 -131446 73559 900000 142553 -78325 -68436 900000 900000 -49076 79978 97058 -92051 5844 -6412 900000 19216 -57269 -58026 59548 173082 71383 20471 44679 900000 3189 7763 96073 234148 44489 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-1585 160 -4747 -393 -2614 -819 -80 -767 577 785 -1647 -1275 -3103 -2926 -2281 -2259 -2102 -2180 -373 1635 -17 -1469 -2716 -4238 -2306 1017 -1202 -5776 -2225 -1623 -2140 -277 1167 3616 22 775 -2455 2853 4167 5396 1394 2731 529 3801 2001 -785 1426 3183 3959 2685 2315 -1446 667 515 -1275 -2992 -2576 -1645 -1115 -2300 SS 20250125T132341.8Z 9156.558122 156 1 50.56 2 79.01 126.93 69.43 177.01 0.00 1 0.00 1 0 25 5.292e-01 9.656e-03 6.961e-02 1.552e-03 7.589979e-01 8.410422e-04 8.516733e-03 -6.000000e+00 3.115780e-01 224.13 -2.00 3.51 -2.00 320.95 0.00e+00 4.856858e-03 3.714260e-04 1.606468e-03 -6.000000e+00 1.363644e-02 275.30 -2.00 20.00 -2.00 320.48 0.00e+00 5.058 0.002 302.00 328.00 3 7.8580e-01 2.6501e-03 6.4884e-02 -6.0000e+00 7.6977e-01 1.2482e-01 3.6497e-03 4.3078e-02 -6.0000e+00 8.3792e-01 -1.2572e-01 3.9105e-03 2.1538e-02 -6.0000e+00 4.9705e-01 4.1208e-02 1.8953e-03 9.0447e-03 -6.0000e+00 2.0869e-01 6.9192e-04 -1.1279e-03 4.3138e-05 9.2534e-05 -6.0000e+00 1.6024e-02 8.5152e-03 0.0000e+00 12 8 8 10 0 0 10.22 22.61 0.25 0.00852 0.00004 204 39 1 5 0 247.780 26.00 20.03 22.61 1.87 35.3 1026.14 -187132 -234526 900000 -232382 -139132 -127516 -183010 900000 -146766 -133473 -193216 -135114 -157793 -74276 5555 -49780 -79728 -67544 70885 5510 -53112 -23159 -12485 -60004 -17567 -39679 71753 -34710 -29017 -48122 -20208 -2646 -14634 -8519 -5340 25201 -19040 -9103 1011 9330 -6541 5046 -6168 -2043 2077 9536 1732 4735 8166 5670 4837 3990 3784 8821 7320 3323 4663 2120 1458 607 -955 4943 2478 1728 2638 858 4172 1521 2363 2585 1628 1250 1215 -821 1237 -401 1035 1724 1132 -610 -533 717 -1613 -1079 -1912 -968 -2007 -629 -1080 -454 10 325 705 871 634 665 -148 222 -400 -705 -362 -592 236 969 -441 -1285 -865 -902 -291 46 -295 -536 -84 -45 2 675 1033 1079 373 -551 -606 -309 283 148 132 23 321 1511 807 219 429 261 523 253 169 -421 -176 101 -551 -642 -192 63 111 69 -1313 -3290 900000 -3708 -842 -666 -1737 900000 -1231 -1083 -3109 -1394 -2583 -705 31 -616 -1590 -1366 400 64 -1169 -385 -192 -1593 -333 -1010 622 -878 -702 -1509 -561 -76 -528 -327 -205 773 -869 -430 53 541 -519 398 -586 -195 197 862 176 488 864 664 583 548 586 1434 1309 656 945 448 307 126 -201 1042 602 485 759 264 1247 474 780 960 691 576 576 -386 532 -159 369 589 412 -260 -271 394 -1031 -752 -1344 -717 -1588 -514 -902 -373 8 238 521 634 460 549 -135 235 -457 -873 -448 -687 259 972 -448 -1386 -984 -1029 -355 62 -427 -821 -137 -75 4 1028 1596 1674 575 -901 -1017 -510 445 235 202 35 458 2091 1179 345 765 493 1011 520 355 -946 -397 233 -1293 -1499 -431 139 237 143 SS 20250125T132943.6Z 9156.562310 159 1 50.53 2 78.10 128.05 69.40 178.40 0.00 1 0.00 1 0 25 3.710e-01 7.491e-03 5.871e-02 1.225e-03 7.081718e-01 6.576922e-04 8.068108e-03 -6.000000e+00 2.168863e-01 224.13 -2.00 3.51 -2.00 320.65 0.00e+00 3.203654e-03 2.653927e-04 1.524271e-03 -6.000000e+00 9.558947e-03 275.30 -2.00 20.00 -2.00 320.16 0.00e+00 4.702 0.002 302.00 328.00 3 7.6552e-01 1.9955e-03 6.0091e-02 -6.0000e+00 5.3523e-01 8.2110e-02 2.6399e-03 3.9264e-02 -6.0000e+00 5.8228e-01 -6.0813e-02 2.7455e-03 1.9411e-02 -6.0000e+00 3.4686e-01 1.2391e-02 1.3594e-03 7.2035e-03 -6.0000e+00 1.4628e-01 1.0455e-03 -9.3585e-04 3.4406e-05 7.9068e-05 -6.0000e+00 1.1067e-02 8.2503e-03 0.0000e+00 11 8 0 10 0 0 11.02 22.62 0.21 0.00825 0.00122 248 47 1 5 0 203.700 26.00 19.98 22.62 2.20 35.2 1026.08 -174189 -167621 900000 -163249 -82523 -108409 -117958 -11033 -96603 -93017 -125319 -89770 -102341 -53242 -12291 -33065 -54124 -51439 18561 -253 -37704 -13890 -15623 -34255 -25204 -19065 21487 -22686 -21181 -34732 -7962 -5440 -4496 -6314 670 8045 -6826 -7814 -482 3290 -3876 482 -4460 -1145 -1956 6098 -1950 3293 3235 3964 2993 1618 1454 5029 3945 1331 3076 -9 1418 107 -72 2308 2368 664 1790 618 2387 1400 1862 1694 607 552 136 -1067 271 -115 1048 1108 836 -958 -154 12 -1691 -1583 -1690 -1235 -1352 -905 -940 -38 103 577 691 1575 1142 1107 575 605 -428 -445 -213 -333 364 688 -258 -1323 -769 -918 -98 119 51 -485 -211 119 -58 828 955 937 293 -440 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