File name: Pandora55s1_QueensNY_20250415_L2Fit_fwvt1c18d20230426p1-8.txt
File generation date: 20250416T050557.6Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c18p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 55
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora55_OF_v5d20190723.txt
Instrument calibration file used: Pandora55s1_CF_v18d20230426.txt
Level 1 file used: Pandora55s1_QueensNY_20250415_L1_smca1c18d20230426p1-8.txt
Full location name: Queens College NYSDEC (USEPA AQS ID 36-081-0124)
Short location name: QueensNY
Country of location: USA
Location latitude [deg]: 40.7361
Location longitude [deg]: -73.8215
Location altitude [m]: 25
Local noon date: 20250415
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Based on session 17 for new VP from 20230426
First and last pixel inside fitting window: 1689 1839
Nominal wavelengths inside fitting window [nm]: 492.0793 492.1997 492.3201 492.4405 492.5609 492.6813 492.8016 492.9220 493.0423 493.1626 493.2829 493.4032 493.5234 493.6436 493.7639 493.8841 494.0043 494.1244 494.2446 494.3647 494.4848 494.6049 494.7250 494.8451 494.9652 495.0852 495.2052 495.3252 495.4452 495.5652 495.6852 495.8051 495.9250 496.0449 496.1648 496.2847 496.4046 496.5244 496.6442 496.7640 496.8838 497.0036 497.1234 497.2431 497.3628 497.4826 497.6022 497.7219 497.8416 497.9612 498.0809 498.2005 498.3201 498.4397 498.5592 498.6788 498.7983 498.9178 499.0373 499.1568 499.2762 499.3957 499.5151 499.6345 499.7539 499.8733 499.9927 500.1120 500.2314 500.3507 500.4700 500.5893 500.7085 500.8278 500.9470 501.0662 501.1854 501.3046 501.4238 501.5429 501.6621 501.7812 501.9003 502.0194 502.1384 502.2575 502.3765 502.4955 502.6145 502.7335 502.8525 502.9714 503.0904 503.2093 503.3282 503.4471 503.5659 503.6848 503.8036 503.9225 504.0413 504.1600 504.2788 504.3976 504.5163 504.6350 504.7537 504.8724 504.9911 505.1097 505.2284 505.3470 505.4656 505.5842 505.7028 505.8213 505.9399 506.0584 506.1769 506.2954 506.4138 506.5323 506.6507 506.7692 506.8876 507.0060 507.1243 507.2427 507.3610 507.4793 507.5976 507.7159 507.8342 507.9525 508.0707 508.1889 508.3071 508.4253 508.5435 508.6617 508.7798 508.8979 509.0160 509.1341 509.2522 509.3702 509.4883 509.6063 509.7243 509.8423 509.9603
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250415T143915.6Z 9236.610597 347 1 1.75 2 42.95 126.08 127.46 269.94 0.00 1 0.00 1 0 15 3.348e-03 3.345e-03 2.012e-03 2.009e-03 1.704466e+03 1.126884e+02 1.501648e+02 -6.000000e+00 1.784982e+02 280.37 -2.00 20.00 -2.00 505.27 0.00e+00 1.213186e-03 5.406496e-05 6.912627e-05 -6.000000e+00 9.204142e-05 280.37 -2.00 20.00 -2.00 500.50 0.00e+00 4.584264e-02 3.890655e-02 1.248200e-02 -6.000000e+00 6.533962e-02 228.60 -2.00 3.51 -2.00 502.09 0.00e+00 1.365 0.000 489.00 513.00 1 5.1855e+00 2.9737e-03 2.7593e-03 -6.0000e+00 4.9967e-03 -9.0719e-03 7.7618e-04 2.8434e-04 -6.0000e+00 1.3076e-03 8.8329e-03 1.4239e-03 1.7903e-04 3.0078e-05 -6.0000e+00 3.0526e-04 -5.6508e-03 1.1740e-05 12 1 1 12 1 1 999.00 22.96 0.93 -0.00565 0.00423 2 16 1 4 0 580.200 26.21 19.93 22.96 23.18 38.0 1100.00 -651 -91 245 646 529 1 553 418 596 131 -164 -137 18 -190 -10 257 -32 -347 70 919 634 228 89 -178 180 80 -150 -195 -305 86 -547 -181 -445 -79 135 78 -62 117 -428 -17 -535 -227 -95 39 455 146 528 164 -7 -410 -721 -764 -711 -834 -697 141 280 437 264 365 -224 362 -207 138 245 -155 267 -376 -127 -216 -379 -128 -19 -16 -259 326 -20 -113 -192 -181 91 -432 35 122 -449 85 -144 -36 -97 -331 210 30 341 502 457 4 -126 355 -36 -215 -710 -555 -462 -515 185 105 -228 -165 -246 -444 -239 162 86 343 296 187 413 21 151 146 -138 98 362 -402 10 236 -139 637 296 -190 204 127 -43 -101 -117 -554 85 -194 254 270 175 646 -134 469 413 236 170 -66 -173 -438 -166 -631 -89 244 651 537 1 574 437 619 135 -170 -139 19 -192 -10 258 -32 -353 72 957 663 239 91 -185 188 83 -156 -204 -310 86 -549 -178 -450 -82 140 82 -64 119 -442 -17 -549 -234 -97 40 475 151 548 169 -7 -413 -719 -743 -695 -808 -694 141 282 445 269 370 -228 369 -209 142 250 -156 269 -375 -125 -210 -372 -125 -18 -16 -259 324 -20 -111 -186 -175 87 -422 34 118 -444 84 -142 -36 -95 -326 207 30 341 505 457 4 -124 347 -34 -205 -673 -531 -446 -509 184 105 -226 -163 -241 -437 -234 161 86 344 299 190 421 21 151 147 -137 97 354 -397 10 234 -137 629 292 -188 201 123 -41 -97 -111 -533 82 -191 249 267 175 645 -133 466 412 235 167 -64 -168 -420 -159
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SQ 20250415T152001.9Z 9236.638911 374 1 15.85 2 37.24 138.94 134.91 276.65 0.00 1 0.00 1 0 22 2.625e-03 2.620e-03 7.187e-04 7.177e-04 1.668258e+03 4.028314e+01 1.313687e+02 -6.000000e+00 1.399692e+02 280.37 -2.00 20.00 -2.00 505.27 0.00e+00 1.123860e-03 1.931345e-05 6.384438e-05 -6.000000e+00 7.217502e-05 280.37 -2.00 20.00 -2.00 500.48 0.00e+00 2.821333e-02 1.391244e-02 1.413446e-02 -6.000000e+00 5.124315e-02 228.61 -2.00 3.51 -2.00 502.07 0.00e+00 1.255 0.000 489.00 513.00 1 5.7059e+00 1.0636e-03 2.6285e-03 -6.0000e+00 3.9186e-03 -6.7083e-03 2.7751e-04 3.1021e-04 -6.0000e+00 1.0257e-03 5.3455e-03 1.6036e-03 6.3915e-05 2.6783e-05 -6.0000e+00 2.3938e-04 -4.0949e-03 -8.9737e-06 12 1 1 12 1 1 99.97 22.96 0.93 -0.00409 0.00703 23 14 1 4 0 660.100 26.21 20.02 22.96 23.32 37.8 1100.00 -496 -219 -80 275 475 305 526 318 444 453 -248 -24 -308 -183 -329 -90 63 -27 205 369 203 98 213 -80 99 350 209 -69 166 -218 -563 -173 -280 -162 130 413 81 -244 -137 -172 -305 -162 -3 42 323 259 216 15 -193 -158 -473 -567 -463 -511 -249 105 134 217 233 174 19 -18 223 149 94 143 162 -278 -198 -66 -369 -414 -123 15 -94 175 71 -149 -425 -81 -342 -365 -102 161 -99 -264 -188 89 -21 -139 -21 -34 27 135 607 -49 60 -76 -128 -267 -500 -353 -216 -403 15 126 -101 27 -226 -478 -372 221 175 199 496 398 330 171 476 392 -91 -37 -1 -173 158 255 74 135 191 -67 144 112 -184 -230 24 -128 -287 206 296 189 335 402 197 166 194 78 64 -1 -293 -531 -349 -483 -215 -80 279 487 316 550 334 465 470 -256 -24 -313 -185 -331 -90 64 -27 213 386 212 102 222 -84 104 366 218 -71 170 -219 -561 -172 -283 -166 136 431 84 -252 -141 -176 -312 -166 -3 43 336 270 224 16 -197 -159 -469 -555 -450 -498 -246 105 136 222 238 177 19 -18 228 153 96 144 162 -276 -196 -65 -359 -405 -120 15 -94 173 70 -145 -411 -78 -330 -354 -99 157 -97 -260 -186 87 -21 -137 -21 -34 27 136 607 -49 59 -74 -122 -253 -472 -335 -207 -396 15 126 -100 26 -221 -467 -367 219 175 200 499 401 334 173 480 393 -90 -37 -1 -170 155 251 73 133 188 -66 142 109 -177 -220 23 -123 -277 201 291 186 332 398 196 165 193 78 63 -1 -282 -508 -335
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