File name: Pandora55s1_QueensNY_20250416_L2Fit_fwvt1c18d20230426p1-8.txt
File generation date: 20250417T062750.1Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c18p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 55
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora55_OF_v5d20190723.txt
Instrument calibration file used: Pandora55s1_CF_v18d20230426.txt
Level 1 file used: Pandora55s1_QueensNY_20250416_L1_smca1c18d20230426p1-8.txt
Full location name: Queens College NYSDEC (USEPA AQS ID 36-081-0124)
Short location name: QueensNY
Country of location: USA
Location latitude [deg]: 40.7361
Location longitude [deg]: -73.8215
Location altitude [m]: 25
Local noon date: 20250416
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Based on session 17 for new VP from 20230426
First and last pixel inside fitting window: 1689 1839
Nominal wavelengths inside fitting window [nm]: 492.0793 492.1997 492.3201 492.4405 492.5609 492.6813 492.8016 492.9220 493.0423 493.1626 493.2829 493.4032 493.5234 493.6436 493.7639 493.8841 494.0043 494.1244 494.2446 494.3647 494.4848 494.6049 494.7250 494.8451 494.9652 495.0852 495.2052 495.3252 495.4452 495.5652 495.6852 495.8051 495.9250 496.0449 496.1648 496.2847 496.4046 496.5244 496.6442 496.7640 496.8838 497.0036 497.1234 497.2431 497.3628 497.4826 497.6022 497.7219 497.8416 497.9612 498.0809 498.2005 498.3201 498.4397 498.5592 498.6788 498.7983 498.9178 499.0373 499.1568 499.2762 499.3957 499.5151 499.6345 499.7539 499.8733 499.9927 500.1120 500.2314 500.3507 500.4700 500.5893 500.7085 500.8278 500.9470 501.0662 501.1854 501.3046 501.4238 501.5429 501.6621 501.7812 501.9003 502.0194 502.1384 502.2575 502.3765 502.4955 502.6145 502.7335 502.8525 502.9714 503.0904 503.2093 503.3282 503.4471 503.5659 503.6848 503.8036 503.9225 504.0413 504.1600 504.2788 504.3976 504.5163 504.6350 504.7537 504.8724 504.9911 505.1097 505.2284 505.3470 505.4656 505.5842 505.7028 505.8213 505.9399 506.0584 506.1769 506.2954 506.4138 506.5323 506.6507 506.7692 506.8876 507.0060 507.1243 507.2427 507.3610 507.4793 507.5976 507.7159 507.8342 507.9525 508.0707 508.1889 508.3071 508.4253 508.5435 508.6617 508.7798 508.8979 509.0160 509.1341 509.2522 509.3702 509.4883 509.6063 509.7243 509.8423 509.9603
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250416T112154.5Z 9237.473547 233 1 15.11 2 78.24 86.46 87.65 231.46 0.00 1 0.00 1 0 15 2.839e-03 2.831e-03 5.774e-04 5.768e-04 2.378991e+03 3.308883e+01 1.751135e+02 -6.000000e+00 1.514127e+02 280.46 -2.00 20.00 -2.00 505.28 0.00e+00 1.519525e-03 1.554408e-05 8.558066e-05 -6.000000e+00 7.806357e-05 280.46 -2.00 20.00 -2.00 500.52 0.00e+00 7.334812e-01 1.116489e-02 2.172700e-02 -6.000000e+00 5.540865e-02 228.68 -2.00 3.51 -2.00 502.10 0.00e+00 4.751 0.002 489.00 513.00 1 4.6723e+00 8.5340e-04 7.3344e-03 -6.0000e+00 4.2373e-03 -3.6322e-03 2.2193e-04 5.8399e-04 -6.0000e+00 1.1089e-03 8.6006e-03 1.6699e-03 5.1211e-05 3.5575e-05 -6.0000e+00 2.5885e-04 -2.3909e-03 -1.1831e-05 12 1 1 12 1 1 97.97 23.03 0.79 -0.00239 0.00919 23 15 1 4 0 629.500 26.32 20.00 23.03 13.35 36.9 1048.05 -768 -261 -177 424 622 437 419 420 473 251 -64 -175 -154 -261 -254 -165 50 35 271 506 156 81 174 -4 164 292 134 -199 266 -286 -562 -365 -132 -185 309 461 102 -205 -173 -151 -332 -85 154 198 167 283 180 95 -155 -165 -419 -627 -560 -509 -329 -28 195 138 203 107 -8 160 225 236 236 246 25 -182 -295 -11 -234 -356 -261 -142 -167 123 21 -323 -407 -255 -440 -463 -36 -97 -172 -93 -104 43 -152 -169 79 3 -44 319 341 -116 68 -208 -118 -302 -474 -259 -357 -544 22 164 -110 -198 -245 -405 -210 209 184 313 405 457 466 242 503 426 37 210 121 -291 279 373 71 257 193 -63 55 297 3 -194 129 -190 -228 121 235 233 334 256 68 268 87 171 -90 -109 -273 -563 -470 -750 -254 -175 425 639 451 432 437 490 257 -66 -178 -156 -262 -254 -166 50 36 281 528 160 83 179 -5 171 305 139 -205 270 -286 -564 -361 -134 -191 321 482 106 -211 -175 -155 -342 -87 158 206 173 293 186 99 -158 -167 -419 -612 -549 -494 -329 -28 198 142 209 110 -9 162 229 240 239 248 25 -183 -293 -11 -231 -346 -256 -141 -165 121 20 -312 -395 -247 -428 -447 -35 -94 -170 -91 -102 43 -149 -166 79 3 -44 321 341 -114 67 -203 -112 -286 -446 -246 -343 -537 22 164 -109 -193 -240 -399 -206 208 183 316 410 458 470 246 507 430 37 206 120 -285 274 368 70 253 190 -62 54 292 3 -185 124 -181 -223 118 234 232 334 257 68 268 88 172 -90 -107 -265 -543 -455
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SQ 20250416T113253.5Z 9237.481175 239 1 41.17 2 76.16 88.22 89.25 233.23 0.00 1 0.00 1 0 15 2.698e-03 2.688e-03 1.175e-04 1.174e-04 2.138041e+03 6.680771e+00 1.611151e+02 -6.000000e+00 1.439152e+02 280.46 -2.00 20.00 -2.00 505.28 0.00e+00 1.427836e-03 3.162560e-06 8.056433e-05 -6.000000e+00 7.419582e-05 280.46 -2.00 20.00 -2.00 500.52 0.00e+00 5.981465e-01 2.271084e-03 1.927733e-02 -6.000000e+00 5.265622e-02 228.68 -2.00 3.51 -2.00 502.10 0.00e+00 4.084 0.001 489.00 513.00 1 2.6456e+00 1.7365e-04 6.3638e-03 -6.0000e+00 4.0269e-03 -4.7239e-03 4.5163e-05 5.1036e-04 -6.0000e+00 1.0537e-03 7.2639e-02 1.3693e-03 1.0428e-05 3.3232e-05 -6.0000e+00 2.4601e-04 -4.1579e-03 1.0216e-05 12 1 1 12 1 1 96.35 23.05 0.84 -0.00416 0.00534 542 126 1 4 0 75.660 26.32 20.00 23.05 13.44 37.0 1048.69 -645 -286 -148 371 543 432 510 425 419 269 -107 -140 -140 -279 -288 -156 34 -57 216 425 160 140 174 12 149 309 107 -89 150 -278 -657 -239 -119 -189 267 428 52 -126 -169 -199 -202 -71 49 148 256 287 250 91 -185 -148 -435 -628 -542 -565 -336 16 231 239 186 138 88 139 246 183 160 133 68 -214 -280 -97 -324 -366 -138 -165 -85 120 72 -299 -408 -242 -444 -337 -36 -138 -182 -82 -81 -34 -107 -88 75 -33 4 318 365 67 40 -81 -240 -297 -545 -369 -333 -440 31 155 -93 -93 -207 -442 -209 58 173 283 418 497 351 261 470 303 77 198 112 -156 169 301 27 247 268 -47 146 271 -75 -169 42 -230 -226 165 261 125 279 256 151 206 167 61 -36 -67 -289 -494 -411 -624 -281 -146 371 556 445 527 443 434 279 -110 -142 -142 -279 -287 -156 35 -59 224 444 166 145 180 12 155 322 112 -92 153 -278 -657 -239 -120 -196 279 442 54 -130 -172 -204 -207 -72 51 152 265 298 258 93 -189 -150 -434 -611 -528 -555 -334 16 235 246 189 141 88 141 250 186 163 134 68 -214 -278 -95 -318 -361 -135 -164 -84 118 71 -293 -396 -233 -430 -329 -35 -134 -180 -80 -80 -33 -105 -87 75 -33 4 318 367 66 40 -79 -229 -282 -513 -350 -321 -435 31 153 -93 -91 -204 -430 -206 58 173 282 420 501 357 263 477 304 77 194 109 -154 167 298 26 244 264 -47 144 263 -73 -162 41 -220 -218 162 257 125 280 254 151 207 169 62 -36 -66 -282 -476 -398
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