File name: Pandora224s1_QuezonCity_20240827_L2Fit_fwvt1c2d20220621p1-8.txt File generation date: 20240827T160733.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 224 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora224_OF_v1d20220531.txt Instrument calibration file used: Pandora224s1_CF_v2d20220621.txt Level 1 file used: Pandora224s1_QuezonCity_20240827_L1_smca1c2d20220621p1-8.txt Full location name: Manila Observatory, Ateneo De Manila University Short location name: QuezonCity Country of location: Philippines Location latitude [deg]: 14.6350 Location longitude [deg]: 121.0780 Location altitude [m]: 63 Local noon date: 20240827 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB based on session 1 for initial deployment period First and last pixel inside fitting window: 1622 1771 Nominal wavelengths inside fitting window [nm]: 492.1198 492.2406 492.3615 492.4823 492.6032 492.7240 492.8448 492.9655 493.0863 493.2070 493.3278 493.4485 493.5692 493.6898 493.8105 493.9311 494.0517 494.1724 494.2929 494.4135 494.5341 494.6546 494.7751 494.8956 495.0161 495.1366 495.2571 495.3775 495.4979 495.6183 495.7387 495.8591 495.9794 496.0998 496.2201 496.3404 496.4607 496.5809 496.7012 496.8214 496.9416 497.0618 497.1820 497.3022 497.4223 497.5424 497.6626 497.7827 497.9027 498.0228 498.1428 498.2629 498.3829 498.5029 498.6229 498.7428 498.8628 498.9827 499.1026 499.2225 499.3424 499.4622 499.5821 499.7019 499.8217 499.9415 500.0613 500.1810 500.3008 500.4205 500.5402 500.6599 500.7795 500.8992 501.0188 501.1384 501.2580 501.3776 501.4972 501.6167 501.7363 501.8558 501.9753 502.0948 502.2142 502.3337 502.4531 502.5725 502.6919 502.8113 502.9307 503.0500 503.1693 503.2886 503.4079 503.5272 503.6465 503.7657 503.8849 504.0041 504.1233 504.2425 504.3617 504.4808 504.5999 504.7190 504.8381 504.9572 505.0762 505.1953 505.3143 505.4333 505.5523 505.6712 505.7902 505.9091 506.0280 506.1469 506.2658 506.3847 506.5035 506.6223 506.7411 506.8599 506.9787 507.0975 507.2162 507.3349 507.4536 507.5723 507.6910 507.8096 507.9283 508.0469 508.1655 508.2841 508.4026 508.5212 508.6397 508.7582 508.8767 508.9952 509.1137 509.2321 509.3506 509.4690 509.5874 509.7057 509.8241 509.9424 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240826T230849.5Z 9004.964462 262 1 26.78 2 70.34 84.45 18.73 313.69 0.00 1 0.00 1 0 22 3.035e-03 3.004e-03 3.140e-04 3.134e-04 9.815189e+03 2.146187e+01 6.540419e+02 -6.000000e+00 1.712112e+02 294.71 -2.00 20.00 -2.00 505.28 0.00e+00 1.123573e-03 8.795709e-06 7.204035e-05 -6.000000e+00 8.676542e-05 294.71 -2.00 20.00 -2.00 500.45 0.00e+00 2.448344e-01 6.085589e-03 5.353339e-02 -6.000000e+00 5.892494e-02 227.17 -2.00 3.09 -2.00 502.04 0.00e+00 2.938 0.000 489.00 513.00 1 4.8600e+00 4.6760e-04 6.4242e-03 -6.0000e+00 4.5297e-03 8.4052e-03 1.2049e-04 1.3392e-03 -6.0000e+00 1.1844e-03 9.5507e-03 1.4534e-03 2.7070e-05 6.4863e-05 -6.0000e+00 2.7884e-04 -1.4574e-02 5.8192e-05 12 1 1 12 1 1 99.01 23.97 1.57 -0.01457 -0.00449 78 24 1 4 0 338.880 26.32 20.00 23.97 31.20 3.7 1021.06 -605 -290 -95 -11 300 530 530 371 286 196 164 -121 -328 -258 -310 -239 -21 128 67 83 216 109 176 281 268 437 446 -111 -385 -326 -405 -433 118 260 13 66 79 -118 -227 -142 -151 7 173 310 395 322 354 232 21 -376 -537 -660 -750 -362 -181 -72 -14 36 38 122 253 264 253 326 139 114 46 -99 -378 -345 -241 -193 -9 136 -7 -205 -134 -349 -419 -455 -314 -364 -285 -86 -52 -185 -193 -183 -116 -29 205 455 397 375 509 322 113 -214 -587 -789 -667 -520 -215 -68 -142 -47 -212 -314 -162 -87 -137 60 250 246 402 585 684 458 341 194 48 -9 213 224 104 295 150 139 401 306 -68 -71 -163 -346 -241 -107 -122 -61 147 82 109 213 236 298 344 147 -191 -388 -511 -451 -587 -288 -96 -12 309 555 553 389 298 204 169 -123 -333 -260 -312 -242 -21 133 70 87 228 115 186 297 280 462 468 -115 -393 -328 -406 -439 121 270 13 69 83 -122 -233 -144 -155 8 181 322 413 336 366 240 21 -378 -534 -644 -729 -357 -181 -73 -15 37 39 126 261 269 258 331 142 114 46 -98 -372 -341 -237 -188 -9 136 -7 -203 -133 -340 -404 -437 -303 -355 -280 -83 -51 -183 -191 -181 -114 -29 203 450 396 369 495 310 108 -198 -546 -726 -618 -487 -206 -67 -142 -46 -208 -310 -159 -85 -135 59 246 244 399 584 690 466 343 192 47 -9 205 217 102 288 147 135 390 297 -65 -68 -155 -327 -229 -103 -119 -59 145 82 109 211 235 297 341 147 -187 -379 -492 -436 SQ 20240826T231436.2Z 9004.968474 265 1 51.90 2 68.95 84.77 19.74 311.42 0.00 1 0.00 1 0 22 2.987e-03 2.958e-03 1.343e-04 1.341e-04 9.255160e+03 9.113144e+00 6.183781e+02 -6.000000e+00 1.685002e+02 294.71 -2.00 20.00 -2.00 505.27 0.00e+00 9.289313e-04 3.762907e-06 6.213836e-05 -6.000000e+00 8.539067e-05 294.71 -2.00 20.00 -2.00 500.45 0.00e+00 2.093286e-01 2.603909e-03 5.070753e-02 -6.000000e+00 5.798893e-02 227.17 -2.00 3.09 -2.00 502.04 0.00e+00 2.756 0.000 489.00 513.00 1 3.8672e+00 2.0005e-04 6.0228e-03 -6.0000e+00 4.4578e-03 8.7246e-03 5.1597e-05 1.2687e-03 -6.0000e+00 1.1656e-03 2.6614e-02 1.3734e-03 1.1620e-05 6.0978e-05 -6.0000e+00 2.7444e-04 -1.5009e-02 6.4142e-05 10 0 0 10 0 0 99.00 23.96 1.58 -0.01501 -0.00548 519 82 1 4 0 99.800 26.32 20.00 23.96 31.45 3.7 1023.24 -578 -307 -72 16 268 516 513 404 269 209 215 -100 -250 -243 -342 -197 22 180 49 74 168 61 152 296 260 410 415 -61 -417 -378 -420 -435 114 240 36 101 96 -109 -221 -145 -88 8 157 278 307 345 324 247 33 -341 -533 -722 -706 -362 -219 -86 8 -26 27 141 239 299 269 286 146 125 34 -64 -341 -348 -262 -200 -48 99 -37 -179 -107 -246 -414 -450 -352 -408 -333 -77 -90 -149 -173 -183 -153 -41 167 458 408 368 459 331 63 -186 -588 -786 -671 -510 -160 -15 -111 -61 -206 -332 -168 -130 -138 61 176 297 376 588 634 466 322 207 77 55 256 233 83 257 191 195 403 282 -65 -61 -120 -414 -209 -46 -159 -38 149 100 121 198 232 301 307 119 -205 -387 -487 -413 -563 -301 -72 17 276 541 537 425 281 218 222 -102 -255 -245 -346 -200 22 185 51 78 177 65 161 308 272 428 437 -63 -427 -382 -422 -435 117 250 37 106 100 -113 -227 -148 -91 8 162 289 321 360 335 256 34 -343 -531 -705 -688 -358 -219 -87 9 -27 28 145 247 305 274 291 149 125 34 -63 -336 -338 -258 -195 -47 98 -37 -178 -104 -239 -400 -434 -341 -399 -322 -75 -89 -148 -172 -181 -151 -40 163 453 407 363 449 320 59 -174 -550 -728 -626 -480 -155 -14 -111 -60 -203 -323 -165 -127 -137 60 174 295 374 588 642 467 325 205 76 53 247 227 81 252 187 191 392 274 -63 -58 -114 -392 -199 -45 -155 -37 146 100 119 196 231 301 305 117 -201 -378 -469 -399 SQ 20240826T231937.2Z 9004.971959 268 1 15.46 2 67.74 85.05 20.65 309.64 0.00 1 0.00 1 0 22 2.995e-03 2.965e-03 1.253e-04 1.251e-04 8.768564e+03 8.454336e+00 5.859274e+02 -6.000000e+00 1.689554e+02 294.71 -2.00 20.00 -2.00 505.28 0.00e+00 8.906513e-04 3.512348e-06 5.975465e-05 -6.000000e+00 8.561849e-05 294.71 -2.00 20.00 -2.00 500.47 0.00e+00 1.839581e-01 2.426218e-03 4.872668e-02 -6.000000e+00 5.813419e-02 227.17 -2.00 3.09 -2.00 502.06 0.00e+00 2.617 0.000 489.00 513.00 1 2.5445e+00 1.8645e-04 5.7541e-03 -6.0000e+00 4.4692e-03 6.7322e-03 4.8068e-05 1.2128e-03 -6.0000e+00 1.1682e-03 1.0221e-01 1.0937e-03 1.0868e-05 5.7819e-05 -6.0000e+00 2.7521e-04 -1.6919e-02 8.8643e-05 12 1 1 12 1 1 92.80 23.97 1.58 -0.01692 -0.00933 466 91 1 4 0 33.100 26.32 20.00 23.97 31.73 3.7 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