File name: Pandora224s1_QuezonCity_20241102_L2Fit_fout2c2d20220621p1-8.txt File generation date: 20241103T012655.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Ellison Castro Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 224 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora224_OF_v2d20220531.txt Instrument calibration file used: Pandora224s1_CF_v2d20220621.txt Level 1 file used: Pandora224s1_QuezonCity_20241102_L1_smca1c2d20220621p1-8.txt Full location name: Manila Observatory, Ateneo De Manila University Short location name: QuezonCity Country of location: Philippines Location latitude [deg]: 14.6350 Location longitude [deg]: 121.0780 Location altitude [m]: 63 Local noon date: 20241102 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB based on session 1 for initial deployment period First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.0004 305.1414 305.2823 305.4232 305.5642 305.7051 305.8460 305.9869 306.1278 306.2686 306.4095 306.5504 306.6912 306.8320 306.9728 307.1136 307.2544 307.3952 307.5360 307.6767 307.8175 307.9582 308.0990 308.2397 308.3804 308.5211 308.6617 308.8024 308.9431 309.0837 309.2243 309.3650 309.5056 309.6462 309.7868 309.9273 310.0679 310.2085 310.3490 310.4895 310.6300 310.7705 310.9110 311.0515 311.1920 311.3325 311.4729 311.6133 311.7538 311.8942 312.0346 312.1750 312.3154 312.4557 312.5961 312.7364 312.8768 313.0171 313.1574 313.2977 313.4380 313.5783 313.7185 313.8588 313.9990 314.1392 314.2795 314.4197 314.5599 314.7000 314.8402 314.9804 315.1205 315.2607 315.4008 315.5409 315.6810 315.8211 315.9612 316.1012 316.2413 316.3813 316.5214 316.6614 316.8014 316.9414 317.0814 317.2213 317.3613 317.5012 317.6412 317.7811 317.9210 318.0609 318.2008 318.3407 318.4806 318.6204 318.7603 318.9001 319.0399 319.1797 319.3195 319.4593 319.5991 319.7388 319.8786 320.0183 320.1580 320.2978 320.4375 320.5772 320.7168 320.8565 320.9962 321.1358 321.2754 321.4150 321.5547 321.6943 321.8338 321.9734 322.1130 322.2525 322.3921 322.5316 322.6711 322.8106 322.9501 323.0896 323.2290 323.3685 323.5079 323.6473 323.7868 323.9262 324.0656 324.2049 324.3443 324.4837 324.6230 324.7624 324.9017 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241101T222949.3Z 9071.937377 48 1 52.09 2 81.95 107.69 87.27 110.95 0.00 1 0.00 1 0 17 4.936e-01 1.950e-02 3.359e-01 1.228e-02 6.816940e-01 7.327586e-03 7.232095e-03 -6.000000e+00 3.029791e-01 226.80 -2.00 3.09 -2.00 321.72 0.00e+00 -1.660663e-04 4.283387e-03 5.969962e-03 -6.000000e+00 1.550037e-02 294.31 -2.00 20.00 -2.00 321.11 0.00e+00 6.674 0.001 302.00 328.00 3 2.1265e+00 2.9465e-02 8.0245e-02 -6.0000e+00 7.5114e-01 3.3949e-01 4.0808e-02 5.6089e-02 -6.0000e+00 8.1491e-01 -4.6567e-01 3.5547e-02 2.0557e-02 -6.0000e+00 4.8519e-01 1.8841e-01 1.6403e-02 6.1751e-03 -6.0000e+00 2.0777e-01 4.6646e-05 -7.3746e-04 4.0180e-04 7.9049e-05 -6.0000e+00 1.5594e-02 -1.8946e-02 7.8678e-06 12 9 8 11 16 0 51.41 24.37 0.84 -0.01895 -0.02449 31 5 1 5 0 1680.160 26.62 20.00 24.37 32.78 4.1 1027.06 900000 -116746 1966 -170950 900000 -177634 900000 -98271 -149718 900000 -181318 900000 -183106 900000 -126878 900000 -54621 900000 141802 900000 -99112 -76897 900000 72738 80826 -79333 123365 -43224 100439 17235 -22258 -29412 219 -44389 39129 42692 21888 43602 -24823 6366 38089 79050 15271 27828 44172 63102 -3502 7695 19696 15574 41118 6461 53184 -349 19434 22663 18574 16065 28835 667 23266 8788 16165 1151 4055 5148 5879 1726 10812 9940 7039 4522 3212 -113 -9595 2711 -2177 2352 -4631 4203 3333 -4843 -5114 -3579 751 -261 1196 1944 247 -1789 3932 2540 449 1990 -3206 -3787 -4607 599 -1012 962 -3962 1448 -3729 -2970 -169 -1544 -2024 -1413 -875 -2253 2071 734 -2 -402 1564 -949 -1840 587 2298 815 452 650 856 1439 655 1408 24 -998 1460 1549 -902 -19 -112 -1191 699 -429 290 373 873 -563 385 -1380 -516 900000 -1396 23 -3158 900000 -3089 900000 -1175 -2441 900000 -4729 900000 -6169 900000 -3723 900000 -1068 900000 1695 900000 -3878 -2423 900000 870 966 -3190 1475 -1221 1201 262 -556 -927 6 -2074 808 835 547 995 -1349 304 1532 2319 896 1482 2016 2400 -263 580 1366 1192 2654 657 3751 -46 2253 2682 2376 2132 3309 99 2753 1271 2415 224 834 1071 1202 374 2288 2388 1952 1378 1010 -35 -3085 700 -541 545 -1229 1176 1108 -2021 -2402 -1797 386 -145 692 1162 152 -1104 2181 1342 231 1013 -1859 -2522 -3591 510 -975 951 -4012 1286 -3191 -2425 -139 -1371 -1916 -1422 -954 -2775 2726 1063 -2 -605 2223 -1326 -2559 818 3314 1252 708 995 1263 2041 905 1863 31 -1330 2067 2471 -1645 -37 -233 -2669 1640 -1083 753 989 2314 -1483 955 -3286 -1166 SS 20241101T224426.0Z 9071.947523 53 1 51.75 2 78.60 108.80 84.09 112.01 0.00 1 0.00 1 0 17 2.202e-01 8.014e-03 3.735e-02 1.526e-03 5.415387e-01 8.254647e-04 5.689753e-03 -6.000000e+00 1.326451e-01 226.80 -2.00 3.09 -2.00 320.10 0.00e+00 1.732040e-03 2.993234e-04 1.732723e-03 -6.000000e+00 6.177059e-03 294.31 -2.00 20.00 -2.00 319.30 0.00e+00 4.885 0.000 302.00 328.00 3 1.5804e+00 2.5012e-03 5.4340e-02 -6.0000e+00 3.2714e-01 -1.5553e-02 3.1173e-03 2.6565e-02 -6.0000e+00 3.5317e-01 -1.7957e-02 2.6286e-03 1.3022e-02 -6.0000e+00 2.1216e-01 2.3015e-04 1.3469e-03 3.5932e-03 -6.0000e+00 9.1483e-02 5.2145e-04 -6.0505e-05 4.6575e-05 5.3878e-05 -6.0000e+00 6.8171e-03 -1.9660e-02 6.7936e-05 11 8 0 10 0 0 35.20 24.37 0.44 -0.01966 -0.02011 154 24 1 5 0 335.990 26.62 19.99 24.37 33.58 4.1 1032.84 900000 -80467 -88073 -58444 -119593 -68804 -90861 -64065 -44943 -61582 -48314 -741 -63049 -32368 -19287 -12784 -26605 -19179 -9909 -11706 -7359 -4711 -7235 -16240 -8508 -11435 -8748 -878 -556 -10274 -15148 -9032 -3083 -2 -8858 -6280 -4007 -3418 -2355 -503 1299 -358 -378 1147 1913 468 -1581 1487 1951 -251 2733 1766 1795 1677 2652 793 1759 1114 136 1449 202 2083 2229 3636 1935 900 611 89 -584 2329 1517 770 813 788 694 -499 -718 -1655 -2216 -1187 -1553 -1449 -2022 -2412 -1182 -646 -73 1005 831 1046 525 779 -227 -484 -424 -292 -63 820 825 -154 -289 -1206 -1333 -543 -68 -1761 -1297 -1032 -421 523 1048 790 354 300 -287 -188 87 267 235 401 -210 85 669 735 181 484 -460 222 1077 -67 -45 -590 -376 -426 152 -244 -147 659 500 -147 -69 -151 -678 900000 -982 -1297 -661 -2402 -798 -1352 -810 -535 -962 -711 -7 -1369 -640 -416 -312 -859 -639 -329 -423 -267 -171 -278 -727 -383 -570 -441 -41 -25 -527 -897 -584 -217 0 -747 -512 -335 -325 -267 -68 199 -61 -69 215 364 92 -323 301 405 -56 637 418 468 476 799 256 583 378 46 480 69 741 879 1573 915 434 288 42 -295 1173 863 474 512 484 401 -266 -385 -863 -1218 -670 -1023 -1091 -1573 -2033 -1051 -612 -68 962 809 1000 480 715 -198 -418 -387 -277 -69 936 1038 -204 -371 -1449 -1479 -622 -75 -2116 -1642 -1385 -566 764 1572 1269 582 482 -441 -274 132 414 361 649 -349 140 1061 1127 268 732 -677 326 1676 -109 -77 -1081 -684 -818 307 -499 -312 1422 1090 -317 -142 -313 -1364 SS 20241101T225006.8Z 9071.951468 56 1 52.06 2 77.30 109.26 82.86 112.44 0.00 1 0.00 1 0 17 1.199e-01 7.352e-03 1.907e-02 1.022e-03 4.951715e-01 5.485797e-04 5.210180e-03 -6.000000e+00 7.225888e-02 226.80 -2.00 3.09 -2.00 319.65 0.00e+00 1.973044e-03 1.721679e-04 1.321828e-03 -6.000000e+00 3.364991e-03 294.31 -2.00 20.00 -2.00 318.80 0.00e+00 4.422 0.000 302.00 328.00 3 1.3325e+00 1.5930e-03 4.9138e-02 -6.0000e+00 1.7821e-01 -2.8807e-02 1.9232e-03 2.3568e-02 -6.0000e+00 1.9239e-01 2.4200e-03 1.5273e-03 1.1763e-02 -6.0000e+00 1.1558e-01 -8.1308e-03 7.9897e-04 3.4307e-03 -6.0000e+00 4.9835e-02 1.0811e-03 -7.0640e-05 3.1425e-05 4.7191e-05 -6.0000e+00 3.7136e-03 -1.9458e-02 7.4762e-05 11 8 0 10 0 0 22.90 24.37 0.38 -0.01946 -0.01999 248 39 1 5 0 209.070 26.62 20.00 24.37 34.06 4.0 1035.63 900000 -43430 -27141 -46415 -59917 -48398 -50404 -32977 -28954 -34124 -27930 -18888 -26019 -17123 -14246 -2906 -14893 -7908 -5568 -3147 -2630 -2950 -5953 -6319 -4823 -4236 -3643 -4298 -2054 -6107 -5009 -959 292 -788 -4017 -6553 -4692 -4968 -1274 -908 -682 -1739 -415 99 332 1231 -1002 25 33 783 1457 1194 1855 1935 1595 731 1825 577 -157 197 912 1735 2440 2698 1697 77 -2 -196 -234 1907 924 697 910 680 673 6 -719 -1665 -2127 -1124 -1329 -1562 -1893 -2463 -1218 -436 -139 654 955 1072 670 562 -59 -773 -63 -17 128 733 681 -163 -494 -1011 -1316 -142 -134 -1610 -1429 -882 -508 598 854 715 370 256 -207 -278 380 212 355 448 5 27 534 626 294 324 -487 275 1003 44 -93 -658 -592 -471 176 -165 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