File name: Pandora224s1_QuezonCity_20250104_L2Fit_fout2c2d20220621p1-8.txt File generation date: 20250104T161138.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Ellison Castro Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 224 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora224_OF_v2d20220531.txt Instrument calibration file used: Pandora224s1_CF_v2d20220621.txt Level 1 file used: Pandora224s1_QuezonCity_20250104_L1_smca1c2d20220621p1-8.txt Full location name: Manila Observatory, Ateneo De Manila University Short location name: QuezonCity Country of location: Philippines Location latitude [deg]: 14.6350 Location longitude [deg]: 121.0780 Location altitude [m]: 63 Local noon date: 20250104 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB based on session 1 for initial deployment period First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.0004 305.1414 305.2823 305.4232 305.5642 305.7051 305.8460 305.9869 306.1278 306.2686 306.4095 306.5504 306.6912 306.8320 306.9728 307.1136 307.2544 307.3952 307.5360 307.6767 307.8175 307.9582 308.0990 308.2397 308.3804 308.5211 308.6617 308.8024 308.9431 309.0837 309.2243 309.3650 309.5056 309.6462 309.7868 309.9273 310.0679 310.2085 310.3490 310.4895 310.6300 310.7705 310.9110 311.0515 311.1920 311.3325 311.4729 311.6133 311.7538 311.8942 312.0346 312.1750 312.3154 312.4557 312.5961 312.7364 312.8768 313.0171 313.1574 313.2977 313.4380 313.5783 313.7185 313.8588 313.9990 314.1392 314.2795 314.4197 314.5599 314.7000 314.8402 314.9804 315.1205 315.2607 315.4008 315.5409 315.6810 315.8211 315.9612 316.1012 316.2413 316.3813 316.5214 316.6614 316.8014 316.9414 317.0814 317.2213 317.3613 317.5012 317.6412 317.7811 317.9210 318.0609 318.2008 318.3407 318.4806 318.6204 318.7603 318.9001 319.0399 319.1797 319.3195 319.4593 319.5991 319.7388 319.8786 320.0183 320.1580 320.2978 320.4375 320.5772 320.7168 320.8565 320.9962 321.1358 321.2754 321.4150 321.5547 321.6943 321.8338 321.9734 322.1130 322.2525 322.3921 322.5316 322.6711 322.8106 322.9501 323.0896 323.2290 323.3685 323.5079 323.6473 323.7868 323.9262 324.0656 324.2049 324.3443 324.4837 324.6230 324.7624 324.9017 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250103T230024.6Z 9134.958617 51 1 52.70 2 82.36 115.96 129.35 93.72 0.00 1 0.00 1 0 25 5.404e-01 3.333e-02 3.854e-01 2.710e-02 5.812956e-01 1.610619e-02 8.453825e-03 -6.000000e+00 3.310992e-01 225.01 -2.00 3.09 -2.00 321.48 0.00e+00 2.087755e-02 8.495004e-03 8.829451e-03 -6.000000e+00 1.818323e-02 293.12 -2.00 20.00 -2.00 320.83 0.00e+00 6.983 0.001 302.00 328.00 3 2.8096e+00 5.9493e-02 8.1275e-02 -6.0000e+00 8.1753e-01 5.9838e-01 7.5109e-02 4.5851e-02 -6.0000e+00 8.8976e-01 -6.8546e-01 5.7821e-02 2.4153e-02 -6.0000e+00 5.2961e-01 2.7352e-01 2.8530e-02 9.2643e-03 -6.0000e+00 2.2762e-01 1.7115e-05 -4.3672e-03 9.1529e-04 2.8984e-04 -6.0000e+00 1.7423e-02 -1.0554e-02 -1.6343e-04 12 9 8 11 16 0 99.98 24.00 0.84 -0.01055 -0.04337 18 3 1 5 0 2927.360 26.32 20.01 24.00 32.99 4.4 1023.90 900000 44440 193108 900000 900000 -170253 900000 -150431 900000 -64186 900000 -4370 900000 900000 900000 900000 11418 900000 28412 900000 -48530 900000 42669 900000 126811 900000 -16500 -30232 64110 33763 277179 -76380 21212 30273 319828 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-4408 -1958 -828 -1249 1524 645 -3045 -1778 -5491 -2086 1385 986 462 -5436 -613 -5008 -372 -2088 1366 2958 272 -2434 3009 987 3171 -565 -4282 1779 -6107 -2576 -1341 -270 -5279 -106 -1790 2758 1282 -1079 -293 904 2176 -436 4220 -1809 -4123 -518 7332 4055 2331 -649 1973 451 -1748 4591 -465 1134 -2535 2281 149 -162 -327 -2252 -860 -166 753 -2513 2953 -1183 -1241 SS 20250104T001902.6Z 9135.013225 90 1 10.24 2 65.83 123.69 111.13 97.19 0.00 1 0.00 1 0 17 1.336e-02 8.584e-03 1.070e-02 4.160e-03 2.498186e-01 2.183855e-03 2.670053e-03 -6.000000e+00 7.987669e-03 225.00 -2.00 3.09 -2.00 316.82 0.00e+00 9.439064e-04 2.949019e-04 1.213081e-04 -6.000000e+00 3.726845e-04 293.12 -2.00 20.00 -2.00 315.94 0.00e+00 2.424 0.000 302.00 328.00 3 4.3995e+00 5.6796e-03 2.6311e-02 -6.0000e+00 1.9626e-02 4.6873e-02 6.3736e-03 1.1342e-02 -6.0000e+00 2.1223e-02 3.8677e-03 3.7483e-03 5.5391e-03 -6.0000e+00 1.2759e-02 -7.8622e-03 1.8133e-03 1.6508e-03 -6.0000e+00 5.5113e-03 4.4536e-04 -3.2380e-04 1.3135e-04 2.1039e-05 -6.0000e+00 4.1339e-04 -1.6267e-02 3.9341e-05 12 9 1 12 17 1 -47.13 23.96 0.35 -0.01627 -0.01870 3 3 1 5 0 2560.390 26.32 20.00 23.96 34.93 4.3 1035.99 900000 -2718 -3351 4889 -4870 -1500 82 -458 283 1119 -4655 -1254 -2516 -1369 -927 485 668 168 -78 2208 1666 -1269 -83 986 1491 -483 -1428 643 -1523 55 3275 1121 1120 1666 -2135 -2000 -1766 -3443 -770 22 -857 -392 60 -219 -445 -321 469 250 -1124 -376 -243 -764 448 579 1616 276 1531 -4 420 852 400 2238 1778 1968 1374 -687 173 -272 -501 1254 122 975 655 859 957 -726 -239 -1999 -1594 -522 -2001 -1800 -1655 -2596 -1358 -1181 235 824 761 939 417 419 -465 -334 172 -61 -340 919 987 -546 445 -1013 -702 -327 284 -1491 -1492 -1136 -388 848 1182 983 -5 84 -560 -200 121 383 119 399 101 -364 765 597 -129 674 -285 656 1107 212 403 -387 -440 -300 127 112 185 571 674 -325 -354 -814 -910 900000 -397 -521 690 -703 -194 10 -63 43 180 -816 -216 -468 -284 -199 115 170 45 -22 622 485 -384 -25 303 479 -165 -500 214 -491 17 981 366 393 611 -806 -730 -662 -1472 -346 12 -509 -230 37 -136 -279 -201 288 163 -729 -240 -159 -492 303 413 1186 211 1175 -3 325 650 311 1795 1434 1694 1224 -603 140 -227 -396 1061 115 910 627 807 913 -648 -206 -1635 -1292 -452 -1827 -1820 -1694 -2845 -1558 -1356 283 1028 965 1169 494 457 -500 -338 175 -67 -388 1144 1246 -715 557 -1275 -825 -379 345 -1970 -1954 -1553 -553 1192 1748 1501 -7 121 -798 -264 155 496 163 582 145 -532 1084 868 -180 890 -385 859 1492 289 582 -553 -644 -452 199 177 302 952 1137 -550 -582 -1297 -1490 SS 20250104T002755.6Z 9135.019393 96 1 9.72 2 64.05 124.81 109.07 97.60 0.00 1 0.00 1 0 17 1.395e-02 8.792e-03 6.171e-03 3.188e-03 2.321293e-01 1.686343e-03 2.478787e-03 -6.000000e+00 8.344530e-03 225.00 -2.00 3.09 -2.00 316.03 0.00e+00 8.267734e-04 1.893946e-04 1.137823e-04 -6.000000e+00 3.892509e-04 293.12 -2.00 20.00 -2.00 315.20 0.00e+00 2.271 0.000 302.00 328.00 3 4.2261e+00 4.3322e-03 2.4582e-02 -6.0000e+00 2.0503e-02 3.9246e-02 4.8349e-03 1.0464e-02 -6.0000e+00 2.2168e-02 7.9434e-03 2.7963e-03 5.0962e-03 -6.0000e+00 1.3326e-02 -7.7002e-03 1.3040e-03 1.4949e-03 -6.0000e+00 5.7593e-03 6.3351e-04 2.1530e-04 1.0029e-04 1.9697e-05 -6.0000e+00 4.3155e-04 -1.7472e-02 1.2285e-04 12 9 1 12 1 1 88.79 23.96 0.48 -0.01747 -0.01585 4 4 1 5 0 1943.700 26.32 20.00 23.96 35.34 4.4 1040.22 900000 -684 -1608 -1491 -6924 -1097 -4059 884 -554 -2231 -5178 -618 -2336 315 71 -175 -194 1055 3810 1558 2319 1071 1603 2140 1428 613 428 -1211 571 -1007 1176 1946 2354 666 -3598 -2597 -1874 -1702 -1089 -410 -1026 -1160 -14 146 289 485 -876 -549 -790 -400 569 1284 479 295 489 952 976 1219 236 525 298 2503 1225 1827 712 -790 -309 -770 -1209 1444 862 411 994 270 699 -293 -151 -1637 -1427 -1099 -1566 -1719 -2115 -2473 -1344 -636 -258 738 669 1026 -99 523 -1002 -235 26 -222 -159 1250 690 313 -120 -1264 -926 -411 201 -1474 -1109 -803 -767 674 1466 1043 577 9 -117 193 -173 360 563 500 9 -1 747 493 389 394 -198 440 902 -29 290 -714 -624 -862 213 -165 197 311 229 205 -254 -324 -929 900000 -142 -356 -324 -1473 -204 -770 172 -121 -532 -1304 -150 -614 83 21 -59 -70 360 1310 566 858 405 606 829 585 264 187 -522 229 -392 452 787 1017 307 -1709 -1180 -870 -820 -613 -251 -665 -808 -10 106 211 353 -640 -390 -550 -275 396 937 352 229 393 781 815 1021 198 435 251 2045 1091 1635 661 -717 -274 -651 -1040 1318 828 402 989 266 686 -267 -131 -1416 -1222 -953 -1444 -1759 -2238 -2652 -1510 -725 -311 920 811 1274 -118 597 -1114 -243 28 -237 -187 1528 873 406 -151 -1567 -1074 -493 241 -1836 -1449 -1051 -1051 961 2097 1540 844 12 -157 251 -219 461 759 690 12 -1 1066 682 537 517 -249 562 1183 -39 394 -1017 -908 -1242 319 -252 309 501 360 321 -403 -497 -1397 SS 20250104T004259.2Z 9135.029852 106 1 51.88 2 61.10 126.87 105.59 98.31 0.00 1 0.00 1 0 17 1.044e-02 7.927e-03 4.630e-04 2.790e-04 2.128604e-01 1.480827e-04 2.290469e-03 -6.000000e+00 6.245131e-03 225.00 -2.00 3.09 -2.00 315.54 0.00e+00 5.990409e-04 1.499160e-05 5.680255e-05 -6.000000e+00 2.913325e-04 293.12 -2.00 20.00 -2.00 314.75 0.00e+00 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