File name: Pandora224s1_QuezonCity_20250426_L2Fit_fout2c2d20220621p1-8.txt File generation date: 20250426T162047.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Ellison Castro Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 224 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora224_OF_v2d20220531.txt Instrument calibration file used: Pandora224s1_CF_v2d20220621.txt Level 1 file used: Pandora224s1_QuezonCity_20250426_L1_smca1c2d20220621p1-8.txt Full location name: Manila Observatory, Ateneo De Manila University Short location name: QuezonCity Country of location: Philippines Location latitude [deg]: 14.6350 Location longitude [deg]: 121.0780 Location altitude [m]: 63 Local noon date: 20250426 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB based on session 1 for initial deployment period First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.0004 305.1414 305.2823 305.4232 305.5642 305.7051 305.8460 305.9869 306.1278 306.2686 306.4095 306.5504 306.6912 306.8320 306.9728 307.1136 307.2544 307.3952 307.5360 307.6767 307.8175 307.9582 308.0990 308.2397 308.3804 308.5211 308.6617 308.8024 308.9431 309.0837 309.2243 309.3650 309.5056 309.6462 309.7868 309.9273 310.0679 310.2085 310.3490 310.4895 310.6300 310.7705 310.9110 311.0515 311.1920 311.3325 311.4729 311.6133 311.7538 311.8942 312.0346 312.1750 312.3154 312.4557 312.5961 312.7364 312.8768 313.0171 313.1574 313.2977 313.4380 313.5783 313.7185 313.8588 313.9990 314.1392 314.2795 314.4197 314.5599 314.7000 314.8402 314.9804 315.1205 315.2607 315.4008 315.5409 315.6810 315.8211 315.9612 316.1012 316.2413 316.3813 316.5214 316.6614 316.8014 316.9414 317.0814 317.2213 317.3613 317.5012 317.6412 317.7811 317.9210 318.0609 318.2008 318.3407 318.4806 318.6204 318.7603 318.9001 319.0399 319.1797 319.3195 319.4593 319.5991 319.7388 319.8786 320.0183 320.1580 320.2978 320.4375 320.5772 320.7168 320.8565 320.9962 321.1358 321.2754 321.4150 321.5547 321.6943 321.8338 321.9734 322.1130 322.2525 322.3921 322.5316 322.6711 322.8106 322.9501 323.0896 323.2290 323.3685 323.5079 323.6473 323.7868 323.9262 324.0656 324.2049 324.3443 324.4837 324.6230 324.7624 324.9017 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250425T220340.4Z 9246.919217 84 1 51.73 2 84.24 77.51 62.44 92.61 0.00 1 0.00 1 0 17 5.216e-01 2.310e-02 2.644e-01 6.769e-03 8.642011e-01 4.003764e-03 9.070517e-03 -6.000000e+00 3.175001e-01 229.74 -2.00 3.09 -2.00 322.08 0.00e+00 5.126793e-03 2.652393e-03 5.134920e-03 -6.000000e+00 1.548214e-02 294.35 -2.00 20.00 -2.00 321.56 0.00e+00 8.796 0.002 302.00 328.00 3 -2.4366e-01 1.7741e-02 9.7863e-02 -6.0000e+00 7.8857e-01 9.2806e-01 2.3840e-02 4.7630e-02 -6.0000e+00 8.5001e-01 -1.2656e+00 1.8803e-02 2.3829e-02 -6.0000e+00 5.0924e-01 5.1186e-01 8.6565e-03 7.3800e-03 -6.0000e+00 2.1869e-01 5.3479e-05 -1.7045e-03 1.9397e-04 2.0861e-04 -6.0000e+00 1.6440e-02 -1.4259e-02 3.4555e-05 12 8 8 10 0 0 39.02 24.07 0.75 -0.01426 -0.02707 84 13 1 5 0 615.750 26.41 19.99 24.07 31.46 5.1 1010.32 900000 -51309 -55054 -78534 -192370 -121554 -141074 -102854 -166418 2843 -114970 900000 -57023 -46690 -72556 250076 -104825 31298 115385 738 74927 4984 67811 -71424 103029 -68306 -33042 16874 900000 -65039 24435 50717 28418 31618 66869 21855 8198 32079 47554 80092 65842 112921 42681 118706 56408 60063 -9180 42854 66279 25600 74626 41986 64004 34281 39819 34821 43605 32685 22648 26770 23493 17368 22800 31839 7154 25894 21055 20350 -3211 19867 19652 16647 20854 10062 7160 5317 7964 -1644 1976 564 7963 1522 1676 -830 279 550 65 2333 2759 2277 -2750 -2139 -359 -5864 -6799 -1298 -2513 -879 -2575 -249 -1280 -3255 -3472 -3972 -3302 -3803 -1486 -1515 -2782 -1677 -1168 -867 -671 -503 -820 -107 -792 -64 291 1087 1042 2784 3051 2869 5 990 1013 812 1938 397 174 -950 3086 -694 -270 -448 126 629 673 -598 -562 -806 -1558 900000 -646 -759 -1319 -8999 -2479 -3300 -1666 -5290 19 -2275 900000 -787 -728 -1828 1650 -4967 413 761 14 674 87 610 -2613 680 -2540 -852 253 900000 -2184 381 730 597 772 1147 562 243 825 1224 1744 1868 2160 1718 2271 2010 2060 -636 1809 2317 1436 2806 2438 3294 2578 3021 2894 3395 2825 2092 2278 2046 1696 2362 3424 1086 3382 2903 2913 -629 3486 3864 3591 4347 2230 1497 1017 1361 -307 390 133 2096 501 625 -346 123 257 32 1173 1396 1136 -1375 -1005 -160 -2847 -3700 -783 -1824 -669 -2256 -226 -1151 -2761 -2674 -3207 -2721 -3047 -1239 -1366 -2816 -1914 -1518 -1248 -1021 -772 -1238 -156 -1157 -97 459 1778 1718 4381 4592 4182 7 1387 1391 1147 3011 663 332 -2032 6852 -1721 -661 -1172 340 1720 1846 -1618 -1435 -1922 -3841 SS 20250425T221429.5Z 9246.926731 87 1 51.84 2 81.68 78.13 59.88 93.29 0.00 1 0.00 1 0 25 5.515e-01 8.509e-03 8.030e-02 1.514e-03 7.052780e-01 8.515716e-04 7.518340e-03 -6.000000e+00 3.356530e-01 229.74 -2.00 3.09 -2.00 321.14 0.00e+00 2.393160e-03 4.402410e-04 4.383461e-03 -6.000000e+00 1.547022e-02 294.35 -2.00 20.00 -2.00 320.47 0.00e+00 6.483 0.001 302.00 328.00 3 -2.5301e-01 3.0353e-03 7.4445e-02 -6.0000e+00 8.3364e-01 4.3201e-02 4.2644e-03 4.2936e-02 -6.0000e+00 8.9833e-01 -9.1937e-02 4.1309e-03 1.9885e-02 -6.0000e+00 5.3835e-01 3.3596e-02 1.9600e-03 4.9987e-03 -6.0000e+00 2.3050e-01 6.1738e-04 1.6336e-05 4.3838e-05 9.7354e-05 -6.0000e+00 1.7094e-02 -1.5136e-02 3.8197e-05 11 8 0 10 0 0 3.09 24.07 0.42 -0.01514 -0.01501 344 55 1 5 0 150.680 26.41 20.00 24.07 32.73 5.1 1019.00 900000 -156827 -231500 -125789 -238118 -186673 -214878 -168136 -171407 -174517 -131127 -118771 -96034 -111872 -69022 -66694 -62524 -58558 -22570 -62441 -33154 -39645 -25875 -51069 -42142 -35723 -36542 -37914 -28352 -29736 -43274 -6541 -14474 -12260 -10563 -14430 -10588 -16287 -4773 -5630 884 -1830 1278 2408 5350 4105 -1924 -29 1081 -659 2864 847 3612 3689 1931 1632 2999 3123 186 1512 539 2253 3363 5873 2963 1784 934 767 661 3792 2347 1742 2099 1436 1826 -625 -889 -1637 -2287 -1766 -1354 -1104 -1676 -1769 -649 -140 43 1479 734 1252 312 743 -224 -1090 -715 -643 -175 747 597 -243 -551 -1280 -1453 -296 -67 -1791 -1384 -1079 -675 527 812 534 102 37 -527 -463 -55 465 457 560 74 289 1066 874 202 244 -488 138 875 -144 -137 -677 -476 -545 79 -34 75 717 612 -37 15 -403 -726 900000 -674 -2392 -473 -2685 -1228 -1961 -1083 -1311 -1546 -910 -824 -652 -1156 -601 -709 -757 -778 -233 -1042 -436 -574 -340 -935 -778 -670 -723 -767 -523 -588 -1131 -144 -410 -382 -335 -477 -358 -676 -216 -313 54 -128 93 181 403 322 -166 -3 100 -67 310 106 492 554 320 288 546 579 35 279 102 450 750 1449 824 517 273 231 216 1239 876 703 860 574 677 -216 -314 -576 -797 -712 -644 -609 -1046 -1201 -428 -98 32 1129 572 952 228 509 -149 -738 -526 -543 -171 772 688 -295 -651 -1408 -1466 -308 -67 -1932 -1579 -1314 -830 716 1229 820 163 59 -809 -729 -86 741 716 917 123 470 1654 1409 317 369 -724 207 1426 -250 -249 -1345 -1005 -1154 179 -76 176 1702 1461 -88 35 -903 -1565 SS 20250425T222743.3Z 9246.935918 92 1 51.77 2 78.54 78.85 56.75 94.15 0.00 1 0.00 1 0 17 1.804e-01 7.419e-03 1.417e-02 5.466e-04 5.570760e-01 2.973680e-04 5.833333e-03 -6.000000e+00 1.097927e-01 229.74 -2.00 3.09 -2.00 319.97 0.00e+00 1.663540e-03 1.032168e-04 1.871936e-03 -6.000000e+00 5.060162e-03 294.35 -2.00 20.00 -2.00 319.15 0.00e+00 4.863 0.000 302.00 328.00 3 -4.3129e-01 8.8975e-04 5.4802e-02 -6.0000e+00 2.7268e-01 -6.3396e-03 1.1002e-03 2.7791e-02 -6.0000e+00 2.9384e-01 -4.3424e-03 9.2597e-04 1.3503e-02 -6.0000e+00 1.7609e-01 -4.8098e-03 4.7704e-04 3.6520e-03 -6.0000e+00 7.5401e-02 3.8184e-03 2.5916e-05 1.6436e-05 5.2933e-05 -6.0000e+00 5.5912e-03 -1.5438e-02 4.3404e-05 11 8 0 10 0 0 19.62 24.06 0.35 -0.01544 -0.01524 949 151 1 5 0 54.550 26.41 19.99 24.06 34.37 5.1 1029.03 900000 -63729 -64480 -60332 -72534 -71604 -61966 -59216 -53601 -49717 -45876 -39295 -37099 -28456 -27476 -17015 -19255 -14635 -10345 -9540 -10966 -10193 -7856 -8224 -9372 -9930 -9129 -10419 -8641 -10628 -7777 -4535 -4428 -3975 -7070 -7594 -6603 -5401 -2384 -920 -1385 -741 -79 363 334 1294 163 162 -23 -208 1124 1750 1362 2177 1760 1349 1706 819 484 682 939 1921 2852 2985 2028 391 102 -116 319 2120 1185 816 1061 627 518 -482 -870 -1576 -1818 -1343 -1675 -1507 -1874 -2293 -1106 -535 -98 744 805 970 592 512 -376 -650 -240 -129 196 939 766 -166 -550 -1102 -1297 -84 10 -1599 -1223 -849 -500 547 874 656 295 90 -276 -305 270 425 492 419 -3 200 703 693 361 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