File name: Pandora224s1_QuezonCity_20250610_L2Fit_fout2c2d20220621p1-8.txt File generation date: 20250610T160503.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Ellison Castro Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 224 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora224_OF_v2d20220531.txt Instrument calibration file used: Pandora224s1_CF_v2d20220621.txt Level 1 file used: Pandora224s1_QuezonCity_20250610_L1_smca1c2d20220621p1-8.txt Full location name: Manila Observatory, Ateneo De Manila University Short location name: QuezonCity Country of location: Philippines Location latitude [deg]: 14.6350 Location longitude [deg]: 121.0780 Location altitude [m]: 63 Local noon date: 20250610 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB based on session 1 for initial deployment period First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.0004 305.1414 305.2823 305.4232 305.5642 305.7051 305.8460 305.9869 306.1278 306.2686 306.4095 306.5504 306.6912 306.8320 306.9728 307.1136 307.2544 307.3952 307.5360 307.6767 307.8175 307.9582 308.0990 308.2397 308.3804 308.5211 308.6617 308.8024 308.9431 309.0837 309.2243 309.3650 309.5056 309.6462 309.7868 309.9273 310.0679 310.2085 310.3490 310.4895 310.6300 310.7705 310.9110 311.0515 311.1920 311.3325 311.4729 311.6133 311.7538 311.8942 312.0346 312.1750 312.3154 312.4557 312.5961 312.7364 312.8768 313.0171 313.1574 313.2977 313.4380 313.5783 313.7185 313.8588 313.9990 314.1392 314.2795 314.4197 314.5599 314.7000 314.8402 314.9804 315.1205 315.2607 315.4008 315.5409 315.6810 315.8211 315.9612 316.1012 316.2413 316.3813 316.5214 316.6614 316.8014 316.9414 317.0814 317.2213 317.3613 317.5012 317.6412 317.7811 317.9210 318.0609 318.2008 318.3407 318.4806 318.6204 318.7603 318.9001 319.0399 319.1797 319.3195 319.4593 319.5991 319.7388 319.8786 320.0183 320.1580 320.2978 320.4375 320.5772 320.7168 320.8565 320.9962 321.1358 321.2754 321.4150 321.5547 321.6943 321.8338 321.9734 322.1130 322.2525 322.3921 322.5316 322.6711 322.8106 322.9501 323.0896 323.2290 323.3685 323.5079 323.6473 323.7868 323.9262 324.0656 324.2049 324.3443 324.4837 324.6230 324.7624 324.9017 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250609T220334.0Z 9291.919144 198 1 52.04 2 82.44 68.11 114.80 248.27 0.00 1 0.00 1 0 25 5.108e-01 1.072e-02 2.964e-01 4.054e-03 7.322499e-01 2.338324e-03 7.616485e-03 -6.000000e+00 3.124358e-01 228.65 -2.00 3.09 -2.00 321.38 0.00e+00 -1.536489e-04 1.311184e-03 4.315221e-03 -6.000000e+00 1.521137e-02 295.02 -2.00 20.00 -2.00 320.74 0.00e+00 7.045 0.001 302.00 328.00 3 9.5943e-01 8.9010e-03 8.0127e-02 -6.0000e+00 7.7474e-01 1.0778e-01 1.2797e-02 4.5623e-02 -6.0000e+00 8.3648e-01 -1.0729e-01 1.2548e-02 1.9589e-02 -6.0000e+00 4.9981e-01 3.4526e-02 5.8684e-03 5.7337e-03 -6.0000e+00 2.1419e-01 1.0418e-04 -2.9042e-04 1.2047e-04 8.5931e-05 -6.0000e+00 1.6318e-02 -1.5921e-02 2.8700e-05 12 8 8 10 0 0 36.81 23.82 0.32 -0.01592 -0.01810 71 11 1 5 0 732.940 26.21 20.00 23.82 32.01 5.3 1009.90 900000 58935 -205248 7275 -310749 -271170 8411 900000 -101750 -144998 -127215 900000 -114740 -82563 19036 900000 -144140 -51609 -11943 -51568 111475 -15045 50293 -72855 1020 -65362 -3910 11683 900000 -46582 22777 -37606 -7602 -22056 -19617 -2117 -8657 -16204 -2541 12425 -5761 10807 -9337 -1853 668 -2366 -15482 -9914 -462 -3023 10953 -3684 8876 9144 4122 2174 9479 1546 1607 1901 2189 5697 5174 9318 1312 2785 -479 2748 -5261 5859 4082 3077 2331 1452 3287 691 -342 1023 -1581 -905 -690 -1171 -2437 -3343 -1664 626 -117 1417 1023 1180 -919 193 778 -1795 -682 -443 -566 567 786 674 -207 -1567 -2085 -1068 -943 -1678 -1238 -655 -148 495 724 258 251 -227 -1075 -455 -83 638 721 387 46 949 1347 1122 -268 -4 -352 -94 1289 -473 -368 -1164 988 -674 -66 -348 112 436 783 5 64 -315 -808 900000 233 -1179 29 -5244 -3019 33 900000 -402 -729 -594 900000 -659 -445 75 900000 -2743 -489 -85 -591 440 -131 238 -1295 10 -1317 -45 115 900000 -865 243 -891 -159 -601 -542 -49 -229 -538 -90 466 -305 542 -616 -119 43 -160 -1229 -775 -35 -253 887 -391 936 1065 550 316 1344 242 249 289 336 902 928 1822 305 660 -118 674 -1519 1722 1377 1128 878 535 1106 217 -100 292 -503 -333 -301 -543 -1291 -1946 -1021 402 -80 995 730 825 -625 122 471 -1131 -464 -346 -517 542 836 750 -226 -1603 -1958 -1040 -951 -1662 -1295 -730 -179 668 1008 393 398 -359 -1652 -668 -121 944 1120 630 75 1517 2063 1664 -390 -5 -522 -141 1938 -820 -663 -2305 2046 -1512 -146 -826 276 1086 1955 13 149 -696 -1838 SS 20250609T222033.8Z 9291.930946 203 1 52.30 2 78.62 68.93 118.47 248.57 0.00 1 0.00 1 0 17 2.502e-01 1.312e-02 1.206e-01 4.668e-03 5.362189e-01 2.531631e-03 5.958828e-03 -6.000000e+00 1.516626e-01 228.65 -2.00 3.09 -2.00 320.24 0.00e+00 2.219081e-03 9.405476e-04 3.311928e-03 -6.000000e+00 7.038449e-03 295.02 -2.00 20.00 -2.00 319.42 0.00e+00 4.893 0.000 302.00 328.00 3 3.4340e+00 7.8458e-03 5.6056e-02 -6.0000e+00 3.7558e-01 1.3022e-01 9.7770e-03 3.2150e-02 -6.0000e+00 4.0500e-01 -1.0221e-01 7.9984e-03 1.3804e-02 -6.0000e+00 2.4304e-01 3.4238e-02 4.0868e-03 3.4246e-03 -6.0000e+00 1.0438e-01 7.5825e-05 -2.5906e-04 1.4392e-04 6.2948e-05 -6.0000e+00 7.7532e-03 -1.5554e-02 1.7980e-05 12 8 8 10 0 0 98.45 23.82 0.45 -0.01555 -0.01750 26 4 1 5 0 2011.470 26.21 20.00 23.82 33.22 5.3 1017.29 900000 -3670 -79257 -58065 -152671 -105295 -77305 29442 -83945 -43827 -59907 -82644 -14967 5643 -14057 41611 -73130 12908 22527 6527 18742 -1156 14670 -18511 -3669 -10990 -8015 -12192 59123 -11107 -2052 -10423 8550 6351 5561 -551 -11055 63 497 5830 176 12379 -2926 9083 4165 2671 -8459 -1207 3875 5844 2452 -1044 3827 2212 3831 1284 2562 -2112 2303 -450 -563 3804 1912 4171 2975 -370 847 1848 -6054 4667 3354 1597 2005 839 1294 -12 -542 -826 -4272 -2567 -564 -3040 -2080 -2125 -897 336 495 1613 593 324 -390 -713 -444 -1716 -2378 261 -490 692 24 1299 -431 -1144 -1984 -1142 -90 -1885 -1113 -721 -1053 559 1473 1324 358 -18 -685 49 -305 83 691 1283 -170 395 1625 1390 -522 638 -668 -29 1684 -379 -131 -701 -1328 -294 -79 -373 51 263 1275 372 -136 -637 -941 900000 -26 -1312 -793 -5117 -2091 -1302 188 -1872 -718 -1227 -2294 -245 92 -345 701 -4427 364 625 226 597 -46 507 -944 -174 -595 -434 -682 1588 -612 -113 -721 560 465 418 -43 -1011 6 55 738 27 1848 -539 1538 754 498 -1790 -241 755 1165 543 -264 1010 642 1166 420 853 -746 769 -152 -193 1331 754 1782 1249 -161 355 764 -2860 2213 1799 933 1188 489 703 -6 -250 -406 -2068 -1382 -345 -2173 -1633 -1796 -732 289 451 1512 569 305 -352 -602 -384 -1477 -1999 240 -518 819 29 1605 -525 -1406 -2270 -1259 -103 -2326 -1330 -911 -1433 819 2339 2079 577 -29 -1111 75 -458 127 1108 2000 -275 628 2664 2208 -811 940 -963 -42 2542 -599 -227 -1300 -2600 -559 -158 -796 113 592 2858 826 -291 -1301 -1856 SS 20250609T223505.3Z 9291.941033 212 1 43.73 2 75.33 69.56 121.61 248.73 0.00 1 0.00 1 0 17 9.995e-02 8.668e-03 3.893e-02 2.895e-03 4.375877e-01 1.547220e-03 4.550717e-03 -6.000000e+00 6.060305e-02 228.65 -2.00 3.09 -2.00 319.04 0.00e+00 1.611512e-03 3.951784e-04 5.878837e-04 -6.000000e+00 2.812088e-03 295.03 -2.00 20.00 -2.00 318.14 0.00e+00 3.867 0.000 302.00 328.00 3 3.6446e+00 4.3337e-03 4.3011e-02 -6.0000e+00 1.5008e-01 4.3533e-02 5.0592e-03 2.0307e-02 -6.0000e+00 1.6182e-01 5.2489e-04 3.6280e-03 1.0004e-02 -6.0000e+00 9.7108e-02 -6.3222e-03 1.9185e-03 3.0215e-03 -6.0000e+00 4.1719e-02 1.8286e-04 -1.3210e-04 9.0105e-05 3.7370e-05 -6.0000e+00 3.0970e-03 -1.6946e-02 3.8340e-05 12 9 1 12 1 1 67.96 23.82 0.41 -0.01695 -0.01794 16 3 1 5 0 2572.210 26.21 20.00 23.82 33.96 5.3 1020.95 900000 17299 -24612 -12558 -64620 -7250 -30685 32277 350 -17495 -11935 68610 7415 -10678 2222 4152 -21268 1608 -919 -2777 -48 8304 2875 -5638 -4258 -6608 -3252 838 5572 -1235 -3347 -2586 -274 -298 -3155 -2234 -5592 -3444 -1964 -1858 -1268 1900 858 207 588 120 1700 -1853 242 2341 1048 954 1315 151 2181 1458 1214 113 -203 -502 267 1237 1304 2323 2104 -164 -417 -523 -1803 2195 1301 -98 1279 638 1096 76 -1083 -814 -804 -658 -1000 -1709 -2245 -2122 -1528 -791 -45 848 801 1116 258 1131 -132 -953 -637 -670 -50 692 532 389 32 -1171 -1297 -514 595 -1746 -1371 -663 -201 686 1115 716 359 177 -288 -537 -231 226 7 711 -279 89 1033 617 -360 545 -517 -321 1474 -139 -112 -881 774 -302 109 -194 -64 521 714 -75 -184 -405 -941 900000 293 -695 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