File name: Pandora224s1_QuezonCity_20250701_L2Fit_fout2c2d20220621p1-8.txt File generation date: 20250702T064347.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Ellison Castro Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 224 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora224_OF_v2d20220531.txt Instrument calibration file used: Pandora224s1_CF_v2d20220621.txt Level 1 file used: Pandora224s1_QuezonCity_20250701_L1_smca1c2d20220621p1-8.txt Full location name: Manila Observatory, Ateneo De Manila University Short location name: QuezonCity Country of location: Philippines Location latitude [deg]: 14.6350 Location longitude [deg]: 121.0780 Location altitude [m]: 63 Local noon date: 20250701 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB based on session 1 for initial deployment period First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.0004 305.1414 305.2823 305.4232 305.5642 305.7051 305.8460 305.9869 306.1278 306.2686 306.4095 306.5504 306.6912 306.8320 306.9728 307.1136 307.2544 307.3952 307.5360 307.6767 307.8175 307.9582 308.0990 308.2397 308.3804 308.5211 308.6617 308.8024 308.9431 309.0837 309.2243 309.3650 309.5056 309.6462 309.7868 309.9273 310.0679 310.2085 310.3490 310.4895 310.6300 310.7705 310.9110 311.0515 311.1920 311.3325 311.4729 311.6133 311.7538 311.8942 312.0346 312.1750 312.3154 312.4557 312.5961 312.7364 312.8768 313.0171 313.1574 313.2977 313.4380 313.5783 313.7185 313.8588 313.9990 314.1392 314.2795 314.4197 314.5599 314.7000 314.8402 314.9804 315.1205 315.2607 315.4008 315.5409 315.6810 315.8211 315.9612 316.1012 316.2413 316.3813 316.5214 316.6614 316.8014 316.9414 317.0814 317.2213 317.3613 317.5012 317.6412 317.7811 317.9210 318.0609 318.2008 318.3407 318.4806 318.6204 318.7603 318.9001 319.0399 319.1797 319.3195 319.4593 319.5991 319.7388 319.8786 320.0183 320.1580 320.2978 320.4375 320.5772 320.7168 320.8565 320.9962 321.1358 321.2754 321.4150 321.5547 321.6943 321.8338 321.9734 322.1130 322.2525 322.3921 322.5316 322.6711 322.8106 322.9501 323.0896 323.2290 323.3685 323.5079 323.6473 323.7868 323.9262 324.0656 324.2049 324.3443 324.4837 324.6230 324.7624 324.9017 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250630T222426.7Z 9312.933642 53 1 51.61 2 78.72 68.81 147.32 56.09 0.00 1 0.00 1 0 17 1.882e-01 7.805e-03 7.789e-02 2.102e-03 5.490139e-01 1.133558e-03 5.755173e-03 -6.000000e+00 1.137864e-01 227.93 -2.00 3.09 -2.00 320.03 0.00e+00 2.745097e-03 4.012621e-04 1.719556e-03 -6.000000e+00 5.291742e-03 294.91 -2.00 20.00 -2.00 319.21 0.00e+00 4.935 0.000 302.00 328.00 3 2.0620e+00 3.4179e-03 5.4903e-02 -6.0000e+00 2.8131e-01 5.5828e-02 4.2377e-03 2.6605e-02 -6.0000e+00 3.0349e-01 -2.6715e-02 3.5644e-03 1.3613e-02 -6.0000e+00 1.8222e-01 2.6429e-04 1.8387e-03 4.1831e-03 -6.0000e+00 7.8385e-02 2.9046e-04 -1.4373e-04 6.3630e-05 6.0610e-05 -6.0000e+00 5.8300e-03 -1.6792e-02 1.7342e-05 11 8 0 10 0 0 21.66 24.07 0.46 -0.01679 -0.01787 67 11 1 5 0 770.190 26.41 20.00 24.07 31.78 5.6 1007.37 900000 -1807 -69822 -60351 -119204 -27761 -56942 -4385 -41277 -44008 -35440 103193 -34689 -35087 -17648 450 -35294 43 -456 -2279 -1102 -8368 -2926 -22659 -15153 -10906 -4965 -3535 -3651 -6812 -17006 3330 669 287 -2010 -4625 -2362 -1102 1023 575 -1434 -702 -194 3161 2321 1826 -1995 -1180 424 -625 1369 425 833 1441 1062 800 1833 12 -883 -111 904 2085 2229 3885 1381 -478 -641 -171 -1703 2167 1613 1520 1366 524 1527 -232 -769 -1996 -1740 -1213 -1447 -1708 -1547 -2220 -1031 -437 -83 1169 994 1272 287 641 -183 -979 -413 -382 220 1315 731 -77 -399 -1152 -1178 -160 -170 -1818 -1274 -1092 -441 649 648 907 227 -60 -427 -282 126 334 361 344 11 336 829 707 185 428 -687 276 742 -106 -244 -671 -73 -548 29 -70 -154 583 569 -72 -5 -306 -546 900000 -11 -916 -742 -2541 -228 -642 -32 -499 -604 -479 381 -597 -755 -398 10 -1324 1 -15 -80 -40 -335 -114 -1143 -767 -566 -251 -176 -180 -355 -1084 202 48 23 -167 -392 -205 -108 118 80 -236 -126 -37 606 460 371 -429 -257 94 -147 339 107 230 430 340 269 632 4 -314 -39 317 771 914 1743 682 -242 -318 -84 -828 1135 950 960 881 332 896 -126 -387 -1071 -897 -706 -981 -1225 -1231 -1916 -938 -392 -79 1140 984 1233 267 597 -162 -861 -384 -370 242 1520 935 -96 -518 -1396 -1315 -183 -190 -2202 -1623 -1476 -598 953 981 1460 375 -98 -657 -438 192 518 554 556 19 548 1303 1076 289 641 -1005 401 1150 -173 -412 -1219 -138 -1042 58 -141 -324 1241 1221 -154 -11 -624 -1074 SS 20250630T223006.3Z 9312.937573 56 1 51.94 2 77.45 69.06 146.23 57.56 0.00 1 0.00 1 0 17 1.080e-01 7.319e-03 2.747e-02 1.431e-03 5.022447e-01 7.685295e-04 5.227085e-03 -6.000000e+00 6.532052e-02 227.93 -2.00 3.09 -2.00 319.57 0.00e+00 1.815449e-03 2.350680e-04 1.135905e-03 -6.000000e+00 3.037517e-03 294.91 -2.00 20.00 -2.00 318.72 0.00e+00 4.470 0.000 302.00 328.00 3 1.8814e+00 2.2196e-03 4.9672e-02 -6.0000e+00 1.6149e-01 2.8408e-02 2.6671e-03 2.3680e-02 -6.0000e+00 1.7421e-01 -1.0907e-02 2.0945e-03 1.1770e-02 -6.0000e+00 1.0460e-01 -4.2638e-03 1.0983e-03 3.4556e-03 -6.0000e+00 4.5003e-02 5.7267e-04 -1.3191e-04 4.3716e-05 4.6320e-05 -6.0000e+00 3.3459e-03 -1.7167e-02 4.9982e-05 11 8 0 10 0 0 27.70 24.10 0.33 -0.01717 -0.01816 104 17 1 5 0 499.390 26.41 20.00 24.10 32.11 5.5 1009.78 900000 -10733 -23404 -42847 -68951 -39925 -25302 -38290 -29604 -17347 -37331 16656 -25500 -15120 -11639 -3737 -19050 -4403 -4487 -3476 -2329 2047 -3096 -5988 -6870 -9362 -2276 -7959 -2113 -7776 -4629 -980 984 -2047 -5027 -3610 -3065 -3025 -1794 -647 396 28 -450 1703 -406 2586 -1028 1690 487 -51 1749 528 1268 1266 1131 912 1046 504 402 -340 160 1469 1988 3082 1524 -143 -343 -365 -493 1997 1063 885 1185 703 628 -194 -1033 -1306 -1715 -1091 -1536 -1488 -1716 -2590 -1284 -564 -52 834 605 1255 406 459 -62 -745 -33 -49 77 996 684 -17 -311 -1059 -1455 -136 105 -1459 -1100 -691 -578 418 849 501 278 100 -404 -176 238 353 501 296 40 -14 648 741 198 547 -511 153 948 -181 -209 -764 -390 -485 51 -41 -42 592 710 -115 52 -410 -687 900000 -121 -333 -759 -1520 -630 -353 -673 -541 -310 -870 244 -658 -430 -393 -139 -944 -208 -230 -188 -130 112 -183 -387 -484 -722 -169 -623 -153 -602 -378 -89 100 -234 -603 -422 -373 -420 -296 -127 80 6 -107 412 -103 643 -269 436 130 -14 515 173 452 488 465 361 428 210 166 -140 66 641 953 1616 865 -83 -193 -203 -290 1179 707 632 862 501 421 -120 -638 -776 -1066 -700 -1144 -1171 -1498 -2290 -1195 -558 -54 898 621 1341 416 437 -56 -708 -30 -51 85 1230 876 -23 -403 -1281 -1736 -155 126 -1775 -1409 -935 -791 617 1288 809 455 160 -614 -266 352 533 754 471 66 -22 1013 1119 304 805 -732 218 1426 -288 -344 -1346 -682 -891 99 -80 -85 1224 1478 -237 104 -777 -1320 SS 20250630T223520.9Z 9312.941214 59 1 51.81 2 76.26 69.29 145.21 58.85 0.00 1 0.00 1 0 17 6.752e-02 7.164e-03 1.174e-02 8.576e-04 4.695495e-01 4.572625e-04 4.890386e-03 -6.000000e+00 4.083331e-02 227.93 -2.00 3.09 -2.00 319.13 0.00e+00 1.689169e-03 1.200944e-04 8.199682e-04 -6.000000e+00 1.898740e-03 294.91 -2.00 20.00 -2.00 318.23 0.00e+00 4.110 0.000 302.00 328.00 3 1.2872e+00 1.2846e-03 4.5782e-02 -6.0000e+00 1.0095e-01 1.6310e-02 1.5113e-03 2.1844e-02 -6.0000e+00 1.0890e-01 -4.4741e-03 1.1161e-03 1.0835e-02 -6.0000e+00 6.5386e-02 -5.4206e-03 5.9001e-04 3.2385e-03 -6.0000e+00 2.8134e-02 1.5133e-03 -4.9858e-05 2.6214e-05 4.0189e-05 -6.0000e+00 2.0913e-03 -1.7411e-02 6.1507e-05 11 8 0 10 0 0 63.44 24.12 0.37 -0.01741 -0.01779 232 37 1 5 0 223.290 26.41 20.00 24.12 32.50 5.5 1013.11 900000 -3771 -20654 -21687 -37419 -21646 -29893 -13073 -23061 -17220 -25262 -10321 -12764 -11206 -10559 -4602 -7370 -4464 -1103 -3720 431 -3853 -140 -2582 -911 -3615 -1838 -4448 -2390 -2341 -3373 2221 -518 628 -4563 -3442 -4064 -2846 -1120 74 -1165 -386 -471 921 621 1618 351 -113 479 -62 1375 615 1254 1594 1023 150 1258 747 -175 178 83 1640 1928 2687 1179 -77 -474 -239 -305 1875 1028 677 1245 610 531 -420 -1002 -1675 -1499 -1294 -1367 -1619 -1950 -2374 -1231 -530 -170 764 717 936 578 659 -263 -363 22 -21 111 900 803 -147 -420 -889 -1142 -233 299 -1610 -1186 -847 -547 556 945 593 251 110 -235 -105 230 318 376 364 -128 108 668 571 187 368 -498 257 937 -18 -171 -676 -616 -348 197 -81 -86 625 525 -75 -83 -208 -715 900000 -62 -442 -479 -923 -434 -665 -271 -598 -464 -784 -295 -428 -448 -510 -248 -463 -298 -77 -283 33 -313 -11 -224 -84 -364 -188 -463 -237 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