File name: Pandora52s1_RichmondCA_20230407_L2Fit_fout2c2d20220121p1-8.txt File generation date: 20240131T152047.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 52 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora52_OF_v2d20211014.txt Instrument calibration file used: Pandora52s1_CF_v2d20220121.txt Level 1 file used: Pandora52s1_RichmondCA_20230407_L1_smca1c2d20220121p1-8.txt Full location name: University Of California Berkeley Short location name: RichmondCA Country of location: USA Location latitude [deg]: 37.9130 Location longitude [deg]: -122.3360 Location altitude [m]: 5 Local noon date: 20230407 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 1 for new VP First and last pixel inside fitting window: 260 401 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2640 305.4050 305.5460 305.6869 305.8279 305.9688 306.1097 306.2507 306.3916 306.5325 306.6733 306.8142 306.9551 307.0959 307.2367 307.3775 307.5183 307.6591 307.7999 307.9407 308.0814 308.2222 308.3629 308.5036 308.6444 308.7850 308.9257 309.0664 309.2071 309.3477 309.4883 309.6290 309.7696 309.9102 310.0508 310.1913 310.3319 310.4724 310.6130 310.7535 310.8940 311.0345 311.1750 311.3155 311.4559 311.5964 311.7368 311.8773 312.0177 312.1581 312.2985 312.4388 312.5792 312.7196 312.8599 313.0002 313.1405 313.2809 313.4211 313.5614 313.7017 313.8419 313.9822 314.1224 314.2626 314.4028 314.5430 314.6832 314.8234 314.9636 315.1037 315.2438 315.3840 315.5241 315.6642 315.8042 315.9443 316.0844 316.2244 316.3645 316.5045 316.6445 316.7845 316.9245 317.0645 317.2044 317.3444 317.4843 317.6242 317.7641 317.9040 318.0439 318.1838 318.3237 318.4635 318.6034 318.7432 318.8830 319.0228 319.1626 319.3024 319.4422 319.5819 319.7216 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9788 321.1184 321.2580 321.3976 321.5372 321.6768 321.8163 321.9559 322.0954 322.2349 322.3744 322.5139 322.6534 322.7929 322.9323 323.0718 323.2112 323.3506 323.4901 323.6295 323.7688 323.9082 324.0476 324.1869 324.3263 324.4656 324.6049 324.7442 324.8835 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230407T214824.6Z 8497.908619 517 1 17.69 2 37.92 221.53 156.75 11.82 0.00 1 0.00 1 0 17 1.033e-02 6.162e-03 6.075e-03 2.909e-03 2.115758e-01 1.472700e-03 2.541161e-03 -6.000000e+00 5.856846e-03 228.34 -2.00 3.45 -2.00 316.25 0.00e+00 1.777058e-04 1.620023e-04 7.713896e-05 -6.000000e+00 2.557845e-04 281.64 -2.00 20.00 -2.00 315.59 0.00e+00 1.267 0.000 302.00 328.00 3 5.8294e+00 3.8309e-03 1.6722e-02 -6.0000e+00 1.4591e-02 5.6278e-02 4.2681e-03 1.0714e-02 -6.0000e+00 1.5811e-02 -2.9094e-03 2.4856e-03 5.2820e-03 -6.0000e+00 9.4010e-03 -2.6993e-03 1.1834e-03 1.4882e-03 -6.0000e+00 4.0655e-03 3.3481e-04 -8.4711e-04 7.9777e-05 1.6844e-05 -6.0000e+00 2.6600e-04 1.4863e-03 0.0000e+00 12 1 1 12 1 1 99.98 21.32 0.43 0.00149 -0.00488 9 6 1 5 0 1752.060 26.94 20.00 21.32 17.74 16.4 1030.65 -18 -252 -1184 -2224 -1866 -438 1222 -20 1905 -3220 -3522 1133 -2766 371 1588 137 2759 -1 1118 1339 1602 1180 1329 -234 608 734 -1187 289 231 1036 1355 -396 -423 -2428 -3437 -2979 -1959 -10 -436 -243 -598 379 -1398 -19 -456 288 -595 -1530 -798 47 -139 614 1030 1129 1099 355 128 698 525 419 1008 1028 1946 671 -297 -9 -432 630 201 133 462 410 397 610 -223 -1026 -1228 -1531 -1369 -1220 -1045 -1454 -752 -535 -373 144 360 629 101 93 275 -215 203 -450 -104 -345 931 310 8 249 -684 65 468 -759 -1198 -757 -724 270 654 557 116 755 209 -420 -128 -252 -409 99 336 -451 168 278 504 334 136 -269 803 300 -134 -106 -304 91 -103 88 204 -230 416 78 65 -114 -390 -481 -4 -53 -246 -416 -309 -70 212 -4 407 -729 -772 248 -710 105 480 44 889 0 389 480 573 417 484 -91 248 304 -482 110 82 364 507 -162 -179 -1051 -1382 -1208 -859 -5 -261 -159 -416 268 -994 -14 -329 204 -409 -1027 -534 31 -97 452 791 872 863 286 104 556 422 340 827 913 1790 647 -275 -8 -354 511 177 128 474 418 408 595 -206 -874 -981 -1198 -1129 -1102 -1046 -1539 -804 -600 -437 175 456 807 128 114 316 -230 204 -459 -112 -397 1137 404 11 317 -830 74 541 -928 -1545 -989 -986 378 938 826 178 1131 303 -573 -164 -319 -516 131 470 -652 244 403 703 455 177 -340 990 374 -176 -147 -424 128 -148 129 317 -364 668 127 105 -180 -610 -725 SS 20230407T220230.5Z 8497.918408 524 1 1.93 2 39.85 226.19 156.08 19.77 0.00 1 0.00 1 0 17 1.071e-02 7.923e-03 8.603e-03 5.305e-03 2.175519e-01 2.706352e-03 2.605670e-03 -6.000000e+00 6.076899e-03 228.34 -2.00 3.45 -2.00 315.38 0.00e+00 3.403849e-04 2.477264e-04 2.542479e-05 -6.000000e+00 2.653004e-04 281.65 -2.00 20.00 -2.00 314.78 0.00e+00 1.301 0.000 302.00 328.00 3 4.5096e+00 6.9678e-03 1.7149e-02 -6.0000e+00 1.5140e-02 5.5465e-02 7.7388e-03 1.0956e-02 -6.0000e+00 1.6401e-02 -1.1589e-02 4.4502e-03 5.3931e-03 -6.0000e+00 9.7514e-03 2.0492e-03 2.0408e-03 1.5301e-03 -6.0000e+00 4.2210e-03 1.1998e-03 -2.4825e-04 1.4313e-04 1.8059e-05 -6.0000e+00 2.7568e-04 -3.8001e-03 0.0000e+00 12 9 1 12 1 1 999.00 21.35 0.41 -0.00380 -0.00567 1 12 1 5 0 881.980 26.94 20.01 21.35 18.25 16.5 1035.47 905 -996 -3060 1676 -3256 1129 -135 157 851 451 -880 -2787 869 -421 452 -635 1166 738 3223 1190 1201 -88 379 2773 -1141 785 -2176 1164 764 199 -191 1710 -52 -2403 -345 -2369 -1151 -2280 -693 -889 526 -984 -1683 147 -1397 -272 -667 -1006 -791 399 1080 -48 1119 -525 1087 524 1354 1150 116 2639 662 687 1165 1411 -171 892 -961 774 309 -670 756 -437 273 900 227 -716 -1037 -563 -986 -1390 -519 -2042 -1643 -602 -244 185 382 387 657 114 1358 -398 -774 1072 -1079 554 922 -30 -408 -386 -1228 153 901 -913 -1372 -248 -473 -305 790 756 -550 234 207 -242 -247 501 432 557 -24 -653 -211 -328 766 756 51 -366 689 -69 569 -450 169 431 180 460 293 -124 819 -89 -543 -143 -562 -711 249 -294 -904 432 -803 269 -35 45 256 137 -268 -884 293 -160 183 -275 504 324 1422 553 557 -41 180 1332 -586 402 -1105 550 346 90 -91 845 -27 -1256 -169 -1203 -624 -1408 -475 -652 397 -764 -1337 114 -1099 -213 -507 -754 -587 297 836 -39 918 -447 927 458 1183 990 99 2238 581 633 1116 1398 -166 808 -836 675 287 -666 780 -458 283 909 217 -645 -879 -472 -875 -1334 -524 -2170 -1794 -674 -285 224 470 484 817 137 1547 -433 -801 1112 -1183 633 1115 -38 -530 -486 -1486 175 1025 -1092 -1710 -315 -620 -409 1081 1069 -797 334 287 -321 -312 619 539 717 -32 -907 -295 -452 1035 996 66 -455 837 -85 729 -601 229 587 248 648 428 -185 1235 -136 -829 -216 -827 -1035 SS 20230407T220655.4Z 8497.921474 527 1 49.79 2 40.48 227.57 155.79 22.17 0.00 1 0.00 1 0 17 7.180e-03 4.990e-03 3.323e-04 1.540e-04 2.125205e-01 7.792364e-05 2.548256e-03 -6.000000e+00 4.071750e-03 228.35 -2.00 3.45 -2.00 316.34 0.00e+00 4.442543e-04 8.713651e-06 3.803365e-05 -6.000000e+00 1.777664e-04 281.65 -2.00 20.00 -2.00 315.65 0.00e+00 1.313 0.000 302.00 328.00 3 1.0857e+00 2.0294e-04 1.7103e-02 -6.0000e+00 1.0144e-02 2.3987e-02 2.2595e-04 1.0774e-02 -6.0000e+00 1.0990e-02 -1.4857e-03 1.3216e-04 5.3092e-03 -6.0000e+00 6.5340e-03 -3.4577e-03 6.3244e-05 1.5223e-03 -6.0000e+00 2.8281e-03 3.7138e-02 -1.3476e-04 4.2746e-06 1.6711e-05 -6.0000e+00 1.8473e-04 -3.3583e-03 0.0000e+00 10 0 0 10 0 0 99.94 21.34 0.28 -0.00336 -0.00437 2455 506 1 5 0 20.180 26.94 19.99 21.34 19.02 16.5 1042.61 -1468 -461 -1778 -1746 -1628 -1241 -377 -261 -553 -1406 -859 -758 -523 106 -32 82 1079 745 1276 1272 792 1643 1099 776 151 -247 -83 -179 115 714 558 1087 -446 -1887 -1252 -1800 -1150 -613 -922 -807 -517 -572 -607 -306 -147 -603 -285 -814 -459 243 273 417 806 589 984 788 378 589 418 953 1128 1078 1380 395 -126 132 -467 668 195 -144 250 6 516 128 -71 -106 -874 -372 -905 -1339 -904 -1695 -1103 -694 -447 -52 28 334 235 302 142 -121 410 368 -217 168 804 240 -242 -373 -559 -123 226 -672 -1067 -449 -570 49 536 442 122 319 74 -37 14 292 6 282 53 -397 38 129 225 372 108 -193 871 467 84 27 -308 282 152 200 -1 -117 421 -45 -126 -324 -438 -382 -281 -92 -352 -309 -256 -191 -63 -50 -115 -296 -174 -161 -125 29 -10 27 351 251 442 455 285 578 400 300 62 -103 -33 -66 40 245 205 428 -190 -794 -482 -706 -507 -292 -527 -519 -352 -402 -434 -217 -104 -424 -193 -536 -294 157 188 305 616 468 793 649 315 482 336 766 951 903 1243 372 -113 107 -383 544 163 -136 251 6 519 123 -62 -90 -682 -282 -753 -1160 -867 -1777 -1202 -793 -507 -62 35 428 297 360 167 -129 398 360 -232 197 959 314 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