File name: Pandora52s1_RichmondCA_20230521_L2Fit_fout2c2d20220121p1-8.txt File generation date: 20240131T153829.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 52 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora52_OF_v2d20211014.txt Instrument calibration file used: Pandora52s1_CF_v2d20220121.txt Level 1 file used: Pandora52s1_RichmondCA_20230521_L1_smca1c2d20220121p1-8.txt Full location name: University Of California Berkeley Short location name: RichmondCA Country of location: USA Location latitude [deg]: 37.9130 Location longitude [deg]: -122.3360 Location altitude [m]: 5 Local noon date: 20230521 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 1 for new VP First and last pixel inside fitting window: 260 401 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2640 305.4050 305.5460 305.6869 305.8279 305.9688 306.1097 306.2507 306.3916 306.5325 306.6733 306.8142 306.9551 307.0959 307.2367 307.3775 307.5183 307.6591 307.7999 307.9407 308.0814 308.2222 308.3629 308.5036 308.6444 308.7850 308.9257 309.0664 309.2071 309.3477 309.4883 309.6290 309.7696 309.9102 310.0508 310.1913 310.3319 310.4724 310.6130 310.7535 310.8940 311.0345 311.1750 311.3155 311.4559 311.5964 311.7368 311.8773 312.0177 312.1581 312.2985 312.4388 312.5792 312.7196 312.8599 313.0002 313.1405 313.2809 313.4211 313.5614 313.7017 313.8419 313.9822 314.1224 314.2626 314.4028 314.5430 314.6832 314.8234 314.9636 315.1037 315.2438 315.3840 315.5241 315.6642 315.8042 315.9443 316.0844 316.2244 316.3645 316.5045 316.6445 316.7845 316.9245 317.0645 317.2044 317.3444 317.4843 317.6242 317.7641 317.9040 318.0439 318.1838 318.3237 318.4635 318.6034 318.7432 318.8830 319.0228 319.1626 319.3024 319.4422 319.5819 319.7216 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9788 321.1184 321.2580 321.3976 321.5372 321.6768 321.8163 321.9559 322.0954 322.2349 322.3744 322.5139 322.6534 322.7929 322.9323 323.0718 323.2112 323.3506 323.4901 323.6295 323.7688 323.9082 324.0476 324.1869 324.3263 324.4656 324.6049 324.7442 324.8835 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230521T163605.6Z 8541.691731 167 1 50.56 2 48.44 96.02 65.43 74.05 0.00 1 0.00 1 0 17 1.613e-02 9.011e-03 6.350e-03 2.577e-03 2.102119e-01 1.312591e-03 2.505629e-03 -6.000000e+00 9.248086e-03 231.57 -2.00 3.45 -2.00 316.83 0.00e+00 -3.316399e-05 1.653870e-04 1.409214e-04 -6.000000e+00 4.068427e-04 286.06 -2.00 20.00 -2.00 316.05 0.00e+00 1.505 0.000 302.00 328.00 3 6.0541e+00 3.4604e-03 1.8651e-02 -6.0000e+00 2.3183e-02 5.8722e-02 3.8641e-03 1.0868e-02 -6.0000e+00 2.5052e-02 -7.9656e-04 2.2715e-03 5.2733e-03 -6.0000e+00 1.4895e-02 -3.2777e-03 1.0976e-03 1.4790e-03 -6.0000e+00 6.4140e-03 2.1323e-04 -9.2148e-04 7.1698e-05 1.6265e-05 -6.0000e+00 4.1596e-04 9.2936e-03 0.0000e+00 11 9 0 11 8 0 99.95 21.28 0.30 0.00929 0.00237 17 4 1 5 0 2973.870 26.94 19.99 21.28 19.08 17.5 1031.82 -4671 -937 900 -439 648 -5768 1941 -4184 -2897 -1342 930 -639 -3232 2185 -802 108 -226 1050 523 534 576 1660 1719 662 1310 -941 925 -884 -427 -1391 -734 256 -1286 -659 -2494 -2438 -1863 116 -1938 120 -320 295 -179 -1079 -101 -1110 12366 -1697 -616 38 -324 -324 259 724 681 429 462 1076 -219 1270 1347 854 2250 -243 -450 -294 -1082 -515 197 466 421 -188 407 484 -705 -26 -2371 -1221 -1580 -1790 -948 -2069 -1074 -868 229 339 751 733 230 578 -188 -880 -1098 -101 -485 223 807 583 -182 -348 -596 -571 -47 -1105 -940 -488 -483 282 699 1173 208 810 330 34 -325 453 -51 167 -134 -741 477 516 520 169 -200 -142 -222 149 175 276 -616 181 -151 82 -6 119 673 176 90 -563 -294 -658 -775 -157 144 -63 85 -803 276 -722 -536 -245 161 -118 -691 503 -212 30 -64 302 156 164 177 498 533 220 455 -339 314 -281 -131 -429 -240 89 -470 -238 -847 -845 -729 52 -1052 72 -198 186 -115 -698 -66 -728 6842 -1044 -366 23 -208 -221 185 532 510 329 356 810 -164 943 1051 704 1965 -224 -393 -238 -820 -391 167 428 412 -188 398 449 -622 -20 -1773 -886 -1257 -1563 -911 -2109 -1133 -963 263 415 958 948 294 693 -214 -932 -1074 -99 -517 253 1005 769 -247 -451 -730 -645 -52 -1348 -1199 -646 -667 401 1017 1798 331 1256 496 46 -425 565 -66 227 -193 -1126 721 759 739 237 -267 -183 -276 192 234 391 -909 267 -223 127 -10 197 1130 301 153 -935 -483 -1045 SS 20230521T164453.0Z 8541.697835 173 1 50.54 2 46.72 97.55 63.80 75.12 0.00 1 0.00 1 0 17 1.097e-02 6.969e-03 8.507e-03 3.335e-03 2.024118e-01 1.695546e-03 2.400360e-03 -6.000000e+00 6.289478e-03 231.57 -2.00 3.45 -2.00 316.94 0.00e+00 3.827682e-04 2.189558e-04 6.330736e-05 -6.000000e+00 2.766755e-04 286.06 -2.00 20.00 -2.00 316.16 0.00e+00 1.456 0.000 302.00 328.00 3 6.2950e+00 4.4813e-03 1.8011e-02 -6.0000e+00 1.5767e-02 5.6234e-02 5.0066e-03 1.0440e-02 -6.0000e+00 1.7037e-02 1.0124e-02 2.9504e-03 5.0754e-03 -6.0000e+00 1.0130e-02 -9.8461e-03 1.4294e-03 1.4166e-03 -6.0000e+00 4.3622e-03 1.7772e-04 -7.0011e-04 9.3203e-05 1.5294e-05 -6.0000e+00 2.8287e-04 8.9572e-03 0.0000e+00 11 8 0 10 0 0 99.98 21.27 0.92 0.00896 0.00370 27 6 1 5 0 1871.570 26.94 20.00 21.27 19.25 17.6 1032.96 -2370 58 -3034 -2680 -165 -2007 3858 881 -1503 -272 1613 267 -1260 -702 1067 824 -524 780 1735 863 855 2126 -149 817 -768 -1254 1947 -830 -814 140 1104 1215 -1336 -2583 -2308 -2392 -1431 536 -1809 -473 -842 -454 -1207 69 221 -1085 3255 -1277 -1078 64 573 961 639 -61 800 1939 -85 705 561 197 1145 1662 1999 -189 -6 -699 -1178 -406 -150 86 226 248 822 1153 -17 -282 -1563 -1304 -1458 -1105 -886 -1883 -625 -806 -489 26 787 782 686 450 -142 -692 -392 -735 -893 -420 1165 505 464 -319 -844 -659 246 -1456 -690 -462 -527 388 722 935 414 713 -30 -20 -505 -335 -316 -459 266 -605 253 147 622 223 -89 -306 326 37 -338 15 -119 336 157 380 102 245 843 -161 88 -174 -631 -754 -374 9 -492 -385 -21 -262 523 140 -265 -48 267 47 -255 -161 268 218 -143 217 494 256 253 614 -45 261 -262 -436 628 -253 -240 41 342 404 -484 -914 -752 -797 -536 236 -941 -272 -515 -285 -774 43 139 -682 1952 -774 -634 38 360 639 447 -45 587 1436 -64 523 409 145 882 1379 1720 -171 -5 -556 -874 -302 -124 80 216 242 805 1071 -15 -222 -1133 -925 -1133 -935 -830 -1923 -658 -897 -566 32 1004 1012 873 540 -161 -710 -381 -724 -925 -479 1444 665 622 -409 -1032 -743 274 -1780 -903 -629 -726 549 1076 1468 673 1130 -45 -28 -654 -417 -403 -625 389 -909 380 222 903 308 -118 -394 401 48 -452 21 -173 489 234 596 164 410 1434 -281 153 -292 -1057 -1223 SS 20230521T164947.9Z 8541.701249 176 1 49.28 2 45.76 98.44 62.89 75.72 0.00 1 0.00 1 0 17 7.966e-03 5.317e-03 3.814e-03 1.653e-03 1.978124e-01 8.446185e-04 2.342380e-03 -6.000000e+00 4.568073e-03 231.57 -2.00 3.45 -2.00 316.63 0.00e+00 6.082848e-04 1.011863e-04 6.179402e-05 -6.000000e+00 2.008702e-04 286.06 -2.00 20.00 -2.00 315.86 0.00e+00 1.431 0.000 302.00 328.00 3 5.2828e+00 2.2245e-03 1.7654e-02 -6.0000e+00 1.1452e-02 5.4522e-02 2.4834e-03 1.0185e-02 -6.0000e+00 1.2372e-02 2.7688e-04 1.4478e-03 4.9494e-03 -6.0000e+00 7.3562e-03 -4.9822e-03 6.9073e-04 1.4103e-03 -6.0000e+00 3.1698e-03 5.0749e-04 -4.7457e-04 4.5875e-05 1.4919e-05 -6.0000e+00 2.0529e-04 5.1834e-03 0.0000e+00 11 1 0 11 8 0 99.80 21.28 0.34 0.00518 0.00162 48 10 1 5 0 1026.610 26.94 20.00 21.28 19.42 17.6 1034.56 -607 -57 -1976 -3285 0 -1967 -163 -885 1055 -829 -776 -64 665 344 -556 -13 1241 1347 372 423 715 1515 943 622 270 -387 140 -584 311 382 838 2052 -342 -2068 -2173 -1850 -1359 -346 -1076 -762 -474 -237 -299 -248 -170 -737 284 -1228 -746 337 33 646 1003 941 763 656 -176 102 304 824 1059 1035 1568 151 -34 -269 -412 583 -44 87 450 390 518 95 -123 -240 -1456 -902 -1135 -1355 -693 -1602 -714 -652 -244 4 170 741 412 626 130 -142 -92 -109 -424 186 725 156 -76 -244 -677 -266 11 -992 -1287 -423 -487 279 526 629 151 502 -27 -4 -147 37 -233 60 56 -207 318 172 225 199 66 -94 794 462 -200 -177 -543 243 51 260 141 80 513 91 201 -481 -519 -510 -110 -11 -370 -554 0 -288 -26 -160 203 -162 -146 -13 146 86 -157 -4 368 411 118 139 233 483 312 218 99 -145 50 -194 96 118 274 712 -129 -765 -742 -700 -532 -160 -598 -473 -311 -159 -205 -169 -116 -497 183 -774 -455 207 21 447 724 703 580 509 -138 79 230 625 843 893 1446 145 -31 -220 -314 442 -38 83 456 404 525 92 -108 -189 -1052 -635 -874 -1181 -664 -1677 -774 -744 -275 5 213 941 516 738 152 -150 -89 -106 -449 216 926 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