File name: Pandora52s1_RichmondCA_20240420_L2Fit_fout2c2d20220121p1-8.txt File generation date: 20240421T081626.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 52 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora52_OF_v2d20211014.txt Instrument calibration file used: Pandora52s1_CF_v2d20220121.txt Level 1 file used: Pandora52s1_RichmondCA_20240420_L1_smca1c2d20220121p1-8.txt Full location name: University Of California Berkeley Short location name: RichmondCA Country of location: USA Location latitude [deg]: 37.9130 Location longitude [deg]: -122.3360 Location altitude [m]: 5 Local noon date: 20240420 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 1 for new VP First and last pixel inside fitting window: 260 401 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2640 305.4050 305.5460 305.6869 305.8279 305.9688 306.1097 306.2507 306.3916 306.5325 306.6733 306.8142 306.9551 307.0959 307.2367 307.3775 307.5183 307.6591 307.7999 307.9407 308.0814 308.2222 308.3629 308.5036 308.6444 308.7850 308.9257 309.0664 309.2071 309.3477 309.4883 309.6290 309.7696 309.9102 310.0508 310.1913 310.3319 310.4724 310.6130 310.7535 310.8940 311.0345 311.1750 311.3155 311.4559 311.5964 311.7368 311.8773 312.0177 312.1581 312.2985 312.4388 312.5792 312.7196 312.8599 313.0002 313.1405 313.2809 313.4211 313.5614 313.7017 313.8419 313.9822 314.1224 314.2626 314.4028 314.5430 314.6832 314.8234 314.9636 315.1037 315.2438 315.3840 315.5241 315.6642 315.8042 315.9443 316.0844 316.2244 316.3645 316.5045 316.6445 316.7845 316.9245 317.0645 317.2044 317.3444 317.4843 317.6242 317.7641 317.9040 318.0439 318.1838 318.3237 318.4635 318.6034 318.7432 318.8830 319.0228 319.1626 319.3024 319.4422 319.5819 319.7216 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9788 321.1184 321.2580 321.3976 321.5372 321.6768 321.8163 321.9559 322.0954 322.2349 322.3744 322.5139 322.6534 322.7929 322.9323 323.0718 323.2112 323.3506 323.4901 323.6295 323.7688 323.9082 324.0476 324.1869 324.3263 324.4656 324.6049 324.7442 324.8835 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240420T143858.4Z 8876.610398 216 1 30.41 2 76.74 85.22 119.16 301.80 0.00 1 0.00 1 0 17 4.611e-01 3.310e-02 3.433e-01 1.240e-02 5.922906e-01 6.709056e-03 7.539914e-03 -6.000000e+00 2.637386e-01 229.41 -2.00 3.45 -2.00 320.92 0.00e+00 2.375666e-02 2.799558e-03 1.954698e-03 -6.000000e+00 1.238862e-02 283.01 -2.00 20.00 -2.00 320.34 0.00e+00 4.250 0.001 302.00 328.00 3 4.4336e+00 2.1537e-02 5.3563e-02 -6.0000e+00 6.6125e-01 4.4223e-01 2.7664e-02 3.6147e-02 -6.0000e+00 7.1804e-01 -4.2078e-01 2.6849e-02 3.1725e-02 -6.0000e+00 4.2363e-01 1.6288e-01 1.3405e-02 2.8650e-02 -6.0000e+00 1.8503e-01 3.7458e-05 -2.2248e-03 3.4525e-04 2.5058e-04 -6.0000e+00 1.2347e-02 2.0326e-02 0.0000e+00 12 9 9 12 9 1 99.99 21.22 0.38 0.02033 0.00361 17 6 1 5 0 1688.980 26.83 19.99 21.22 14.89 30.0 898.64 900000 30327 900000 900000 -108929 -104519 56139 900000 900000 82407 116400 139024 71696 59418 53555 163593 206900 114018 63166 30908 97856 89640 39906 -3860 -31430 -19720 54417 34100 56914 221614 67287 59024 52805 42474 22987 45763 19045 12863 24799 11544 14346 13722 15383 21139 24787 48296 -85783 22620 30319 27815 20855 29239 30783 12160 3825 5317 1333 225 -3960 3192 6299 5379 22383 9080 9170 10169 3269 7690 -969 3945 7475 2060 628 -375 2582 -8 -1121 -768 -3600 -2464 5436 940 -683 -169 -880 -280 -1543 1084 1909 385 -1947 -2211 -2857 -1950 -4063 -236 1083 2151 188 740 -1302 725 -1678 -1338 -3821 -1856 -2933 183 603 -346 179 -542 1073 -2272 -68 -1155 -23 -304 -181 332 1236 2840 77 2016 37 1197 1032 927 515 1358 422 196 339 -511 -597 -816 563 -81 -585 114 -543 -120 900000 366 900000 900000 -3215 -2776 678 900000 900000 995 1405 1679 866 739 901 1975 2498 1502 1413 977 1575 1476 1006 -145 -1518 -840 1135 886 1270 2676 2019 2222 2363 2066 1249 2043 1190 991 1955 1148 1477 1467 1770 2395 2834 4562 -30325 2972 3822 3842 3407 4776 5269 2604 867 1218 312 52 -935 724 1517 1494 5993 3041 3061 3192 1077 2531 -395 1720 3321 967 285 -158 947 -3 -373 -273 -1555 -1248 2917 584 -455 -118 -657 -220 -1280 886 1518 293 -1397 -1474 -1867 -1361 -3343 -218 1141 2453 228 853 -1421 690 -1566 -1319 -4142 -2068 -3502 228 832 -521 289 -892 1683 -3463 -98 -1656 -35 -477 -292 542 2002 4325 117 2870 52 1570 1345 1326 841 2436 792 384 696 -1123 -1395 -1966 1357 -199 -1410 259 -1159 -247 SS 20240420T144907.8Z 8876.617451 219 1 8.52 2 74.74 86.75 120.81 303.88 0.00 1 0.00 1 0 25 1.166e-01 5.107e-03 4.115e-02 1.475e-03 5.502355e-01 7.626501e-04 6.282367e-03 -6.000000e+00 6.625375e-02 229.41 -2.00 3.45 -2.00 319.98 0.00e+00 2.204119e-03 2.503730e-04 3.624052e-04 -6.000000e+00 2.903157e-03 283.01 -2.00 20.00 -2.00 319.34 0.00e+00 3.728 0.001 302.00 328.00 3 1.0877e+00 2.2360e-03 4.7083e-02 -6.0000e+00 1.6538e-01 4.0827e-02 2.7437e-03 2.8628e-02 -6.0000e+00 1.7916e-01 -1.9505e-02 2.4811e-03 1.4580e-02 -6.0000e+00 1.0652e-01 -4.8233e-04 1.2825e-03 4.8131e-03 -6.0000e+00 4.5905e-02 2.1962e-03 -1.2149e-03 3.9567e-05 4.5898e-05 -6.0000e+00 3.0057e-03 1.5578e-02 0.0000e+00 12 1 1 12 1 1 99.46 21.23 0.31 0.01558 0.00645 93 113 1 5 0 90.550 26.94 20.00 21.23 15.31 30.0 901.82 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620 116 556 -327 -35 -410 -628 -814 -625 -672 -644 -1290 -991 -542 -497 332 20 624 638 756 499 -104 330 -131 -165 22 956 299 -182 -528 -1105 225 -87 -1284 -1830 -726 -741 411 1018 505 465 601 267 -93 265 572 -37 61 -400 -549 420 577 244 324 -623 -299 1366 344 -225 -352 -466 429 230 -240 -425 -78 977 23 -340 -532 -528 353 SS 20240420T145837.1Z 8876.624041 222 1 38.00 2 72.87 88.18 122.32 305.89 0.00 1 0.00 1 0 25 6.042e-02 4.698e-03 3.159e-02 1.242e-03 4.946808e-01 6.431988e-04 5.683045e-03 -6.000000e+00 3.428687e-02 229.41 -2.00 3.45 -2.00 320.26 0.00e+00 2.243619e-03 2.239781e-04 2.808934e-04 -6.000000e+00 1.504873e-03 283.01 -2.00 20.00 -2.00 319.63 0.00e+00 3.344 0.001 302.00 328.00 3 1.9445e+00 1.9199e-03 4.2366e-02 -6.0000e+00 8.5581e-02 3.7668e-02 2.3770e-03 2.6003e-02 -6.0000e+00 9.2747e-02 -3.1768e-03 2.1420e-03 1.3037e-02 -6.0000e+00 5.5143e-02 -7.5366e-03 1.0981e-03 4.2574e-03 -6.0000e+00 2.3732e-02 1.4281e-03 -2.3399e-03 3.4726e-05 4.1164e-05 -6.0000e+00 1.5577e-03 2.4120e-02 0.0000e+00 12 1 1 12 1 1 99.99 21.23 0.26 0.02412 0.00654 422 114 1 5 0 89.610 26.83 20.00 21.23 15.98 30.0 906.47 -22332 -18495 -16493 -19466 -18332 -28375 -15189 -21773 -14102 -22942 -11621 -17471 -8057 -6382 -7774 -213 410 4606 214 1636 -218 1039 489 -2247 -1644 -4713 -2625 -3493 -3217 -2639 -1295 2957 -2206 -1300 -2751 -2944 -2465 -1054 -1374 -1501 -1154 -1221 267 56 576 -34 -8445 -678 326 1144 573 1233 1445 1392 1377 866 -12 139 -120 1039 1710 1395 2413 1226 810 685 -159 819 445 41 201 266 552 390 -287 -512 -1969 -701 -1100 -1341 -515 -1513 -1094 -649 -139 77 254 579 616 902 577 -126 168 163 -508 184 827 175 -114 -351 -507 -350 156 -1157 -1319 -722 -529 135 601 446 144 430 -3 -11 -7 221 -62 68 -225 -464 239 370 279 93 -223 -228 836 301 -133 -60 -317 270 -130 -49 -131 -41 548 31 -87 -247 -215 -9 -243 -215 -192 -214 -184 -323 -171 -303 -201 -372 -174 -324 -170 -165 -245 -7 15 171 9 70 -10 45 23 -118 -92 -281 -150 -193 -176 -158 -90 227 -198 -115 -232 -259 -249 -129 -186 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