File name: Pandora52s1_RichmondCA_20240721_L2Fit_fout2c2d20220121p1-8.txt File generation date: 20240722T171336.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 52 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora52_OF_v2d20211014.txt Instrument calibration file used: Pandora52s1_CF_v2d20220121.txt Level 1 file used: Pandora52s1_RichmondCA_20240721_L1_smca1c2d20220121p1-8.txt Full location name: University Of California Berkeley Short location name: RichmondCA Country of location: USA Location latitude [deg]: 37.9130 Location longitude [deg]: -122.3360 Location altitude [m]: 5 Local noon date: 20240721 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 1 for new VP First and last pixel inside fitting window: 260 401 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2640 305.4050 305.5460 305.6869 305.8279 305.9688 306.1097 306.2507 306.3916 306.5325 306.6733 306.8142 306.9551 307.0959 307.2367 307.3775 307.5183 307.6591 307.7999 307.9407 308.0814 308.2222 308.3629 308.5036 308.6444 308.7850 308.9257 309.0664 309.2071 309.3477 309.4883 309.6290 309.7696 309.9102 310.0508 310.1913 310.3319 310.4724 310.6130 310.7535 310.8940 311.0345 311.1750 311.3155 311.4559 311.5964 311.7368 311.8773 312.0177 312.1581 312.2985 312.4388 312.5792 312.7196 312.8599 313.0002 313.1405 313.2809 313.4211 313.5614 313.7017 313.8419 313.9822 314.1224 314.2626 314.4028 314.5430 314.6832 314.8234 314.9636 315.1037 315.2438 315.3840 315.5241 315.6642 315.8042 315.9443 316.0844 316.2244 316.3645 316.5045 316.6445 316.7845 316.9245 317.0645 317.2044 317.3444 317.4843 317.6242 317.7641 317.9040 318.0439 318.1838 318.3237 318.4635 318.6034 318.7432 318.8830 319.0228 319.1626 319.3024 319.4422 319.5819 319.7216 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9788 321.1184 321.2580 321.3976 321.5372 321.6768 321.8163 321.9559 322.0954 322.2349 322.3744 322.5139 322.6534 322.7929 322.9323 323.0718 323.2112 323.3506 323.4901 323.6295 323.7688 323.9082 324.0476 324.1869 324.3263 324.4656 324.6049 324.7442 324.8835 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [�C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [�C], 999=no temperature signal Column 95: Spectrometer control temperature [�C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [�C], 999=no temperature signal Column 97: Temperature in head sensor [�C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240721T155134.6Z 8968.660818 283 1 50.07 2 59.13 87.35 120.38 261.13 0.00 1 0.00 1 0 17 2.706e-02 9.722e-03 1.441e-02 3.481e-03 2.596576e-01 1.767379e-03 3.089353e-03 -6.000000e+00 1.553981e-02 232.42 -2.00 3.45 -2.00 318.03 0.00e+00 2.458811e-03 3.082883e-04 2.193758e-04 -6.000000e+00 6.981473e-04 291.34 -2.00 20.00 -2.00 317.13 0.00e+00 1.941 0.000 302.00 328.00 3 5.6374e+00 4.7829e-03 2.3787e-02 -6.0000e+00 3.8962e-02 6.2598e-02 5.4114e-03 1.3656e-02 -6.0000e+00 4.2058e-02 7.0820e-04 3.3672e-03 6.7116e-03 -6.0000e+00 2.5069e-02 -5.8642e-03 1.7206e-03 2.4822e-03 -6.0000e+00 1.0811e-02 1.9069e-04 -1.1037e-03 9.8371e-05 2.2491e-05 -6.0000e+00 6.9814e-04 2.0049e-02 0.0000e+00 12 8 8 10 0 0 99.99 21.25 -0.01 0.02005 0.01176 43 9 1 5 0 1164.310 26.94 20.00 21.25 18.53 31.4 967.58 217 -1353 -4137 -4408 -9790 11714 5531 13185 -7620 -3396 -10 -1630 -2212 -4304 711 -2129 6875 3848 4892 1521 103 1831 -2205 1008 -2531 1194 -404 2420 254 1717 1823 954 522 -1682 399 -2692 -15 703 745 -1492 -1064 650 -1494 1912 215 819 -14496 460 195 1009 260 27 2376 210 1990 163 348 202 91 78 773 2589 1976 2013 579 1759 -655 341 156 564 632 -458 1061 -786 380 -722 -1221 -608 -1814 -1176 -1397 -1403 -1099 -621 -324 610 222 836 389 603 475 -906 -163 71 -552 96 603 145 95 -395 -684 -390 -332 -1103 -1530 -292 -576 476 909 630 738 751 264 -249 -527 -542 -617 -227 -244 -246 -50 901 126 435 -123 -313 817 -237 7 -345 -61 299 130 193 76 257 312 165 -246 -457 -453 9 19 -124 -384 -366 -772 765 423 1057 -787 -346 -1 -174 -276 -639 114 -375 1143 689 900 300 21 355 -460 215 -584 270 -89 484 51 351 407 235 138 -438 94 -678 -4 235 287 -659 -496 309 -740 917 105 408 -7969 219 92 486 135 15 1364 128 1211 103 221 126 56 48 508 1823 1515 1598 441 1200 -431 227 117 474 564 -419 932 -665 288 -509 -796 -394 -1321 -938 -1244 -1353 -1106 -658 -368 711 271 1027 471 705 507 -884 -152 68 -563 109 753 192 129 -524 -833 -437 -370 -1340 -2007 -395 -816 677 1369 1013 1225 1222 405 -362 -709 -707 -831 -324 -376 -384 -80 1393 190 619 -167 -416 1040 -321 10 -521 -94 469 210 330 134 468 580 312 -461 -828 -812 15 SS 20240721T163344.8Z 8968.690102 303 1 27.62 2 50.82 93.91 128.19 266.94 0.00 1 0.00 1 0 17 1.034e-02 6.503e-03 8.953e-03 3.486e-03 2.149690e-01 1.775406e-03 2.545786e-03 -6.000000e+00 5.938957e-03 232.42 -2.00 3.45 -2.00 316.92 0.00e+00 3.685560e-04 2.328919e-04 1.710895e-04 -6.000000e+00 2.667536e-04 291.34 -2.00 20.00 -2.00 316.05 0.00e+00 1.579 0.000 302.00 328.00 3 6.0090e+00 4.6980e-03 1.9415e-02 -6.0000e+00 1.4891e-02 4.8767e-02 5.2548e-03 1.1130e-02 -6.0000e+00 1.6073e-02 6.5294e-03 3.0905e-03 5.3756e-03 -6.0000e+00 9.5804e-03 -7.6061e-03 1.5033e-03 1.4699e-03 -6.0000e+00 4.1322e-03 2.0566e-04 -9.1077e-04 9.6659e-05 1.5864e-05 -6.0000e+00 2.6676e-04 1.8934e-02 0.0000e+00 12 9 1 12 1 1 99.99 21.25 0.31 0.01893 0.01209 12 5 1 5 0 2124.290 26.94 20.00 21.25 19.35 31.6 973.45 623 -975 -1440 1609 -1943 -1565 -2930 168 -2838 -3041 -2114 -157 -1331 -616 1133 -909 1809 586 901 -299 1023 950 1284 1440 -458 738 -2021 -575 313 1099 1442 1314 -81 -1564 -879 -4030 -171 -1572 -550 -696 -854 1632 -645 296 -198 -116 -110 -1282 -756 236 -381 344 1607 105 407 1418 322 511 189 1369 1319 1293 1458 699 -374 154 -1612 -148 171 7 672 369 766 -58 -384 -685 -2006 -1328 -1807 -1085 -1139 -1375 -1229 12 -317 306 525 852 321 747 67 -814 -176 -677 -437 -51 985 528 367 -368 -1114 -350 -593 -963 -1547 -333 -304 193 667 493 542 564 425 -288 -219 50 -483 128 92 24 573 369 364 861 -392 -488 444 -165 263 137 -175 -399 64 146 -130 -236 541 188 -22 32 -390 -620 92 -153 -221 219 -247 -198 -416 26 -496 -532 -356 -28 -268 -141 283 -244 483 164 260 -90 303 279 390 463 -157 254 -683 -177 93 325 456 436 -29 -560 -290 -1413 -66 -716 -286 -406 -527 1012 -416 188 -126 -73 -67 -786 -451 143 -241 229 1109 76 299 1054 244 378 138 999 1017 1083 1272 632 -330 122 -1248 -115 144 6 653 366 739 -55 -332 -544 -1476 -960 -1446 -945 -1101 -1398 -1303 13 -369 378 675 1075 410 893 75 -857 -171 -671 -471 -59 1208 707 487 -478 -1376 -397 -675 -1192 -2014 -447 -425 272 989 755 853 865 627 -401 -288 63 -636 173 134 36 855 537 527 1175 -531 -622 557 -211 362 193 -255 -589 97 225 -213 -392 911 323 -37 54 -637 -981 SS 20240721T163842.4Z 8968.693546 306 1 15.19 2 49.84 94.74 129.11 267.65 0.00 1 0.00 1 0 17 1.448e-02 8.065e-03 9.442e-03 4.227e-03 2.116846e-01 2.159202e-03 2.503886e-03 -6.000000e+00 8.322178e-03 232.42 -2.00 3.45 -2.00 316.49 0.00e+00 6.255670e-04 2.567058e-04 8.192451e-05 -6.000000e+00 3.736614e-04 291.34 -2.00 20.00 -2.00 315.64 0.00e+00 1.547 0.000 302.00 328.00 3 5.9928e+00 5.6793e-03 1.9049e-02 -6.0000e+00 2.0866e-02 5.4766e-02 6.3308e-03 1.0938e-02 -6.0000e+00 2.2521e-02 2.2424e-03 3.6779e-03 5.2900e-03 -6.0000e+00 1.3424e-02 -5.3503e-03 1.7588e-03 1.4733e-03 -6.0000e+00 5.7917e-03 2.1642e-04 -8.7220e-04 1.1603e-04 1.5794e-05 -6.0000e+00 3.7369e-04 1.7065e-02 0.0000e+00 12 9 1 12 9 1 99.93 21.24 0.09 0.01707 0.01051 4 3 1 5 0 3036.540 26.94 20.00 21.24 19.57 31.5 974.97 678 755 -96 -414 2934 -1633 -1594 -1024 947 -8331 1684 3805 -26 -628 245 1721 -1053 -199 1951 2056 1109 3825 3179 863 -818 -539 1749 -1890 -757 2374 2976 564 -2804 -2514 -3959 -3291 -2765 -647 -784 -1069 86 372 -1015 31 -805 -878 342 -2035 -1455 -127 883 -663 285 501 278 180 -392 1627 965 610 1298 1383 2418 754 310 98 -670 -151 289 1026 1037 698 920 595 -1206 -284 -2111 -1187 -835 -1934 -1459 -1838 -542 -1085 -56 -35 1119 1248 567 862 -27 -936 73 -269 -566 3 1093 430 372 -278 -487 -880 -852 -934 -1239 -533 -661 -479 1257 571 459 527 -138 -394 -300 -45 -687 -76 68 -364 603 269 749 370 102 -273 219 -72 -370 196 -66 669 -194 262 261 151 661 64 95 -603 -680 -402 122 142 -18 -68 430 -250 -269 -190 186 -1791 327 768 -6 -167 72 523 -336 -65 645 702 380 1263 1092 313 -315 -210 655 -677 -252 773 1032 216 -1180 -1011 -1495 -1270 -1210 -324 -454 -676 57 253 -709 21 -558 -601 223 -1318 -940 -83 592 -480 214 379 214 142 -312 1279 750 481 1046 1209 2190 714 277 81 -534 -121 254 977 1022 702 926 570 -1097 -234 -1655 -912 -684 -1763 -1431 -1907 -579 -1203 -67 -43 1423 1568 720 1051 -31 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