File name: Pandora52s1_RichmondCA_20240827_L2Fit_fout2c2d20220121p1-8.txt File generation date: 20240828T081947.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 52 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora52_OF_v2d20211014.txt Instrument calibration file used: Pandora52s1_CF_v2d20220121.txt Level 1 file used: Pandora52s1_RichmondCA_20240827_L1_smca1c2d20220121p1-8.txt Full location name: University Of California Berkeley Short location name: RichmondCA Country of location: USA Location latitude [deg]: 37.9130 Location longitude [deg]: -122.3360 Location altitude [m]: 5 Local noon date: 20240827 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 1 for new VP First and last pixel inside fitting window: 260 401 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2640 305.4050 305.5460 305.6869 305.8279 305.9688 306.1097 306.2507 306.3916 306.5325 306.6733 306.8142 306.9551 307.0959 307.2367 307.3775 307.5183 307.6591 307.7999 307.9407 308.0814 308.2222 308.3629 308.5036 308.6444 308.7850 308.9257 309.0664 309.2071 309.3477 309.4883 309.6290 309.7696 309.9102 310.0508 310.1913 310.3319 310.4724 310.6130 310.7535 310.8940 311.0345 311.1750 311.3155 311.4559 311.5964 311.7368 311.8773 312.0177 312.1581 312.2985 312.4388 312.5792 312.7196 312.8599 313.0002 313.1405 313.2809 313.4211 313.5614 313.7017 313.8419 313.9822 314.1224 314.2626 314.4028 314.5430 314.6832 314.8234 314.9636 315.1037 315.2438 315.3840 315.5241 315.6642 315.8042 315.9443 316.0844 316.2244 316.3645 316.5045 316.6445 316.7845 316.9245 317.0645 317.2044 317.3444 317.4843 317.6242 317.7641 317.9040 318.0439 318.1838 318.3237 318.4635 318.6034 318.7432 318.8830 319.0228 319.1626 319.3024 319.4422 319.5819 319.7216 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9788 321.1184 321.2580 321.3976 321.5372 321.6768 321.8163 321.9559 322.0954 322.2349 322.3744 322.5139 322.6534 322.7929 322.9323 323.0718 323.2112 323.3506 323.4901 323.6295 323.7688 323.9082 324.0476 324.1869 324.3263 324.4656 324.6049 324.7442 324.8835 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240827T152935.8Z 9005.645553 275 1 19.70 2 68.52 94.38 11.69 213.41 0.00 1 0.00 1 0 17 4.305e-02 9.702e-03 3.998e-02 5.406e-03 3.394651e-01 2.734793e-03 4.012368e-03 -6.000000e+00 2.454287e-02 230.68 -2.00 3.45 -2.00 318.63 0.00e+00 2.518281e-03 5.827373e-04 2.582622e-04 -6.000000e+00 1.109786e-03 291.03 -2.00 20.00 -2.00 317.76 0.00e+00 2.705 0.000 302.00 328.00 3 5.2961e+00 7.5071e-03 3.2331e-02 -6.0000e+00 6.1275e-02 5.2161e-02 8.6233e-03 1.7744e-02 -6.0000e+00 6.6259e-02 1.8121e-03 5.8914e-03 8.7868e-03 -6.0000e+00 3.9545e-02 -7.2794e-03 3.1152e-03 3.0617e-03 -6.0000e+00 1.7093e-02 1.1430e-04 -1.2731e-03 1.5081e-04 2.8650e-05 -6.0000e+00 1.1107e-03 2.8010e-02 0.0000e+00 12 9 9 12 1 1 99.87 21.30 0.41 0.02801 0.01844 4 3 1 5 0 3938.350 26.94 20.00 21.30 21.22 32.0 967.53 6403 10020 -4775 25027 9506 4082 -6080 3040 19054 -2321 -11556 -4509 15273 -2109 10344 -989 1698 -3036 4394 -3121 -4911 -2313 -6058 6845 -11663 393 -343 -4097 1322 6691 2650 6923 810 -3059 3863 -1630 -220 -1916 -1410 790 307 1559 -905 -1009 -260 -1465 -11836 938 116 -450 -956 690 2068 1553 2317 1854 -1733 1069 656 -190 1914 2310 1777 2123 2163 621 -829 -362 -28 1175 945 -1090 -82 133 -10 699 -3114 -790 -1064 -2162 -252 -2709 -1209 -954 1197 527 765 307 1024 677 -1115 642 -264 1295 -725 -712 1206 850 -452 -89 -923 -385 -239 -1669 -1030 -452 -907 -469 777 1258 270 317 626 141 -812 -527 -927 151 -412 -340 261 707 285 763 48 -376 530 14 550 811 -481 222 -59 -494 93 543 6 518 -161 -439 -461 -347 267 432 -236 827 335 158 -283 147 877 -130 -710 -289 991 -188 941 -110 193 -383 539 -429 -686 -314 -895 979 -2051 63 -55 -638 190 965 447 1247 168 -636 702 -326 -50 -521 -457 282 114 596 -364 -408 -105 -600 -5312 378 47 -193 -437 334 1047 826 1254 1034 -1008 593 359 -106 1121 1445 1223 1522 1479 407 -528 -238 -20 920 787 -938 -68 106 -8 462 -1995 -505 -770 -1764 -221 -2572 -1188 -991 1275 602 886 361 1199 746 -1175 622 -245 1235 -763 -820 1488 1124 -617 -118 -1147 -448 -277 -2067 -1327 -606 -1248 -675 1163 1966 443 513 978 209 -1128 -729 -1301 224 -643 -548 415 1084 434 1103 69 -508 713 20 821 1263 -790 369 -100 -868 173 1012 11 998 -307 -826 -828 -614 SS 20240827T155219.2Z 9005.661333 287 1 49.76 2 64.07 98.09 14.63 230.78 0.00 1 0.00 1 0 17 1.031e-02 4.956e-03 3.304e-03 6.965e-04 2.922894e-01 3.525099e-04 3.455725e-03 -6.000000e+00 5.882363e-03 230.68 -2.00 3.45 -2.00 318.18 0.00e+00 5.638250e-04 6.485119e-05 1.583078e-04 -6.000000e+00 2.658262e-04 291.03 -2.00 20.00 -2.00 317.29 0.00e+00 2.273 0.000 302.00 328.00 3 2.7620e+00 9.5352e-04 2.7348e-02 -6.0000e+00 1.4686e-02 1.9699e-02 1.0843e-03 1.5161e-02 -6.0000e+00 1.5878e-02 6.4800e-03 6.9164e-04 7.3825e-03 -6.0000e+00 9.4766e-03 -7.8618e-03 3.5770e-04 2.0561e-03 -6.0000e+00 4.0983e-03 2.4027e-03 -7.9021e-04 1.9503e-05 2.1012e-05 -6.0000e+00 2.6605e-04 2.4425e-02 0.0000e+00 10 0 0 10 0 0 99.96 21.30 0.29 0.02442 0.01849 283 58 1 5 0 175.820 26.94 20.00 21.30 21.64 32.3 971.60 -2309 -356 -2846 -2462 -3937 -2991 -1197 -2060 -2255 -3189 -1006 -2667 -1013 -129 -860 -241 871 277 135 1238 995 1903 966 102 -166 -1022 -294 -1256 297 378 389 535 -1210 -2409 -2223 -2424 -1560 -657 -1100 -453 -355 -444 -385 110 -87 -595 759 -1057 -186 412 333 648 808 813 871 711 191 495 341 998 1315 1518 1743 562 189 -82 -429 670 239 -1 386 183 603 213 -284 -392 -1346 -609 -1040 -1219 -779 -1736 -911 -707 -232 62 246 454 438 572 197 185 284 264 -382 170 599 73 -234 -407 -676 -279 48 -1097 -1182 -627 -545 170 595 584 100 413 -5 23 -44 225 -135 171 -126 -402 206 250 182 330 -92 -17 963 332 53 -51 -261 295 191 123 39 67 451 -43 -141 -414 -453 -262 -164 -26 -211 -162 -240 -183 -81 -161 -192 -276 -84 -250 -109 -16 -122 -36 135 46 23 218 175 332 178 20 -35 -222 -61 -244 54 72 81 123 -304 -590 -508 -578 -425 -215 -432 -199 -165 -196 -190 54 -43 -293 361 -502 -87 200 175 364 436 457 501 420 115 290 196 636 808 1019 1268 429 137 -54 -299 434 177 -1 339 163 521 174 -211 -287 -922 -419 -804 -979 -695 -1699 -927 -761 -268 70 288 537 507 676 214 182 263 253 -406 201 720 97 -314 -519 -862 -326 56 -1403 -1490 -821 -746 242 904 947 170 683 -8 33 -58 291 -181 244 -194 -645 326 385 270 467 -125 -23 1298 477 76 -78 -416 474 318 217 67 119 820 -79 -258 -732 -832 -463 SS 20240827T155643.1Z 9005.664388 290 1 49.86 2 63.21 98.83 15.30 233.39 0.00 1 0.00 1 0 17 9.147e-03 4.906e-03 1.154e-03 2.543e-04 2.836807e-01 1.284593e-04 3.332807e-03 -6.000000e+00 5.221080e-03 230.67 -2.00 3.45 -2.00 318.12 0.00e+00 6.406648e-04 2.327860e-05 1.586015e-04 -6.000000e+00 2.356889e-04 291.03 -2.00 20.00 -2.00 317.23 0.00e+00 2.206 0.000 302.00 328.00 3 8.2916e-01 3.4727e-04 2.6516e-02 -6.0000e+00 1.3036e-02 5.6859e-03 3.9461e-04 1.4656e-02 -6.0000e+00 1.4090e-02 5.8904e-03 2.4988e-04 7.1362e-03 -6.0000e+00 8.4097e-03 -7.1153e-03 1.2887e-04 2.0185e-03 -6.0000e+00 3.6399e-03 1.8083e-02 -2.6602e-05 7.1454e-06 2.0350e-05 -6.0000e+00 2.3592e-04 1.8932e-02 0.0000e+00 10 0 0 10 0 0 99.97 21.30 0.28 0.01893 0.01873 2427 501 1 5 0 20.490 26.94 20.00 21.30 22.27 32.4 977.50 -1636 -699 -1996 -3071 -2732 -2851 -1456 -1395 -1247 -2552 -1859 -1512 -1002 -160 -543 95 831 487 948 876 546 1243 960 254 -45 -651 -407 -998 -95 308 333 986 -1054 -2034 -2171 -2414 -1466 -739 -946 -755 -404 -452 -388 -140 1 -475 496 -846 -307 342 311 576 759 735 1011 710 262 512 320 973 1291 1351 1644 469 200 56 -383 739 75 153 404 153 590 65 -149 -374 -1199 -661 -1165 -1315 -886 -1779 -888 -622 -320 131 215 575 401 554 213 -14 237 174 -302 260 816 71 -264 -480 -660 -243 4 -1127 -1152 -518 -507 283 611 563 151 420 19 -38 -11 143 -111 106 -127 -459 151 217 217 387 -133 -36 867 305 -24 -7 -298 281 122 159 17 41 488 -10 -109 -376 -426 -273 -122 -55 -155 -216 -174 -184 -104 -114 -110 -230 -165 -147 -112 -21 -80 15 134 83 167 160 100 226 183 52 -10 -145 -87 -199 -18 60 71 231 -270 -506 -505 -586 -407 -246 -378 -339 -192 -202 -195 -70 1 -237 240 -407 -146 168 165 326 413 417 585 423 158 302 186 625 799 915 1205 361 146 37 -267 526 55 127 354 137 511 53 -111 -274 -821 -455 -901 -1056 -791 -1737 -902 -667 -369 147 251 678 463 655 231 -14 219 166 -320 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