File name: Pandora52s1_RichmondCA_20241218_L2Fit_fout2c2d20220121p1-8.txt File generation date: 20241221T003536.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 52 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora52_OF_v2d20211014.txt Instrument calibration file used: Pandora52s1_CF_v2d20220121.txt Level 1 file used: Pandora52s1_RichmondCA_20241218_L1_smca1c2d20220121p1-8.txt Full location name: University Of California Berkeley Short location name: RichmondCA Country of location: USA Location latitude [deg]: 37.9130 Location longitude [deg]: -122.3360 Location altitude [m]: 5 Local noon date: 20241218 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 1 for new VP First and last pixel inside fitting window: 260 401 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2640 305.4050 305.5460 305.6869 305.8279 305.9688 306.1097 306.2507 306.3916 306.5325 306.6733 306.8142 306.9551 307.0959 307.2367 307.3775 307.5183 307.6591 307.7999 307.9407 308.0814 308.2222 308.3629 308.5036 308.6444 308.7850 308.9257 309.0664 309.2071 309.3477 309.4883 309.6290 309.7696 309.9102 310.0508 310.1913 310.3319 310.4724 310.6130 310.7535 310.8940 311.0345 311.1750 311.3155 311.4559 311.5964 311.7368 311.8773 312.0177 312.1581 312.2985 312.4388 312.5792 312.7196 312.8599 313.0002 313.1405 313.2809 313.4211 313.5614 313.7017 313.8419 313.9822 314.1224 314.2626 314.4028 314.5430 314.6832 314.8234 314.9636 315.1037 315.2438 315.3840 315.5241 315.6642 315.8042 315.9443 316.0844 316.2244 316.3645 316.5045 316.6445 316.7845 316.9245 317.0645 317.2044 317.3444 317.4843 317.6242 317.7641 317.9040 318.0439 318.1838 318.3237 318.4635 318.6034 318.7432 318.8830 319.0228 319.1626 319.3024 319.4422 319.5819 319.7216 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9788 321.1184 321.2580 321.3976 321.5372 321.6768 321.8163 321.9559 322.0954 322.2349 322.3744 322.5139 322.6534 322.7929 322.9323 323.0718 323.2112 323.3506 323.4901 323.6295 323.7688 323.9082 324.0476 324.1869 324.3263 324.4656 324.6049 324.7442 324.8835 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241218T160333.5Z 9118.669138 294 1 49.41 2 83.66 126.38 65.10 278.54 0.00 1 0.00 1 0 33 6.122e-01 4.229e-02 4.673e-01 2.746e-02 8.374457e-01 1.638514e-02 9.387298e-03 -6.000000e+00 3.548928e-01 223.44 -2.00 3.45 -2.00 322.18 0.00e+00 1.045245e-02 8.496007e-03 1.163967e-03 -6.000000e+00 1.717384e-02 279.49 -2.00 20.00 -2.00 321.72 0.00e+00 8.176 0.009 302.00 328.00 3 1.5483e+00 6.0810e-02 9.2566e-02 -6.0000e+00 8.7302e-01 1.2193e+00 7.7393e-02 4.4974e-02 -6.0000e+00 9.5459e-01 -1.4886e+00 6.2965e-02 2.3846e-02 -6.0000e+00 5.6977e-01 5.9037e-01 3.0775e-02 8.5961e-03 -6.0000e+00 2.4943e-01 1.2821e-05 -3.9750e-03 7.8512e-04 1.2195e-04 -6.0000e+00 1.6442e-02 1.6789e-02 0.0000e+00 12 8 8 10 0 0 99.92 20.83 1.09 0.01679 -0.01308 35 7 1 5 0 1411.540 26.51 20.00 20.83 12.09 34.3 983.65 900000 48092 -47019 -60936 900000 90254 -8178 78126 -13420 71379 -16335 900000 900000 -32829 900000 -26763 900000 -45771 98610 51838 121355 112547 -96339 900000 -98819 900000 -65846 900000 265375 900000 62840 56983 900000 -13615 900000 -20494 245971 -58044 900000 49670 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4060 2253 -1401 3928 -306 -1801 -3365 4835 -4509 2842 3437 -7174 5622 -4466 3276 -5423 1908 -3007 778 481 -1677 2344 -4907 3862 -13846 909 -6785 854 -4459 -4173 45 -213 4463 -5411 4742 -4790 5538 1075 -2616 298 -6141 4300 1635 7321 5023 3502 -127 727 4507 1228 2893 -7891 8075 -7518 -92 -288 4360 6113 637 -2610 -3608 1283 -6952 1924 SS 20241218T161428.4Z 9118.676718 297 1 37.40 2 81.95 128.22 67.18 279.98 0.00 1 0.00 1 0 17 4.761e-01 1.819e-02 3.762e-01 1.285e-02 7.596399e-01 7.214885e-03 8.375379e-03 -6.000000e+00 2.698942e-01 223.44 -2.00 3.45 -2.00 321.74 0.00e+00 -1.143525e-03 3.761284e-03 1.537193e-03 -6.000000e+00 1.294537e-02 279.49 -2.00 20.00 -2.00 321.26 0.00e+00 6.684 0.005 302.00 328.00 3 2.3211e+00 2.6052e-02 7.7984e-02 -6.0000e+00 6.6557e-01 4.9758e-01 3.7206e-02 4.2985e-02 -6.0000e+00 7.2505e-01 -5.4360e-01 3.8017e-02 2.3008e-02 -6.0000e+00 4.2933e-01 2.0270e-01 1.7765e-02 7.3343e-03 -6.0000e+00 1.8841e-01 3.0305e-05 -1.8138e-03 3.6086e-04 8.5731e-05 -6.0000e+00 1.2847e-02 1.5548e-02 0.0000e+00 12 9 9 12 1 1 99.83 20.83 0.72 0.01555 0.00192 23 7 1 5 0 1558.210 26.51 19.99 20.83 13.08 34.3 990.84 -102927 -134241 900000 900000 -181032 900000 -76606 900000 -158632 900000 -51794 30610 -158301 -108883 68350 -109205 -15682 -75743 180893 -93919 20643 -57094 900000 -2131 -10306 -90479 -110002 125159 -52726 114542 -36834 5016 122297 -3880 51204 -6240 69219 -22298 32570 -13987 52719 44105 -6892 25874 -20903 16819 900000 33174 21830 8575 -3637 20409 14552 12892 10522 14545 19963 7638 26646 8259 5367 13972 8144 20431 3459 9592 -988 11175 1875 3877 11594 9882 8257 233 4274 -4464 5914 -10593 -3497 -2889 1220 -459 -4527 -2060 -1254 5208 -394 -2662 32 3280 -2323 -857 -2166 -2062 -1681 -3463 2188 -3022 -663 918 -3426 420 -513 -1392 -3983 -1355 -173 -155 544 -1142 1113 1283 782 -2577 1421 -782 -1210 -222 648 1014 922 2484 -259 1289 104 671 -309 683 573 -88 -225 -248 753 -274 654 -207 404 195 -601 257 -1021 -615 -1288 -1680 900000 900000 -2596 900000 -958 900000 -2662 900000 -648 383 -4492 -2452 855 -3399 -216 -2061 2263 -3290 258 -1357 900000 -36 -205 -4019 -5746 1566 -1505 1433 -1253 134 1530 -127 927 -200 1231 -1187 1233 -983 2135 1995 -531 1428 -1844 1058 900000 1900 1488 715 -388 1912 1582 1538 1354 1876 2530 1059 2904 1063 753 2038 1451 3572 727 1844 -214 2318 481 1137 3359 2938 2376 66 1040 -1071 1254 -2877 -1051 -1035 489 -212 -2340 -1100 -708 2915 -243 -1687 19 1797 -1254 -434 -1119 -1176 -1117 -2746 1904 -3057 -688 901 -3247 339 -397 -1152 -3640 -1266 -170 -166 658 -1558 1634 1951 1184 -3856 1943 -1102 -1730 -332 1014 1589 1426 3593 -373 1775 140 860 -401 983 961 -163 -455 -529 1695 -668 1646 -542 1066 518 -1611 642 -2390 -1349 SS 20241218T162501.1Z 9118.684041 300 1 9.27 2 80.34 130.05 69.19 281.36 0.00 1 0.00 1 0 17 4.463e-01 1.287e-02 3.346e-01 9.177e-03 6.564186e-01 4.897805e-03 7.590929e-03 -6.000000e+00 2.499202e-01 223.44 -2.00 3.45 -2.00 321.18 0.00e+00 6.566396e-03 2.319348e-03 2.030500e-03 -6.000000e+00 1.145992e-02 279.49 -2.00 20.00 -2.00 320.67 0.00e+00 5.685 0.003 302.00 328.00 3 2.3389e+00 1.6458e-02 6.6122e-02 -6.0000e+00 6.1542e-01 1.7124e-01 2.2859e-02 3.5233e-02 -6.0000e+00 6.7025e-01 -1.9262e-01 2.3934e-02 2.1647e-02 -6.0000e+00 3.9834e-01 7.3049e-02 1.1445e-02 9.8514e-03 -6.0000e+00 1.7458e-01 8.9838e-05 -1.0600e-03 2.5048e-04 1.1720e-04 -6.0000e+00 1.1717e-02 1.1599e-02 0.0000e+00 12 9 9 12 1 1 85.09 20.83 0.48 0.01160 0.00363 10 12 1 5 0 841.820 26.51 19.99 20.83 13.25 34.3 991.04 -249756 900000 -180872 900000 -174993 900000 -212880 -179225 24169 -41144 -63744 -29824 -63061 -88256 49188 11405 92007 24678 -16658 35693 -29988 51951 14176 34478 -52547 50566 4598 -28469 31875 -43805 62373 -29379 68744 11178 36553 3685 10881 7732 1738 16291 8298 9232 5578 -5203 7390 4953 30375 -449 10791 -1170 3162 -5480 11848 9171 5029 6641 -1204 2484 2770 10762 -3190 10343 741 7284 3037 2178 2776 1381 5415 -883 2840 2801 2443 1556 -2229 -175 -3816 -181 -6110 -1551 -1377 -2269 -2294 -557 638 526 2485 -779 2343 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