File name: Pandora52s1_RichmondCA_20241228_L2Fit_fout2c2d20220121p1-8.txt File generation date: 20241229T081418.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 52 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora52_OF_v2d20211014.txt Instrument calibration file used: Pandora52s1_CF_v2d20220121.txt Level 1 file used: Pandora52s1_RichmondCA_20241228_L1_smca1c2d20220121p1-8.txt Full location name: University Of California Berkeley Short location name: RichmondCA Country of location: USA Location latitude [deg]: 37.9130 Location longitude [deg]: -122.3360 Location altitude [m]: 5 Local noon date: 20241228 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 1 for new VP First and last pixel inside fitting window: 260 401 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2640 305.4050 305.5460 305.6869 305.8279 305.9688 306.1097 306.2507 306.3916 306.5325 306.6733 306.8142 306.9551 307.0959 307.2367 307.3775 307.5183 307.6591 307.7999 307.9407 308.0814 308.2222 308.3629 308.5036 308.6444 308.7850 308.9257 309.0664 309.2071 309.3477 309.4883 309.6290 309.7696 309.9102 310.0508 310.1913 310.3319 310.4724 310.6130 310.7535 310.8940 311.0345 311.1750 311.3155 311.4559 311.5964 311.7368 311.8773 312.0177 312.1581 312.2985 312.4388 312.5792 312.7196 312.8599 313.0002 313.1405 313.2809 313.4211 313.5614 313.7017 313.8419 313.9822 314.1224 314.2626 314.4028 314.5430 314.6832 314.8234 314.9636 315.1037 315.2438 315.3840 315.5241 315.6642 315.8042 315.9443 316.0844 316.2244 316.3645 316.5045 316.6445 316.7845 316.9245 317.0645 317.2044 317.3444 317.4843 317.6242 317.7641 317.9040 318.0439 318.1838 318.3237 318.4635 318.6034 318.7432 318.8830 319.0228 319.1626 319.3024 319.4422 319.5819 319.7216 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9788 321.1184 321.2580 321.3976 321.5372 321.6768 321.8163 321.9559 322.0954 322.2349 322.3744 322.5139 322.6534 322.7929 322.9323 323.0718 323.2112 323.3506 323.4901 323.6295 323.7688 323.9082 324.0476 324.1869 324.3263 324.4656 324.6049 324.7442 324.8835 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241228T185656.2Z 9128.789539 202 1 21.58 2 63.58 160.91 66.31 189.60 0.00 1 0.00 1 0 17 2.795e-02 1.351e-02 1.863e-02 4.164e-03 2.813061e-01 2.054093e-03 3.401142e-03 -6.000000e+00 1.552547e-02 223.67 -2.00 3.45 -2.00 317.94 0.00e+00 3.295801e-03 3.497188e-04 1.995324e-04 -6.000000e+00 6.841343e-04 278.92 -2.00 20.00 -2.00 317.29 0.00e+00 2.235 0.000 302.00 328.00 3 5.5240e+00 5.4522e-03 2.6365e-02 -6.0000e+00 3.8297e-02 4.9567e-02 6.1692e-03 1.4378e-02 -6.0000e+00 4.1701e-02 5.2672e-03 3.9879e-03 7.3176e-03 -6.0000e+00 2.4846e-02 -9.3174e-03 2.0851e-03 3.1622e-03 -6.0000e+00 1.0793e-02 1.5780e-04 -2.0294e-03 1.1622e-04 2.7879e-05 -6.0000e+00 7.1952e-04 2.1865e-02 0.0000e+00 12 9 9 12 9 1 99.99 21.24 0.35 0.02186 0.00662 7 4 1 5 0 2697.000 26.94 20.00 21.24 17.98 35.0 1026.88 12166 1871 4463 2486 8512 7733 84 5127 -700 -2937 -3290 -1745 230 5322 3311 -13 -820 2220 5313 2486 2168 3459 -123 73 -2427 387 -3235 2905 6 2142 1036 4287 494 -1361 -396 -752 -1429 -1576 -2429 -870 953 -1618 98 796 643 998 -20540 -1275 -68 718 798 1777 1354 1970 2977 -91 256 803 -266 1024 1990 1964 3182 3461 1220 1512 -1443 296 -177 1046 456 -131 592 545 -794 -510 -1454 -3180 -1430 -1667 -643 -1820 -998 545 -477 820 501 723 421 1155 178 -957 -552 -1359 -598 -496 1619 426 441 -99 -303 -511 -516 -2020 -1340 -451 -397 485 884 1559 225 306 488 -561 -33 -968 -593 -359 -57 -526 528 189 379 851 -213 -602 289 265 472 -222 -678 -63 349 -478 119 -69 675 132 -15 -266 -195 -7 856 156 359 183 530 481 6 405 -63 -272 -302 -173 26 684 497 -2 -145 398 962 480 418 651 -25 15 -552 87 -730 597 1 443 239 1024 132 -359 -99 -194 -409 -542 -974 -386 442 -800 49 396 323 499 -12122 -628 -33 355 424 1002 809 1217 1854 -58 168 515 -169 652 1332 1401 2442 2764 951 1069 -1020 210 -138 881 411 -121 527 472 -633 -372 -988 -2204 -1085 -1405 -582 -1814 -1034 571 -543 957 613 894 513 1349 192 -971 -537 -1328 -638 -575 1993 566 599 -129 -370 -589 -589 -2459 -1744 -608 -546 691 1307 2447 362 485 747 -815 -45 -1296 -815 -511 -85 -819 813 290 563 1231 -297 -817 376 364 685 -338 -1074 -97 557 -813 209 -122 1215 243 -27 -480 -336 -12 SS 20241228T190152.2Z 9128.792965 205 1 49.93 2 63.27 162.13 66.49 190.75 0.00 1 0.00 1 0 17 1.838e-02 7.105e-03 1.216e-02 2.336e-03 2.791357e-01 1.151059e-03 3.366433e-03 -6.000000e+00 1.020928e-02 223.67 -2.00 3.45 -2.00 318.46 0.00e+00 2.157859e-04 2.238126e-04 1.832677e-04 -6.000000e+00 4.498371e-04 278.92 -2.00 20.00 -2.00 317.80 0.00e+00 2.211 0.000 302.00 328.00 3 4.6541e+00 3.0910e-03 2.6116e-02 -6.0000e+00 2.5183e-02 7.0574e-03 3.5234e-03 1.4146e-02 -6.0000e+00 2.7421e-02 2.1071e-02 2.3633e-03 7.0576e-03 -6.0000e+00 1.6338e-02 -1.2823e-02 1.2415e-03 2.0492e-03 -6.0000e+00 7.0977e-03 3.9740e-04 -1.6339e-03 6.6688e-05 2.2113e-05 -6.0000e+00 4.7311e-04 2.1417e-02 0.0000e+00 11 8 0 10 0 0 99.95 21.25 0.19 0.02142 0.00914 128 26 1 5 0 390.060 26.94 20.00 21.25 18.22 35.0 1028.71 -2707 -2344 -3132 -4972 -5363 -3020 -3091 -362 -5763 -465 -990 -3406 153 1701 -2341 -2182 -177 -584 113 2992 -731 1364 1170 48 -704 -1245 -1138 -778 -792 -1004 1411 1602 -1107 -2775 -3416 -5142 -3386 -1266 -1503 -126 -179 842 -240 150 -365 -1942 12931 -1176 -545 -683 165 -482 1236 168 1098 382 179 541 51 1302 1076 1111 1970 430 -298 -182 -255 272 454 -113 525 215 738 75 -439 -633 -2263 -1073 -1730 -1336 -961 -1460 -1376 -759 -188 -34 456 674 678 796 178 -393 -235 -206 -442 244 938 279 -110 -441 -593 -816 -253 -1320 -1050 -458 -458 474 705 688 275 741 79 55 -324 -22 -500 192 -120 -330 21 236 389 85 -48 -100 817 132 42 18 -233 229 82 186 -89 104 525 156 31 -407 -467 -414 -175 -160 -212 -308 -302 -167 -192 -25 -460 -36 -75 -288 14 185 -301 -301 -25 -86 17 459 -116 212 191 9 -133 -241 -212 -140 -136 -177 267 332 -253 -626 -722 -1140 -845 -374 -512 -48 -72 350 -103 64 -163 -879 4927 -506 -231 -300 77 -245 652 94 620 223 106 312 29 737 646 730 1395 322 -214 -119 -157 171 322 -91 446 186 620 60 -320 -412 -1383 -649 -1172 -1028 -823 -1367 -1351 -783 -208 -38 535 798 787 907 187 -375 -209 -189 -446 274 1161 364 -147 -587 -723 -916 -280 -1600 -1366 -619 -648 666 1057 1102 460 1212 123 81 -445 -30 -688 279 -189 -519 35 374 596 124 -67 -132 1037 178 61 28 -379 376 139 319 -163 196 1008 306 60 -764 -877 -748 SS 20241228T190646.5Z 9128.796371 208 1 33.94 2 62.99 163.35 66.68 191.88 0.00 1 0.00 1 0 17 1.690e-02 6.595e-03 8.938e-03 2.020e-03 2.766118e-01 9.967279e-04 3.343024e-03 -6.000000e+00 9.387474e-03 223.67 -2.00 3.45 -2.00 318.05 0.00e+00 3.540331e-04 1.744899e-04 1.772287e-04 -6.000000e+00 4.135927e-04 278.92 -2.00 20.00 -2.00 317.40 0.00e+00 2.190 0.000 302.00 328.00 3 4.6019e+00 2.6502e-03 2.5855e-02 -6.0000e+00 2.3156e-02 6.6452e-03 3.0024e-03 1.3972e-02 -6.0000e+00 2.5213e-02 1.7582e-02 1.9467e-03 6.9731e-03 -6.0000e+00 1.5023e-02 -1.0187e-02 1.0173e-03 2.0176e-03 -6.0000e+00 6.5266e-03 4.2938e-04 -1.6225e-03 5.6843e-05 2.1414e-05 -6.0000e+00 4.3499e-04 2.0992e-02 0.0000e+00 12 9 1 12 1 1 99.98 21.25 0.24 0.02099 0.00880 40 12 1 5 0 827.560 26.94 20.00 21.25 18.48 35.0 1030.33 -5149 -1637 -5068 -2673 -3865 -6840 -2706 -6260 -180 -4412 2846 -2761 -774 1106 1062 -1016 -879 -946 -1369 1155 365 2613 -450 1508 657 -100 1409 -2135 625 -1221 1109 383 -864 -2721 -2810 -2687 -2724 -1103 -2293 183 -571 513 -332 -660 -31 -243 8478 -1329 -159 -621 702 414 501 290 891 787 165 844 -609 1249 926 1073 1673 743 114 -144 -981 -74 199 201 557 372 520 328 -644 -443 -2318 -576 -1720 -1005 -965 -1366 -897 -979 -174 -349 474 480 533 582 59 -85 -392 -59 -677 405 540 501 -29 -440 -603 -402 -201 -1380 -1152 -407 -428 331 875 782 396 716 -21 -125 -331 39 -287 109 -77 -382 340 47 324 246 -151 -157 874 190 -35 -35 -224 224 -16 334 -208 262 612 139 -188 -520 -384 -413 -394 -128 -419 -193 -255 -469 -199 -546 -16 -417 247 -274 -88 143 156 -163 -146 -165 -249 213 68 472 -88 309 143 -22 300 -438 123 -251 244 90 -221 -687 -684 -674 -755 -364 -918 81 -261 241 -160 -320 -15 -121 3769 -638 -75 -304 366 224 286 173 541 491 105 521 -374 760 598 757 1276 595 87 -101 -654 -50 152 173 490 333 454 280 -505 -320 -1572 -384 -1291 -825 -885 -1324 -908 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