File name: Pandora52s1_RichmondCA_20250616_L2Fit_fout2c2d20220121p1-8.txt File generation date: 20250617T082654.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 52 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora52_OF_v2d20211014.txt Instrument calibration file used: Pandora52s1_CF_v2d20220121.txt Level 1 file used: Pandora52s1_RichmondCA_20250616_L1_smca1c2d20220121p1-8.txt Full location name: University Of California Berkeley Short location name: RichmondCA Country of location: USA Location latitude [deg]: 37.9130 Location longitude [deg]: -122.3360 Location altitude [m]: 5 Local noon date: 20250616 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 1 for new VP First and last pixel inside fitting window: 260 401 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2640 305.4050 305.5460 305.6869 305.8279 305.9688 306.1097 306.2507 306.3916 306.5325 306.6733 306.8142 306.9551 307.0959 307.2367 307.3775 307.5183 307.6591 307.7999 307.9407 308.0814 308.2222 308.3629 308.5036 308.6444 308.7850 308.9257 309.0664 309.2071 309.3477 309.4883 309.6290 309.7696 309.9102 310.0508 310.1913 310.3319 310.4724 310.6130 310.7535 310.8940 311.0345 311.1750 311.3155 311.4559 311.5964 311.7368 311.8773 312.0177 312.1581 312.2985 312.4388 312.5792 312.7196 312.8599 313.0002 313.1405 313.2809 313.4211 313.5614 313.7017 313.8419 313.9822 314.1224 314.2626 314.4028 314.5430 314.6832 314.8234 314.9636 315.1037 315.2438 315.3840 315.5241 315.6642 315.8042 315.9443 316.0844 316.2244 316.3645 316.5045 316.6445 316.7845 316.9245 317.0645 317.2044 317.3444 317.4843 317.6242 317.7641 317.9040 318.0439 318.1838 318.3237 318.4635 318.6034 318.7432 318.8830 319.0228 319.1626 319.3024 319.4422 319.5819 319.7216 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9788 321.1184 321.2580 321.3976 321.5372 321.6768 321.8163 321.9559 322.0954 322.2349 322.3744 322.5139 322.6534 322.7929 322.9323 323.0718 323.2112 323.3506 323.4901 323.6295 323.7688 323.9082 324.0476 324.1869 324.3263 324.4656 324.6049 324.7442 324.8835 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250616T170721.1Z 9298.713439 335 1 50.04 2 41.46 97.02 82.31 245.31 0.00 1 0.00 1 0 17 1.097e-02 6.338e-03 7.266e-03 2.853e-03 2.063264e-01 1.455133e-03 2.445083e-03 -6.000000e+00 6.311725e-03 232.85 -2.00 3.45 -2.00 316.97 0.00e+00 6.304967e-04 1.902196e-04 9.562201e-05 -6.000000e+00 2.796679e-04 288.54 -2.00 20.00 -2.00 316.14 0.00e+00 1.333 0.000 302.00 328.00 3 6.0202e+00 3.8582e-03 1.7232e-02 -6.0000e+00 1.5858e-02 5.8737e-02 4.3117e-03 1.0692e-02 -6.0000e+00 1.7119e-02 -8.2768e-05 2.5353e-03 5.1844e-03 -6.0000e+00 1.0183e-02 -4.5903e-03 1.2255e-03 1.4583e-03 -6.0000e+00 4.3764e-03 2.6145e-04 -5.0150e-04 7.9820e-05 1.5549e-05 -6.0000e+00 2.8306e-04 1.8220e-02 0.0000e+00 10 0 0 10 0 0 99.98 21.04 0.28 0.01822 0.01445 46 9 1 5 0 1087.620 26.73 20.00 21.04 17.75 35.8 1004.27 -3522 188 -2469 -940 -4542 1772 -1287 1074 1242 -4087 -603 -46 2260 198 277 1635 1627 1894 1760 1980 -92 1829 442 286 137 -1279 112 -1121 128 -974 -311 -44 510 -2890 -2156 -1157 -1492 -381 -1344 -417 -1040 866 -564 -421 -307 -778 4 -1698 258 -521 981 133 726 249 986 1126 783 207 150 1084 1518 1285 1581 384 13 -565 -567 66 562 -92 661 95 756 -301 110 -1599 -1226 -921 -2042 -921 -1100 -1788 -935 -553 176 130 478 759 173 277 451 -253 241 -228 -417 335 836 581 302 -414 -898 -572 -501 -1436 -968 -592 -329 57 856 647 563 515 154 -2 -489 -463 -519 4 -254 -352 401 340 646 389 -91 -108 1130 -293 -25 -310 -412 191 324 163 -164 185 486 233 10 -365 -578 -355 -567 30 -397 -132 -611 224 -185 171 213 -734 -101 -8 444 45 70 429 435 522 501 580 -27 527 134 92 46 -439 36 -349 37 -287 -98 -15 181 -1012 -694 -380 -562 -170 -696 -238 -631 531 -355 -264 -192 -497 3 -1020 149 -309 612 88 504 179 716 832 583 152 108 785 1157 1065 1401 353 12 -441 -413 48 463 -85 644 95 731 -278 92 -1251 -872 -646 -1594 -803 -1028 -1812 -981 -611 208 158 606 970 218 338 500 -262 230 -223 -428 378 1036 783 414 -541 -1079 -634 -577 -1747 -1260 -800 -462 83 1262 1011 903 804 233 -2 -623 -590 -660 6 -371 -540 612 505 923 529 -122 -137 1364 -374 -34 -435 -593 275 478 254 -273 316 847 414 17 -623 -953 -564 SS 20250616T171140.2Z 9298.716437 338 1 7.18 2 40.62 97.81 83.05 246.01 0.00 1 0.00 1 0 25 2.209e-02 1.393e-02 1.071e-02 6.060e-03 2.137633e-01 3.125010e-03 2.548059e-03 -6.000000e+00 1.271420e-02 232.85 -2.00 3.45 -2.00 315.72 0.00e+00 -2.094649e-05 3.100713e-04 6.483630e-05 -6.000000e+00 5.629553e-04 288.54 -2.00 20.00 -2.00 314.97 0.00e+00 1.316 0.000 302.00 328.00 3 5.9836e+00 8.1467e-03 1.7352e-02 -6.0000e+00 3.1945e-02 7.5108e-02 9.0318e-03 1.1032e-02 -6.0000e+00 3.4479e-02 -1.9416e-02 5.1879e-03 5.3521e-03 -6.0000e+00 2.0509e-02 5.5596e-03 2.3935e-03 1.4686e-03 -6.0000e+00 8.8204e-03 2.7196e-04 4.8563e-06 1.6480e-04 1.7244e-05 -6.0000e+00 5.6983e-04 1.4014e-02 0.0000e+00 12 9 9 12 1 1 999.00 21.05 0.37 0.01401 0.01405 1 3 1 5 0 3589.320 26.73 20.00 21.05 18.08 35.7 1006.28 -355 -431 -1405 -3617 -4403 606 2927 474 -32 2856 -363 -201 -4378 607 -891 2075 -782 949 284 250 -264 120 1642 -2189 1224 887 100 -556 499 573 -2168 1720 -2343 -2742 -1563 -3269 -979 -760 -26 -1342 -56 -488 -956 149 -334 233 21660 -2071 -1639 50 -1839 8 -554 1054 2642 1023 317 1142 63 -632 1009 -205 1438 -322 -752 -315 -1050 71 -203 753 701 512 -181 -557 -932 -678 -1906 -2410 -1017 -1645 -570 -1139 -662 -288 -1100 599 -241 620 -835 -556 79 -144 241 -815 420 1096 1514 213 307 -112 -386 -292 -613 114 -557 -215 56 244 587 558 209 706 65 172 46 -1058 -38 676 -523 -7 413 482 543 434 -5 -34 -273 -708 104 765 -692 -80 857 -462 -178 -53 763 -453 293 -232 -718 -217 -89 -113 -358 -833 -941 123 644 118 -9 747 -97 -56 -1392 208 -336 796 -314 386 117 106 -112 51 700 -1028 582 418 46 -243 208 240 -974 800 -1173 -1316 -703 -1541 -502 -447 -17 -963 -42 -369 -735 112 -252 176 13567 -1520 -1169 36 -1407 6 -455 864 2166 870 273 954 52 -533 883 -189 1373 -321 -719 -280 -897 61 -189 747 725 538 -188 -558 -883 -591 -1570 -1974 -886 -1565 -571 -1215 -720 -324 -1296 728 -302 781 -1045 -673 89 -155 245 -850 454 1253 1841 275 401 -142 -464 -337 -710 137 -711 -280 74 332 828 806 305 1018 91 226 58 -1321 -48 880 -720 -10 580 670 740 571 -6 -42 -335 -896 135 1028 -953 -111 1201 -669 -269 -81 1167 -712 451 -353 -1073 -316 SS 20250616T172812.4Z 9298.727921 350 1 2.92 2 37.40 101.01 85.92 248.66 0.00 1 0.00 1 0 17 8.968e-03 6.383e-03 5.598e-03 3.555e-03 1.952388e-01 1.837945e-03 2.308640e-03 -6.000000e+00 5.161382e-03 232.85 -2.00 3.45 -2.00 315.29 0.00e+00 5.526852e-04 1.668911e-04 4.373638e-05 -6.000000e+00 2.285707e-04 288.55 -2.00 20.00 -2.00 314.58 0.00e+00 1.258 0.000 302.00 328.00 3 4.6306e+00 4.7730e-03 1.6227e-02 -6.0000e+00 1.2968e-02 4.9247e-02 5.2799e-03 1.0026e-02 -6.0000e+00 1.3997e-02 -4.1430e-03 3.0250e-03 4.8463e-03 -6.0000e+00 8.3260e-03 -1.3219e-03 1.3708e-03 1.3507e-03 -6.0000e+00 3.5802e-03 1.1607e-03 -3.7873e-04 9.6095e-05 1.5938e-05 -6.0000e+00 2.3136e-04 1.5029e-02 0.0000e+00 12 1 1 12 1 1 99.83 21.06 0.26 0.01503 0.01218 3 14 1 5 0 730.190 26.73 20.00 21.06 18.80 35.8 1011.11 -2899 887 -724 -1774 -1590 947 773 -778 342 -1596 -324 -858 -515 2123 1178 -426 2290 587 2410 247 1062 1213 55 183 393 412 137 229 -865 632 205 1667 -937 -1757 -1948 -2515 -1967 -1050 -1309 -425 -644 -112 -788 -506 -368 -588 -351 -777 -1009 1213 -235 203 889 553 761 1121 274 262 951 367 1603 1882 1419 408 -420 -179 -1049 1119 159 191 467 984 742 -2 211 -94 -1398 -1180 -951 -1732 -758 -1500 -1103 -810 -220 47 62 280 393 -25 383 -234 -335 176 -77 538 680 370 -116 -516 -565 5 -103 -835 -805 -553 -389 -114 438 837 -212 561 173 142 240 262 -612 183 454 11 447 146 375 312 -170 -294 336 342 -129 94 -754 81 236 163 -196 14 489 -172 -217 -150 -264 -174 -888 272 -219 -494 -409 236 206 -232 108 -512 -102 -279 -183 832 501 -187 995 267 1109 116 508 572 26 92 207 213 70 110 -406 293 99 852 -505 -912 -964 -1286 -1108 -666 -914 -320 -501 -89 -625 -399 -295 -465 -274 -586 -761 913 -186 166 739 476 648 970 240 231 816 320 1427 1771 1377 410 -407 -162 -912 964 149 192 485 1034 764 -2 201 -83 -1197 -994 -856 -1657 -778 -1602 -1200 -910 -260 57 76 351 491 -30 433 -254 -343 182 -83 611 820 468 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