File name: Pandora52s1_RichmondCA_20250714_L2Fit_fout2c2d20220121p1-8.txt File generation date: 20250715T082922.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 52 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora52_OF_v2d20211014.txt Instrument calibration file used: Pandora52s1_CF_v2d20220121.txt Level 1 file used: Pandora52s1_RichmondCA_20250714_L1_smca1c2d20220121p1-8.txt Full location name: University Of California Berkeley Short location name: RichmondCA Country of location: USA Location latitude [deg]: 37.9130 Location longitude [deg]: -122.3360 Location altitude [m]: 5 Local noon date: 20250714 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 1 for new VP First and last pixel inside fitting window: 260 401 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2640 305.4050 305.5460 305.6869 305.8279 305.9688 306.1097 306.2507 306.3916 306.5325 306.6733 306.8142 306.9551 307.0959 307.2367 307.3775 307.5183 307.6591 307.7999 307.9407 308.0814 308.2222 308.3629 308.5036 308.6444 308.7850 308.9257 309.0664 309.2071 309.3477 309.4883 309.6290 309.7696 309.9102 310.0508 310.1913 310.3319 310.4724 310.6130 310.7535 310.8940 311.0345 311.1750 311.3155 311.4559 311.5964 311.7368 311.8773 312.0177 312.1581 312.2985 312.4388 312.5792 312.7196 312.8599 313.0002 313.1405 313.2809 313.4211 313.5614 313.7017 313.8419 313.9822 314.1224 314.2626 314.4028 314.5430 314.6832 314.8234 314.9636 315.1037 315.2438 315.3840 315.5241 315.6642 315.8042 315.9443 316.0844 316.2244 316.3645 316.5045 316.6445 316.7845 316.9245 317.0645 317.2044 317.3444 317.4843 317.6242 317.7641 317.9040 318.0439 318.1838 318.3237 318.4635 318.6034 318.7432 318.8830 319.0228 319.1626 319.3024 319.4422 319.5819 319.7216 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9788 321.1184 321.2580 321.3976 321.5372 321.6768 321.8163 321.9559 322.0954 322.2349 322.3744 322.5139 322.6534 322.7929 322.9323 323.0718 323.2112 323.3506 323.4901 323.6295 323.7688 323.9082 324.0476 324.1869 324.3263 324.4656 324.6049 324.7442 324.8835 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250714T152624.3Z 9326.643336 263 1 14.14 2 63.27 82.56 74.83 244.26 0.00 1 0.00 1 0 17 9.748e-03 5.248e-03 8.397e-03 2.115e-03 2.846252e-01 1.077469e-03 3.361287e-03 -6.000000e+00 5.599868e-03 232.65 -2.00 3.45 -2.00 317.71 0.00e+00 5.149131e-04 1.740151e-04 1.048686e-04 -6.000000e+00 2.513082e-04 291.07 -2.00 20.00 -2.00 316.82 0.00e+00 2.211 0.000 302.00 328.00 3 4.0598e+00 2.8937e-03 2.6733e-02 -6.0000e+00 1.4049e-02 1.6279e-02 3.2600e-03 1.4879e-02 -6.0000e+00 1.5167e-02 1.2500e-02 2.0174e-03 7.1846e-03 -6.0000e+00 9.0369e-03 -1.0524e-02 1.0280e-03 1.9630e-03 -6.0000e+00 3.8913e-03 7.0115e-04 -1.7716e-03 5.8444e-05 2.0209e-05 -6.0000e+00 2.5158e-04 2.4765e-02 0.0000e+00 12 1 1 12 1 1 99.89 21.28 0.42 0.02477 0.01145 22 17 1 5 0 614.410 26.94 20.00 21.28 19.34 36.0 1003.03 2344 -2872 -1131 2642 -2591 2036 809 4484 -3114 1039 -1503 -966 -1133 662 302 -355 -479 -984 1021 1076 896 -102 1019 -587 163 -1310 -50 173 601 157 26 1399 101 -1351 -1339 -2159 -457 -787 -734 -549 -773 -503 -1495 -685 -180 -630 395 -1412 -519 542 -141 698 514 517 1535 1164 645 292 160 799 1155 1140 1831 622 -40 -28 -386 608 -396 -8 -6 364 393 263 411 82 -1110 -513 -1005 -1452 -798 -1691 -872 -291 -550 2 -120 484 523 452 416 -171 140 294 -309 315 803 365 -141 -203 -800 -288 268 -915 -1237 -540 -509 207 589 521 62 427 165 -100 -194 -347 -6 242 -127 -433 236 318 102 434 -223 49 694 227 194 -11 -567 -46 243 266 145 89 642 95 14 -467 -544 -370 191 -262 -100 208 -195 148 66 407 -333 108 -158 -110 -150 97 51 -64 -90 -195 207 226 189 -22 224 -141 41 -340 -12 40 135 35 6 376 30 -388 -359 -604 -144 -293 -317 -267 -390 -263 -804 -366 -96 -335 209 -747 -270 289 -80 418 317 333 1003 784 440 196 106 531 811 852 1476 513 -32 -22 -278 446 -323 -7 -5 340 358 233 339 62 -808 -373 -795 -1280 -760 -1721 -901 -317 -630 3 -146 591 641 534 460 -177 139 292 -331 365 1007 480 -190 -266 -988 -334 308 -1122 -1601 -725 -698 295 874 809 99 662 246 -144 -264 -460 -8 343 -190 -663 359 480 152 615 -311 66 899 311 277 -16 -880 -72 383 434 246 157 1126 170 26 -819 -934 -611 SS 20250714T153032.7Z 9326.646212 266 1 49.78 2 62.46 83.15 75.54 244.98 0.00 1 0.00 1 0 17 8.729e-03 4.821e-03 3.109e-03 6.776e-04 2.776195e-01 3.436930e-04 3.278194e-03 -6.000000e+00 5.019302e-03 232.65 -2.00 3.45 -2.00 318.15 0.00e+00 4.829771e-04 6.204190e-05 1.499231e-04 -6.000000e+00 2.249241e-04 291.07 -2.00 20.00 -2.00 317.24 0.00e+00 2.151 0.000 302.00 328.00 3 2.6335e+00 9.3435e-04 2.6057e-02 -6.0000e+00 1.2593e-02 9.8037e-03 1.0600e-03 1.4555e-02 -6.0000e+00 1.3591e-02 8.0208e-03 6.7044e-04 7.0298e-03 -6.0000e+00 8.0979e-03 -7.7011e-03 3.4436e-04 1.9262e-03 -6.0000e+00 3.4909e-03 3.1431e-03 -7.6304e-04 1.9045e-05 2.0406e-05 -6.0000e+00 2.2521e-04 1.7322e-02 0.0000e+00 10 0 0 10 0 0 99.97 21.27 0.28 0.01732 0.01159 558 115 1 5 0 89.190 26.94 20.00 21.27 19.69 36.1 1006.60 -739 -257 -2327 -2851 -3439 -331 -1894 227 -754 -1390 -1740 -1387 -1042 196 263 -248 919 744 427 783 839 1214 706 271 -56 -597 -481 -795 -301 529 183 415 -878 -2545 -1881 -2319 -1766 -900 -1042 -778 -448 -437 -675 -20 -265 -643 1720 -1153 -615 265 220 432 719 530 757 733 315 473 312 993 1310 1256 1672 482 43 -32 -604 601 75 -9 394 231 704 130 -209 -462 -1265 -604 -971 -1315 -830 -1759 -937 -653 -330 79 272 594 468 557 107 -138 247 106 -345 166 802 155 -223 -341 -617 -267 -32 -1075 -1175 -538 -520 144 592 489 153 381 4 -92 -84 63 -118 162 -26 -358 140 223 220 354 -21 -39 815 295 -69 -54 -277 239 147 106 -6 50 521 80 -87 -295 -444 -319 -55 -20 -182 -201 -221 -21 -135 18 -66 -124 -154 -133 -115 25 38 -38 146 124 74 141 151 216 132 55 -12 -131 -101 -156 -56 100 38 95 -218 -621 -425 -544 -473 -289 -401 -337 -206 -208 -328 -10 -129 -311 794 -537 -282 125 112 235 412 317 463 460 200 295 192 611 852 894 1286 355 33 -23 -403 407 58 -8 328 196 581 112 -164 -325 -827 -393 -707 -1094 -767 -1621 -899 -661 -359 91 328 723 560 626 111 -143 237 105 -342 183 978 208 -306 -446 -738 -294 -35 -1284 -1514 -720 -728 210 915 808 241 642 6 -135 -114 82 -160 233 -40 -582 226 350 334 511 -29 -50 1023 392 -100 -84 -445 387 246 187 -10 89 947 148 -160 -523 -826 -572 SS 20250714T153446.6Z 9326.649150 269 1 37.75 2 61.63 83.75 76.26 245.72 0.00 1 0.00 1 0 17 8.118e-03 4.921e-03 2.524e-03 6.468e-04 2.700697e-01 3.294566e-04 3.185481e-03 -6.000000e+00 4.667863e-03 232.65 -2.00 3.45 -2.00 317.86 0.00e+00 6.640759e-04 5.475185e-05 1.261527e-04 -6.000000e+00 2.092145e-04 291.07 -2.00 20.00 -2.00 316.96 0.00e+00 2.094 0.000 302.00 328.00 3 2.6334e+00 8.8593e-04 2.5334e-02 -6.0000e+00 1.1712e-02 1.2472e-02 9.9941e-04 1.4101e-02 -6.0000e+00 1.2639e-02 5.0675e-03 6.1797e-04 6.8166e-03 -6.0000e+00 7.5311e-03 -6.0551e-03 3.1479e-04 1.8935e-03 -6.0000e+00 3.2461e-03 3.3598e-03 -8.9049e-04 1.8126e-05 1.9506e-05 -6.0000e+00 2.0947e-04 1.8260e-02 0.0000e+00 12 1 1 12 1 1 99.98 21.27 0.23 0.01826 0.01157 308 84 1 5 0 122.150 26.94 20.00 21.27 20.14 35.9 1009.08 -309 -869 -1430 -1180 -2369 -989 -962 -591 -1919 -1435 -2917 -1480 -921 514 359 -137 1277 300 1027 627 448 1166 829 737 -80 -53 -497 -224 -615 1000 -157 946 -414 -2176 -1628 -2481 -1023 -811 -896 -774 -459 -599 -604 -223 -136 -327 -602 -729 -440 224 158 539 912 772 1132 665 307 423 300 988 1141 1308 1729 548 -56 172 -491 731 -56 176 350 178 705 158 -60 -406 -1309 -804 -1070 -1403 -745 -1746 -921 -585 -407 122 139 520 300 486 170 -142 263 143 -122 266 936 177 -166 -450 -626 -192 83 -979 -1130 -523 -546 214 581 485 204 393 53 -99 -59 65 -130 94 -135 -389 176 278 273 514 -133 -78 755 280 15 -70 -271 239 213 176 8 -40 495 8 -110 -315 -486 -283 -27 -82 -133 -98 -180 -75 -81 -57 -203 -152 -309 -167 -120 77 61 -25 236 59 207 132 94 243 181 172 -20 -13 -121 -50 -133 218 -38 247 -117 -607 -420 -668 -311 -298 -394 -347 -218 -296 -304 -112 -68 -164 -294 -384 -229 119 83 300 535 473 706 427 199 270 188 622 761 951 1358 451 -44 123 -332 501 -44 154 326 169 649 138 -48 -289 -868 -584 -787 -1180 -694 -1785 -979 -601 -450 144 170 644 366 555 178 -148 254 142 -134 296 1151 239 -229 -594 -757 -214 92 -1182 -1470 -707 -773 313 835 746 325 614 78 -145 -80 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