File name: Pandora52s1_RichmondCA_20250819_L2Fit_fwvt1c2d20220121p1-8.txt File generation date: 20250820T082550.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 52 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora52_OF_v2d20211014.txt Instrument calibration file used: Pandora52s1_CF_v2d20220121.txt Level 1 file used: Pandora52s1_RichmondCA_20250819_L1_smca1c2d20220121p1-8.txt Full location name: University Of California Berkeley Short location name: RichmondCA Country of location: USA Location latitude [deg]: 37.9130 Location longitude [deg]: -122.3360 Location altitude [m]: 5 Local noon date: 20250819 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 1 for new VP First and last pixel inside fitting window: 1682 1831 Nominal wavelengths inside fitting window [nm]: 492.1029 492.2238 492.3447 492.4656 492.5865 492.7073 492.8282 492.9490 493.0698 493.1906 493.3114 493.4322 493.5529 493.6736 493.7944 493.9151 494.0357 494.1564 494.2771 494.3977 494.5183 494.6389 494.7595 494.8801 495.0007 495.1212 495.2417 495.3623 495.4828 495.6032 495.7237 495.8441 495.9646 496.0850 496.2054 496.3258 496.4462 496.5665 496.6868 496.8072 496.9275 497.0478 497.1680 497.2883 497.4085 497.5288 497.6490 497.7692 497.8894 498.0095 498.1297 498.2498 498.3699 498.4900 498.6101 498.7302 498.8502 498.9703 499.0903 499.2103 499.3303 499.4502 499.5702 499.6901 499.8101 499.9300 500.0499 500.1697 500.2896 500.4095 500.5293 500.6491 500.7689 500.8887 501.0084 501.1282 501.2479 501.3676 501.4874 501.6070 501.7267 501.8464 501.9660 502.0856 502.2052 502.3248 502.4444 502.5640 502.6835 502.8030 502.9225 503.0420 503.1615 503.2810 503.4004 503.5199 503.6393 503.7587 503.8781 503.9974 504.1168 504.2361 504.3555 504.4748 504.5941 504.7133 504.8326 504.9518 505.0711 505.1903 505.3095 505.4286 505.5478 505.6669 505.7861 505.9052 506.0243 506.1434 506.2624 506.3815 506.5005 506.6196 506.7386 506.8575 506.9765 507.0955 507.2144 507.3333 507.4522 507.5711 507.6900 507.8089 507.9277 508.0466 508.1654 508.2842 508.4029 508.5217 508.6405 508.7592 508.8779 508.9966 509.1153 509.2340 509.3526 509.4713 509.5899 509.7085 509.8271 509.9457 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250819T135855.7Z 9362.582589 184 1 50.03 2 85.03 77.94 40.75 90.35 0.00 1 0.00 1 0 22 2.097e-03 2.109e-03 2.466e-04 2.463e-04 7.189125e+03 1.741912e+01 4.625904e+02 -6.000000e+00 1.270530e+02 291.64 -2.00 20.00 -2.00 505.33 0.00e+00 2.015072e-03 7.100060e-06 1.182159e-04 -6.000000e+00 6.145498e-05 291.64 -2.00 20.00 -2.00 500.73 0.00e+00 7.758366e-01 4.914854e-03 5.249371e-02 -6.000000e+00 4.256799e-02 231.34 -2.00 3.45 -2.00 502.28 0.00e+00 9.834 0.016 489.00 513.00 1 4.3660e+00 3.7830e-04 1.5216e-02 -6.0000e+00 3.2859e-03 -2.1757e-03 9.4415e-05 1.4068e-03 -6.0000e+00 8.3492e-04 5.5515e-03 1.1985e-03 2.8089e-05 5.9938e-05 -6.0000e+00 2.5161e-04 1.2832e-02 -1.3629e-05 10 0 0 10 0 0 99.08 21.28 1.32 0.01283 0.02115 216 45 1 4 0 230.550 26.94 20.00 21.28 17.90 36.2 966.91 123 58 34 -48 20 351 254 327 241 120 162 28 -30 9 0 -36 -19 69 -32 -187 99 211 224 399 184 -24 51 151 -163 81 266 -34 67 6 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98 -119 -65 112 13 87 211 -46 -100 17 82 32 191 114 -83 -154 -159 -180 -168 53 -36 SQ 20250819T140945.1Z 9362.590106 187 1 9.65 2 82.94 79.56 38.68 92.02 0.00 1 0.00 1 0 15 2.295e-03 2.299e-03 8.318e-04 8.312e-04 4.577653e+03 5.623399e+01 2.936313e+02 -6.000000e+00 1.390275e+02 291.64 -2.00 20.00 -2.00 505.31 0.00e+00 1.535099e-03 2.399886e-05 9.143572e-05 -6.000000e+00 6.724294e-05 291.64 -2.00 20.00 -2.00 500.66 0.00e+00 5.894809e-01 1.666963e-02 3.653557e-02 -6.000000e+00 4.656710e-02 231.34 -2.00 3.45 -2.00 502.22 0.00e+00 7.460 0.007 489.00 513.00 1 5.5956e+00 1.2861e-03 1.1379e-02 -6.0000e+00 3.5947e-03 5.6432e-03 3.2277e-04 9.7698e-04 -6.0000e+00 9.1309e-04 2.3356e-03 6.5300e-04 9.6163e-05 4.4570e-05 -6.0000e+00 2.7529e-04 1.3809e-02 -1.3084e-06 12 1 1 12 1 1 99.53 21.28 1.10 0.01381 0.01834 10 12 1 4 0 877.100 26.94 19.99 21.28 17.96 36.2 967.51 40 -126 -10 -236 63 412 490 301 158 97 213 12 20 72 76 -138 -169 166 162 -133 234 158 288 365 122 -102 121 27 -292 -98 101 -122 97 6 -388 -444 -224 144 30 149 189 -22 53 116 106 131 -85 -93 -152 -269 -21 -196 -266 -115 -290 -347 -320 -275 82 269 323 359 151 329 -37 120 -77 25 -40 -120 -23 -170 -248 -90 -196 -476 -257 64 -279 2 -266 -350 -415 -62 -305 -190 -418 -16 68 7 -121 27 26 -193 -57 -37 -205 -37 27 -195 -223 -204 -110 -390 -710 -495 -254 75 469 242 66 27 390 462 374 322 431 251 144 250 333 375 514 323 196 78 138 -72 64 85 -97 -55 14 140 195 190 3 -202 -82 -11 157 183 -46 -79 -90 -311 -134 -135 101 -72 39 -120 -10 -232 64 421 493 304 160 100 215 12 20 70 74 -136 -171 166 164 -137 240 163 297 378 127 -106 125 28 -290 -98 100 -122 96 6 -405 -453 -233 148 31 151 192 -22 54 119 109 134 -86 -96 -153 -266 -21 -191 -260 -114 -287 -352 -321 -278 83 271 326 364 153 332 -37 122 -78 24 -39 -117 -22 -165 -244 -90 -195 -469 -250 63 -274 2 -262 -338 -404 -61 -302 -189 -418 -16 68 7 -120 27 26 -193 -56 -37 -199 -36 26 -186 -214 -194 -108 -383 -711 -494 -252 74 459 239 66 28 389 465 379 328 440 257 146 250 337 376 513 324 198 79 139 -73 65 85 -96 -54 14 135 190 188 3 -201 -83 -12 161 189 -46 -80 -91 -319 -134 -134 98 -71 SQ 20250819T141954.1Z 9362.597154 190 1 6.03 2 80.97 81.07 36.74 93.66 0.00 1 0.00 1 0 15 2.034e-03 2.036e-03 7.607e-05 7.598e-05 3.777940e+03 5.069410e+00 2.454776e+02 -6.000000e+00 1.232320e+02 291.64 -2.00 20.00 -2.00 505.30 0.00e+00 1.434805e-03 2.184726e-06 8.421295e-05 -6.000000e+00 5.960652e-05 291.64 -2.00 20.00 -2.00 500.63 0.00e+00 4.644458e-01 1.522931e-03 3.057719e-02 -6.000000e+00 4.129950e-02 231.34 -2.00 3.45 -2.00 502.19 0.00e+00 6.030 0.004 489.00 513.00 1 5.4477e-01 1.1732e-04 9.2486e-03 -6.0000e+00 3.1877e-03 1.0757e-03 2.9564e-05 8.0226e-04 -6.0000e+00 8.1035e-04 4.5277e-01 1.5990e-03 8.8299e-06 4.0955e-05 -6.0000e+00 2.4406e-04 1.8812e-02 -7.4640e-05 10 0 0 10 0 0 12.41 21.27 1.16 0.01881 0.02990 1432 295 1 4 0 4.100 26.94 20.00 21.27 18.44 36.2 970.98 108 4 58 -89 11 300 259 272 229 121 169 52 -3 33 13 -48 3 152 -29 -139 139 210 211 362 171 -69 17 73 -182 35 240 -5 32 24 -399 -457 -77 59 20 73 98 21 27 48 16 -28 -134 -132 -147 -267 -136 -107 -226 -116 -152 -335 -332 -169 64 214 338 224 107 158 63 39 3 88 -2 -99 -37 -184 -251 -144 -278 -422 -280 13 11 -152 -153 -283 -349 -169 -221 -287 -161 -42 75 29 -26 65 -46 -247 -204 -76 -106 -3 49 -47 -105 -284 -261 -392 -717 -502 -161 56 250 276 82 87 181 256 308 386 420 268 195 349 358 322 454 350 28 146 124 -71 86 128 -137 -36 148 88 152 239 -52 -172 22 91 57 151 99 -87 -191 -205 -198 -144 35 -3 103 4 55 -88 12 310 261 275 230 125 172 53 -3 33 13 -48 3 152 -29 -142 142 215 217 373 177 -72 17 74 -180 35 238 -5 31 25 -414 -476 -79 60 20 73 99 22 28 51 17 -29 -140 -136 -148 -263 -136 -105 -222 -115 -149 -337 -339 -174 66 220 348 231 111 163 64 39 3 86 -2 -95 -36 -178 -245 -142 -274 -413 -270 12 11 -150 -146 -271 -338 -164 -217 -284 -159 -42 74 29 -26 66 -45 -244 -206 -75 -102 -2 47 -45 -101 -270 -255 -393 -706 -494 -163 56 250 278 81 86 183 260 314 396 432 276 199 351 355 317 446 345 27 145 123 -71 85 126 -134 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