File name: Pandora138s1_Rome-IIA_20230914_L2Fit_fout2c1d20220121p1-8.txt File generation date: 20230916T144156.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v1d20220121.txt Level 1 file used: Pandora138s1_Rome-IIA_20230914_L1_smca1c1d20220121p1-8.txt Full location name: CNR-IIA Montelibretti Rome Short location name: Rome-IIA Country of location: Italy Location latitude [deg]: 42.1057 Location longitude [deg]: 12.6402 Location altitude [m]: 92 Local noon date: 20230914 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 210 351 Nominal wavelengths inside fitting window [nm]: 305.1046 305.2456 305.3867 305.5277 305.6687 305.8098 305.9508 306.0917 306.2327 306.3737 306.5147 306.6556 306.7965 306.9375 307.0784 307.2193 307.3602 307.5010 307.6419 307.7828 307.9236 308.0644 308.2053 308.3461 308.4869 308.6276 308.7684 308.9092 309.0499 309.1907 309.3314 309.4721 309.6128 309.7535 309.8942 310.0349 310.1756 310.3162 310.4569 310.5975 310.7381 310.8787 311.0193 311.1599 311.3005 311.4410 311.5816 311.7221 311.8627 312.0032 312.1437 312.2842 312.4247 312.5651 312.7056 312.8460 312.9865 313.1269 313.2673 313.4077 313.5481 313.6885 313.8289 313.9692 314.1096 314.2499 314.3902 314.5305 314.6709 314.8111 314.9514 315.0917 315.2319 315.3722 315.5124 315.6526 315.7929 315.9331 316.0732 316.2134 316.3536 316.4937 316.6339 316.7740 316.9141 317.0542 317.1943 317.3344 317.4745 317.6146 317.7546 317.8947 318.0347 318.1747 318.3147 318.4547 318.5947 318.7347 318.8746 319.0146 319.1545 319.2944 319.4344 319.5743 319.7141 319.8540 319.9939 320.1338 320.2736 320.4134 320.5533 320.6931 320.8329 320.9727 321.1124 321.2522 321.3920 321.5317 321.6714 321.8111 321.9509 322.0905 322.2302 322.3699 322.5096 322.6492 322.7889 322.9285 323.0681 323.2077 323.3473 323.4869 323.6264 323.7660 323.9056 324.0451 324.1846 324.3241 324.4636 324.6031 324.7426 324.8820 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230914T054430.6Z 8657.239242 68 1 49.30 2 80.37 94.01 71.50 93.55 0.00 1 0.00 1 0 25 4.287e-01 6.807e-03 2.138e-01 3.202e-03 6.877775e-01 1.728316e-03 7.559397e-03 -6.000000e+00 2.490697e-01 229.28 -2.00 3.53 -2.00 321.26 0.00e+00 4.146076e-03 6.705007e-04 7.319081e-04 -6.000000e+00 9.937592e-03 286.72 -2.00 20.00 -2.00 320.95 0.00e+00 5.700 0.003 302.00 328.00 3 1.9542e+00 5.2701e-03 6.7536e-02 -6.0000e+00 6.2586e-01 1.1118e-02 7.6780e-03 3.8139e-02 -6.0000e+00 6.7974e-01 -7.2993e-02 9.3692e-03 2.1745e-02 -6.0000e+00 3.9894e-01 2.8584e-02 4.6206e-03 7.4037e-03 -6.0000e+00 1.6782e-01 1.4095e-04 2.3384e-04 9.2475e-05 8.0124e-05 -6.0000e+00 1.1824e-02 2.0686e-03 0.0000e+00 11 9 0 11 8 0 24.97 18.60 0.19 0.00207 0.00383 112 25 4 8 0 438.350 14.99 18.60 26.36 21.88 21.27 13.9 997.71 -68817 -94324 -197945 -184150 -179347 -123516 -149233 -140423 -74697 -139782 -83658 -91967 -67860 86803 -50062 -13139 -39341 -30067 -1623 -66607 38611 -32331 -22741 -19332 -33126 -33201 -20366 -10845 -40546 -22577 4792 -5156 -18377 -10423 7691 7541 -8071 -8673 -2915 -2427 4684 -1280 8538 4730 5502 -209 2700 1997 -4659 4193 5991 4831 747 9966 1735 4853 1694 -1147 -1369 -1031 -11573 2416 6294 2632 3876 2449 831 -219 2726 -1328 2067 -296 743 2713 -2462 -915 -1474 -1693 -1198 -1538 -886 -1026 -437 -1635 -229 -51 199 569 1950 1395 577 836 -736 -578 -345 218 741 396 55 -398 -289 -1625 63 -895 -908 -989 -1384 -365 253 456 310 106 215 -31 102 -17 -188 113 99 -165 418 212 293 -51 683 -574 257 458 210 445 -27 -133 -217 -62 -260 -144 326 -114 194 -20 -137 -196 -215 -353 -2023 -1568 -1374 -617 -974 -957 -327 -1151 -470 -689 -530 271 -547 -119 -480 -375 -18 -1380 313 -496 -342 -307 -649 -688 -376 -196 -932 -506 101 -143 -673 -364 216 223 -321 -421 -165 -161 322 -92 640 347 412 -17 224 176 -469 427 680 620 110 1457 291 822 302 -208 -243 -184 -2460 506 1459 703 1042 656 231 -66 837 -485 788 -118 284 945 -816 -295 -466 -575 -439 -675 -450 -590 -269 -1086 -161 -36 143 416 1387 1017 395 543 -484 -411 -262 193 757 459 63 -469 -313 -1604 59 -878 -955 -1096 -1646 -436 335 678 504 167 333 -50 154 -25 -288 182 159 -269 701 342 459 -77 986 -810 361 710 372 821 -54 -284 -463 -140 -632 -362 784 -278 489 -48 -307 -420 SS 20230914T055511.3Z 8657.246659 73 1 49.23 2 78.40 95.83 69.60 95.38 0.00 1 0.00 1 0 25 2.613e-01 6.071e-03 7.766e-02 2.330e-03 5.933483e-01 1.226155e-03 6.663491e-03 -6.000000e+00 1.518377e-01 229.28 -2.00 3.53 -2.00 320.66 0.00e+00 3.300934e-03 4.153599e-04 4.713051e-04 -6.000000e+00 6.056493e-03 286.71 -2.00 20.00 -2.00 320.36 0.00e+00 4.811 0.002 302.00 328.00 3 2.3954e+00 3.5805e-03 5.7090e-02 -6.0000e+00 3.8154e-01 1.2043e-02 4.5783e-03 3.1808e-02 -6.0000e+00 4.1434e-01 -4.2753e-02 5.0278e-03 1.7096e-02 -6.0000e+00 2.4317e-01 1.3814e-02 2.5930e-03 5.5157e-03 -6.0000e+00 1.0233e-01 2.2478e-04 7.1146e-04 6.7424e-05 5.9181e-05 -6.0000e+00 7.2051e-03 -3.4785e-04 0.0000e+00 10 0 0 10 0 0 99.90 18.59 0.18 -0.00035 0.00500 113 25 4 8 0 435.630 15.00 18.59 27.54 21.88 21.27 14.1 1003.79 -59372 -117014 -107066 -120786 -91435 -93014 -68837 -82259 -56494 -80250 -51910 -25950 -43781 -37840 -31878 -13910 -28526 -4539 14818 -25628 6177 -12422 -3197 5042 -12922 -9663 -4473 6058 -11177 -7491 -129 2909 -7958 -7391 -5573 3075 -4481 -2905 -1258 -1053 2871 -1084 4533 2815 3627 -432 1898 2604 -1200 1554 -5126 769 1148 3739 1204 2790 -727 306 -517 287 772 891 3932 1650 1850 1813 1088 216 2019 120 1276 -104 541 1354 -1815 -2183 -1299 -1517 -564 -775 -535 -1462 -1564 -1727 -499 -286 446 469 1476 1311 784 197 -470 -318 -433 -24 584 627 197 -86 -542 -1028 -399 -444 -1183 -875 -895 -503 186 328 357 264 377 95 -102 167 -185 215 85 -256 -12 -76 117 276 598 -205 531 557 330 468 -36 -108 -319 -114 -276 -172 379 62 -170 105 -115 -247 -368 -1474 -1282 -1571 -831 -884 -625 -883 -578 -1011 -578 -265 -624 -649 -639 -273 -725 -100 291 -794 142 -349 -88 138 -454 -345 -152 180 -402 -294 -6 144 -458 -432 -335 177 -293 -225 -118 -115 333 -139 578 373 487 -62 273 386 -194 266 -1050 164 246 843 292 691 -190 78 -130 72 207 267 1299 610 686 651 395 83 869 60 630 -53 287 666 -834 -914 -519 -641 -273 -443 -327 -1010 -1160 -1364 -419 -237 383 410 1259 1133 632 150 -355 -256 -397 -24 658 743 244 -103 -639 -1101 -406 -479 -1379 -1067 -1090 -658 266 490 576 435 605 145 -156 250 -287 330 139 -428 -20 -120 190 427 886 -295 756 865 543 849 -67 -211 -653 -248 -608 -393 876 145 -391 229 -252 -516 SS 20230914T060214.1Z 8657.251552 76 1 50.33 2 77.10 97.05 68.34 96.60 0.00 1 0.00 1 0 25 5.344e-01 1.552e-02 2.734e-01 7.048e-03 5.354001e-01 3.756809e-03 6.086405e-03 -6.000000e+00 3.106026e-01 229.28 -2.00 3.53 -2.00 320.49 0.00e+00 4.059222e-04 1.198852e-03 3.869432e-04 -6.000000e+00 1.327440e-02 286.71 -2.00 20.00 -2.00 320.18 0.00e+00 4.361 0.001 302.00 328.00 3 4.8241e+00 1.0853e-02 5.1668e-02 -6.0000e+00 7.8044e-01 3.3545e-02 1.3551e-02 2.8618e-02 -6.0000e+00 8.4800e-01 -1.7353e-02 1.4229e-02 1.5171e-02 -6.0000e+00 4.9819e-01 3.2948e-04 7.3869e-03 4.8202e-03 -6.0000e+00 2.1383e-01 3.1436e-05 5.3608e-04 2.1183e-04 5.3703e-05 -6.0000e+00 1.4907e-02 8.2093e-05 0.0000e+00 12 9 8 11 8 0 99.53 18.58 0.13 0.00008 0.00411 16 4 1 8 0 3145.270 15.00 18.58 27.98 21.88 21.27 13.8 1003.99 900000 900000 -169017 88654 -144029 83431 -24756 -24099 16381 -112424 900000 205788 143861 86505 -3748 -41317 21722 -18714 323534 -38772 102882 -19296 46623 264680 -35499 -10189 39627 98450 21395 34877 110963 16983 14314 -12623 65176 8205 9217 7330 -7959 16152 -1715 7303 6088 24368 4214 4409 640 4231 -3437 -8230 900000 -1690 1756 8863 6520 5328 -683 -217 -795 -4369 -7372 1061 3467 2852 -1440 3740 2066 -3723 5132 -3621 668 -767 3001 3105 -3253 -6745 156 -1277 2631 727 -5350 -1264 -808 -2717 -2389 573 1380 432 4251 2552 4208 -1304 -2597 -1416 -407 -1086 -644 1552 2060 526 -1835 -2425 -1247 766 -941 -1152 -2146 -585 1571 711 1045 -934 -467 -64 1233 638 -870 1262 -791 -375 -291 167 640 -318 1112 -579 501 1069 129 573 -17 -551 349 276 -386 -427 474 -623 470 178 -475 -218 900000 900000 -5704 609 -3452 573 -232 -254 134 -3166 900000 1413 988 714 -84 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