File name: Pandora138s1_Rome-IIA_20230927_L2Fit_fout2c1d20220121p1-8.txt File generation date: 20230928T120503.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v1d20220121.txt Level 1 file used: Pandora138s1_Rome-IIA_20230927_L1_smca1c1d20220121p1-8.txt Full location name: CNR-IIA Montelibretti Rome Short location name: Rome-IIA Country of location: Italy Location latitude [deg]: 42.1057 Location longitude [deg]: 12.6402 Location altitude [m]: 92 Local noon date: 20230927 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 210 351 Nominal wavelengths inside fitting window [nm]: 305.1046 305.2456 305.3867 305.5277 305.6687 305.8098 305.9508 306.0917 306.2327 306.3737 306.5147 306.6556 306.7965 306.9375 307.0784 307.2193 307.3602 307.5010 307.6419 307.7828 307.9236 308.0644 308.2053 308.3461 308.4869 308.6276 308.7684 308.9092 309.0499 309.1907 309.3314 309.4721 309.6128 309.7535 309.8942 310.0349 310.1756 310.3162 310.4569 310.5975 310.7381 310.8787 311.0193 311.1599 311.3005 311.4410 311.5816 311.7221 311.8627 312.0032 312.1437 312.2842 312.4247 312.5651 312.7056 312.8460 312.9865 313.1269 313.2673 313.4077 313.5481 313.6885 313.8289 313.9692 314.1096 314.2499 314.3902 314.5305 314.6709 314.8111 314.9514 315.0917 315.2319 315.3722 315.5124 315.6526 315.7929 315.9331 316.0732 316.2134 316.3536 316.4937 316.6339 316.7740 316.9141 317.0542 317.1943 317.3344 317.4745 317.6146 317.7546 317.8947 318.0347 318.1747 318.3147 318.4547 318.5947 318.7347 318.8746 319.0146 319.1545 319.2944 319.4344 319.5743 319.7141 319.8540 319.9939 320.1338 320.2736 320.4134 320.5533 320.6931 320.8329 320.9727 321.1124 321.2522 321.3920 321.5317 321.6714 321.8111 321.9509 322.0905 322.2302 322.3699 322.5096 322.6492 322.7889 322.9285 323.0681 323.2077 323.3473 323.4869 323.6264 323.7660 323.9056 324.0451 324.1846 324.3241 324.4636 324.6031 324.7426 324.8820 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230927T054219.9Z 8670.237731 141 1 49.24 2 83.33 98.18 127.55 285.33 0.00 1 0.00 1 0 17 4.796e-01 2.744e-02 3.383e-01 1.140e-02 8.273105e-01 6.750619e-03 8.997710e-03 -6.000000e+00 2.869196e-01 227.83 -2.00 3.53 -2.00 321.97 0.00e+00 9.475885e-03 2.916406e-03 1.134769e-03 -6.000000e+00 1.354523e-02 285.17 -2.00 20.00 -2.00 321.63 0.00e+00 7.831 0.009 302.00 328.00 3 1.7350e+00 2.1932e-02 8.9746e-02 -6.0000e+00 7.2375e-01 8.0185e-01 3.1416e-02 4.6029e-02 -6.0000e+00 7.9362e-01 -1.0369e+00 3.6469e-02 2.6266e-02 -6.0000e+00 4.6043e-01 4.1727e-01 1.7827e-02 9.2097e-03 -6.0000e+00 1.9460e-01 1.7882e-05 -1.1343e-03 3.4942e-04 1.2084e-04 -6.0000e+00 1.4195e-02 -2.6097e-03 0.0000e+00 12 8 8 10 0 0 17.68 18.70 0.26 -0.00261 -0.01113 33 7 4 8 0 1491.720 15.00 18.70 21.67 21.98 21.38 13.8 969.17 900000 900000 -143081 -21411 900000 -60947 900000 -18709 900000 -141450 900000 -75654 35567 900000 20934 900000 -72768 900000 900000 9925 167492 3079 900000 900000 33589 -58313 900000 900000 56485 -54410 -115949 142271 -34577 20930 900000 900000 -18097 74628 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0.0000e+00 12 8 8 10 0 0 -11.61 18.72 0.31 -0.00325 -0.01359 74 16 4 8 0 660.730 15.00 18.72 22.15 21.98 21.38 13.8 971.85 283371 -2282 -92111 -37286 -98534 17893 -71227 -24155 -64104 -25550 6240 18191 37564 127384 91982 48669 35939 94753 299226 38837 186450 40754 173944 387615 32454 1703 23734 131124 252 30741 200948 110293 30679 43261 168312 77412 80260 66853 22584 36669 46314 49705 50942 51713 65622 43679 52467 53495 40506 39111 -95170 35006 30833 39422 19645 23790 16986 9238 13656 9536 58315 14050 22100 19406 20242 19688 14590 12245 14645 6358 9500 7215 4175 6793 -3461 -1397 3265 595 3179 1926 1937 3708 1409 -1690 -1299 952 -608 1317 3826 2542 1900 -1329 -2935 -3407 -3616 -2105 -117 1585 1682 1882 971 -527 -947 -2503 -2914 -2212 -3090 -1293 -1812 -645 -578 -1121 -1424 -1138 -468 -1420 -1296 5 499 414 634 847 664 957 1344 902 1207 1316 990 1453 1053 1135 425 196 -77 -491 333 -717 -94 -310 -138 -1315 1497 -22 -2257 -484 -2035 103 -924 -186 -708 -184 33 105 278 673 729 655 621 1101 1581 765 985 705 919 2048 566 36 439 831 6 698 1062 1748 1120 1413 1601 1800 1951 2084 1139 1797 2202 2412 2594 2732 3152 2749 3176 3392 3094 3269 -30969 3699 3644 4507 2765 3188 2399 1362 1876 1388 5630 2409 4055 3768 4020 3858 3032 2728 3566 1904 2945 2313 1320 1923 -972 -348 827 153 950 705 828 1757 733 -956 -781 593 -401 872 2448 1565 1093 -746 -1660 -2099 -2608 -1641 -106 1617 1823 1986 952 -467 -783 -2174 -2722 -2158 -3258 -1463 -2312 -925 -851 -1732 -2194 -1684 -708 -2134 -2014 7 794 669 992 1364 1038 1435 1945 1274 1705 2057 1665 2745 2193 2519 938 462 -195 -1287 880 -1937 -247 -766 -320 -3101 SS 20230927T060850.6Z 8670.256141 150 1 51.11 2 78.50 102.77 131.92 290.92 0.00 1 0.00 1 0 17 2.067e-01 5.541e-03 3.207e-02 1.170e-03 5.653671e-01 6.106109e-04 6.457130e-03 -6.000000e+00 1.195633e-01 227.83 -2.00 3.53 -2.00 320.39 0.00e+00 2.569253e-03 1.940213e-04 4.042413e-04 -6.000000e+00 4.791710e-03 285.17 -2.00 20.00 -2.00 320.09 0.00e+00 4.849 0.002 302.00 328.00 3 1.1181e+00 1.7503e-03 5.6398e-02 -6.0000e+00 2.9942e-01 2.1284e-02 2.1793e-03 3.0076e-02 -6.0000e+00 3.2545e-01 -2.9590e-02 2.3000e-03 1.6022e-02 -6.0000e+00 1.9121e-01 5.9332e-03 1.2033e-03 5.1278e-03 -6.0000e+00 8.0771e-02 8.0209e-04 2.6714e-04 3.3579e-05 5.6733e-05 -6.0000e+00 5.6968e-03 -4.6245e-03 0.0000e+00 10 0 0 10 0 0 16.29 18.78 0.16 -0.00462 -0.00262 348 76 4 8 0 141.170 15.00 18.78 23.95 21.98 21.38 14.0 982.30 -88580 -45351 -79555 -65518 -74643 -79315 -58947 -79383 -55471 -74534 -36710 -51014 -30732 -16113 -20208 -6059 -15834 -3088 -10315 -3024 -8158 -6334 -5460 -3208 -8273 -13269 -6084 -7397 -8909 -12132 3871 -3027 -1968 -6591 -4658 -3251 -2969 -221 -3023 1227 -202 647 573 1838 1911 1220 2500 83 1781 1230 3377 1018 2024 1557 1340 2121 216 266 -637 1008 -927 2087 2412 2246 1159 460 199 -409 1419 -74 1275 193 573 237 -585 -1083 -1820 -1086 -1341 -845 -1169 -1520 -2003 -1317 -729 -192 567 494 1107 701 770 -88 -165 -102 -152 207 676 530 1 81 -537 -700 -299 -598 -1218 -835 -597 -413 395 262 416 277 317 -93 40 69 32 284 -55 -225 -166 286 161 203 322 -284 592 532 212 218 -153 -244 -188 -32 -193 -227 429 28 -99 83 -175 -173 -1051 -399 -1035 -703 -818 -932 -626 -1178 -728 -1267 -452 -850 -530 -303 -489 -149 -434 -90 -317 -91 -263 -204 -186 -117 -338 -600 -258 -306 -376 -590 190 -186 -136 -488 -324 -231 -241 -21 -362 152 -28 94 88 284 300 198 408 14 315 236 709 242 519 433 392 638 68 82 -194 304 -303 739 889 906 475 183 79 -172 660 -40 731 115 330 129 -290 -488 -790 -488 -693 -511 -758 -1110 -1576 -1094 -647 -168 515 457 1006 649 660 -71 -131 -86 -145 210 785 648 1 100 -617 -777 -315 -668 -1472 -990 -751 -558 580 402 686 467 522 -146 59 99 48 442 -92 -384 -277 460 252 303 490 -419 856 834 352 376 -285 -478 -365 -65 -426 -493 944 63 -217 182 -365 -346 SS 20230927T061529.9Z 8670.260762 153 1 51.33 2 77.30 103.95 133.00 292.41 0.00 1 0.00 1 0 17 1.272e-01 5.028e-03 1.782e-02 8.457e-04 5.196412e-01 4.377846e-04 5.991469e-03 -6.000000e+00 7.357445e-02 227.83 -2.00 3.53 -2.00 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