File name: Pandora138s1_Rome-IIA_20240209_L2Fit_fout2c1d20220121p1-8.txt File generation date: 20240209T232934.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v1d20220121.txt Level 1 file used: Pandora138s1_Rome-IIA_20240209_L1_smca1c1d20220121p1-8.txt Full location name: CNR-IIA Montelibretti Rome Short location name: Rome-IIA Country of location: Italy Location latitude [deg]: 42.1057 Location longitude [deg]: 12.6402 Location altitude [m]: 92 Local noon date: 20240209 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 210 351 Nominal wavelengths inside fitting window [nm]: 305.1046 305.2456 305.3867 305.5277 305.6687 305.8098 305.9508 306.0917 306.2327 306.3737 306.5147 306.6556 306.7965 306.9375 307.0784 307.2193 307.3602 307.5010 307.6419 307.7828 307.9236 308.0644 308.2053 308.3461 308.4869 308.6276 308.7684 308.9092 309.0499 309.1907 309.3314 309.4721 309.6128 309.7535 309.8942 310.0349 310.1756 310.3162 310.4569 310.5975 310.7381 310.8787 311.0193 311.1599 311.3005 311.4410 311.5816 311.7221 311.8627 312.0032 312.1437 312.2842 312.4247 312.5651 312.7056 312.8460 312.9865 313.1269 313.2673 313.4077 313.5481 313.6885 313.8289 313.9692 314.1096 314.2499 314.3902 314.5305 314.6709 314.8111 314.9514 315.0917 315.2319 315.3722 315.5124 315.6526 315.7929 315.9331 316.0732 316.2134 316.3536 316.4937 316.6339 316.7740 316.9141 317.0542 317.1943 317.3344 317.4745 317.6146 317.7546 317.8947 318.0347 318.1747 318.3147 318.4547 318.5947 318.7347 318.8746 319.0146 319.1545 319.2944 319.4344 319.5743 319.7141 319.8540 319.9939 320.1338 320.2736 320.4134 320.5533 320.6931 320.8329 320.9727 321.1124 321.2522 321.3920 321.5317 321.6714 321.8111 321.9509 322.0905 322.2302 322.3699 322.5096 322.6492 322.7889 322.9285 323.0681 323.2077 323.3473 323.4869 323.6264 323.7660 323.9056 324.0451 324.1846 324.3241 324.4636 324.6031 324.7426 324.8820 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240209T071250.5Z 8805.300585 66 1 49.85 2 80.93 119.55 82.67 130.01 0.00 1 0.00 1 0 25 4.870e-01 2.806e-02 2.932e-01 7.313e-03 7.867331e-01 4.076026e-03 8.796429e-03 -6.000000e+00 2.809596e-01 224.54 -2.00 3.53 -2.00 321.52 0.00e+00 1.838261e-02 1.637604e-03 8.907904e-04 -6.000000e+00 1.214353e-02 273.73 -2.00 20.00 -2.00 321.20 0.00e+00 6.019 0.004 302.00 328.00 3 2.9686e+00 1.2446e-02 7.2443e-02 -6.0000e+00 6.9943e-01 6.2874e-01 1.7190e-02 4.2010e-02 -6.0000e+00 7.6392e-01 -8.3245e-01 1.9917e-02 2.3374e-02 -6.0000e+00 4.4793e-01 3.5150e-01 9.8862e-03 7.9789e-03 -6.0000e+00 1.9039e-01 2.8886e-05 -1.2175e-03 2.0657e-04 1.0578e-04 -6.0000e+00 1.4051e-02 -1.5321e-03 0.0000e+00 12 8 8 10 0 0 99.74 18.45 0.17 -0.00153 -0.01068 24 5 4 8 0 2076.940 14.99 18.45 16.59 21.79 21.17 14.9 948.94 29259 68534 -152136 900000 -184458 17449 900000 -144011 -150970 -120403 -8702 900000 -59096 900000 2165 84492 93282 40603 900000 47902 140269 22216 900000 900000 111032 78390 149077 900000 -17628 35510 900000 107831 100953 2914 88696 63895 121545 42216 10560 66923 48533 33068 73176 72082 57848 31655 14807 45970 23616 28591 -76838 38436 30019 42172 16147 25781 15663 17384 888 14172 15894 23212 22332 15256 18065 11793 16283 5596 22193 968 6410 2934 3771 1170 -7919 -4312 -3417 -690 3899 4242 -1242 644 1074 -5696 -3173 -1738 1231 -42 4952 1927 5445 -2375 -5132 -5064 -3290 -613 -1466 815 1601 1702 -74 -395 -2125 -3244 -1817 -2045 -3014 -1302 -76 -857 -236 -1286 -1454 31 -522 990 -417 586 -111 -182 46 1829 1307 35 2902 615 2233 1610 486 938 185 427 707 198 -587 31 284 -311 -587 -182 -554 -991 208 488 -5240 900000 -6972 124 900000 -3292 -3677 -2166 -62 900000 -1022 900000 37 789 900 702 900000 822 998 444 900000 900000 892 860 1061 900000 -493 724 900000 1672 1902 137 1765 1590 1911 1563 602 2542 2352 1947 3125 3215 3030 2187 1249 3090 2053 2569 -20224 3812 3471 4613 2277 3351 2214 2346 136 1929 2264 3497 3889 3168 3767 2581 3481 1385 5261 313 2097 1003 1226 359 -2375 -1143 -884 -189 1198 1550 -550 315 559 -3304 -1911 -1083 774 -27 3044 1155 2962 -1327 -2944 -3151 -2313 -493 -1369 839 1724 1791 -74 -355 -1820 -2884 -1691 -2005 -3159 -1451 -93 -1175 -351 -2002 -2268 46 -754 1403 -612 894 -177 -294 73 2718 1907 50 3943 834 2993 2375 812 1729 370 896 1548 457 -1430 78 709 -788 -1461 -429 -1242 -2130 SS 20240209T072627.9Z 8805.310045 72 1 49.12 2 78.76 122.06 80.81 132.44 0.00 1 0.00 1 0 17 4.611e-01 8.469e-03 1.681e-01 2.561e-03 6.917098e-01 1.355655e-03 7.740539e-03 -6.000000e+00 2.633486e-01 224.54 -2.00 3.53 -2.00 321.00 0.00e+00 4.032566e-03 5.030407e-04 6.595976e-04 -6.000000e+00 1.068824e-02 273.73 -2.00 20.00 -2.00 320.70 0.00e+00 4.954 0.002 302.00 328.00 3 2.2794e+00 4.0168e-03 6.0751e-02 -6.0000e+00 6.5460e-01 7.8205e-02 5.5574e-03 3.6913e-02 -6.0000e+00 7.1323e-01 -9.8136e-02 6.5632e-03 2.0857e-02 -6.0000e+00 4.2008e-01 3.7793e-02 3.3066e-03 7.0679e-03 -6.0000e+00 1.7863e-01 1.9585e-04 2.4565e-04 7.1980e-05 8.2743e-05 -6.0000e+00 1.2699e-02 -2.2276e-03 0.0000e+00 11 8 0 10 0 0 99.00 18.43 0.24 -0.00223 -0.00038 138 30 4 8 0 355.750 15.00 18.43 17.49 21.79 21.17 15.1 953.94 -190011 217887 -180450 -102794 -163571 -134529 -58362 -173570 -28204 -162399 125828 -110880 -59272 -51954 -57269 5086 -70366 8169 -33577 19246 -34719 38244 -32186 -7287 -6189 -32956 9374 -31028 -9784 -36782 32894 -11786 3555 -15979 -11372 7736 -12176 13174 -15664 9833 -3986 6772 -3163 8280 8405 -838 6375 -362 5210 -186 18635 1155 5804 1791 2169 5217 204 3948 -2157 3763 -7820 5240 3072 2536 2146 1097 2716 -1189 4514 -424 2453 -402 884 420 -1189 -466 -2887 221 -2647 -104 -2252 -405 -1339 -1472 -1041 -728 565 -283 2238 -194 2215 -964 -71 -644 -446 306 300 788 -307 247 -745 -453 -495 -678 -1287 -1326 -694 -777 533 384 362 -80 -5 -74 49 349 -228 657 -8 39 -171 540 168 95 769 -129 874 263 421 -140 40 -282 28 -210 -169 -233 273 195 -250 169 -162 -250 -2200 544 -2335 -583 -1597 -1008 -248 -2404 -113 -2433 314 -1309 -552 -590 -871 55 -1661 98 -663 236 -741 439 -731 -141 -126 -928 175 -845 -222 -1269 695 -466 139 -784 -511 299 -655 664 -1187 681 -352 575 -312 746 775 -88 642 -41 595 -25 2315 191 1005 351 446 1080 42 828 -468 771 -1771 1177 810 747 648 329 814 -394 1604 -181 1094 -188 394 174 -451 -159 -984 78 -1126 -52 -1323 -245 -881 -1029 -776 -573 456 -234 1776 -149 1542 -657 -48 -471 -374 297 316 933 -384 296 -829 -450 -497 -715 -1362 -1473 -818 -995 704 570 587 -135 -9 -117 74 511 -345 1038 -13 66 -282 845 256 139 1144 -187 1252 392 713 -251 78 -581 62 -459 -394 -559 663 479 -599 381 -362 -533 SS 20240209T074839.3Z 8805.325455 83 1 49.08 2 75.35 126.31 77.92 136.54 0.00 1 0.00 1 0 17 3.519e-01 1.656e-02 1.839e-01 6.546e-03 5.472095e-01 3.388530e-03 6.300288e-03 -6.000000e+00 2.010321e-01 224.54 -2.00 3.53 -2.00 320.27 0.00e+00 -3.433378e-04 1.044069e-03 3.726297e-04 -6.000000e+00 8.205207e-03 273.73 -2.00 20.00 -2.00 319.97 0.00e+00 3.874 0.001 302.00 328.00 3 5.1670e+00 9.6071e-03 4.7501e-02 -6.0000e+00 4.9970e-01 7.5376e-02 1.1851e-02 2.8470e-02 -6.0000e+00 5.4451e-01 -2.5852e-02 1.2073e-02 1.5254e-02 -6.0000e+00 3.2083e-01 -1.6034e-03 6.3479e-03 4.9012e-03 -6.0000e+00 1.3761e-01 3.4344e-05 4.8848e-04 1.8957e-04 5.3839e-05 -6.0000e+00 9.7306e-03 -4.6982e-03 0.0000e+00 12 8 8 10 0 0 99.63 18.48 0.07 -0.00470 -0.00103 15 3 1 8 0 3271.320 15.00 18.48 18.57 21.79 21.27 15.0 959.84 900000 -104419 -95060 -8552 -179638 -37271 34989 -81640 -120808 -83782 -8911 1633 -71812 109529 -2029 19648 5677 2308 146720 -10760 62909 -11484 46992 39028 11602 -6411 12958 16009 2054 -21661 130193 10051 -8696 -16982 17821 12131 28207 5946 -4443 4912 2039 3878 11531 10070 9249 -3515 -8862 8967 1294 -1857 122095 8603 2075 4897 -1371 4281 770 1752 -4858 1050 -4544 -146 6082 2503 1214 2738 2622 -2929 3410 -2088 430 -1226 472 -172 -3210 -24 -2256 -1761 -1781 855 -3403 -1581 -423 -4288 -1272 -253 553 969 3516 -884 2057 -1037 -1973 -1201 -600 1415 -424 710 1640 -142 -1377 -1638 -422 -1232 -951 -1319 -771 -819 1118 1467 936 213 -171 901 -574 994 -923 1814 160 396 253 -188 900 -1854 755 151 457 723 161 27 -786 -162 -290 358 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