File name: Pandora138s1_Rome-IIA_20240211_L2Fit_fout2c1d20220121p1-8.txt File generation date: 20240211T232740.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v1d20220121.txt Level 1 file used: Pandora138s1_Rome-IIA_20240211_L1_smca1c1d20220121p1-8.txt Full location name: CNR-IIA Montelibretti Rome Short location name: Rome-IIA Country of location: Italy Location latitude [deg]: 42.1057 Location longitude [deg]: 12.6402 Location altitude [m]: 92 Local noon date: 20240211 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 210 351 Nominal wavelengths inside fitting window [nm]: 305.1046 305.2456 305.3867 305.5277 305.6687 305.8098 305.9508 306.0917 306.2327 306.3737 306.5147 306.6556 306.7965 306.9375 307.0784 307.2193 307.3602 307.5010 307.6419 307.7828 307.9236 308.0644 308.2053 308.3461 308.4869 308.6276 308.7684 308.9092 309.0499 309.1907 309.3314 309.4721 309.6128 309.7535 309.8942 310.0349 310.1756 310.3162 310.4569 310.5975 310.7381 310.8787 311.0193 311.1599 311.3005 311.4410 311.5816 311.7221 311.8627 312.0032 312.1437 312.2842 312.4247 312.5651 312.7056 312.8460 312.9865 313.1269 313.2673 313.4077 313.5481 313.6885 313.8289 313.9692 314.1096 314.2499 314.3902 314.5305 314.6709 314.8111 314.9514 315.0917 315.2319 315.3722 315.5124 315.6526 315.7929 315.9331 316.0732 316.2134 316.3536 316.4937 316.6339 316.7740 316.9141 317.0542 317.1943 317.3344 317.4745 317.6146 317.7546 317.8947 318.0347 318.1747 318.3147 318.4547 318.5947 318.7347 318.8746 319.0146 319.1545 319.2944 319.4344 319.5743 319.7141 319.8540 319.9939 320.1338 320.2736 320.4134 320.5533 320.6931 320.8329 320.9727 321.1124 321.2522 321.3920 321.5317 321.6714 321.8111 321.9509 322.0905 322.2302 322.3699 322.5096 322.6492 322.7889 322.9285 323.0681 323.2077 323.3473 323.4869 323.6264 323.7660 323.9056 324.0451 324.1846 324.3241 324.4636 324.6031 324.7426 324.8820 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240211T102708.8Z 8807.435519 153 1 43.40 2 57.71 163.74 61.50 139.36 0.00 1 0.00 1 0 17 1.742e-02 5.378e-03 5.568e-03 1.214e-03 3.668468e-01 6.119165e-04 4.429180e-03 -6.000000e+00 9.956447e-03 224.62 -2.00 3.53 -2.00 317.77 0.00e+00 7.293473e-04 9.346697e-05 1.011264e-04 -6.000000e+00 4.037324e-04 273.73 -2.00 20.00 -2.00 317.48 0.00e+00 1.865 0.000 302.00 328.00 3 4.3647e+00 1.6125e-03 2.6361e-02 -6.0000e+00 2.4753e-02 4.2515e-02 1.8088e-03 1.8552e-02 -6.0000e+00 2.6965e-02 1.1751e-03 1.1852e-03 9.3913e-03 -6.0000e+00 1.5881e-02 -6.2936e-03 6.2232e-04 2.7693e-03 -6.0000e+00 6.7553e-03 6.3367e-04 6.1550e-04 3.4511e-05 3.0216e-05 -6.0000e+00 4.7963e-04 -5.7654e-03 0.0000e+00 10 0 0 10 0 0 99.95 18.44 0.12 -0.00577 -0.00114 59 15 2 8 0 735.460 15.00 18.44 17.68 21.79 21.17 15.1 955.79 -3391 -4024 -7180 -4854 -11046 -2129 -4414 -4704 -2152 -5702 -3840 -1160 -1952 -1362 -682 -693 639 -851 2458 561 1118 633 1678 1679 14 -18 -88 -1046 -634 700 1915 2024 -312 -2499 -1873 -1396 -1379 -842 -493 -730 -799 -359 -219 58 287 -478 -542 -694 -520 266 2151 828 1205 841 394 793 315 198 99 774 717 1455 1794 936 -162 144 -285 -132 849 -8 341 -3 176 23 -184 -135 -951 -565 -622 -1093 -1081 -1489 -1740 -1293 -884 -298 22 348 462 315 699 290 272 425 326 477 784 413 71 -301 -550 -464 -120 -371 -1107 -870 -511 -350 263 410 363 302 196 82 113 104 125 145 85 -358 -110 257 135 182 553 -72 717 572 306 270 -230 -22 -243 17 -47 -222 449 -66 -122 -89 -203 -515 -225 -291 -544 -334 -743 -133 -306 -366 -179 -509 -343 -109 -216 -174 -100 -111 107 -152 445 106 213 122 334 354 3 -4 -20 -230 -135 152 451 518 -88 -722 -509 -387 -424 -296 -201 -331 -386 -180 -112 30 147 -247 -278 -354 -266 140 1183 487 742 539 260 530 212 133 66 512 492 1056 1388 755 -130 109 -213 -99 681 -7 312 -3 162 20 -153 -104 -707 -419 -495 -958 -1026 -1502 -1832 -1400 -998 -349 27 421 553 364 766 302 274 435 355 558 981 550 96 -398 -695 -557 -141 -455 -1417 -1144 -691 -490 382 622 566 472 298 120 157 143 173 208 127 -547 -167 384 198 259 766 -98 951 785 442 407 -358 -34 -392 28 -81 -389 793 -118 -216 -154 -343 -856 SS 20240211T103647.6Z 8807.442217 158 1 43.11 2 57.25 166.46 60.35 141.67 0.00 1 0.00 1 0 17 2.122e-02 5.729e-03 8.830e-03 1.495e-03 3.636385e-01 7.514832e-04 4.367832e-03 -6.000000e+00 1.213090e-02 224.62 -2.00 3.53 -2.00 318.31 0.00e+00 1.149164e-03 1.322163e-04 1.146867e-04 -6.000000e+00 4.919054e-04 273.73 -2.00 20.00 -2.00 318.01 0.00e+00 1.842 0.000 302.00 328.00 3 4.5346e+00 1.9979e-03 2.6096e-02 -6.0000e+00 3.0160e-02 3.3188e-02 2.2517e-03 1.8408e-02 -6.0000e+00 3.2854e-02 9.2206e-03 1.5646e-03 9.3651e-03 -6.0000e+00 1.9349e-02 -1.0550e-02 8.3534e-04 2.7920e-03 -6.0000e+00 8.2306e-03 5.4983e-04 6.3693e-04 4.3190e-05 3.0057e-05 -6.0000e+00 5.8438e-04 -5.7674e-03 0.0000e+00 10 0 0 10 0 0 99.98 18.46 0.25 -0.00577 -0.00098 154 38 4 8 0 279.860 15.00 18.46 18.52 21.79 21.17 15.3 961.42 -6172 -179 -7220 -3273 -15022 -7018 -4093 -3607 -2003 -8555 454 -3058 -751 202 231 2223 1740 1298 1660 1361 -552 2084 1118 1134 -1265 -1256 -628 -1467 -145 -418 2468 1088 1132 -2636 -1009 -1447 -1307 -487 -792 0 -1405 -495 -897 -224 50 -142 -45 -291 -196 328 -4258 560 1635 430 10 700 416 312 -179 1108 3488 1637 1610 1255 -20 376 -272 81 1292 -99 776 -14 178 -294 -264 -205 -478 -264 -91 -717 -1166 -1410 -1847 -980 -899 -298 -74 284 590 436 875 -36 181 43 109 411 779 438 71 -160 -526 -519 -396 -344 -1197 -757 -727 -423 192 372 561 200 291 -56 202 16 90 249 122 -260 -362 386 238 114 321 -141 602 665 381 100 11 -258 -122 -72 -115 -126 378 74 -146 -9 -260 -381 -321 -10 -422 -170 -797 -344 -212 -209 -126 -601 30 -225 -64 20 27 280 234 186 249 212 -82 325 171 184 -222 -228 -112 -268 -25 -76 446 220 251 -608 -215 -318 -322 -141 -277 0 -571 -208 -391 -98 22 -62 -19 -125 -85 146 -2153 290 893 251 6 430 259 191 -108 663 2143 1044 1126 932 -15 256 -179 54 940 -83 686 -12 158 -247 -202 -151 -328 -181 -69 -582 -1070 -1337 -1860 -1032 -1015 -334 -86 336 685 507 929 -35 179 44 114 478 955 592 98 -214 -654 -627 -462 -426 -1511 -995 -1003 -615 280 582 921 329 456 -82 288 22 126 369 182 -404 -561 577 365 167 445 -187 821 899 561 150 18 -419 -204 -126 -204 -230 702 140 -272 -16 -469 -663 SS 20240211T111153.4Z 8807.466591 174 1 1.50 2 56.28 176.57 56.66 150.57 0.00 1 0.00 1 0 17 2.547e-02 6.503e-03 1.230e-02 3.304e-03 3.570646e-01 1.668774e-03 4.318152e-03 -6.000000e+00 1.456757e-02 224.62 -2.00 3.53 -2.00 317.37 0.00e+00 3.346979e-04 2.290376e-04 8.621905e-05 -6.000000e+00 5.901447e-04 273.73 -2.00 20.00 -2.00 317.08 0.00e+00 1.796 0.000 302.00 328.00 3 2.9959e+00 4.3703e-03 2.5492e-02 -6.0000e+00 3.6219e-02 3.6156e-02 4.8912e-03 1.8002e-02 -6.0000e+00 3.9443e-02 -6.5451e-04 3.0753e-03 9.0936e-03 -6.0000e+00 2.3230e-02 -5.7342e-03 1.5806e-03 2.6715e-03 -6.0000e+00 9.8905e-03 2.7169e-03 1.3458e-03 9.3470e-05 2.9617e-05 -6.0000e+00 7.0088e-04 -1.1695e-02 0.0000e+00 12 9 1 12 9 1 55.06 18.47 0.05 -0.01170 -0.00158 5 43 2 8 0 248.930 15.00 18.47 19.26 21.79 21.17 14.9 962.69 -2858 3133 -6538 8126 -12665 11957 -12348 587 -4497 -5334 -5560 -4915 4506 -4962 2810 -2926 2124 32 -2 1056 -1235 2751 312 3412 -1191 1782 -1255 1093 -1614 -895 289 1181 2672 -5033 -258 -2630 -1455 256 -76 -610 -1445 636 -1494 91 55 641 4 338 87 167 428 1327 1211 199 1153 940 612 439 1019 537 -1196 1411 1553 968 -1205 638 -530 259 1131 397 754 -360 123 -144 590 -1269 439 -523 -588 -572 -757 -1181 -2237 -1158 -1189 -541 -479 166 -58 627 713 72 77 695 810 199 819 115 -289 -237 -391 -235 -32 -501 -1403 -239 -508 21 226 110 592 177 597 -54 175 43 592 34 -91 -423 -129 -93 201 216 357 313 574 855 411 196 449 -357 -35 -159 -4 -405 131 -175 -75 -193 -167 -298 -245 275 -637 647 -1113 851 -1183 56 -492 -610 -647 -615 596 -818 493 -587 429 7 0 243 -291 628 76 853 -323 486 -348 283 -411 -236 81 355 856 -1714 -81 -855 -512 101 -35 -308 -777 348 -844 51 31 359 2 188 48 96 258 835 798 137 805 668 440 312 713 379 -878 1079 1259 816 -1010 507 -414 204 941 358 708 -345 117 -131 508 -1034 339 -405 -485 -513 -730 -1210 -2384 -1267 -1358 -638 -577 202 -70 730 790 76 79 718 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