File name: Pandora138s1_Rome-IIA_20240410_L2Fit_fout2c1d20220121p1-8.txt File generation date: 20240410T231644.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v1d20220121.txt Level 1 file used: Pandora138s1_Rome-IIA_20240410_L1_smca1c1d20220121p1-8.txt Full location name: CNR-IIA Montelibretti Rome Short location name: Rome-IIA Country of location: Italy Location latitude [deg]: 42.1057 Location longitude [deg]: 12.6402 Location altitude [m]: 92 Local noon date: 20240410 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 210 351 Nominal wavelengths inside fitting window [nm]: 305.1046 305.2456 305.3867 305.5277 305.6687 305.8098 305.9508 306.0917 306.2327 306.3737 306.5147 306.6556 306.7965 306.9375 307.0784 307.2193 307.3602 307.5010 307.6419 307.7828 307.9236 308.0644 308.2053 308.3461 308.4869 308.6276 308.7684 308.9092 309.0499 309.1907 309.3314 309.4721 309.6128 309.7535 309.8942 310.0349 310.1756 310.3162 310.4569 310.5975 310.7381 310.8787 311.0193 311.1599 311.3005 311.4410 311.5816 311.7221 311.8627 312.0032 312.1437 312.2842 312.4247 312.5651 312.7056 312.8460 312.9865 313.1269 313.2673 313.4077 313.5481 313.6885 313.8289 313.9692 314.1096 314.2499 314.3902 314.5305 314.6709 314.8111 314.9514 315.0917 315.2319 315.3722 315.5124 315.6526 315.7929 315.9331 316.0732 316.2134 316.3536 316.4937 316.6339 316.7740 316.9141 317.0542 317.1943 317.3344 317.4745 317.6146 317.7546 317.8947 318.0347 318.1747 318.3147 318.4547 318.5947 318.7347 318.8746 319.0146 319.1545 319.2944 319.4344 319.5743 319.7141 319.8540 319.9939 320.1338 320.2736 320.4134 320.5533 320.6931 320.8329 320.9727 321.1124 321.2522 321.3920 321.5317 321.6714 321.8111 321.9509 322.0905 322.2302 322.3699 322.5096 322.6492 322.7889 322.9285 323.0681 323.2077 323.3473 323.4869 323.6264 323.7660 323.9056 324.0451 324.1846 324.3241 324.4636 324.6031 324.7426 324.8820 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240410T061744.7Z 8866.262323 84 1 2.57 2 72.13 95.20 81.07 75.28 0.00 1 0.00 1 0 17 1.148e-01 8.256e-03 7.375e-02 6.071e-03 4.960826e-01 3.110549e-03 5.766038e-03 -6.000000e+00 6.647068e-02 228.06 -2.00 3.53 -2.00 319.24 0.00e+00 1.153800e-03 7.132632e-04 2.281975e-04 -6.000000e+00 2.659918e-03 278.59 -2.00 20.00 -2.00 318.95 0.00e+00 3.215 0.001 302.00 328.00 3 2.9874e+00 8.4932e-03 4.1090e-02 -6.0000e+00 1.6656e-01 6.6330e-02 9.7485e-03 2.5634e-02 -6.0000e+00 1.8097e-01 -4.0431e-02 8.1057e-03 1.3100e-02 -6.0000e+00 1.0631e-01 8.8446e-03 4.3951e-03 3.9532e-03 -6.0000e+00 4.4909e-02 5.8549e-04 8.6437e-04 1.7102e-04 4.0849e-05 -6.0000e+00 3.1620e-03 -8.4028e-03 0.0000e+00 12 9 1 12 1 1 97.10 18.66 0.10 -0.00840 -0.00191 4 21 4 8 0 508.450 15.00 18.66 20.77 21.88 21.38 15.7 975.23 -37928 6291 -44590 -23724 -49753 -41312 -27296 -1483 -46032 -54552 -20280 -36734 -8098 -17209 -396 5581 -14820 11577 -16988 11022 -9722 13446 -1394 13607 -1718 -4143 -7866 -9 5304 -49 1771 -1462 1343 -6735 2717 4036 -508 -1627 -727 572 -2542 3177 -2025 6756 155 -663 2359 66 1179 -652 602 1641 2650 279 1174 1486 163 1289 -1850 1647 791 3792 552 2367 330 -791 676 -81 -1049 1558 110 -73 288 270 1276 -1438 -2101 -1629 -1098 -462 -1315 -1468 -1588 -1514 -390 -417 -81 441 1383 -335 37 266 -564 -785 -645 12 1349 455 -827 134 -250 95 -329 23 -1576 -925 -25 -375 798 282 270 343 30 -154 434 354 562 30 250 -171 86 413 461 141 -26 -788 840 285 313 1028 -113 -944 -321 -181 -351 -223 570 271 -206 265 -409 -349 -938 115 -1351 -559 -1381 -1087 -688 -33 -1723 -2338 -661 -1567 -320 -891 -21 315 -1094 722 -1463 767 -824 933 -118 1077 -166 -426 -835 -1 471 -5 199 -190 190 -1033 368 556 -81 -311 -164 145 -719 895 -615 1927 47 -205 717 21 375 -223 221 644 1098 125 540 699 78 608 -883 766 386 1962 319 1433 201 -469 393 -48 -689 1105 83 -57 218 195 850 -907 -1276 -1010 -742 -346 -1092 -1323 -1495 -1485 -398 -443 -88 485 1498 -354 37 253 -526 -754 -672 14 1642 597 -1117 177 -313 111 -377 27 -1980 -1198 -33 -520 1159 436 435 557 48 -236 638 513 824 46 396 -275 137 647 707 211 -38 -1123 1174 418 489 1688 -194 -1670 -577 -337 -681 -441 1135 544 -411 513 -772 -642 SS 20240410T062305.9Z 8866.266041 87 1 49.30 2 71.14 96.13 80.13 76.09 0.00 1 0.00 1 0 17 6.898e-02 7.729e-03 2.974e-02 2.000e-03 4.752815e-01 1.028587e-03 5.512410e-03 -6.000000e+00 3.993042e-02 228.06 -2.00 3.53 -2.00 319.56 0.00e+00 1.846194e-03 2.562468e-04 2.411062e-04 -6.000000e+00 1.598884e-03 278.59 -2.00 20.00 -2.00 319.27 0.00e+00 3.057 0.000 302.00 328.00 3 3.8452e+00 2.8386e-03 3.9237e-02 -6.0000e+00 1.0005e-01 3.9628e-02 3.2937e-03 2.4679e-02 -6.0000e+00 1.0873e-01 -1.0963e-03 2.8872e-03 1.2740e-02 -6.0000e+00 6.3872e-02 -6.8372e-03 1.5613e-03 3.8978e-03 -6.0000e+00 2.6967e-02 2.9569e-04 6.1062e-04 5.7937e-05 4.1130e-05 -6.0000e+00 1.9010e-03 -4.5897e-03 0.0000e+00 11 8 0 10 0 0 100.00 18.66 0.24 -0.00459 -0.00000 121 27 4 8 0 407.370 15.00 18.66 20.85 21.98 21.38 15.8 976.68 -27517 -4067 -35007 -13026 -21971 -9592 -31167 -25989 -17191 -28791 -12070 -11130 -5119 -2501 -7802 -282 -4619 -825 4760 1770 1621 3525 420 2171 -1225 -2556 185 -802 -2115 -4891 1184 883 403 -4978 853 1619 -665 -2315 -1705 -1579 -1849 -1988 -123 1463 1008 -75 -1294 -587 -63 -48 -1985 158 1215 353 167 728 -311 -485 -366 422 18786 1073 1522 563 347 -392 567 -224 1416 -34 251 -117 161 -279 -777 -541 -944 -426 -187 -566 -1229 -1085 -1496 -1246 -1154 -599 -167 174 975 637 1214 167 -23 49 139 486 545 416 16 -27 -501 -772 16 -433 -1264 -1037 -594 -570 307 342 333 261 392 118 253 116 -39 445 22 -377 -19 269 26 162 406 -321 459 800 93 40 -246 -258 -188 -41 -27 -181 469 7 -68 -15 -178 -238 -551 -72 -802 -245 -417 -163 -724 -650 -439 -873 -321 -333 -162 -95 -374 -14 -266 -50 288 115 107 231 30 165 -102 -225 16 -66 -174 -447 117 100 47 -621 103 201 -88 -374 -333 -358 -459 -521 -33 390 273 -21 -365 -167 -18 -15 -635 54 443 139 68 305 -134 -206 -152 174 6823 514 809 325 198 -214 301 -123 860 -22 175 -84 112 -183 -498 -312 -515 -237 -117 -385 -957 -937 -1380 -1137 -1130 -619 -179 189 1036 639 1191 154 -21 46 134 530 675 539 21 -35 -601 -896 17 -509 -1606 -1295 -781 -798 462 531 548 434 628 178 376 168 -58 694 34 -612 -30 415 40 244 583 -444 658 1148 149 65 -430 -468 -354 -77 -55 -376 988 15 -142 -31 -340 -460 SS 20240410T062826.9Z 8866.269755 89 1 51.72 2 70.16 97.06 79.18 76.89 0.00 1 0.00 1 0 17 3.825e-02 4.995e-03 4.267e-03 4.510e-04 4.519017e-01 2.303728e-04 5.310656e-03 -6.000000e+00 2.213992e-02 228.06 -2.00 3.53 -2.00 318.82 0.00e+00 1.119539e-03 4.648143e-05 1.751867e-04 -6.000000e+00 8.865840e-04 278.59 -2.00 20.00 -2.00 318.52 0.00e+00 2.914 0.000 302.00 328.00 3 1.3816e+00 6.2163e-04 3.7301e-02 -6.0000e+00 5.5476e-02 3.8680e-02 7.0418e-04 2.3289e-02 -6.0000e+00 6.0288e-02 -2.0069e-02 5.3765e-04 1.1764e-02 -6.0000e+00 3.5415e-02 1.7904e-03 2.9130e-04 3.4844e-03 -6.0000e+00 1.4951e-02 4.1412e-03 5.7598e-04 1.2763e-05 3.6140e-05 -6.0000e+00 1.0541e-03 -4.1762e-03 0.0000e+00 12 1 1 12 1 1 99.91 18.66 0.13 -0.00418 0.00015 608 134 2 8 0 80.670 15.00 18.66 20.98 21.98 21.38 15.8 977.44 -11724 -8332 -10079 -12753 -16003 -15860 -15390 -12225 -8870 -13266 -11685 -8567 -6156 -3130 -2330 -149 -300 197 842 860 678 -78 813 -907 -1215 -1697 -2133 -2699 -2394 -1124 89 1111 253 -2456 -2608 -2321 -2260 -959 -325 -828 -760 -581 -320 176 571 -77 2 181 -214 913 556 921 1517 1100 815 1198 375 293 334 615 1185 1548 2031 1093 191 282 -278 139 771 181 440 30 224 167 -218 -268 -853 -795 -592 -975 -993 -1592 -1811 -1173 -881 -396 40 292 497 494 676 238 186 393 71 334 771 368 -87 -150 -571 -625 18 -305 -1074 -651 -585 -377 184 306 314 191 231 -48 150 322 221 300 18 -319 -126 249 195 255 423 -123 678 610 116 181 -197 -190 -177 30 -110 -178 443 -7 -133 -33 -200 -392 -340 -259 -328 -398 -474 -475 -505 -441 -345 -568 -507 -405 -344 -206 -181 -13 -28 20 88 94 75 -9 88 -108 -153 -224 -281 -339 -293 -146 13 181 46 -464 -467 -428 -472 -236 -89 -265 -264 -212 -121 67 217 -28 1 71 -79 353 237 425 748 542 418 631 202 156 173 319 646 926 1257 732 127 177 -183 94 541 136 355 25 181 126 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