File name: Pandora138s1_Rome-IIA_20240424_L2Fit_fout2c1d20220121p1-8.txt File generation date: 20240424T231147.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v1d20220121.txt Level 1 file used: Pandora138s1_Rome-IIA_20240424_L1_smca1c1d20220121p1-8.txt Full location name: CNR-IIA Montelibretti Rome Short location name: Rome-IIA Country of location: Italy Location latitude [deg]: 42.1057 Location longitude [deg]: 12.6402 Location altitude [m]: 92 Local noon date: 20240424 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 210 351 Nominal wavelengths inside fitting window [nm]: 305.1046 305.2456 305.3867 305.5277 305.6687 305.8098 305.9508 306.0917 306.2327 306.3737 306.5147 306.6556 306.7965 306.9375 307.0784 307.2193 307.3602 307.5010 307.6419 307.7828 307.9236 308.0644 308.2053 308.3461 308.4869 308.6276 308.7684 308.9092 309.0499 309.1907 309.3314 309.4721 309.6128 309.7535 309.8942 310.0349 310.1756 310.3162 310.4569 310.5975 310.7381 310.8787 311.0193 311.1599 311.3005 311.4410 311.5816 311.7221 311.8627 312.0032 312.1437 312.2842 312.4247 312.5651 312.7056 312.8460 312.9865 313.1269 313.2673 313.4077 313.5481 313.6885 313.8289 313.9692 314.1096 314.2499 314.3902 314.5305 314.6709 314.8111 314.9514 315.0917 315.2319 315.3722 315.5124 315.6526 315.7929 315.9331 316.0732 316.2134 316.3536 316.4937 316.6339 316.7740 316.9141 317.0542 317.1943 317.3344 317.4745 317.6146 317.7546 317.8947 318.0347 318.1747 318.3147 318.4547 318.5947 318.7347 318.8746 319.0146 319.1545 319.2944 319.4344 319.5743 319.7141 319.8540 319.9939 320.1338 320.2736 320.4134 320.5533 320.6931 320.8329 320.9727 321.1124 321.2522 321.3920 321.5317 321.6714 321.8111 321.9509 322.0905 322.2302 322.3699 322.5096 322.6492 322.7889 322.9285 323.0681 323.2077 323.3473 323.4869 323.6264 323.7660 323.9056 324.0451 324.1846 324.3241 324.4636 324.6031 324.7426 324.8820 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240424T061207.7Z 8880.258423 223 1 29.61 2 69.38 90.87 111.65 267.05 0.00 1 0.00 1 0 25 1.256e-01 1.024e-02 3.898e-02 2.057e-03 5.676919e-01 1.064101e-03 6.555622e-03 -6.000000e+00 7.298540e-02 229.24 -2.00 3.53 -2.00 319.63 0.00e+00 3.090076e-03 2.756187e-04 3.026125e-04 -6.000000e+00 2.910804e-03 280.14 -2.00 20.00 -2.00 319.35 0.00e+00 2.811 0.000 302.00 328.00 3 3.6742e+00 2.9402e-03 4.1122e-02 -6.0000e+00 1.8338e-01 7.3521e-02 3.4503e-03 2.9602e-02 -6.0000e+00 1.9914e-01 -3.6657e-02 3.1942e-03 1.5312e-02 -6.0000e+00 1.1687e-01 8.8593e-03 1.7239e-03 4.6674e-03 -6.0000e+00 4.9203e-02 3.7907e-04 4.9518e-04 5.6727e-05 4.8667e-05 -6.0000e+00 3.4623e-03 -2.3945e-03 0.0000e+00 12 9 9 12 9 1 99.97 18.47 0.15 -0.00239 0.00133 44 16 4 8 0 657.890 15.01 18.47 13.60 21.79 21.27 15.7 935.72 -25763 -47823 -45252 -30284 -54883 -46582 -38302 -55339 -27852 -40536 -21602 -19578 -30872 -11831 -6919 -2357 -612 -5035 11315 2899 1038 876 5412 3155 -2632 -2996 -3354 -505 -11973 -2642 2469 1897 1263 -5138 -112 -105 -691 -1437 -1535 -1826 -1011 -1496 940 821 1039 34 -579 1301 1056 1680 -15780 1415 1972 1523 788 1503 -321 -98 -85 -150 22357 1967 2671 2429 1079 1013 -50 300 1064 315 752 -272 55 -462 -1252 -756 -1158 -1102 -500 -1067 -1044 -1491 -1728 -1877 -821 -432 -67 360 871 503 1050 90 -293 198 26 122 616 596 168 134 -135 -649 -32 -418 -1451 -827 -734 -379 -23 508 216 236 346 120 115 227 53 235 -245 -473 -63 255 166 174 237 -165 869 698 90 384 -107 -105 -178 230 -212 -199 352 9 -234 24 -175 -350 -318 -814 -784 -436 -916 -737 -620 -1172 -505 -877 -412 -423 -923 -369 -249 -93 -26 -245 507 146 54 46 290 186 -173 -207 -232 -33 -872 -196 203 180 134 -594 -12 -12 -86 -210 -268 -369 -220 -347 220 195 250 8 -147 333 282 474 -5667 474 707 582 313 612 -135 -40 -35 -61 7931 909 1354 1317 593 539 -27 166 643 210 527 -196 38 -309 -782 -435 -644 -632 -317 -770 -836 -1294 -1579 -1789 -816 -446 -71 384 912 509 998 83 -265 185 27 137 754 786 227 176 -169 -760 -36 -493 -1797 -1058 -973 -526 -33 789 351 388 558 188 172 334 80 364 -396 -775 -101 400 255 260 345 -233 1222 1027 142 646 -188 -190 -330 442 -423 -406 721 18 -479 48 -337 -653 SS 20240424T061816.8Z 8880.262695 226 1 9.85 2 68.24 91.91 112.77 268.02 0.00 1 0.00 1 0 17 1.735e-01 9.433e-03 1.064e-01 4.863e-03 5.373087e-01 2.506416e-03 6.231789e-03 -6.000000e+00 1.008633e-01 229.24 -2.00 3.53 -2.00 319.38 0.00e+00 7.986223e-04 6.061280e-04 2.647776e-04 -6.000000e+00 4.022227e-03 280.14 -2.00 20.00 -2.00 319.09 0.00e+00 2.673 0.000 302.00 328.00 3 4.3562e+00 6.8837e-03 3.8984e-02 -6.0000e+00 2.5343e-01 5.2028e-02 7.9788e-03 2.7949e-02 -6.0000e+00 2.7519e-01 -1.4832e-02 7.0335e-03 1.4354e-02 -6.0000e+00 1.6151e-01 -1.2684e-03 3.8148e-03 4.3340e-03 -6.0000e+00 6.8002e-02 2.2993e-04 6.1507e-04 1.3500e-04 4.4623e-05 -6.0000e+00 4.7840e-03 -3.0413e-03 0.0000e+00 12 9 9 12 1 1 96.62 18.48 0.22 -0.00304 0.00158 5 7 1 8 0 1640.710 15.01 18.48 14.31 21.79 21.27 15.8 940.19 -39874 11808 -67360 49355 -60699 -35076 -16812 -60210 72995 -70865 81024 -38733 36145 -20528 -2423 1180 -4798 18788 9119 17290 -8577 21613 -7623 20822 -8002 -3514 13894 -7426 -298 -7907 15338 -2620 6918 -11977 3757 618 -7623 -956 -8797 3425 -2513 3505 -69 5265 -550 -1669 1991 -359 2261 -2715 -2621 -1345 4439 -114 1652 2087 -479 1429 -1514 1353 3864 2920 1859 1546 -578 1455 709 -1876 2328 -323 599 -1826 2390 -1076 -1031 -28 -1860 -636 -1307 87 -3088 -1230 -2146 -644 -643 -582 1117 138 1436 161 1535 1 530 -816 -448 521 72 854 85 415 -906 -23 -616 346 -1540 -779 -1056 -218 759 8 814 65 471 -394 -27 -27 154 623 -277 150 -546 294 -125 434 -234 -412 675 748 801 -389 703 -421 -417 -338 23 150 119 147 -326 608 -311 -582 -706 144 -1785 418 -1339 -627 -282 -1713 670 -2640 774 -1291 734 -861 -103 55 -260 886 499 919 -588 1139 -562 1284 -686 -302 1013 -634 -24 -732 1317 -302 813 -1708 444 78 -1163 -163 -1927 771 -647 903 -19 1391 -155 -481 562 -105 668 -888 -933 -513 1730 -49 722 940 -222 647 -687 601 1766 1462 1027 908 -345 825 403 -1121 1476 -229 446 -1404 1748 -768 -685 -17 -1110 -385 -879 65 -2599 -1101 -2022 -628 -657 -619 1204 152 1545 168 1506 1 490 -785 -467 590 90 1126 115 547 -1144 -27 -709 411 -1932 -1002 -1414 -303 1107 13 1313 106 753 -611 -40 -40 229 954 -442 242 -875 459 -192 644 -340 -585 945 1096 1253 -646 1208 -747 -759 -636 44 298 240 296 -651 1174 -584 -1067 SS 20240424T062300.1Z 8880.265974 228 1 11.63 2 67.36 92.71 113.62 268.76 0.00 1 0.00 1 0 17 6.828e-02 5.634e-03 3.624e-02 2.485e-03 5.182857e-01 1.278231e-03 6.033244e-03 -6.000000e+00 3.968878e-02 229.24 -2.00 3.53 -2.00 319.20 0.00e+00 8.532966e-04 2.923750e-04 2.373881e-04 -6.000000e+00 1.582723e-03 280.14 -2.00 20.00 -2.00 318.91 0.00e+00 2.577 0.000 302.00 328.00 3 3.4680e+00 3.4928e-03 3.7562e-02 -6.0000e+00 9.9723e-02 3.9900e-02 4.0136e-03 2.6893e-02 -6.0000e+00 1.0829e-01 -4.0665e-03 3.3854e-03 1.3742e-02 -6.0000e+00 6.3553e-02 -6.2434e-03 1.8397e-03 4.1194e-03 -6.0000e+00 2.6758e-02 6.3010e-04 6.8211e-04 6.9118e-05 4.2252e-05 -6.0000e+00 1.8825e-03 -2.9813e-03 0.0000e+00 12 1 1 12 1 1 99.92 18.50 0.12 -0.00298 0.00214 21 20 1 8 0 528.310 14.99 18.50 14.85 21.79 21.27 15.7 943.11 -26165 -2395 -30209 -13414 -27341 -17470 -20093 -19065 -22083 -34981 -5348 -23326 -1739 -7947 -3878 -1112 -7944 814 -1641 3148 -5174 2150 -623 1633 -2783 -626 -4700 -5040 -3049 -4768 4604 1597 2321 -5339 1021 -1896 -2357 -1720 -1475 -650 -1714 242 -283 1051 1032 -16 -43 -235 -53 -1005 537 818 519 315 893 1193 920 577 -392 246 978 2475 1938 2059 555 645 -320 125 1223 192 552 -36 714 243 -1030 -183 -1261 -966 -1410 -465 -1362 -888 -1707 -771 -1236 -400 -70 -1 877 340 1203 182 303 -128 265 351 652 270 -249 110 -537 -470 -241 -408 -1296 -239 -614 -451 30 385 360 171 363 -169 115 408 272 129 -91 -317 -388 610 -33 324 329 -340 985 583 100 330 -113 -154 -256 42 -127 -208 506 70 -406 59 -338 -164 -499 -41 -691 -250 -539 -323 -419 -450 -592 -1127 -136 -803 -59 -349 -196 -62 -515 53 -115 221 -398 157 -50 138 -261 -60 -464 -480 -284 -489 493 200 321 -801 138 -273 -382 -328 -334 -166 -482 70 -85 316 313 -5 -13 -74 -17 -349 200 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