File name: Pandora138s1_Rome-IIA_20241010_L2Fit_fout2c1d20220121p1-8.txt File generation date: 20241010T230333.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v1d20220121.txt Level 1 file used: Pandora138s1_Rome-IIA_20241010_L1_smca1c1d20220121p1-8.txt Full location name: CNR-IIA Montelibretti Rome Short location name: Rome-IIA Country of location: Italy Location latitude [deg]: 42.1057 Location longitude [deg]: 12.6402 Location altitude [m]: 92 Local noon date: 20241010 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 210 351 Nominal wavelengths inside fitting window [nm]: 305.1046 305.2456 305.3867 305.5277 305.6687 305.8098 305.9508 306.0917 306.2327 306.3737 306.5147 306.6556 306.7965 306.9375 307.0784 307.2193 307.3602 307.5010 307.6419 307.7828 307.9236 308.0644 308.2053 308.3461 308.4869 308.6276 308.7684 308.9092 309.0499 309.1907 309.3314 309.4721 309.6128 309.7535 309.8942 310.0349 310.1756 310.3162 310.4569 310.5975 310.7381 310.8787 311.0193 311.1599 311.3005 311.4410 311.5816 311.7221 311.8627 312.0032 312.1437 312.2842 312.4247 312.5651 312.7056 312.8460 312.9865 313.1269 313.2673 313.4077 313.5481 313.6885 313.8289 313.9692 314.1096 314.2499 314.3902 314.5305 314.6709 314.8111 314.9514 315.0917 315.2319 315.3722 315.5124 315.6526 315.7929 315.9331 316.0732 316.2134 316.3536 316.4937 316.6339 316.7740 316.9141 317.0542 317.1943 317.3344 317.4745 317.6146 317.7546 317.8947 318.0347 318.1747 318.3147 318.4547 318.5947 318.7347 318.8746 319.0146 319.1545 319.2944 319.4344 319.5743 319.7141 319.8540 319.9939 320.1338 320.2736 320.4134 320.5533 320.6931 320.8329 320.9727 321.1124 321.2522 321.3920 321.5317 321.6714 321.8111 321.9509 322.0905 322.2302 322.3699 322.5096 322.6492 322.7889 322.9285 323.0681 323.2077 323.3473 323.4869 323.6264 323.7660 323.9056 324.0451 324.1846 324.3241 324.4636 324.6031 324.7426 324.8820 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241010T055529.1Z 9049.246865 56 1 37.39 2 83.81 105.05 159.88 53.31 0.00 1 0.00 1 0 25 8.806e-01 4.122e-02 3.410e-01 1.756e-02 8.482754e-01 1.107482e-02 9.232506e-03 -6.000000e+00 5.431761e-01 226.23 -2.00 3.53 -2.00 322.07 0.00e+00 -6.266070e-03 4.962867e-03 1.236825e-03 -6.000000e+00 3.354673e-02 283.45 -2.00 20.00 -2.00 321.74 0.00e+00 8.320 0.011 302.00 328.00 3 1.8435e+00 3.6616e-02 9.4466e-02 -6.0000e+00 1.3779e+00 9.4910e-01 5.1499e-02 4.6645e-02 -6.0000e+00 1.5204e+00 -1.3023e+00 5.7956e-02 2.6297e-02 -6.0000e+00 8.6568e-01 5.3021e-01 2.8213e-02 9.2812e-03 -6.0000e+00 3.6239e-01 1.0395e-05 -8.1717e-04 5.8645e-04 1.3212e-04 -6.0000e+00 2.7898e-02 -9.3640e-03 0.0000e+00 12 9 9 12 1 1 82.20 19.05 0.16 -0.00936 -0.01550 14 4 4 8 0 2492.590 15.00 19.05 24.37 22.29 21.58 18.5 989.26 900000 98669 -101352 900000 3588 900000 900000 900000 900000 -132488 900000 900000 900000 900000 191003 900000 -39037 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 -9023 900000 900000 900000 75588 900000 -115968 134565 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1280 -2261 7570 1979 3637 1310 4935 5484 -2768 2890 -2165 -2097 1727 3840 -5076 3682 5919 -3297 -8880 1993 1661 -3532 9109 2998 7952 -946 -1079 -1517 -1357 2577 -10637 288 1653 1836 -4721 -1910 -5146 -1391 -1430 -3906 -1915 -5498 -792 696 3755 -2803 -187 303 3618 -997 -1425 4474 -849 3051 773 6515 3167 531 -11325 1709 3570 -1337 4051 1404 4646 1321 2340 1652 -4318 -966 -3203 950 -5317 1774 -635 1973 SS 20241010T060132.9Z 9049.251076 59 1 48.86 2 82.72 106.10 159.00 55.92 0.00 1 0.00 1 0 17 7.677e-01 1.187e-02 3.549e-01 5.899e-03 7.938329e-01 3.336715e-03 8.614046e-03 -6.000000e+00 4.431421e-01 226.23 -2.00 3.53 -2.00 321.79 0.00e+00 4.763588e-03 1.452847e-03 1.094632e-03 -6.000000e+00 1.929899e-02 283.45 -2.00 20.00 -2.00 321.47 0.00e+00 7.284 0.007 302.00 328.00 3 1.3696e+00 1.0815e-02 8.3931e-02 -6.0000e+00 1.1085e+00 1.9996e-01 1.7708e-02 4.5004e-02 -6.0000e+00 1.2079e+00 -2.9258e-01 2.2414e-02 2.6962e-02 -6.0000e+00 7.0767e-01 1.2054e-01 1.0615e-02 9.6521e-03 -6.0000e+00 3.0352e-01 5.1410e-05 -2.0868e-04 1.7566e-04 1.1557e-04 -6.0000e+00 2.1773e-02 -9.0403e-03 0.0000e+00 12 8 8 10 0 0 98.02 19.05 0.21 -0.00904 -0.01061 69 15 4 8 0 708.090 15.00 19.05 24.52 22.29 21.58 18.5 990.21 900000 -215709 -239229 -222385 -203982 -294521 -181625 -180261 900000 -158591 -139518 900000 -200364 900000 -85783 -92606 -96971 -10104 323955 -63509 900000 -79971 900000 113398 44599 -50462 -48563 900000 -13021 -63779 248021 46741 -20110 -49315 259043 900000 9671 66482 -156 25657 16465 4716 52616 6704 75770 -2926 24580 22203 -14917 -6498 -28920 3623 -844 31517 -1859 11825 -2327 11762 -5900 3807 -2418 -5141 9378 -2038 10631 2772 1334 3105 11901 2834 1078 1568 6647 6684 -7305 2852 -6156 1180 1470 1472 -4158 -377 781 -3683 96 -463 2156 233 4514 3015 3108 216 -1573 -1197 -1595 695 -1216 1129 27 106 -655 -1278 -496 -1901 -1722 -3024 -1052 -1229 -244 319 0 515 -539 -390 -788 680 -517 552 497 33 179 306 796 -471 1880 -74 761 175 567 602 27 36 -251 314 -516 156 111 -89 99 -156 -67 -563 900000 -1404 -2107 -1605 -1171 -4028 -1043 -1035 900000 -911 -801 900000 -2955 900000 -718 -998 -1259 -64 1860 -770 900000 -1151 900000 651 256 -725 -693 900000 -135 -1259 1424 491 -462 -1565 1488 900000 197 955 -5 779 604 207 1552 313 1898 -159 1087 1059 -1086 -484 -3004 310 -83 2515 -211 1240 -284 1257 -721 427 -303 -744 1367 -372 1781 501 252 619 2454 727 301 447 1759 1657 -1872 608 -1408 272 396 474 -1630 -163 359 -1884 50 -258 1222 137 2516 1638 1595 109 -816 -670 -1036 515 -1057 1087 28 106 -611 -1095 -398 -1589 -1542 -2859 -1047 -1328 -288 424 0 772 -817 -577 -1131 946 -752 830 788 53 278 458 1162 -671 2561 -100 1032 259 952 1120 54 76 -562 745 -1295 400 289 -234 258 -386 -157 -1269 SS 20241010T064500.5Z 9049.281255 81 1 49.73 2 75.16 113.95 152.15 70.45 0.00 1 0.00 1 0 17 5.687e-02 4.581e-03 9.963e-03 6.292e-04 4.638145e-01 3.215315e-04 5.425680e-03 -6.000000e+00 3.272582e-02 226.22 -2.00 3.53 -2.00 319.60 0.00e+00 1.268557e-03 8.155695e-05 2.390905e-04 -6.000000e+00 1.317818e-03 283.44 -2.00 20.00 -2.00 319.30 0.00e+00 3.826 0.001 302.00 328.00 3 9.8950e-01 8.8481e-04 4.4756e-02 -6.0000e+00 8.1658e-02 1.0402e-02 1.0300e-03 2.4099e-02 -6.0000e+00 8.8827e-02 5.1538e-03 9.2032e-04 1.2461e-02 -6.0000e+00 5.2253e-02 -9.3513e-03 4.9813e-04 3.8437e-03 -6.0000e+00 2.2172e-02 2.6536e-03 4.9045e-04 1.8205e-05 4.0908e-05 -6.0000e+00 1.5657e-03 -1.1827e-02 0.0000e+00 10 0 0 10 0 0 99.99 19.08 0.14 -0.01183 -0.00814 994 218 2 8 0 49.480 15.00 19.08 25.28 22.29 21.58 18.5 994.59 -17137 -19588 -18310 -19592 -22793 -24019 -22120 -14183 -15966 -15161 -16135 -14012 -9667 -4053 -2732 -1962 -1040 -481 2797 -1357 271 -156 787 -847 -2038 -1064 -2567 -2560 -3383 -1585 -877 787 -55 -2887 -3194 -2544 -2234 -1145 -391 -1053 -650 -820 -180 -686 521 -132 271 213 -522 702 564 1042 1294 1171 839 1109 262 128 21 52 940 1457 2188 1410 215 413 -394 130 834 393 339 249 212 74 -470 -496 -1053 -1131 -656 -969 -1080 -1492 -1662 -1146 -750 -190 208 477 701 742 724 274 212 339 132 319 773 486 26 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