File name: Pandora138s1_Rome-IIA_20241015_L2Fit_fout2c1d20220121p1-8.txt File generation date: 20241015T225752.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v1d20220121.txt Level 1 file used: Pandora138s1_Rome-IIA_20241015_L1_smca1c1d20220121p1-8.txt Full location name: CNR-IIA Montelibretti Rome Short location name: Rome-IIA Country of location: Italy Location latitude [deg]: 42.1057 Location longitude [deg]: 12.6402 Location altitude [m]: 92 Local noon date: 20241015 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 210 351 Nominal wavelengths inside fitting window [nm]: 305.1046 305.2456 305.3867 305.5277 305.6687 305.8098 305.9508 306.0917 306.2327 306.3737 306.5147 306.6556 306.7965 306.9375 307.0784 307.2193 307.3602 307.5010 307.6419 307.7828 307.9236 308.0644 308.2053 308.3461 308.4869 308.6276 308.7684 308.9092 309.0499 309.1907 309.3314 309.4721 309.6128 309.7535 309.8942 310.0349 310.1756 310.3162 310.4569 310.5975 310.7381 310.8787 311.0193 311.1599 311.3005 311.4410 311.5816 311.7221 311.8627 312.0032 312.1437 312.2842 312.4247 312.5651 312.7056 312.8460 312.9865 313.1269 313.2673 313.4077 313.5481 313.6885 313.8289 313.9692 314.1096 314.2499 314.3902 314.5305 314.6709 314.8111 314.9514 315.0917 315.2319 315.3722 315.5124 315.6526 315.7929 315.9331 316.0732 316.2134 316.3536 316.4937 316.6339 316.7740 316.9141 317.0542 317.1943 317.3344 317.4745 317.6146 317.7546 317.8947 318.0347 318.1747 318.3147 318.4547 318.5947 318.7347 318.8746 319.0146 319.1545 319.2944 319.4344 319.5743 319.7141 319.8540 319.9939 320.1338 320.2736 320.4134 320.5533 320.6931 320.8329 320.9727 321.1124 321.2522 321.3920 321.5317 321.6714 321.8111 321.9509 322.0905 322.2302 322.3699 322.5096 322.6492 322.7889 322.9285 323.0681 323.2077 323.3473 323.4869 323.6264 323.7660 323.9056 324.0451 324.1846 324.3241 324.4636 324.6031 324.7426 324.8820 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241015T062031.5Z 9054.264254 170 1 43.43 2 80.49 111.01 129.09 304.73 0.00 1 0.00 1 0 17 4.146e-01 2.386e-02 2.886e-01 7.132e-03 6.499777e-01 3.815595e-03 7.352815e-03 -6.000000e+00 2.386655e-01 225.66 -2.00 3.53 -2.00 321.05 0.00e+00 9.330379e-03 1.392861e-03 6.005782e-04 -6.000000e+00 9.755774e-03 282.83 -2.00 20.00 -2.00 320.75 0.00e+00 5.767 0.004 302.00 328.00 3 3.2463e+00 1.1285e-02 6.6418e-02 -6.0000e+00 5.9549e-01 3.2519e-01 1.4856e-02 3.4869e-02 -6.0000e+00 6.4923e-01 -4.0252e-01 1.6715e-02 1.9229e-02 -6.0000e+00 3.8156e-01 1.6481e-01 8.5398e-03 6.4340e-03 -6.0000e+00 1.6179e-01 3.4243e-05 -2.4019e-04 2.0714e-04 7.6225e-05 -6.0000e+00 1.1416e-02 -9.0859e-03 0.0000e+00 12 8 8 10 0 0 91.15 19.05 0.19 -0.00909 -0.01089 18 4 1 8 0 2412.650 15.00 19.05 20.19 22.19 21.58 18.3 965.79 -17650 -112056 -119662 33126 -129941 -343 -69256 819 33056 -174014 -30863 210645 -120147 58642 -5208 -34126 -4658 73634 900000 -4661 900000 25583 154237 119666 -12909 33049 90495 21928 20206 -22426 900000 32282 6020 14696 24813 101370 24103 23263 44 7588 11707 -2842 48893 32739 23993 -1308 21333 9954 21054 10641 -57199 25983 356 33662 4351 22228 -1502 10245 -3247 5462 -23426 11284 15886 3049 14263 4496 837 793 11284 2283 7655 329 4045 6319 -5495 -492 -5812 -1863 71 1670 380 -3534 23 -4200 -65 -1369 2358 260 5531 2244 2714 -357 -4738 -1051 -2328 1211 -2305 1777 216 631 -795 -1939 -464 -3166 -784 -3880 -1363 -1858 -978 572 172 -99 -535 145 -855 559 -737 979 521 1399 262 665 1072 -569 1762 -863 1368 612 2393 781 1070 -354 -398 -30 -814 69 465 -423 -679 -227 -153 -218 -126 -2208 -2631 230 -2702 -2 -826 6 230 -6382 -309 1464 -4175 495 -100 -998 -115 958 900000 -139 900000 561 1072 1153 -438 756 1214 545 519 -969 900000 1176 317 732 1061 2180 1169 1311 4 671 1084 -318 3555 2825 2295 -162 2222 1200 2382 1431 -15806 3675 69 5080 892 3950 -336 2008 -708 1104 -6535 2554 3892 927 3978 1334 258 256 3685 915 3129 146 1689 2413 -2129 -168 -2008 -653 28 759 200 -2149 14 -2885 -46 -1032 1786 203 4119 1636 1851 -239 -3225 -736 -1856 1072 -2390 1980 255 727 -868 -1947 -437 -3181 -820 -4343 -1575 -2307 -1318 834 270 -160 -857 222 -1271 810 -1107 1519 845 2294 426 1052 1644 -857 2530 -1236 1916 925 3939 1420 2070 -720 -845 -67 -1904 164 1118 -1041 -1648 -526 -339 -468 SS 20241015T063335.6Z 9054.273328 175 1 43.16 2 78.25 113.37 130.90 308.03 0.00 1 0.00 1 0 17 1.963e-01 9.737e-03 9.865e-02 3.043e-03 5.630915e-01 1.577988e-03 6.446980e-03 -6.000000e+00 1.127209e-01 225.66 -2.00 3.53 -2.00 320.38 0.00e+00 4.777525e-03 5.014241e-04 4.052099e-04 -6.000000e+00 4.550149e-03 282.83 -2.00 20.00 -2.00 320.09 0.00e+00 4.755 0.002 302.00 328.00 3 2.9126e+00 4.4953e-03 5.5309e-02 -6.0000e+00 2.8090e-01 6.5964e-02 5.5946e-03 2.9641e-02 -6.0000e+00 3.0571e-01 -5.8543e-02 5.9405e-03 1.5910e-02 -6.0000e+00 1.7991e-01 1.9249e-02 3.1216e-03 5.1409e-03 -6.0000e+00 7.6409e-02 1.4215e-04 4.3607e-04 8.7340e-05 5.6437e-05 -6.0000e+00 5.4057e-03 -9.7640e-03 0.0000e+00 12 8 8 10 0 0 9.98 19.06 0.19 -0.00976 -0.00649 48 12 1 8 0 899.040 14.99 19.06 20.81 22.19 21.58 18.4 969.64 -58283 -69075 -65910 8311 -45508 -101082 -56027 -73442 26903 -100691 -17091 -30985 -3725 33510 -33997 1449 -22571 31545 1579 9398 5439 4812 7387 13705 1408 -5692 3782 9025 468 -3786 27319 5042 -5261 -2562 9326 11830 -2573 5715 -5791 1593 -282 -3734 7334 3007 7947 -11 6114 1318 4294 2514 -27366 1219 1576 5255 152 3942 -834 1725 -27 1421 2081 2447 2869 2135 1616 602 -458 468 3193 -268 1369 -314 863 240 -2385 136 -2853 -1347 -1083 -13 -1685 -401 -1245 -1403 -772 -603 209 281 1480 973 1526 51 -168 -371 -371 769 -159 1045 676 580 -296 -1010 26 -1048 -1219 -1568 -338 -593 375 397 58 188 -50 -97 -288 320 -307 481 -201 -193 -24 218 48 118 499 -355 870 483 660 137 188 -283 -517 119 -115 57 276 -81 -440 192 -61 -151 -573 -856 -834 50 -422 -1588 -633 -1079 171 -2230 -184 -438 -52 416 -966 34 -739 687 49 281 172 154 243 454 55 -251 152 339 19 -181 1148 298 -388 -189 589 759 -211 509 -688 206 -40 -583 1089 477 1227 -2 1008 233 768 492 -7703 290 407 1391 44 1139 -254 511 -8 416 643 833 1089 885 679 246 -188 199 1467 -142 765 -182 487 129 -1205 62 -1276 -618 -557 -8 -1133 -293 -973 -1142 -665 -546 194 266 1380 870 1281 41 -133 -309 -339 779 -182 1293 862 727 -351 -1121 27 -1163 -1431 -1921 -427 -794 536 609 95 312 -82 -152 -433 468 -466 752 -329 -322 -40 349 76 180 739 -514 1243 735 1089 242 349 -547 -1031 245 -248 125 617 -182 -986 415 -127 -306 SS 20241015T064355.1Z 9054.280499 178 1 43.19 2 76.51 115.28 132.27 310.75 0.00 1 0.00 1 0 17 1.154e-01 5.636e-03 3.649e-02 2.010e-03 5.050912e-01 1.029618e-03 5.875463e-03 -6.000000e+00 6.624870e-02 225.66 -2.00 3.53 -2.00 319.83 0.00e+00 1.604911e-03 2.814857e-04 2.874241e-04 -6.000000e+00 2.674444e-03 282.83 -2.00 20.00 -2.00 319.54 0.00e+00 4.182 0.001 302.00 328.00 3 2.8199e+00 2.8632e-03 4.8838e-02 -6.0000e+00 1.6509e-01 3.5156e-02 3.3888e-03 2.6273e-02 -6.0000e+00 1.7968e-01 -1.8566e-02 3.1898e-03 1.3729e-02 -6.0000e+00 1.0574e-01 1.7931e-03 1.7140e-03 4.2932e-03 -6.0000e+00 4.4905e-02 2.8803e-04 3.3898e-04 5.7821e-05 4.6144e-05 -6.0000e+00 3.1774e-03 -9.2894e-03 0.0000e+00 10 0 0 10 0 0 55.95 19.05 0.11 -0.00929 -0.00674 71 17 1 8 0 608.220 14.99 19.05 21.55 22.19 21.58 18.4 973.77 -25410 -34836 -45636 -21515 -63475 -45974 -39578 -34192 -32646 -32977 -28894 -26136 -15091 -4837 -17856 -4918 -9484 216 4809 -217 -1185 -3512 2401 1389 -1783 -3887 -4052 -5613 -3813 -8376 3805 -971 -2786 -3900 3839 1378 -2806 -436 -2686 -673 -1682 -697 1010 1452 1950 0 1787 588 1730 579 -858 462 1463 2849 931 1427 -475 218 -250 439 1796 1041 2176 1355 1084 201 -366 237 451 -88 510 99 521 744 -1187 -419 -1359 -1554 -771 -674 -1436 -1600 -1637 -1443 -841 -130 605 603 1239 606 971 242 -121 403 -174 504 378 536 -77 -109 -510 -828 -167 -612 -1248 -994 -747 -518 348 548 508 346 -10 -121 117 309 -68 457 -16 -90 -155 189 131 -107 478 -210 784 392 141 101 40 -196 -173 71 -135 -190 409 -84 -260 39 -98 -164 -341 -565 -849 -308 -1246 -779 -693 -646 -673 -728 -638 -642 -405 -143 -713 -199 -441 10 225 -11 -62 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