File name: Pandora138s1_Rome-IIA_20241018_L2Fit_fout2c1d20220121p1-8.txt File generation date: 20241018T230046.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v1d20220121.txt Level 1 file used: Pandora138s1_Rome-IIA_20241018_L1_smca1c1d20220121p1-8.txt Full location name: CNR-IIA Montelibretti Rome Short location name: Rome-IIA Country of location: Italy Location latitude [deg]: 42.1057 Location longitude [deg]: 12.6402 Location altitude [m]: 92 Local noon date: 20241018 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 210 351 Nominal wavelengths inside fitting window [nm]: 305.1046 305.2456 305.3867 305.5277 305.6687 305.8098 305.9508 306.0917 306.2327 306.3737 306.5147 306.6556 306.7965 306.9375 307.0784 307.2193 307.3602 307.5010 307.6419 307.7828 307.9236 308.0644 308.2053 308.3461 308.4869 308.6276 308.7684 308.9092 309.0499 309.1907 309.3314 309.4721 309.6128 309.7535 309.8942 310.0349 310.1756 310.3162 310.4569 310.5975 310.7381 310.8787 311.0193 311.1599 311.3005 311.4410 311.5816 311.7221 311.8627 312.0032 312.1437 312.2842 312.4247 312.5651 312.7056 312.8460 312.9865 313.1269 313.2673 313.4077 313.5481 313.6885 313.8289 313.9692 314.1096 314.2499 314.3902 314.5305 314.6709 314.8111 314.9514 315.0917 315.2319 315.3722 315.5124 315.6526 315.7929 315.9331 316.0732 316.2134 316.3536 316.4937 316.6339 316.7740 316.9141 317.0542 317.1943 317.3344 317.4745 317.6146 317.7546 317.8947 318.0347 318.1747 318.3147 318.4547 318.5947 318.7347 318.8746 319.0146 319.1545 319.2944 319.4344 319.5743 319.7141 319.8540 319.9939 320.1338 320.2736 320.4134 320.5533 320.6931 320.8329 320.9727 321.1124 321.2522 321.3920 321.5317 321.6714 321.8111 321.9509 322.0905 322.2302 322.3699 322.5096 322.6492 322.7889 322.9285 323.0681 323.2077 323.3473 323.4869 323.6264 323.7660 323.9056 324.0451 324.1846 324.3241 324.4636 324.6031 324.7426 324.8820 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241018T081353.5Z 9057.342981 285 1 5.84 2 63.64 134.83 105.78 309.61 0.00 1 0.00 1 0 17 1.783e-02 7.362e-03 1.646e-02 5.531e-03 2.804017e-01 2.797898e-03 3.403190e-03 -6.000000e+00 1.022625e-02 225.38 -2.00 3.53 -2.00 317.10 0.00e+00 4.719346e-04 3.519923e-04 5.911347e-05 -6.000000e+00 4.130975e-04 282.45 -2.00 20.00 -2.00 316.79 0.00e+00 2.239 0.000 302.00 328.00 3 4.7747e+00 7.3146e-03 2.6334e-02 -6.0000e+00 2.5468e-02 2.5847e-02 8.1650e-03 1.4294e-02 -6.0000e+00 2.7721e-02 3.9927e-03 4.9744e-03 7.1390e-03 -6.0000e+00 1.6317e-02 -6.6852e-03 2.4849e-03 2.0828e-03 -6.0000e+00 6.9360e-03 3.4707e-04 8.9077e-04 1.5953e-04 2.3540e-05 -6.0000e+00 4.9069e-04 -1.1666e-02 0.0000e+00 12 9 1 12 1 1 999.00 19.05 0.16 -0.01167 -0.00497 2 5 1 8 0 1945.720 15.01 19.05 24.34 22.29 21.58 18.7 989.76 3672 -5498 -2648 3906 -6067 512 -610 -4871 4493 1146 -6446 6043 -3205 1736 -555 -905 -4367 4069 -3024 39 1536 2506 3586 -2066 825 -2710 935 2549 2434 -1892 3118 53 -1019 -391 -3277 380 -953 1410 -1261 -345 265 -1373 -812 -730 1281 -1490 437 -648 811 516 -975 303 260 3030 -770 1548 552 741 -515 1176 472 1318 2064 67 502 -471 -604 -275 1758 187 -1476 -1103 465 721 -1081 -234 -1994 -47 -748 -530 -729 -217 -1285 -1875 42 -342 188 -614 1058 520 1015 751 -27 757 -320 498 824 298 90 -351 -388 -581 -358 228 -737 -1391 -462 -592 316 444 405 -218 263 584 112 645 -614 247 368 136 -173 44 -56 -381 1097 -829 1087 533 -144 178 188 -149 -154 302 -316 -495 181 242 -416 176 27 -391 409 -711 -337 435 -673 53 -69 -640 593 162 -971 861 -562 330 -121 -213 -1098 995 -812 10 413 670 981 -623 252 -879 291 740 677 -554 932 17 -359 -137 -1122 128 -356 590 -619 -187 151 -815 -490 -441 762 -904 259 -382 468 305 -611 198 177 2098 -558 1124 406 542 -375 849 355 1042 1720 58 427 -383 -475 -216 1454 169 -1413 -1077 445 667 -957 -192 -1565 -36 -610 -470 -697 -220 -1353 -2055 47 -404 228 -757 1286 613 1131 796 -27 772 -347 574 1013 388 119 -457 -484 -692 -419 277 -940 -1834 -624 -827 454 662 620 -334 389 826 152 852 -826 342 532 203 -259 64 -82 -539 1497 -1113 1415 716 -203 259 282 -226 -238 479 -523 -835 309 418 -715 296 44 -635 SS 20241018T090329.2Z 9057.377421 312 1 2.41 2 57.86 147.18 111.87 319.76 0.00 1 0.00 1 0 17 8.906e-03 5.875e-03 4.027e-03 2.018e-03 2.388279e-01 1.026986e-03 2.939749e-03 -6.000000e+00 5.107829e-03 225.38 -2.00 3.53 -2.00 316.14 0.00e+00 1.724043e-04 1.025151e-04 3.496508e-05 -6.000000e+00 2.063885e-04 282.44 -2.00 20.00 -2.00 315.84 0.00e+00 1.873 0.000 302.00 328.00 3 2.7159e+00 2.6548e-03 2.2162e-02 -6.0000e+00 1.2721e-02 2.2086e-02 2.9568e-03 1.2193e-02 -6.0000e+00 1.3847e-02 -7.7023e-04 1.7234e-03 6.0751e-03 -6.0000e+00 8.1506e-03 -4.4811e-03 8.1072e-04 1.7579e-03 -6.0000e+00 3.4638e-03 4.1642e-03 5.1346e-04 5.7867e-05 2.1387e-05 -6.0000e+00 2.4518e-04 -1.0115e-02 0.0000e+00 12 1 1 12 1 1 86.82 19.07 0.10 -0.01012 -0.00626 12 58 1 8 0 185.180 15.00 19.07 27.56 22.29 21.58 18.7 1008.20 -1285 -553 -2030 -2572 -2652 -2205 -1124 -422 861 -2920 -1481 -553 -1214 -718 611 -267 766 252 1794 1621 1638 487 1068 255 871 1050 -324 161 513 1197 992 321 296 -1919 -1472 -1603 -1415 -718 -788 -926 -743 -560 -768 -152 212 -800 -416 -350 -675 545 1908 309 1397 921 1026 420 459 327 470 386 930 1174 1315 578 -48 116 -830 259 777 269 -23 6 174 239 111 -296 -206 -543 -537 -1163 -870 -1873 -1379 -1036 -999 -533 -132 -66 273 663 94 -4 202 686 620 443 1140 111 -173 -435 -688 -605 -426 -63 -1164 -822 -496 -338 245 310 461 263 260 262 198 239 281 324 316 -146 30 174 79 199 78 334 1061 993 350 170 -205 -231 -309 -143 -162 -88 404 -114 -156 -260 -231 -498 -256 -117 -435 -506 -484 -395 -215 -87 192 -697 -343 -133 -321 -209 198 -91 268 89 647 604 613 183 415 102 363 450 -138 65 193 465 399 135 134 -858 -628 -696 -667 -374 -468 -600 -504 -393 -540 -106 147 -558 -288 -241 -458 371 1333 228 1051 715 813 341 369 265 374 310 759 1012 1198 542 -43 100 -694 219 683 257 -23 6 174 233 103 -257 -171 -441 -461 -1066 -851 -1947 -1475 -1143 -1146 -637 -162 -81 337 782 108 -5 210 709 667 509 1373 143 -226 -554 -845 -711 -496 -75 -1468 -1064 -659 -462 341 451 683 387 372 357 261 307 361 433 440 -208 43 249 111 270 104 430 1352 1290 474 236 -293 -332 -454 -213 -253 -141 649 -185 -254 -417 -363 -771 SS 20241018T090752.4Z 9057.380468 314 1 25.27 2 57.42 148.35 112.35 320.71 0.00 1 0.00 1 0 17 8.125e-03 5.504e-03 1.974e-03 9.723e-04 2.358037e-01 4.945399e-04 2.891540e-03 -6.000000e+00 4.659691e-03 225.38 -2.00 3.53 -2.00 316.17 0.00e+00 4.031016e-04 4.990648e-05 3.536991e-05 -6.000000e+00 1.882813e-04 282.44 -2.00 20.00 -2.00 315.88 0.00e+00 1.851 0.000 302.00 328.00 3 3.6665e+00 1.2788e-03 2.1882e-02 -6.0000e+00 1.1605e-02 2.6113e-02 1.4240e-03 1.2013e-02 -6.0000e+00 1.2632e-02 4.0352e-04 8.2984e-04 5.9823e-03 -6.0000e+00 7.4355e-03 -4.7482e-03 3.9146e-04 1.7302e-03 -6.0000e+00 3.1599e-03 1.6471e-03 5.8623e-04 2.7837e-05 2.1195e-05 -6.0000e+00 2.2367e-04 -1.0106e-02 0.0000e+00 12 1 1 12 1 1 98.47 19.07 0.14 -0.01011 -0.00570 55 24 1 8 0 451.210 15.00 19.07 27.78 22.29 21.58 18.8 1010.12 -865 -1799 -2111 -2582 -2540 -1474 -933 -54 -284 -1214 -1613 -710 -977 27 262 -794 342 1092 1096 958 827 1068 1546 630 680 407 42 -321 274 752 1421 1396 556 -1507 -1687 -1242 -1548 -749 -178 -1022 -998 -643 -602 -334 -108 -581 -302 -482 -666 569 659 621 1073 878 508 993 400 390 392 593 1024 1292 1573 743 -388 -13 -565 177 937 -5 191 104 82 261 -115 -188 -514 -531 -383 -843 -1088 -1529 -1741 -1092 -793 -452 -19 270 147 122 482 318 431 618 178 254 768 293 -136 -75 -574 -746 -223 -167 -1100 -760 -583 -330 73 498 402 273 78 70 104 264 232 337 154 -220 -92 337 149 294 585 50 746 770 331 261 -102 -72 -111 67 -163 -69 228 -26 -231 -161 -371 -586 -169 -380 -447 -501 -441 -250 -169 -11 -63 -279 -366 -168 -261 8 82 -270 119 390 406 366 318 407 607 244 275 170 17 -132 105 289 577 564 243 -667 -697 -519 -725 -381 -108 -668 -657 -438 -419 -232 -75 -401 -215 -334 -454 390 452 452 819 704 394 781 320 308 322 489 831 1130 1404 696 -353 -11 -468 145 834 -4 186 105 81 258 -104 -162 -430 -434 -318 -794 -1084 -1586 -1905 -1192 -930 -537 -23 340 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