File name: Pandora138s1_Rome-IIA_20241101_L2Fit_fout2c1d20220121p1-8.txt File generation date: 20241102T001717.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v1d20220121.txt Level 1 file used: Pandora138s1_Rome-IIA_20241101_L1_smca1c1d20220121p1-8.txt Full location name: CNR-IIA Montelibretti Rome Short location name: Rome-IIA Country of location: Italy Location latitude [deg]: 42.1057 Location longitude [deg]: 12.6402 Location altitude [m]: 92 Local noon date: 20241101 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 210 351 Nominal wavelengths inside fitting window [nm]: 305.1046 305.2456 305.3867 305.5277 305.6687 305.8098 305.9508 306.0917 306.2327 306.3737 306.5147 306.6556 306.7965 306.9375 307.0784 307.2193 307.3602 307.5010 307.6419 307.7828 307.9236 308.0644 308.2053 308.3461 308.4869 308.6276 308.7684 308.9092 309.0499 309.1907 309.3314 309.4721 309.6128 309.7535 309.8942 310.0349 310.1756 310.3162 310.4569 310.5975 310.7381 310.8787 311.0193 311.1599 311.3005 311.4410 311.5816 311.7221 311.8627 312.0032 312.1437 312.2842 312.4247 312.5651 312.7056 312.8460 312.9865 313.1269 313.2673 313.4077 313.5481 313.6885 313.8289 313.9692 314.1096 314.2499 314.3902 314.5305 314.6709 314.8111 314.9514 315.0917 315.2319 315.3722 315.5124 315.6526 315.7929 315.9331 316.0732 316.2134 316.3536 316.4937 316.6339 316.7740 316.9141 317.0542 317.1943 317.3344 317.4745 317.6146 317.7546 317.8947 318.0347 318.1747 318.3147 318.4547 318.5947 318.7347 318.8746 319.0146 319.1545 319.2944 319.4344 319.5743 319.7141 319.8540 319.9939 320.1338 320.2736 320.4134 320.5533 320.6931 320.8329 320.9727 321.1124 321.2522 321.3920 321.5317 321.6714 321.8111 321.9509 322.0905 322.2302 322.3699 322.5096 322.6492 322.7889 322.9285 323.0681 323.2077 323.3473 323.4869 323.6264 323.7660 323.9056 324.0451 324.1846 324.3241 324.4636 324.6031 324.7426 324.8820 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241101T062211.5Z 9071.265411 60 1 49.21 2 84.07 115.81 83.61 119.50 0.00 1 0.00 1 0 17 5.883e-01 2.252e-02 3.781e-01 1.212e-02 8.433238e-01 7.125858e-03 9.166150e-03 -6.000000e+00 3.438625e-01 224.14 -2.00 3.53 -2.00 322.12 0.00e+00 6.477175e-03 3.254784e-03 1.297542e-03 -6.000000e+00 1.526746e-02 280.71 -2.00 20.00 -2.00 321.78 0.00e+00 8.627 0.012 302.00 328.00 3 1.0241e+00 2.3689e-02 9.6915e-02 -6.0000e+00 8.6104e-01 8.2115e-01 3.4397e-02 4.6396e-02 -6.0000e+00 9.4435e-01 -1.0614e+00 3.9749e-02 2.6428e-02 -6.0000e+00 5.4746e-01 4.1994e-01 1.9121e-02 9.4533e-03 -6.0000e+00 2.3267e-01 1.7975e-05 -9.8507e-04 3.7382e-04 1.3241e-04 -6.0000e+00 1.7055e-02 -1.8480e-03 0.0000e+00 12 8 8 10 0 0 -0.13 18.78 0.56 -0.00185 -0.00925 46 10 4 8 0 1069.570 14.99 18.78 15.42 22.09 21.38 18.4 938.86 900000 -136272 -124290 183957 -219805 900000 -158394 900000 900000 -123006 -129456 900000 -121053 900000 48659 -106352 170591 900000 900000 -11825 900000 9630 900000 48832 39502 3177 32620 900000 11002 235342 900000 122438 -27991 -62716 195804 900000 20454 98815 32450 21462 22704 69669 122836 89921 70434 18081 78745 42670 44243 -422 900000 5780 30495 63974 9050 60886 20496 28675 10732 17278 -16834 -5597 33153 -2299 22665 2559 1326 -3197 7972 1388 15710 3082 8277 13204 -6213 -4682 1991 -2218 1552 -2010 -3609 2025 9077 -8164 3054 5779 5869 -1589 12636 4242 8579 -6995 -6860 -372 -5093 -4 -5840 3371 -90 418 -1203 -3151 2045 -4485 -2840 -6223 -3873 -3323 -1977 317 -332 -919 -161 -1020 -1533 965 -1728 3100 806 1185 1584 2118 1684 -906 1040 648 1374 338 2454 442 1216 -280 -54 424 -1026 -187 273 216 -767 -87 -395 -471 900000 -2709 -2206 2168 -7787 900000 -2998 900000 900000 -1826 -2115 900000 -2817 900000 573 -3989 2010 900000 900000 -218 900000 133 900000 575 466 51 384 900000 155 2774 900000 1443 -1100 -3476 2308 900000 519 1353 1015 858 973 1984 2147 2177 2081 900 2260 1822 1981 -32 900000 505 2297 3760 933 3930 1945 2435 1039 1540 -2193 -735 3465 -376 3020 411 221 -593 1501 314 3318 742 1830 2556 -1299 -877 345 -434 347 -556 -1180 715 3238 -3604 1296 2521 2656 -781 5377 1859 3404 -3098 -3079 -173 -2873 -3 -4553 2757 -80 363 -982 -2360 1370 -3307 -2196 -5255 -3421 -3201 -2114 377 -440 -1288 -227 -1409 -2060 1258 -2384 4337 1200 1773 2286 2941 2291 -1223 1347 826 1759 484 3961 816 2439 -608 -124 1032 -2682 -500 737 589 -2068 -219 -945 -1075 SS 20241101T062809.1Z 9071.269550 63 1 49.36 2 83.08 116.87 82.69 120.56 0.00 1 0.00 1 0 17 6.145e-01 1.772e-02 2.599e-01 5.979e-03 7.782173e-01 3.373885e-03 8.565840e-03 -6.000000e+00 3.521496e-01 224.14 -2.00 3.53 -2.00 321.81 0.00e+00 8.973596e-03 1.465862e-03 1.052731e-03 -6.000000e+00 1.617858e-02 280.71 -2.00 20.00 -2.00 321.48 0.00e+00 7.607 0.008 302.00 328.00 3 1.0294e+00 1.0898e-02 8.5967e-02 -6.0000e+00 8.7593e-01 4.3005e-01 1.6083e-02 4.2856e-02 -6.0000e+00 9.5590e-01 -6.3407e-01 1.9021e-02 2.4560e-02 -6.0000e+00 5.6230e-01 2.6948e-01 9.1730e-03 8.6401e-03 -6.0000e+00 2.4277e-01 5.2857e-05 -4.9155e-04 1.7893e-04 1.1582e-04 -6.0000e+00 1.7407e-02 -3.5746e-03 0.0000e+00 12 9 8 11 8 0 -8.03 18.78 0.25 -0.00357 -0.00727 86 19 4 8 0 573.870 15.01 18.78 15.95 21.98 21.38 18.4 941.13 -185213 900000 -236569 900000 -263746 -73836 -190977 -153938 900000 -188468 900000 -169432 900000 -78861 900000 -66464 -54399 80592 -23463 99399 17901 900000 -48190 900000 -48751 50116 32427 84483 -1532 -66685 900000 2304 43445 -46355 326160 23083 61141 16225 -4332 46139 -892 63087 19826 80682 23390 17087 37113 17076 22906 7404 16375 1643 34146 24327 14102 8979 12688 11828 488 12358 -16004 12594 6571 11880 5372 12468 3273 5091 11197 4122 13297 1624 13374 2607 5948 -4345 3816 -2398 1894 2602 -6968 2210 -2803 -2310 -2376 743 784 1264 5142 -643 2957 -2548 -2273 -3885 -1680 -1993 -1545 606 493 525 -1086 -523 -2310 -1007 -3236 -2941 -2347 -1450 -690 -467 622 -1583 46 -1144 599 -179 -494 59 -62 796 802 1825 586 1796 428 1573 1009 1280 792 578 1165 -115 207 -422 -87 -99 705 -132 -302 -134 -822 -968 -2605 900000 -6539 900000 -7930 -430 -2779 -1792 900000 -3108 900000 -3227 900000 -1085 900000 -1231 -1007 469 -372 578 189 900000 -994 900000 -1083 424 326 492 -22 -2152 900000 56 804 -1978 1898 513 1035 506 -199 1489 -46 2003 1017 2305 1213 976 1806 1075 1454 553 1263 163 2683 2277 1525 1049 1440 1319 59 1324 -2429 1631 1048 2022 1008 2159 636 1037 2438 1100 3482 448 3418 684 1353 -995 790 -573 516 851 -2717 895 -1292 -1126 -1242 399 439 717 2772 -348 1441 -1256 -1124 -2143 -1061 -1496 -1359 555 478 496 -1034 -442 -1858 -833 -2938 -2807 -2393 -1493 -796 -615 899 -2453 70 -1704 839 -249 -713 89 -99 1281 1248 2694 849 2480 581 2052 1333 1881 1356 1046 2307 -247 471 -1036 -213 -250 1802 -345 -769 -341 -1967 -2190 SS 20241101T064045.5Z 9071.278304 66 1 49.13 2 81.02 119.14 80.79 122.83 0.00 1 0.00 1 0 17 3.904e-01 5.809e-03 9.726e-02 2.053e-03 6.632163e-01 1.083175e-03 7.407951e-03 -6.000000e+00 2.226942e-01 224.14 -2.00 3.53 -2.00 321.09 0.00e+00 3.402543e-03 4.133063e-04 6.770427e-04 -6.000000e+00 9.048842e-03 280.70 -2.00 20.00 -2.00 320.79 0.00e+00 6.071 0.004 302.00 328.00 3 8.3166e-01 3.2451e-03 6.9214e-02 -6.0000e+00 5.5306e-01 4.6040e-02 4.5702e-03 3.5870e-02 -6.0000e+00 6.0270e-01 -6.8918e-02 5.4706e-03 2.0453e-02 -6.0000e+00 3.5508e-01 2.4339e-02 2.7383e-03 7.0224e-03 -6.0000e+00 1.5117e-01 3.1533e-04 1.6149e-04 5.8635e-05 7.6604e-05 -6.0000e+00 1.0749e-02 -4.4447e-03 0.0000e+00 10 0 0 10 0 0 16.36 18.82 0.18 -0.00444 -0.00323 247 54 4 8 0 198.880 14.99 18.82 16.77 22.09 21.48 18.4 946.21 -131906 -138101 -155795 -88725 -166519 -136943 -153174 -118705 -82980 -101362 -76992 -86719 -87217 -43735 -52881 -50019 -30721 -22249 -14182 -40035 -13119 -8817 -2518 -20553 -7372 -17571 -32236 -19580 -28371 -23104 2649 -2662 -14183 -7349 1787 -4832 -5168 -4414 -2498 -526 -51 -2365 3490 3225 4331 -156 1820 2707 -66 1378 12255 2354 1509 4388 2076 2338 1114 1229 -12 560 -1003 881 4068 2064 3048 660 -340 654 1691 940 962 819 571 468 -1106 -911 -1775 -686 -943 -916 -1469 -1272 -1610 -1616 -856 -134 -71 627 1174 970 1259 -16 -409 -37 -160 274 609 337 201 -91 -599 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